CN108505335A - A kind of new decorative material and its manufacturing method - Google Patents
A kind of new decorative material and its manufacturing method Download PDFInfo
- Publication number
- CN108505335A CN108505335A CN201810315934.2A CN201810315934A CN108505335A CN 108505335 A CN108505335 A CN 108505335A CN 201810315934 A CN201810315934 A CN 201810315934A CN 108505335 A CN108505335 A CN 108505335A
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- China
- Prior art keywords
- glass fibre
- manufacturing
- glass
- coupling agent
- spray gun
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A kind of color glass fiber ornament materials and its manufacturing method of the present invention, belong to glass fibre manufacture field, manufacturing method is to carry out burning mistake to glass fibre first, then the surface silane coating coupling agent of the glass fibre after being lost to burning finally is painted to obtain color glass fiber ornament materials in the surface spraying for the glass fibre for having been coated with coupling agent or coating organic dyestuff.This method burns the post-processing for coated with coupling agent of becoming estranged by the surface of glass fibre, clean surface and silane coupling agent can greatly improve the stability that dyestuff is combined with glass fibre, realize paint out to molded glass fibre stablize, uniform color, be not in prior art coloring it is unstable and the problem of decolourize, solve the problems, such as that the prior art can not directly paint to glass fibre.
Description
Technical field
The present invention relates to a kind of new decorative material and its manufacturing methods, belong to decoration material field.
Background technology
Currently, ornament materials is although more, but all there are different defects.Such as there are color lists for carbon fibre material
One, to 3C Product signal shielding and higher cost the defects of；Electroplated product the defects of there are environmental pollution and single colors.
Invention content
The problems such as, shielding electric signal single based on existing ornament materials color, the present invention provides a kind of new decorative material
And its manufacturing method.
Technical scheme of the present invention：
1, a kind of manufacturing method of new decorative material, it is characterised in that using glass fibre as raw material, first by glass fibers
Dimension carries out burning mistake, the surface silane coating coupling agent of the glass fibre after then being lost to burning, finally in silane coating coupling agent
The surface spraying or coating organic dyestuff of glass fibre obtain color glass fiber ornament materials.
2, manufacturing method according to claim 1, it is characterised in that it is 380-420 DEG C that the burning, which loses temperature, the time
For 0.5-2h.
3, manufacturing method according to claim 1, it is characterised in that the coupling agent is that silane coupling agent is 3- ammonia
One kind in base propyl-triethoxysilicane or γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicane.
4, manufacturing method according to claim 1, it is characterised in that the thickness of the dyestuff of the fiberglass surfacing
It is 3-5 μm.
5, manufacturing method according to claim 4, it is characterised in that the glass fibre moves through coloring means,
There is the coloring means at least one spray gun, the spray gun glass fibre, the glass fibers are sprayed in round-trip
The movement speed of dimension is 0.5-1.3m/s, and the movement speed of the spray gun is 0.5-1.3m/s, and dye spray amount is 25-45g/
m2, nozzle discharge pressure is 0.1-0.3Ba, is atomized as 1.0-2.0Ba.
6, manufacturing method according to claim 5, it is characterised in that spraying dyestuff after the glass fibre continue into
Row drying, cooling, the drying temperature are 160-180 DEG C, time 10-20min.
7, manufacturing method according to claim 6, it is characterised in that the glass fibre is drawn from unwinding device
It is dynamic, it is wound after Drying and cooling, pulls speed identical with rolling speed.
8, manufacturing method according to claim 5, it is characterised in that the wide cut of the spray gun is 1.3-2.3Ba, is taken out
Wind power is 50%-85%.
9, manufacturing method according to claim 5, it is characterised in that the quantity of the spray gun is 2, every spray gun
Round-trip width be 1000-1800mm, when distance of the glass fibre positioned at front apart from the spray gun be 300-420mm when open
Begin spraying dyestuff.
10, a kind of color glass fiber ornament materials prepared according to any manufacturing methods of claim 1-9.
The technique effect of the present invention：
The manufacturing method of a kind of new decorative material of the present invention, using glass fibre as raw material, after being post-processed to it
Spraying dyestuff paints to obtain this new decorative material of color glass fiber.Post-processing includes burning silane coating of becoming estranged
Coupling agent.Since there is size on the surface of glass fiber yarn or glass fabric in wire drawing or weaving process in remained on surface
With the organic matters such as slurry, remained on surface organic matter can be removed by burning to lose, the surface of fiber is cleaned, to make the organic of spraying
Dyestuff can effectively penetrate into fibrous inside, upper colour-stable.And the silane coupling agent being subsequently coated with is conducive to organic dyestuff and glass
The binding performance of glass fiber so that form the two in fiberglass surfacing and securely closely combine, the color of glass fibre is steady
It is fixed and uniform, it is not easy to decolourize.
Since the surface compact of glass fibre is smooth and contains less active group, it is unfavorable for the diffusion of dye molecule,
The prior art can not directly paint to glass fibre.And there is not folding in glass fibre, and not wear-resisting, processability is poor, glass
The defects of mutual friction coefficient of fiber is big, therefore glass fibre is typically considered to be not suitable as ornament materials.And the present invention is sent out
Showed by the surface to glass fibre carry out cleaning and coated with coupling agent after greatly improve dyestuff combined with glass fibre it is steady
Qualitative, direct spraying dyestuff can paint to glass fibre, to form stable, uniform colouring on molded glass fibre
Effect, be not in prior art coloring it is unstable and the problem of decolourize, solving the prior art can not be direct to glass fibre
The problem of colouring.And process is simple, does not add other polluters, environmental protection.And the good insulation performance of glass fibre
So that this new decorative material tries hard to the problem of shielding electric signal may be not present in the fields 3C for various fields, and can be with shape
At a variety of colors and pattern, solve the problems, such as that existing ornament materials color is single.
Preferably, it is 380-420 DEG C, time 0.5-2h that the burning, which loses temperature, to thoroughly remove fiberglass surfacing
The organic matter of remaining, wherein burning the mistake time can be according to fiber species, specification and its organic substance residues amount in continuous heat
It is how many and determine.
Preferably, the silane coupling agent is one kind in KH-550 or KH-560, is more favorable for glass fibre and resin
And the associativity of organic dyestuff.
Preferably, it is 3-5 μm of organic dyestuff to form thickness in fiberglass surfacing, too thin or too thick be all unfavorable for colouring
Effect.
Preferably, the colouring process of this method is to be coated with engine dyeing to the glass fibre after post-processing by coloring means
Material, and by controlling organic dyestuff quantity for spray, fiber movement speed and spray gun movement speed, nozzle discharge pressure and atomization etc.
Parameter controls unit area organic dyestuff quality and air pressure, is formed in the inside of glass fibre and surface in homogeneous thickness
Dyestuff, realization uniformly paint to glass fibre.In addition, can change dyes as needed forms single or multiple color, no
With the effect of pattern.
Preferably, drying temperature is 160-180 DEG C and the time is 10-20min so that dyestuff is impregnated with to fibrous inside, dye
Material is combined more preferable with glass fibre.
It pulls synchronous with rolling speed to control the movement speed of glass fibre.
The round-trip width of spray gun is set according to the width of the glass fiber yarn or glass fabric used.
A kind of color glass fiber package material of the present invention, with soft texture, dye thickness is uniform, is easy to batch, shape
Shape rule, non-conductive, do not shield electric signal, color and pattern diversification, it is assorted honorable, magnificent beautiful, magical unique to have, special
The pattern effect of other high definition, be existing decorative product can not institute it is unapproachable.In addition, since this color glass fiber fills
Exterior material is soft, thickness is uniform, superior performance, user can freely cut at one's discretion, for existing ornament materials, all be
It is a kind of greatly to be promoted.It can be used for 3C Product, household electrical appliances, indoor decoration, aviation, automobile, rail traffic, yacht, luggage, pleasure waterborne
Garden or sports equipment field, application range are very extensive.Using when can directly by above-mentioned color glass fiber material it is clipped, at
Type forms decorative product；Also can with reapplied after resin compounded.When with resin compounded, by a kind of above-mentioned color glass fiber
It is coated or impregnated with thermosetting property on ornament materials or thermoplastic resin forms fiber prepreg material, is then formed through molding or Shooting Technique
Polychromy product.The silane coupling agent of fiberglass surfacing coating can not only promote the associativity of glass fibre and organic dyestuff
Can, and the organic functional group of coupling agent can be chemically reacted with resin, can substantially improve and reinforce glass fibre and
The associativity of resin prevents from being layered with resin under wet heat condition.And after resin is combined with glass fibre, glass can be greatly improved
The characteristic of glass fiber enhances its folding, wear-resisting, processability and reduces the mutual friction coefficient of glass fibre, makes stained glass
Fiber can be used as ornament to be applied to different field.
Specific implementation mode
The glass fibre of selection in the present invention can be glass fiber yarn or glass fabric, wherein preferably glass
The model glass fabric 7628,2520,1140 of glass fiber cloth.
Embodiment 1
The glass fabric 7628 of the present embodiment.
A kind of the step of manufacturing method of color glass fiber ornament, is as follows：
Glass fibre step is placed in the BH stoves of 400 DEG C or so of temperature first, processing time 1h, removes precursor milli and draw
Wire drawing size coated by fiberglass surfacing in the process, and the slurry that yarn coats in sizing process is removed, so
It cools down to obtain clean glass fibre by natural wind；
Then to the surface silane coating coupling agent of clean glass fabric, type is γ-(2,3- the third oxygen of epoxy)
Propyl trimethoxy silicane (abbreviation KH-560)；
Finally, it paints to the glass fibre that have passed through above-mentioned post-processing, the glass fibers post-processed from unwinding device
Dimension moves through coloring means, and coloring means have two spray guns, is symmetrically distributed in the both sides of glass fabric, and each spray gun will
The organic dyestuff of different colours is sprayed into fiberglass surfacing, and specific parameter of painting is shown in Table 1.After spraying dyestuff, 20min is waited for,
It waits for that dyestuff is impregnated into inside glass fibre, allows dyestuff fully to be combined with glass fibre through 170 DEG C of high temperature dryings, most afterwards through natural wind
It is cooling, the color glass fiber ornament materials of multicolour pattern is obtained, by forming web-like body after batching, is involved in wrap-up
In.
When using glass fibre ornament materials of the invention, different lines are first usually designed according to product appearance size
Or pattern forms a kind of required color glass fiber ornament materials then by technology of painting, it can be according to work
Skill, such as 3C Product, the color glass fiber ornament materials is prepared into thermosetting class or thermoplastic class prepreg, through molding
Or Shooting Technique forms the decorative shell product with protective value of corresponding different lines and pattern.Certain material glass
It also directly can be cut out corresponding product size by glass fiber decorative material by laser, be used for the wallpaper of indoor decoration.
Embodiment 2
The present embodiment, difference lies in colouring parameter, is specifically shown in Table 1 with embodiment 1.Obtain be multicolour pattern colour
Glass fibre ornament materials.
Embodiment 3
The present embodiment and embodiment 1 are specifically shown in Table 1 difference lies in colouring parameter is different.It obtains being solid color figure
The color glass fiber ornament materials of case.
The foregoing is merely the preferable specific implementation modes of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in,
It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims
Subject to enclosing.
1. coloring means parameter of table
Claims (10)
1. a kind of manufacturing method of new decorative material, it is characterised in that using glass fibre as raw material, first by glass fibre into
Row, which is burnt, to be lost, the surface silane coating coupling agent of the glass fibre after then being lost to burning, finally in the glass of silane coating coupling agent
The surface spraying or coating organic dyestuff of fiber obtain color glass fiber ornament materials.
2. manufacturing method according to claim 1, it is characterised in that it is 380-420 DEG C that the burning, which loses temperature, and the time is
0.5-2h。
3. manufacturing method according to claim 1, it is characterised in that the coupling agent is that silane coupling agent is 3- aminopropans
One kind in ethyl triethoxy silicane alkane or γ-(the third oxygen of 2,3- epoxies) propyl trimethoxy silicane.
4. manufacturing method according to claim 1, it is characterised in that the thickness of the dyestuff of the fiberglass surfacing is 3-5
μm。
5. manufacturing method according to claim 4, it is characterised in that the glass fibre moves through coloring means, described
There is coloring means at least one spray gun, the spray gun glass fibre is sprayed in round-trip, the glass fibre
Movement speed is 0.5-1.3m/s, and the movement speed of the spray gun is 0.5-1.3m/s, and dye spray amount is 25-45g/m2, spray
Head discharge pressure is 0.1-0.3Ba, is atomized as 1.0-2.0Ba.
6. manufacturing method according to claim 5, it is characterised in that the glass fibre continues to dry after spraying dyestuff
Dry, cooling, the drying temperature is 160-180 DEG C, time 10-20min.
7. manufacturing method according to claim 6, it is characterised in that the glass fibre is pulled from unwinding device, is dried
Dry rolling after cooling, pulls speed identical with rolling speed.
8. manufacturing method according to claim 5, it is characterised in that the wide cut of the spray gun is 1.3-2.3Ba, exhausting work(
Rate is 50%-85%.
9. manufacturing method according to claim 5, it is characterised in that the quantity of the spray gun is 2, every spray gun it is past
It is 1000-1800mm to return width, starts to spray when distance of the glass fibre positioned at front apart from the spray gun is 300-420mm
Apply dyestuff.
10. a kind of color glass fiber ornament materials prepared according to any manufacturing methods of claim 1-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810315934.2A CN108505335A (en) | 2018-04-10 | 2018-04-10 | A kind of new decorative material and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810315934.2A CN108505335A (en) | 2018-04-10 | 2018-04-10 | A kind of new decorative material and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108505335A true CN108505335A (en) | 2018-09-07 |
Family
ID=63381414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810315934.2A Pending CN108505335A (en) | 2018-04-10 | 2018-04-10 | A kind of new decorative material and its manufacturing method |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007092188A (en) * | 2005-09-27 | 2007-04-12 | Suminoe Textile Co Ltd | Train interior fabric using colored glass fibers |
| CN103058527A (en) * | 2013-01-11 | 2013-04-24 | 成都瀚江新型建筑材料有限公司 | Colored glass cotton product and production method thereof |
| CN103088573A (en) * | 2013-02-20 | 2013-05-08 | 苏州裕克施乐塑料制品有限公司 | Staining method for glass fiber cloth and multiple-shaft transmission device thereof |
| CN203200512U (en) * | 2013-02-20 | 2013-09-18 | 苏州裕克施乐塑料制品有限公司 | Multi-axis transmission device for dyeing method of glass fiber cloth |
| CN103435270A (en) * | 2013-07-22 | 2013-12-11 | 东华大学 | Process for preparing color glass fiber through two-stage dipping method |
| CN105849160A (en) * | 2014-01-28 | 2016-08-10 | 日东纺绩株式会社 | Colored glass fiber and manufacturing method therefor |
-
2018
- 2018-04-10 CN CN201810315934.2A patent/CN108505335A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007092188A (en) * | 2005-09-27 | 2007-04-12 | Suminoe Textile Co Ltd | Train interior fabric using colored glass fibers |
| CN103058527A (en) * | 2013-01-11 | 2013-04-24 | 成都瀚江新型建筑材料有限公司 | Colored glass cotton product and production method thereof |
| CN103088573A (en) * | 2013-02-20 | 2013-05-08 | 苏州裕克施乐塑料制品有限公司 | Staining method for glass fiber cloth and multiple-shaft transmission device thereof |
| CN203200512U (en) * | 2013-02-20 | 2013-09-18 | 苏州裕克施乐塑料制品有限公司 | Multi-axis transmission device for dyeing method of glass fiber cloth |
| CN103435270A (en) * | 2013-07-22 | 2013-12-11 | 东华大学 | Process for preparing color glass fiber through two-stage dipping method |
| CN105849160A (en) * | 2014-01-28 | 2016-08-10 | 日东纺绩株式会社 | Colored glass fiber and manufacturing method therefor |
Non-Patent Citations (1)
| Title |
|---|
| CHEN HONGCHU: "Dyeing of glass fiber fabrics having amino groups with acid dyestuff and after-chroming", 《JOURNAL OF APPLIED POLYMER SCIENCE》 * |
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Application publication date: 20180907 |