CN108503966A - A kind of shock resistance conductive plastic material - Google Patents

A kind of shock resistance conductive plastic material Download PDF

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Publication number
CN108503966A
CN108503966A CN201710542098.7A CN201710542098A CN108503966A CN 108503966 A CN108503966 A CN 108503966A CN 201710542098 A CN201710542098 A CN 201710542098A CN 108503966 A CN108503966 A CN 108503966A
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CN
China
Prior art keywords
parts
plastic material
shock resistance
conductive plastic
resistance conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710542098.7A
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Chinese (zh)
Inventor
黄荣翠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Cuinan Electronic Technology Co Ltd
Original Assignee
Suzhou Cuinan Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Cuinan Electronic Technology Co Ltd filed Critical Suzhou Cuinan Electronic Technology Co Ltd
Priority to CN201710542098.7A priority Critical patent/CN108503966A/en
Priority to PCT/CN2017/101527 priority patent/WO2019006859A1/en
Publication of CN108503966A publication Critical patent/CN108503966A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The present invention proposes a kind of shock resistance conductive plastic material, includes the raw material composition of following parts by weight:30 ~ 50 parts of polystyrene, 15 ~ 20 parts of methacrylic acid, 4 ~ 10 parts of organic silicon resin, 3 ~ 10 parts of conductive material, 3 ~ 12 parts of complex fiber material, 3 ~ 8 parts of titanium dioxide, 1 ~ 5 part of chrome green, 2 ~ 4 parts of strontium oxide strontia, 2 ~ 3 parts of methyl-silicone oil, 0.5 ~ 1.5 part of dispersion moisture agent, 1 ~ 2.5 part of stabilizer, 3 ~ 8 parts of toughening, 1 ~ 4 part of interface coupling agent, 0.5 ~ 1 part of antioxidant.Plastic material proposed by the present invention has excellent electric conductivity, has excellent mechanical strength, is effectively improved its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, preparation process is simple.

Description

A kind of shock resistance conductive plastic material
Technical field
The present invention relates to electronic conductive material technical fields, and in particular to a kind of shock resistance conductive plastic material.
Conductive plastics is to mix resin and conductive materials, the functional macromolecule being processed with the processing method of plastics Material.It is mainly used in the fields such as electronics, integrated circuit packaging, electromagnetic wave shielding.Conductive plastics not only antisatic additive, The application of the anti-electromagnetism screen of computer and smart window etc. quickly develops, and light emitting diode, solar cell, The fields such as mobile phone, micro-television screen or even life science also have wide practical use.In addition, conductive plastics and The combination of nanotechnology will also play a role in promoting to the rapid development of molectronics.
Currently, common conductive plastics, is mixed by adding metallic fiber, metal powder and engineering plastics. The conductive plastics electric conductivity that this mode makes is good by force, can be used as shielding material.But during machine-shaping, metal Fiber is easy to be destroyed, and reduces the electric conductivity of finished product, therefore processing technology difficulty is big, not the good height of rate, and above-mentioned add Add the intensity that object also be easy to cause plastics to decline, is easy to be impacted broken.
Therefore, for needle with the above problem, the present invention proposes a kind of new technical solution.
Invention content
There is excellent conductive effect the object of the present invention is to provide a kind of, high mechanical strength, shock resistance is good to be resisted Impact conductive plastic material.
The present invention is achieved through the following technical solutions:
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:30~50 parts of polystyrene, first 15~20 parts of base acrylic acid, 4~10 parts of organic silicon resin, 3~10 parts of conductive material, 3~12 parts of complex fiber material, titanium dioxide 3~8 parts of titanium, 1~5 part of chrome green, 2~4 parts of strontium oxide strontia, 2~3 parts of methyl-silicone oil, 0.5~1.5 part of dispersion moisture agent, surely Determine 1~2.5 part of agent, 3~8 parts of toughening, 1~4 part of interface coupling agent, 0.5~1 part of antioxidant.
Further, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or a variety of.
Further, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
Further, the complex fiber material includes 1~5 part of nickel-coated carbon fibers, 1~5 part of aluminium silicate fiber peacekeeping 1 ~5 parts of glass fibres.
Further, a diameter of 40~100um of the nickel-coated carbon fibers, the alumina silicate fibre a diameter of 60~ 200um, a diameter of 80~240um of glass fibre.
The beneficial effects of the invention are as follows:Plastic material proposed by the present invention has excellent electric conductivity, has excellent Mechanical strength is effectively improved its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, system It is standby simple for process.
Specific implementation mode
The present invention is described further with reference to embodiment.
Embodiment 1
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:30 parts of polystyrene, methyl-prop 15 parts of olefin(e) acid, 4 parts of organic silicon resin, 3 parts of conductive material, 3 parts of complex fiber material, 3 parts of titanium dioxide, 1 part of chrome green, 2 parts of strontium oxide strontia, 2 parts of methyl-silicone oil, 0.5 part of dispersion moisture agent, 1 part of stabilizer, 3 parts of toughening, 1 part of interface coupling agent are anti-oxidant 0.5 part of agent.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 1 part of nickel-coated carbon fibers, 1 part of 1 part of aluminium silicate fiber peacekeeping Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass A diameter of 100um of fiber.
Embodiment 2
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:40 parts of polystyrene, methyl-prop 18 parts of olefin(e) acid, 6 parts of organic silicon resin, 5 parts of conductive material, 6 parts of complex fiber material, 4 parts of titanium dioxide, 2 parts of chrome green, 3 parts of strontium oxide strontia, 1.5 parts of methyl-silicone oil, 0.8 part of dispersion moisture agent, 1.2 parts of stabilizer, 5 parts of toughening, 3 parts of interface coupling agent resist 0.6 part of oxidant.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 1 part of nickel-coated carbon fibers, 2 parts of 3 parts of aluminium silicate fiber peacekeeping Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass A diameter of 100um of fiber.
Embodiment 3
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:50 parts of polystyrene, methyl-prop 20 parts of olefin(e) acid, 10 parts of organic silicon resin, 10 parts of conductive material, 12 parts of complex fiber material, 8 parts of titanium dioxide, chrome green 5 Part, 4 parts of strontium oxide strontia, 3 parts of methyl-silicone oil, 1.5 parts of dispersion moisture agent, 2.5 parts of stabilizer, 8 parts of toughening, 4 parts of interface coupling agent resist 1 part of oxidant.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 4 parts of nickel-coated carbon fibers, 3 parts of 5 parts of aluminium silicate fiber peacekeeping Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass A diameter of 100um of fiber.
Plastic material proposed by the present invention has excellent electric conductivity, has excellent mechanical strength, effectively improves Its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, preparation process is simple.
Although the above-mentioned specific implementation mode to the present invention is described, not to the limit of the scope of the present invention System, based on the technical solutions of the present invention, those skilled in the art need not make the creative labor can make it is each Kind modification or deformation are still within protection scope of the present invention.

Claims (5)

1. a kind of shock resistance conductive plastic material, it is characterised in that:Raw material composition including following parts by weight:Polystyrene 30 ~ 50 parts, 15 ~ 20 parts of methacrylic acid, 4 ~ 10 parts of organic silicon resin, 3 ~ 10 parts of conductive material, 3 ~ 12 parts of complex fiber material, two 3 ~ 8 parts of titanium oxide, 1 ~ 5 part of chrome green, 2 ~ 4 parts of strontium oxide strontia, 2 ~ 3 parts of methyl-silicone oil, 0.5 ~ 1.5 part of dispersion moisture agent, surely Determine 1 ~ 2.5 part of agent, 3 ~ 8 parts of toughening, 1 ~ 4 part of interface coupling agent, 0.5 ~ 1 part of antioxidant.
2. a kind of shock resistance conductive plastic material according to claim 1, it is characterised in that:The conductive material is graphite Alkene, carbon nanometer micro-pipe, organic RE are one such or a variety of.
3. a kind of shock resistance conductive plastic material according to claim 1, it is characterised in that:The complex fiber material includes Nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
4. according to a kind of shock resistance conductive plastic material of claim 1 or 3, it is characterised in that:The complex fiber material Include 1 ~ 5 part of nickel-coated carbon fibers, 1 ~ 5 part 1 ~ 5 part of glass fibre of aluminium silicate fiber peacekeeping.
5. a kind of shock resistance conductive plastic material according to claim 3, it is characterised in that:The diameter of the nickel-coated carbon fibers For 40 ~ 100um, a diameter of 60 ~ 200 um of alumina silicate fibre, a diameter of 80 ~ 240 um of glass fibre.
CN201710542098.7A 2017-07-05 2017-07-05 A kind of shock resistance conductive plastic material Pending CN108503966A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710542098.7A CN108503966A (en) 2017-07-05 2017-07-05 A kind of shock resistance conductive plastic material
PCT/CN2017/101527 WO2019006859A1 (en) 2017-07-05 2017-09-13 Impact-resistant conductive plastic material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710542098.7A CN108503966A (en) 2017-07-05 2017-07-05 A kind of shock resistance conductive plastic material

Publications (1)

Publication Number Publication Date
CN108503966A true CN108503966A (en) 2018-09-07

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Country Status (2)

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CN (1) CN108503966A (en)
WO (1) WO2019006859A1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103351564A (en) * 2013-04-02 2013-10-16 江门职业技术学院 Electric conduction polystyrene plastic for carrier tape, and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6053546A (en) * 1983-09-05 1985-03-27 Sumitomo Bakelite Co Ltd Electrically conductive plastic composition
CN105482302A (en) * 2015-12-24 2016-04-13 江苏道勤新材料科技有限公司 Novel high-temperature-resisting conductive plastic material
CN105694275A (en) * 2016-01-27 2016-06-22 苏州翠南电子科技有限公司 Novel high-temperature-resisting conductive plastic material
CN105968602A (en) * 2016-05-25 2016-09-28 广州聚注专利研发有限公司 Flame retardant foamed polystyrene resin and preparation method thereof
CN105924818A (en) * 2016-05-25 2016-09-07 广州聚注专利研发有限公司 Polystyrene resin foamed heat insulation board and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103351564A (en) * 2013-04-02 2013-10-16 江门职业技术学院 Electric conduction polystyrene plastic for carrier tape, and preparation method thereof

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Application publication date: 20180907