CN108503966A - A kind of shock resistance conductive plastic material - Google Patents
A kind of shock resistance conductive plastic material Download PDFInfo
- Publication number
- CN108503966A CN108503966A CN201710542098.7A CN201710542098A CN108503966A CN 108503966 A CN108503966 A CN 108503966A CN 201710542098 A CN201710542098 A CN 201710542098A CN 108503966 A CN108503966 A CN 108503966A
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- China
- Prior art keywords
- parts
- plastic material
- shock resistance
- conductive plastic
- resistance conductive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention proposes a kind of shock resistance conductive plastic material, includes the raw material composition of following parts by weight:30 ~ 50 parts of polystyrene, 15 ~ 20 parts of methacrylic acid, 4 ~ 10 parts of organic silicon resin, 3 ~ 10 parts of conductive material, 3 ~ 12 parts of complex fiber material, 3 ~ 8 parts of titanium dioxide, 1 ~ 5 part of chrome green, 2 ~ 4 parts of strontium oxide strontia, 2 ~ 3 parts of methyl-silicone oil, 0.5 ~ 1.5 part of dispersion moisture agent, 1 ~ 2.5 part of stabilizer, 3 ~ 8 parts of toughening, 1 ~ 4 part of interface coupling agent, 0.5 ~ 1 part of antioxidant.Plastic material proposed by the present invention has excellent electric conductivity, has excellent mechanical strength, is effectively improved its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, preparation process is simple.
Description
Technical field
The present invention relates to electronic conductive material technical fields, and in particular to a kind of shock resistance conductive plastic material.
Conductive plastics is to mix resin and conductive materials, the functional macromolecule being processed with the processing method of plastics
Material.It is mainly used in the fields such as electronics, integrated circuit packaging, electromagnetic wave shielding.Conductive plastics not only antisatic additive,
The application of the anti-electromagnetism screen of computer and smart window etc. quickly develops, and light emitting diode, solar cell,
The fields such as mobile phone, micro-television screen or even life science also have wide practical use.In addition, conductive plastics and
The combination of nanotechnology will also play a role in promoting to the rapid development of molectronics.
Currently, common conductive plastics, is mixed by adding metallic fiber, metal powder and engineering plastics.
The conductive plastics electric conductivity that this mode makes is good by force, can be used as shielding material.But during machine-shaping, metal
Fiber is easy to be destroyed, and reduces the electric conductivity of finished product, therefore processing technology difficulty is big, not the good height of rate, and above-mentioned add
Add the intensity that object also be easy to cause plastics to decline, is easy to be impacted broken.
Therefore, for needle with the above problem, the present invention proposes a kind of new technical solution.
Invention content
There is excellent conductive effect the object of the present invention is to provide a kind of, high mechanical strength, shock resistance is good to be resisted
Impact conductive plastic material.
The present invention is achieved through the following technical solutions:
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:30~50 parts of polystyrene, first
15~20 parts of base acrylic acid, 4~10 parts of organic silicon resin, 3~10 parts of conductive material, 3~12 parts of complex fiber material, titanium dioxide
3~8 parts of titanium, 1~5 part of chrome green, 2~4 parts of strontium oxide strontia, 2~3 parts of methyl-silicone oil, 0.5~1.5 part of dispersion moisture agent, surely
Determine 1~2.5 part of agent, 3~8 parts of toughening, 1~4 part of interface coupling agent, 0.5~1 part of antioxidant.
Further, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or a variety of.
Further, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
Further, the complex fiber material includes 1~5 part of nickel-coated carbon fibers, 1~5 part of aluminium silicate fiber peacekeeping 1
~5 parts of glass fibres.
Further, a diameter of 40~100um of the nickel-coated carbon fibers, the alumina silicate fibre a diameter of 60~
200um, a diameter of 80~240um of glass fibre.
The beneficial effects of the invention are as follows:Plastic material proposed by the present invention has excellent electric conductivity, has excellent
Mechanical strength is effectively improved its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, system
It is standby simple for process.
Specific implementation mode
The present invention is described further with reference to embodiment.
Embodiment 1
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:30 parts of polystyrene, methyl-prop
15 parts of olefin(e) acid, 4 parts of organic silicon resin, 3 parts of conductive material, 3 parts of complex fiber material, 3 parts of titanium dioxide, 1 part of chrome green,
2 parts of strontium oxide strontia, 2 parts of methyl-silicone oil, 0.5 part of dispersion moisture agent, 1 part of stabilizer, 3 parts of toughening, 1 part of interface coupling agent are anti-oxidant
0.5 part of agent.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more
Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 1 part of nickel-coated carbon fibers, 1 part of 1 part of aluminium silicate fiber peacekeeping
Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass
A diameter of 100um of fiber.
Embodiment 2
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:40 parts of polystyrene, methyl-prop
18 parts of olefin(e) acid, 6 parts of organic silicon resin, 5 parts of conductive material, 6 parts of complex fiber material, 4 parts of titanium dioxide, 2 parts of chrome green,
3 parts of strontium oxide strontia, 1.5 parts of methyl-silicone oil, 0.8 part of dispersion moisture agent, 1.2 parts of stabilizer, 5 parts of toughening, 3 parts of interface coupling agent resist
0.6 part of oxidant.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more
Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 1 part of nickel-coated carbon fibers, 2 parts of 3 parts of aluminium silicate fiber peacekeeping
Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass
A diameter of 100um of fiber.
Embodiment 3
A kind of shock resistance conductive plastic material includes the raw material composition of following parts by weight:50 parts of polystyrene, methyl-prop
20 parts of olefin(e) acid, 10 parts of organic silicon resin, 10 parts of conductive material, 12 parts of complex fiber material, 8 parts of titanium dioxide, chrome green 5
Part, 4 parts of strontium oxide strontia, 3 parts of methyl-silicone oil, 1.5 parts of dispersion moisture agent, 2.5 parts of stabilizer, 8 parts of toughening, 4 parts of interface coupling agent resist
1 part of oxidant.
In the present embodiment, the conductive material is that graphene, carbon nanometer micro-pipe, organic RE are one such or more
Kind.
In the present embodiment, the complex fiber material includes nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
In the present embodiment, the complex fiber material includes 4 parts of nickel-coated carbon fibers, 3 parts of 5 parts of aluminium silicate fiber peacekeeping
Glass fibre.
In the present embodiment, a diameter of 60um of the nickel-coated carbon fibers, a diameter of 80um of alumina silicate fibre, glass
A diameter of 100um of fiber.
Plastic material proposed by the present invention has excellent electric conductivity, has excellent mechanical strength, effectively improves
Its impact resistance, meanwhile, there is preferable anticorrosion effect, moreover, tensile property is good, preparation process is simple.
Although the above-mentioned specific implementation mode to the present invention is described, not to the limit of the scope of the present invention
System, based on the technical solutions of the present invention, those skilled in the art need not make the creative labor can make it is each
Kind modification or deformation are still within protection scope of the present invention.
Claims (5)
1. a kind of shock resistance conductive plastic material, it is characterised in that:Raw material composition including following parts by weight:Polystyrene 30
~ 50 parts, 15 ~ 20 parts of methacrylic acid, 4 ~ 10 parts of organic silicon resin, 3 ~ 10 parts of conductive material, 3 ~ 12 parts of complex fiber material, two
3 ~ 8 parts of titanium oxide, 1 ~ 5 part of chrome green, 2 ~ 4 parts of strontium oxide strontia, 2 ~ 3 parts of methyl-silicone oil, 0.5 ~ 1.5 part of dispersion moisture agent, surely
Determine 1 ~ 2.5 part of agent, 3 ~ 8 parts of toughening, 1 ~ 4 part of interface coupling agent, 0.5 ~ 1 part of antioxidant.
2. a kind of shock resistance conductive plastic material according to claim 1, it is characterised in that:The conductive material is graphite
Alkene, carbon nanometer micro-pipe, organic RE are one such or a variety of.
3. a kind of shock resistance conductive plastic material according to claim 1, it is characterised in that:The complex fiber material includes
Nickel-coated carbon fibers, aluminium silicate fiber peacekeeping glass fibre.
4. according to a kind of shock resistance conductive plastic material of claim 1 or 3, it is characterised in that:The complex fiber material
Include 1 ~ 5 part of nickel-coated carbon fibers, 1 ~ 5 part 1 ~ 5 part of glass fibre of aluminium silicate fiber peacekeeping.
5. a kind of shock resistance conductive plastic material according to claim 3, it is characterised in that:The diameter of the nickel-coated carbon fibers
For 40 ~ 100um, a diameter of 60 ~ 200 um of alumina silicate fibre, a diameter of 80 ~ 240 um of glass fibre.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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CN201710542098.7A CN108503966A (en) | 2017-07-05 | 2017-07-05 | A kind of shock resistance conductive plastic material |
PCT/CN2017/101527 WO2019006859A1 (en) | 2017-07-05 | 2017-09-13 | Impact-resistant conductive plastic material |
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CN201710542098.7A CN108503966A (en) | 2017-07-05 | 2017-07-05 | A kind of shock resistance conductive plastic material |
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CN108503966A true CN108503966A (en) | 2018-09-07 |
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CN201710542098.7A Pending CN108503966A (en) | 2017-07-05 | 2017-07-05 | A kind of shock resistance conductive plastic material |
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CN (1) | CN108503966A (en) |
WO (1) | WO2019006859A1 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103351564A (en) * | 2013-04-02 | 2013-10-16 | 江门职业技术学院 | Electric conduction polystyrene plastic for carrier tape, and preparation method thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6053546A (en) * | 1983-09-05 | 1985-03-27 | Sumitomo Bakelite Co Ltd | Electrically conductive plastic composition |
CN105482302A (en) * | 2015-12-24 | 2016-04-13 | 江苏道勤新材料科技有限公司 | Novel high-temperature-resisting conductive plastic material |
CN105694275A (en) * | 2016-01-27 | 2016-06-22 | 苏州翠南电子科技有限公司 | Novel high-temperature-resisting conductive plastic material |
CN105968602A (en) * | 2016-05-25 | 2016-09-28 | 广州聚注专利研发有限公司 | Flame retardant foamed polystyrene resin and preparation method thereof |
CN105924818A (en) * | 2016-05-25 | 2016-09-07 | 广州聚注专利研发有限公司 | Polystyrene resin foamed heat insulation board and preparation method thereof |
-
2017
- 2017-07-05 CN CN201710542098.7A patent/CN108503966A/en active Pending
- 2017-09-13 WO PCT/CN2017/101527 patent/WO2019006859A1/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103351564A (en) * | 2013-04-02 | 2013-10-16 | 江门职业技术学院 | Electric conduction polystyrene plastic for carrier tape, and preparation method thereof |
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Application publication date: 20180907 |