CN108503079A - Municipal wastewater construction technology - Google Patents

Municipal wastewater construction technology Download PDF

Info

Publication number
CN108503079A
CN108503079A CN201810285490.2A CN201810285490A CN108503079A CN 108503079 A CN108503079 A CN 108503079A CN 201810285490 A CN201810285490 A CN 201810285490A CN 108503079 A CN108503079 A CN 108503079A
Authority
CN
China
Prior art keywords
parts
filtrate
municipal wastewater
construction technology
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810285490.2A
Other languages
Chinese (zh)
Inventor
胡娅婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810285490.2A priority Critical patent/CN108503079A/en
Publication of CN108503079A publication Critical patent/CN108503079A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079Manufacture of membranes comprising organic and inorganic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/024Oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/08Polysaccharides
    • B01D71/10Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone

Abstract

The invention discloses a kind of municipal wastewater construction technologies, include the following steps:S1, municipal wastewater remove large-sized sundries by grid etc., obtain just treated sewage;S2 is added Fenton reagent into the first treated sewage of step S1 acquisitions, is uniformly mixed, and reaction is filtered for the first time, the first filtrate of acquisition;S3 is passed through ozone into the first filtrate of step S2 acquisitions, adds compound silica gel, fully reacts, second of filtering, the second filtrate of acquisition;S4 is added sodium carbonate or sodium bicarbonate into the second filtrate of step S3 acquisitions, is uniformly mixed, acquisition third filtrate after third time filters;The third filtrate obtained in step S4 is carried out compound film process, obtains drinking water by S5;The composite membrane includes the component of following parts by weight:35 50 parts of nitrocellulose filter;12 15 parts of Nanocrystalline Cellulose Colloid;36 parts of nano-titanium dioxide.Municipal wastewater can reach drinking water discharge standard after this process.

Description

Municipal wastewater construction technology
Technical field
The present invention relates to municipal wastewater process fields, more specifically, it relates to a kind of municipal wastewater construction technology.
Background technology
Municipal wastewater discharge capacity is big, including sanitary wastewater, industrial wastewater etc., wherein containing a large amount of total dissolved solidss, COD, BOD, total silicon, ammonia, other pollutants, municipal wastewater after processing are generally recycled, and can only be used as cleaning, flushing the toilet Aspect, since treatment technology is limited, it is difficult to which the municipal wastewater after directly will be purified is used as drinking water.However, urban human Mouth quantity is big, and drinking water dosage is big, and being used as drinking water after municipal wastewater is purified has higher value.
Invention content
In view of the deficiencies of the prior art, the present invention intends to provide a kind of municipal wastewater construction technology, municipal administration The advantages of can reach the standard of drinking water discharge after the dirty water decontamination handles.
To achieve the above object, the present invention provides following technical solutions:
A kind of municipal wastewater construction technology, includes the following steps:
S1, municipal wastewater remove large-sized sundries by grid etc., obtain just treated sewage;
S2 is added Fenton reagent in the first treated sewage obtained to step S1, is uniformly mixed, and reaction is filtered for the first time, obtains the One filtrate;
S3 is passed through ozone into the first filtrate of step S2 acquisitions, adds compound silica gel, fully reacts, and second of filtering obtains Obtain the second filtrate;
S4 is added sodium carbonate or sodium bicarbonate into the second filtrate of step S3 acquisitions, is uniformly mixed, and third time obtains after filtering Third filtrate;
The third filtrate obtained in step S4 is carried out compound film process, obtains drinking water by S5;
The composite membrane includes the component of following parts by weight:
35-50 parts of nitrocellulose filter;
12-15 parts of Nanocrystalline Cellulose Colloid;
3-6 parts of nano-titanium dioxide.
Through the above technical solutions, grid can remove the large scale sundries in municipal wastewater, including block-like sludge, stone Deng reducing large scale sundries to the burden that is handled in step S2, step S3, step S4.And Fenton reagent has strong oxidizing property, The hydroxyl radical free radical that strong oxidizing property can be generated in first treated sewage, increases electrode potential, and grease difficult to degrade therein etc. is organic Object and generate organic free radical, to destroy the structure of organic matter, i.e. oxygenolysis organic matter.On the other hand, Fenton reagent can The stench that decolourizes and remove is carried out to first treated sewage.Ozone is passed through into the first filtrate, high-oxygen water is formed, further to the first filtrate In remaining organic matter degrade, and cooperate with compound silica gel, the ingredient in compound silica gel gradually discharges, and helps to carry Height carries out more efficiently structure destruction to organic matters such as the greases that has been broken down into short chain, improves purification efficiency, and will Heavy metal in sewage is settled.And during being passed through ozone, ozone forms a large amount of bubbles in the first filtrate, drives Compound silica gel constantly floats wherein, or even floats on the water surface, to swimming in residual grease and sewage on the water surface Organic matter further degraded, improve to the degradation of the first filtrate.And carbonic acid is added to the second filtrate in step 4 Sodium or sodium bicarbonate can play the role of adjusting pH value therein, it is made to tend to be neutral, after being filtered along with third time, wherein It generates or remaining deposit is removed, reduce the burden that composite membrane carries out third filtrate further purified treatment, it can Extend the service life of composite membrane.Carboxylic Acid Fibre element film, Nanocrystalline Cellulose Colloid, the nanometer titanium dioxide contained in composite membrane Titanium carries out sterilization processing and by small size impurity absorption therein to third filtrate, and the municipal wastewater for making after processing, which reaches, to be drunk Water discharge standard.
Further preferably:The preparation method of the composite membrane includes the following steps:
The nano-titanium dioxide of corresponding parts by weight, Nanocrystalline Cellulose Colloid are sufficiently mixed by step 1, and it is mixed to form second Close liquid;Step 2 stops heating and keeping the temperature after the second mixed liquor obtained in step 1 is heated to 45-50 DEG C, by nitric acid fibre The plain film of dimension is divided submergence and is placed in the second mixed liquor, and 30-45min is impregnated, and takes out and is placed on 20-33s in 0 DEG C of environment, dry.
Through the above technical solutions, nano-titanium dioxide has preferable bactericidal effect, and according to the principle of similar compatibility, After the heating of the second mixed liquor, molecular motion aggravation is good to be more easy to make nano-titanium dioxide and nano micro crystal cellulose to be formed Good connection, and nano micro crystal cellulose forms network-like structure between each other, further through similar compatibility principle, makes to be connected with and receive The nano micro crystal cellulose of rice titanium dioxide is formed with nitrocellulose filter to be connected, and is taken out and is placed on 20-33s in 0 DEG C of environment, Nano-titanium dioxide, nano micro crystal cellulose, nitrocellulose filter can be made to connect even closer, third is filtered to improve it The treatment effeciency of liquid.
Further preferably:The grain size of nano micro crystal cellulose is 50-100nm in the composite membrane.
Through the above technical solutions, being found through research (concentration of emission experiment), the nano microcrystalline fiber in the particle size range Element has the specific surface area of bigger, is formed and is connected with nano-titanium dioxide convenient for it.
Further preferably:Nano micro crystal cellulose containing 0.1-0.2wt% in the Nanocrystalline Cellulose Colloid.
Through the above technical solutions, being found through research (concentration of emission experiment), the nano microcrystalline in the content range is fine The adsorbable more nano-titanium dioxide of dimension element, to improve the detergent power of composite membrane.
Further preferably:The compound silica gel includes the component of following parts by weight:
66-71 parts of Bio-sil;
5-8 parts of nano silicon dioxide;
1-5 parts of ethylenediamine tetra-acetic acid;
2-3 parts of calcium acetate;
2-5 parts of hydroxyethyl ethylenediamine;
5-10 parts of water.
Through the above technical solutions, ethylenediamine tetra-acetic acid, calcium acetate, hydroxyethyl ethylenediamine have good chelation, By the heavy metal subsiding and purifying in the first filtrate.Nano silicon dioxide forms network-like structure in water, by ethylenediamine tetra-acetic acid, Calcium acetate, hydroxyethyl ethylenediamine are attached to Bio-sil.And Bio-sil increases specific surface area, helps to improve suction The content of attached nano silicon dioxide, ethylenediamine tetra-acetic acid, calcium acetate, hydroxyethyl ethylenediamine, when the compound silica gel of formation is set to Enter when being filtered in the first filtrate, each component on surface can gradually discharge, and contribute to a more huge sum of moneys in the first filtrate Belong to and carry out settlement treatment, improves the removal rate to heavy metal.On the other hand, silica is realized more preferable under the action of ozone Catalytic action, improve to the degradation effect of organic matter in the first filtrate.
Further preferably:The preparation method of compound silica gel includes the following steps in the step S3:
(1) nano silicon dioxide of corresponding parts by weight, ethylenediamine tetra-acetic acid, calcium acetate, hydroxyethyl ethylenediamine are added together It into the water of corresponding parts by weight, is uniformly mixed, forms the first mixed liquor;
(2) Bio-sil of corresponding parts by weight is added in the first mixed liquor obtained into step (1), ultrasonication 5- 10min is spontaneously dried, and is made.
Through the above technical solutions, by ultrasonication 5-10min, the dispersion effect of nano silicon dioxide can be improved, It is connected to be formed with the outer surface of Bio-sil and pore surface, and then improves heavy metal in the first filtrate of silica pair Processing effect.
In conclusion the invention has the advantages that:
1. the COD (COD) being effectively improved in municipal wastewater, biochemical oxygen demand (BOD) (BOD), concentration of suspension (SS);
2. effectively removing bacterium therein, heavy metal, reach drinking water discharge standard.
Description of the drawings
Fig. 1 is the flow chart of municipal wastewater construction technology in embodiment 1.
Specific implementation mode
With reference to the accompanying drawings and examples, the present invention will be described in detail.
Embodiment 1:Municipal wastewater construction technology, as shown in Figure 1, including the following steps:
S1, municipal wastewater remove large-sized sundries by grid etc., obtain just treated sewage;
S2 is added Fenton reagent in the first treated sewage obtained to step S1, is uniformly mixed, and reaction is filtered for the first time, obtains the One filtrate;
S3 is passed through ozone into the first filtrate of step S2 acquisitions, adds compound silica gel, fully reacts, and second of filtering obtains Obtain the second filtrate;
S4 is added sodium bicarbonate into the second filtrate of step S3 acquisitions, is uniformly mixed, and third time obtains third after filtering and filters Liquid;
The third filtrate obtained in step S4 is carried out compound film process, obtains drinking water by S5.
Wherein, the component of composite membrane and its corresponding parts by weight are as shown in table 1;The component of compound silica gel and its corresponding Parts by weight are as shown in table 2.The preparation method of composite membrane includes the following steps:
Step 1, by nano-titanium dioxide, the nanometer containing the nano micro crystal cellulose that 0.1-0.2wt% grain sizes are 50-100nm Microcrystal cellulose colloid is sufficiently mixed, and forms the second mixed liquor;
Step 2 stops heating and keeping the temperature after the second mixed liquor obtained in step 1 is heated to 45-50 DEG C, by cellulose nitrate Plain film is divided submergence and is placed in the second mixed liquor, and 30-45min is impregnated, and takes out and is placed on 20-33s in 0 DEG C of environment, dry.
And the preparation method of compound silica gel includes the following steps:
(1) nano silicon dioxide of corresponding parts by weight, ethylenediamine tetra-acetic acid, calcium acetate, hydroxyethyl ethylenediamine are added together It into the water of corresponding parts by weight, is uniformly mixed, forms the first mixed liquor;
(2) Bio-sil of corresponding parts by weight is added in the first mixed liquor obtained into step (1), ultrasonication 5- 10min is spontaneously dried, and compound silica gel is made.
Embodiment 2-3:Municipal wastewater construction technology, difference lies in, the components of composite membrane and its corresponding with embodiment 1 Parts by weight are as shown in table 1;The component of compound silica gel and its corresponding parts by weight are as shown in table 2.
The component and its corresponding parts by weight of composite membrane in 1 embodiment 1-3 of table
The component and its corresponding parts by weight of compound silica gel in 2 embodiment 1-3 of table
Embodiment 4:Municipal wastewater construction technology, difference lies in nano micro crystal celluloses in step 1 with embodiment 1 Content is 0.15wt%.
Embodiment 5:Municipal wastewater construction technology, difference lies in nano micro crystal celluloses in step 1 with embodiment 1 Content is 0.2wt%.
Comparative example 1:Municipal wastewater construction technology, difference lies in be not used composite membrane with embodiment 1.
Comparative example 2-5:Municipal wastewater construction technology, difference lies in, the components of composite membrane and its corresponding with embodiment 1 Parts by weight are as shown in table 3.
The component and its corresponding parts by weight of composite membrane in 3 comparative example 2-5 of table
Comparative example 6:Municipal wastewater construction technology, difference lies in be not used compound silica gel with embodiment 1.
Comparative example 7-12:Municipal wastewater construction technology, difference lies in the components and its phase of compound silica gel with embodiment 1 The parts by weight answered are as shown in table 4.
The component and its corresponding parts by weight of compound silica gel in 4 comparative example 7-12 of table
Comparative example 13:Municipal wastewater construction technology, difference lies in nano micro crystal celluloses in step 1 with embodiment 1 Content be 0.05wt%.
Comparative example 14:Municipal wastewater construction technology, difference lies in nano micro crystal celluloses in step 1 with embodiment 1 Content be 0.3wt%.
Comparative example 15:Municipal wastewater construction technology, difference lies in the grain size of nano micro crystal cellulose is with embodiment 1 30-50nm。
Comparative example 16:Municipal wastewater construction technology, difference lies in the grain size of nano micro crystal cellulose is with embodiment 1 150-250nm。
Comparative example 17:Municipal wastewater construction technology, with embodiment 1 difference lies in, in step 2, the second mixed liquor without Heat treatment.
Comparative example 18:Municipal wastewater construction technology, difference lies in step 2, the nitric acid after immersion is fine with embodiment 1 The plain film of dimension is not disposed in 0 DEG C of environment.
Comparative example 19:Municipal wastewater construction technology, difference lies in step 2, will obtain in step 1 with embodiment 1 The second mixed liquor be heated to 35-40 DEG C after stop heat and keep the temperature, nitrocellulose filter, which is divided submergence, is placed in the second mixing In liquid, 20-25min is impregnated, takes out and is placed on 10-15s in 0 DEG C of environment, it is dry.
Comparative example 20:Municipal wastewater construction technology, difference lies in step 2, will obtain in step 1 with embodiment 1 The second mixed liquor be heated to 60-65 DEG C after stop heat and keep the temperature, nitrocellulose filter, which is divided submergence, is placed in the second mixing In liquid, 50-55min is impregnated, takes out and is placed on 35-40s in 0 DEG C of environment, it is dry.
Concentration of emission is tested
Test sample:Using embodiment 1-5 as test sample, with comparative example 1-20 samples as a contrast.
Test method:25 municipal wastewater ponds are chosen, respectively number 1-25, being put in each cesspool has 200m3 municipal Sewage, water temperature is 12 DEG C, and the COD of municipal wastewaterCrFor 495mg/L, BOD5For 203mg/L, SS 232mg/L, vegetable and animals oils A concentration of 113mg/L, wherein 1-5 cesspools use interior embodiment 1-5 processing, and 6-25 cesspools then use comparative example 1-20 processing.
CODCrIt is measured using dichromate titration;
BOD5It is measured using dilution and inocalation method [GB7488-87];
SS, heavy metal concentration, excrement colibacillus group number are measured using GB18918-2002;
PH value detection is carried out to embodiment 1-5, comparative example 1-20 treated municipal wastewater.
Test result:BOD, COD, SS, heavy metal concentration, excrement colibacillus group number are as shown in table 5 in embodiment 1-5;Comparison BOD, COD, SS, heavy metal concentration, excrement colibacillus group number are as shown in table 6 in example 1-20.
BOD, COD, SS, heavy metal concentration, excrement colibacillus group number in 5 embodiment 1-5 of table
BOD, COD, SS, heavy metal concentration, excrement colibacillus group number in 6 comparative example 1-20 of table
By table 5 and table 6 it is found that the pH value through embodiment 1-5 treated municipal wastewaters is in the range of 6.8-7.5, and The pH value of example 1-20 treated municipal wastewaters is between 5.5-6.5 by contrast, overall meta-acid.By table 5 and table 6 it is found that through reality It applies a 1-5 treated in municipal wastewater, BOD, COD, SS, heavy metal concentration, excrement colibacillus group number are discharged in level-one water and marked Within the scope of standard, the requirement of drinking water is reached.And it can not reach simultaneously in example 1-20 treated municipal wastewaters by contrast BOD, COD, SS, heavy metal concentration, excrement colibacillus group number reach while standard compliant situation, and content of beary metal therein with And excrement colibacillus group number is exceeded, cannot meet the requirement of drinking water.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of municipal wastewater construction technology, which is characterized in that include the following steps:
S1, municipal wastewater remove large-sized sundries by grid etc., obtain just treated sewage;
S2 is added Fenton reagent in the first treated sewage obtained to step S1, is uniformly mixed, and reaction is filtered for the first time, obtains the One filtrate;
S3 is passed through ozone into the first filtrate of step S2 acquisitions, adds compound silica gel, fully reacts, and second of filtering obtains Obtain the second filtrate;
S4 is added sodium carbonate or sodium bicarbonate into the second filtrate of step S3 acquisitions, is uniformly mixed, and third time obtains after filtering Third filtrate;
The third filtrate obtained in step S4 is carried out compound film process, obtains drinking water by S5;
The composite membrane includes the component of following parts by weight:
35-50 parts of nitrocellulose filter;
12-15 parts of Nanocrystalline Cellulose Colloid;
3-6 parts of nano-titanium dioxide.
2. municipal wastewater construction technology according to claim 1, which is characterized in that the preparation method of the composite membrane includes Following steps:
The nano-titanium dioxide of corresponding parts by weight, Nanocrystalline Cellulose Colloid are sufficiently mixed by step 1, and it is mixed to form second Close liquid;
Step 2 stops heating and keeping the temperature after the second mixed liquor obtained in step 1 is heated to 45-50 DEG C, by cellulose nitrate Plain film is divided submergence and is placed in the second mixed liquor, and 30-45min is impregnated, and takes out and is placed on 20-33s in 0 DEG C of environment, dry.
3. municipal wastewater construction technology according to claim 1, which is characterized in that nano microcrystalline fiber in the composite membrane The grain size of element is 50-100nm.
4. municipal wastewater construction technology according to claim 1, which is characterized in that in the Nanocrystalline Cellulose Colloid Nano micro crystal cellulose containing 0.1-0.2wt%.
5. municipal wastewater construction technology according to claim 1, which is characterized in that the compound silica gel includes following weight The component of number:
66-71 parts of Bio-sil;
5-8 parts of nano silicon dioxide;
1-5 parts of ethylenediamine tetra-acetic acid;
2-3 parts of calcium acetate;
2-5 parts of hydroxyethyl ethylenediamine;
5-10 parts of water.
6. municipal wastewater construction technology according to claim 4, which is characterized in that the system of compound silica gel in the step S3 Preparation Method includes the following steps:
The nano silicon dioxide of corresponding parts by weight, ethylenediamine tetra-acetic acid, calcium acetate, hydroxyethyl ethylenediamine are added together to phase It in the water for answering parts by weight, is uniformly mixed, forms the first mixed liquor;
The Bio-sil of corresponding parts by weight is added to step(1)In first mixed liquor of middle acquisition, ultrasonication 5- 10min is spontaneously dried, and is made.
CN201810285490.2A 2018-04-02 2018-04-02 Municipal wastewater construction technology Pending CN108503079A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810285490.2A CN108503079A (en) 2018-04-02 2018-04-02 Municipal wastewater construction technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810285490.2A CN108503079A (en) 2018-04-02 2018-04-02 Municipal wastewater construction technology

Publications (1)

Publication Number Publication Date
CN108503079A true CN108503079A (en) 2018-09-07

Family

ID=63379688

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810285490.2A Pending CN108503079A (en) 2018-04-02 2018-04-02 Municipal wastewater construction technology

Country Status (1)

Country Link
CN (1) CN108503079A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3013905A1 (en) * 1980-04-11 1981-08-20 Gkss - Forschungszentrum Geesthacht Gmbh, 2000 Hamburg CATALYST AND METHOD FOR THE OZONE OF WASTEWATER WITH ORGANIC IMPURITIES
US20110226699A1 (en) * 2010-03-22 2011-09-22 Edward Rosenberg Nanoporous Silica Polyamine Composites with Surface-Bound Zirconium (IV) and Methods of Use
CN103990452A (en) * 2014-06-06 2014-08-20 江苏南大环保科技有限公司 Catalyst and catalyst carrier for deep treatment of waste water and preparation methods of catalyst and catalyst carrier
CN104437546A (en) * 2014-12-09 2015-03-25 易志坚 Non-homogeneous phase ozone catalyst and preparation method thereof
CN105923737A (en) * 2016-06-17 2016-09-07 东莞道汇环保科技有限公司 Method for treating waste water by using advanced oxidation technology
CN107098537A (en) * 2017-04-25 2017-08-29 杭州之江市政建设有限公司 Municipal wastewater handling process
CN107651794A (en) * 2016-07-26 2018-02-02 中国科学院过程工程研究所 A kind of processing system and processing method of industrial wastewater bio-chemical effluent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3013905A1 (en) * 1980-04-11 1981-08-20 Gkss - Forschungszentrum Geesthacht Gmbh, 2000 Hamburg CATALYST AND METHOD FOR THE OZONE OF WASTEWATER WITH ORGANIC IMPURITIES
US20110226699A1 (en) * 2010-03-22 2011-09-22 Edward Rosenberg Nanoporous Silica Polyamine Composites with Surface-Bound Zirconium (IV) and Methods of Use
CN103990452A (en) * 2014-06-06 2014-08-20 江苏南大环保科技有限公司 Catalyst and catalyst carrier for deep treatment of waste water and preparation methods of catalyst and catalyst carrier
CN104437546A (en) * 2014-12-09 2015-03-25 易志坚 Non-homogeneous phase ozone catalyst and preparation method thereof
CN105923737A (en) * 2016-06-17 2016-09-07 东莞道汇环保科技有限公司 Method for treating waste water by using advanced oxidation technology
CN107651794A (en) * 2016-07-26 2018-02-02 中国科学院过程工程研究所 A kind of processing system and processing method of industrial wastewater bio-chemical effluent
CN107098537A (en) * 2017-04-25 2017-08-29 杭州之江市政建设有限公司 Municipal wastewater handling process

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
刘方: "改性CA和PA膜的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *
贾红兵等: "《高分子材料》", 30 November 2009 *
陈红莲等: "纳米纤维素晶体的制备及其在聚合物中应用的研究进展", 《热带作物学报》 *

Similar Documents

Publication Publication Date Title
Dharupaneedi et al. Membrane-based separation of potential emerging pollutants
Goswami et al. Membrane bioreactor and integrated membrane bioreactor systems for micropollutant removal from wastewater: A review
CN202322568U (en) Deep treatment system of high-concentration percolate of integrated garbage treatment site
CN109592840A (en) A kind of School Wastewater processing unit
CN103523971B (en) Combined treatment method and combined treatment system for offshore platform domestic sewage
CN101337752A (en) Advanced treatment process for paper-making waste water
CN104591443A (en) Circular treatment equipment for aquiculture agricultural waste water
CN107098537A (en) Municipal wastewater handling process
CN106946407A (en) A kind of process for reclaiming of crushed coal pressure gasifying wastewater biochemical water outlet
CN1478737A (en) Garbage percolation liquid treatment process
CN109133524A (en) The processing system and processing method of high COD medicine intermediate wastewater from chemical industry with high salt
Fazal et al. Membrane separation technology on pharmaceutical wastewater by using MBR (Membrane Bioreactor)
CN102086079B (en) Domestic sewage zero emission treatment method and system
CN107500442A (en) Integrated treatment method and device for micro-polluted source water
CN205603429U (en) Micro -polluted water source water purification system
Yekani et al. Design and annual operation of full scale landfill leachate plant in Iran: focus on multistage membrane technology
CN110104887A (en) Positive infiltration domestic sewage treatment device and processing method
CN208471830U (en) A kind of wastewater ocean disposal device
CN108503079A (en) Municipal wastewater construction technology
CN205907145U (en) Production domestic sewage zero release processing system
CN205974171U (en) Device for treating printing and dyeing wastewater
CN1344690A (en) Water treating method and treater for producing pure health water
CN212403883U (en) Wastewater treatment equipment
CN209890463U (en) Intelligent modularized integrated sewage treatment system
CN107721086A (en) A kind of gallic acid wastewater treatment equipment and its technique

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned

Effective date of abandoning: 20210330

AD01 Patent right deemed abandoned