CN108493265A - A kind of back electrode halftone and dereliction grid solar cell piece - Google Patents

A kind of back electrode halftone and dereliction grid solar cell piece Download PDF

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Publication number
CN108493265A
CN108493265A CN201810232993.3A CN201810232993A CN108493265A CN 108493265 A CN108493265 A CN 108493265A CN 201810232993 A CN201810232993 A CN 201810232993A CN 108493265 A CN108493265 A CN 108493265A
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CN
China
Prior art keywords
back electrode
printing
area
solar cell
electrode
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Pending
Application number
CN201810232993.3A
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Chinese (zh)
Inventor
张治�
卢刚
何凤琴
钱俊
杨振英
郑璐
杨勇洲
张敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huanghe Water Electric Light Volt Industrial Technology Co Ltd
Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd
Original Assignee
Huanghe Water Electric Light Volt Industrial Technology Co Ltd
Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd
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Application filed by Huanghe Water Electric Light Volt Industrial Technology Co Ltd, Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd filed Critical Huanghe Water Electric Light Volt Industrial Technology Co Ltd
Priority to CN201810232993.3A priority Critical patent/CN108493265A/en
Publication of CN108493265A publication Critical patent/CN108493265A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/022441Electrode arrangements specially adapted for back-contact solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention discloses a kind of back electrode halftones, including multiple Printing Zones for being used to prepare back electrode.Multiple Printing Zones are mutually parallel, and the Printing Zone is divided into the printing segmentation of multiple spaced settings, and the printing is divided into the region of more than two and spaced setting.The invention also discloses a kind of dereliction grid solar cell piece, including substrate, the front electrode without main grid being set on the substrate front and the multiple back electrodes being set on substrate back.Multiple back electrodes are mutually parallel, and the back electrode is divided into the back electrode segmentation of multiple spaced settings, and back electrode is divided into the region of more than two and spaced setting.Back electrode made from the back electrode and back electrode halftone of above-mentioned dereliction grid solar cell piece, the pattern that can be formed with front electrode match, and facilitate encapsulation.Moreover, the back electrode saves a large amount of electrode slurry compared to conventional back electrode, production cost is substantially had compressed.

Description

A kind of back electrode halftone and dereliction grid solar cell piece
Technical field
The present invention relates to photovoltaic solar cell technical field, especially a kind of back electrode halftone and dereliction grid solar electricity Pond piece.
Background technology
With the continuous innovation and development of photovoltaic technology, in order to improve efficiency and reduce cost, some new structural light Volt solar cell also comes into being, and how using simpler processing step and lower to be manufactured into original higher of developing and turns The photovoltaic solar cell for changing efficiency is the key that photovoltaic technology progress and innovation.
Dereliction grid solar cell is a kind of novel photovoltaic solar cell, by removing its solar battery sheet just The main gate line in face substitutes main gate line using thin grid line, makes the front of solar battery sheet that more secondary grid lines be used only, and with pole Thin welding is directly welded with secondary bonding wire, and dereliction grid solar cell reduces the light that positive grid line blocks, and increases The light-receiving area of solar battery sheet improves the photoelectric conversion efficiency of solar cell, increases the power of solar cell. But the back electrode figure of dereliction grid solar cell piece can not match with the figure of front electrode, when encapsulation too without main grid Back electrode and front electrode between positive energy cell piece can not be connected matchingly, and print the back of the body of dereliction grid solar cell piece Electrode needs the electrode slurry consumed larger, and the production cost of the dereliction grid solar cell is relatively high.
Invention content
In view of this, the purpose of the present invention is to provide a kind of back electrode halftone and dereliction grid solar cell pieces, to solve The certainly above problem.
In order to achieve the above purpose, present invention employs the following technical solutions:
A kind of back electrode halftone, including multiple Printing Zones for being used to prepare back electrode, multiple Printing Zones are mutually parallel, Along the length direction of the Printing Zone, the Printing Zone is divided into the printing segmentation of multiple spaced settings, and the print Brush is divided into the region of more than two and spaced setting.
Preferably, it is described printing segmentation include the spaced setting along the length direction of the Printing Zone the firstth area, Secondth area and third area.
Preferably, in the orientation of multiple Printing Zones, firstth area, the secondth area and third area length phase Deng.
Preferably, along the length direction of the Printing Zone, firstth area, the secondth area and third area length ratio It is 1:2:1.
Preferably, multiple printing segmentation arrangement forms have the matrix of 5~15 rows and 15 row.
A kind of dereliction grid solar cell piece, including substrate, be set on the substrate front without main grid front electricity Pole and the multiple back electrodes being set on the substrate back, multiple back electrodes are mutually parallel, along the length of the back electrode It spends on direction, the back electrode is divided into the back electrode segmentation of multiple spaced settings, and the back electrode is divided into two The part of a above and spaced setting.
Preferably, the back electrode segmentation includes first of the spaced setting along the length direction of the back electrode Portion, second and third portion.
Preferably, in the orientation of multiple back electrodes, the length phase in described first, second and third portion Deng.
Preferably, along the length direction of the back electrode, the ratio of the length in described first, second and third portion It is 1:2:1.
Preferably, multiple back electrode segmentation arrangement forms have the matrix of 5~15 rows and 15 row.
Back electrode made from the back electrode and back electrode halftone of dereliction grid solar cell piece provided by the invention, is equivalent to With the design of segmented instead of unremitting complete back electrode in conventional dereliction grid solar cell piece so that back electrode is formed Pattern can with front electrode formed pattern match, facilitate encapsulation;On the other hand, it can carry out stablizing welding with welding Under the premise of, compared to the complete back electrode in conventional dereliction grid solar cell piece, the back electrode saves a large amount of electrode slurries Material, substantially has compressed production cost.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of back electrode halftone provided in an embodiment of the present invention;
Fig. 2 is the enlarged diagram of the circular dashed line frame region A in Fig. 1;
Fig. 3 is a kind of structural schematic diagram at the back side of dereliction grid solar cell piece provided in an embodiment of the present invention;
Fig. 4 is the enlarged diagram of the circular dashed line frame region B in Fig. 3.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the accompanying drawings to the specific reality of the present invention The mode of applying is described in detail.The example of these preferred embodiments is illustrated in the accompanying drawings.Shown in attached drawing and according to The embodiments of the present invention of attached drawing description are only exemplary, and the present invention is not limited to these embodiments.
Here, it should also be noted that, in order to avoid having obscured the present invention because of unnecessary details, in the accompanying drawings only Show the structure and/or processing step closely related with scheme according to the present invention, and be omitted relationship it is little other are thin Section.
Refering to fig. 1 with shown in Fig. 2, present embodiments provide a kind of back electrode halftone, including multiple be used to prepare back electrode Printing Zone 1.Multiple Printing Zones 1 are mutually parallel.Along the length direction of the Printing Zone 1, the Printing Zone 1 is divided into The printing segmentation 11 of multiple spaced settings, and area of 11 points of the printing segmentation for more than two and spaced setting Domain.
The Printing Zone 1 of above-mentioned back electrode halftone is divided into the printing segmentation 11 of multiple spaced settings, the printing point Section 11 is divided into as more than two regions, and the pattern for printing back electrode formation obtained can tune to and dereliction grid solar electricity The pattern of the front electrode of pond piece matches, when being packaged, between adjacent dereliction grid solar cell piece, back electrode and Front electrode can be correspondingly connected;On the other hand, back electrode made from the back electrode halftone is equivalent to intermittent back electrode Instead of unremitting complete back electrode in the prior art, compared with the prior art in common dereliction grid solar cell the back of the body Back electrode made from electrode halftone needs the electrode slurry consumed the i.e. amount of silver paste relatively fewer, significantly reduces and be produced into This.
Further, the printing segmentation 11 includes the of the spaced setting along the length direction of the Printing Zone 1 One area 111, the second area 112 and third area 113.Back electrode area made from firstth area 111, the second area 112 and third area 113 Domain is connect with same welding respectively, and secondth area 112 is located at the center in firstth area 111 and third area 113, and described second The contact area of back electrode region and welding made from area 112 is relatively large, can keep being stably connected with welding.
Specifically, in the orientation of the Printing Zone 1, firstth area 111, the second area 112 and third area 113 Equal length.In the present embodiment, in the orientation of the Printing Zone 1, firstth area 111, the second area 112 and third The length D1 in area 113 is 0.8mm.
Specifically, along the length direction of the Printing Zone 1, firstth area 111, the second area 112 and third area 113 The ratio of length is 1:2:1.In the present embodiment, along the length direction of the Printing Zone 1, the length in firstth area 111 L1 is 0.5mm, and the length L2 in secondth area 112 is 1mm, and the length L3 in the third area 113 is 0.5mm, firstth area 111 and the second interval L4 between area 112 is 0.5mm, and the interval L5 between secondth area 112 and third area 113 is 0.5mm。
In the present embodiment, 11 arrangement forms of multiple printing segmentations have the matrix of 5~15 rows and 15 row.The back of the body The pattern that the back electrode of electrode screen painting is formed, can be electric with the dereliction grid solar that substitutes 3 main gate lines with 15 thin grid line The front electrode pattern in pond matches.
With it is the multiple printing be segmented 11 arrangement forms have 10 rows and 15 row matrix calculate, it is provided in this embodiment on The gross area for stating back electrode made from back electrode halftone is:(0.5mm+1mm+0.5mm) × 0.8mm × 15 × 10=240mm2; And be about 21mm, width 3mm with the back electrode of three conventional main grid solar cells length, multiple rear electrode arrangements form 3 rows 3 The matrix of row is calculated, and the gross area of back electrode is 21mm × 3mm × 9=567mm2, therefore it is provided in this embodiment above-mentioned The ratio that back electrode area made from back electrode halftone accounts for about the back electrode area of three conventional main grid solar cells is: (567-240) ÷ 567=57.7%, i.e., back electrode made from above-mentioned back electrode halftone provided in this embodiment can be saved about 57.7% electrode slurry substantially has compressed the production cost of solar cell.
In conjunction with shown in Fig. 3 and Fig. 4, a kind of dereliction grid solar cell piece, including substrate 2, setting are present embodiments provided In without main grid on 2 front of the substrate front electrode and multiple back electrodes 3 for being set on 2 back side of the substrate.It is multiple The back electrode 3 is mutually parallel.Along the length direction of the back electrode 3, the back electrode 3 is divided into multiple spaced set The back electrode segmentation 31 set, and the back electrode is segmented 31 points of parts for more than two and spaced setting.Wherein, described Substrate 2 includes with silicon substrate made of silicon chip.
Similarly, in above-mentioned dereliction grid solar cell piece, the back electrode 3 is divided into the back of the body of multiple spaced settings Electrode segment 31, back electrode segmentation 31 are divided into as more than two parts, the pattern that the back electrode 3 is formed can with it is described The pattern of the front electrode of dereliction grid solar cell piece matches, when being packaged, adjacent dereliction grid solar cell Between piece, back electrode 3 and front electrode can be correspondingly connected;On the other hand, the dereliction grid solar cell piece be equivalent to Intermittent back electrode 3 instead of complete back electrode, compared with the prior art in common dereliction grid solar cell piece, need The amount of the electrode slurry of consumption is relatively small, significantly reduces production cost.
Further, the back electrode segmentation 31 includes the spaced setting along the length direction of the back electrode 3 First 311, second 312 and third portion 313.
Specifically, in the orientation of the back electrode 3, described first 311, second 312 and third portion 313 Equal length.In the present embodiment, in the orientation of the back electrode 3, described first 311, second 312 and third The length W1 in portion 313 is 0.8mm.
Specifically, along the length direction of the back electrode 3, described first 311, second 312 and third portion 313 The ratio of length is 1:2:1.In the present embodiment, along the length direction of the back electrode 3, first 311 length S1 is 0.5mm, and described second 312 length S2 is 1mm, and the length S3 in the third portion 313 is 0.5mm, described first Interval S4 between 311 and second 312 is 0.5mm, and the described second 312 interval S5 between third portion 313 is 0.5mm。
In the present embodiment, multiple back electrodes, which are segmented 31 arrangement forms, has the matrix of 5~15 rows and 15 row.This reality In the dereliction grid solar cell for applying example offer, the pattern that back electrode is formed can substitute 3 masters with 15 thin grid line The pattern that the front electrode of grid line is formed matches.
The present embodiment additionally provides a kind of preparation method of above-mentioned dereliction grid solar cell piece, and the preparation method includes Following steps:
Step 1: providing a silicon chip, the silicon chip is handled using conventional cleaning and process for etching;
In the step 1, the silicon chip is monocrystalline silicon piece, and resistivity is 1~3Ohmcm, and matte is controlled in 2 μ m-4μm。
Step 2: carrying out High temperature diffusion processing to the silicon chip, P-doped zone and N is made in the specified region on silicon chip Type doped region;
In the step 2, square resistance control is 82 Ω or so.
Step 3: carrying out wet etching treatment to the silicon chip, the PN junction of the silicon chip edge is removed;
Step 4: using PECVD device, positive table of the chemical vapour deposition process of using plasma enhancing in the silicon chip The preparation of antireflective film is carried out on face;
In the step 4, the antireflective film is SiNx film layers, and the film thickness monitoring of the antireflective film is in 72nm or so.
Step 5: conventional back electrode halftone is changed to above-mentioned back electrode halftone provided in this embodiment, in the silicon Back electrode 3 is printed on the doped region at the piece back side;
In the step 5, printed using conventional printing slurry and with conventional printing parameter, the printing Slurry is silver paste.
Step 6: being printed using with 3 matched back of the body electric field halftone of the back electrode;
Step 7: using the corresponding halftone of front electrode of dereliction grid solar cell piece, in mixing for the front side of silicon wafer Front electrode is printed in miscellaneous area;
In the step 7, printed using conventional printing slurry and with conventional printing parameter.
Step 8: being sintered to the front electrode and back electrode 3.
In the step 8, it is sintered with normal sintering parameter.
In conclusion the back electrode 3 and back electrode halftone system of above-mentioned dereliction grid solar cell piece provided in this embodiment The back electrode obtained is equivalent to the design of segmented instead of unremitting complete back of the body electricity in conventional dereliction grid solar cell piece Pole so that the pattern that the pattern that back electrode 3 is formed can be formed with front electrode match, and facilitate encapsulation, another aspect, can be with Welding carries out under the premise of stablizing welding, compared to the complete back electrode in conventional dereliction grid solar cell piece, the back of the body electricity Pole 3 saves a large amount of electrode slurrys, substantially has compressed production cost.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
The above is only the specific implementation mode of the application, it is noted that for the ordinary skill people of the art For member, under the premise of not departing from the application principle, several improvements and modifications can also be made, these improvements and modifications are also answered It is considered as the protection domain of the application.

Claims (10)

1. a kind of back electrode halftone, which is characterized in that including multiple Printing Zones (1) for being used to prepare back electrode, multiple prints Brush area (1) is mutually parallel, and along the length direction of the Printing Zone (1), the Printing Zone (1) is divided into multiple spaced set The printing segmentation (11) set, and the printing segmentation (11) is divided into the region of more than two and spaced setting.
2. back electrode halftone according to claim 1, which is characterized in that the printing segmentation (11) includes along the printing The firstth area (111), the secondth area (112) and third area (113) of spaced setting on the length direction in area (1).
3. back electrode halftone according to claim 2, which is characterized in that along the orientation of multiple Printing Zones (1) On, firstth area (111), the secondth area (112) and third area (113) equal length.
4. back electrode halftone according to claim 2, which is characterized in that along the length direction of the Printing Zone (1), institute The ratio for stating the length in the firstth area (111), the secondth area (112) and third area (113) is 1:2:1.
5. back electrode halftone according to claim 1, which is characterized in that multiple printing segmentation (11) arrangement form tools There is the matrix of 5~15 rows and 15 row.
6. a kind of dereliction grid solar cell piece, which is characterized in that including substrate (2), be set on the substrate (2) front The front electrode of no main grid and the multiple back electrodes (3) being set on the substrate (2) back side, multiple back electrode (3) phases Mutually parallel, along the length direction of the back electrode (3), the back electrode (3) is divided into the back of the body electricity of multiple spaced settings Pole is segmented (31), and back electrode segmentation (31) is divided into the part of more than two and spaced setting.
7. dereliction grid solar cell piece according to claim 6, which is characterized in that the back electrode is segmented (31) and includes First (311), second (312) and third portion of spaced setting along the length direction of the back electrode (3) (313)。
8. dereliction grid solar cell piece according to claim 7, which is characterized in that along multiple back electrodes (3) In orientation, the equal length of first (311), second (312) and third portion (313).
9. dereliction grid solar cell piece according to claim 7, which is characterized in that the length along the back electrode (3) On direction, the ratio of the length of first (311), second (312) and third portion (313) is 1:2:1.
10. dereliction grid solar cell piece according to claim 6, which is characterized in that multiple back electrode segmentations (31) arrangement form has the matrix of 5~15 rows and 15 row.
CN201810232993.3A 2018-03-21 2018-03-21 A kind of back electrode halftone and dereliction grid solar cell piece Pending CN108493265A (en)

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Citations (5)

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Publication number Priority date Publication date Assignee Title
CN202934909U (en) * 2012-12-05 2013-05-15 江苏中宇光伏科技有限公司 Sectional type back-electrode screen printing plate
CN104129183A (en) * 2014-08-06 2014-11-05 中利腾晖光伏科技有限公司 Method of printing obverse-side electrode of solar battery piece
CN205881916U (en) * 2016-07-21 2017-01-11 内蒙古日月太阳能科技有限责任公司 Two -sided electricity generation solar battery of five main grid N types
CN206412372U (en) * 2016-12-23 2017-08-15 泰州乐叶光伏科技有限公司 Interconnection structure and solar energy laminated batteries between a kind of solar energy laminated batteries piece
CN208000922U (en) * 2018-03-21 2018-10-23 青海黄河上游水电开发有限责任公司光伏产业技术分公司 A kind of back electrode halftone and dereliction grid solar cell piece

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Publication number Priority date Publication date Assignee Title
CN202934909U (en) * 2012-12-05 2013-05-15 江苏中宇光伏科技有限公司 Sectional type back-electrode screen printing plate
CN104129183A (en) * 2014-08-06 2014-11-05 中利腾晖光伏科技有限公司 Method of printing obverse-side electrode of solar battery piece
CN205881916U (en) * 2016-07-21 2017-01-11 内蒙古日月太阳能科技有限责任公司 Two -sided electricity generation solar battery of five main grid N types
CN206412372U (en) * 2016-12-23 2017-08-15 泰州乐叶光伏科技有限公司 Interconnection structure and solar energy laminated batteries between a kind of solar energy laminated batteries piece
CN208000922U (en) * 2018-03-21 2018-10-23 青海黄河上游水电开发有限责任公司光伏产业技术分公司 A kind of back electrode halftone and dereliction grid solar cell piece

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