CN108485541A - A kind of decorative wall paper stickup environmentally friendly corrosion resistant adhesive and preparation method thereof - Google Patents
A kind of decorative wall paper stickup environmentally friendly corrosion resistant adhesive and preparation method thereof Download PDFInfo
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- CN108485541A CN108485541A CN201810417929.2A CN201810417929A CN108485541A CN 108485541 A CN108485541 A CN 108485541A CN 201810417929 A CN201810417929 A CN 201810417929A CN 108485541 A CN108485541 A CN 108485541A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
It is pasted the invention discloses a kind of decorative wall paper and uses environmentally friendly corrosion resistant adhesive and preparation method thereof, be related to field of adhesive technology, which includes following raw material by weight:Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N n-butoxy methyl acrylamides, glycidyl methacrylate, isoprene styrene body, crosslinking agent, coupling agent, accelerating agent, antioxidant, fibrous plaster, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite.Preparation method is obtained by the mixing reaction to raw material.The adhesive of the present invention prepares simple and convenient, environment friendly corrosion protection, high comprehensive performance, solves the problems, such as that wallpaper occurs that the quality such as jaundice, blackening, drum, alice are bad, and applicable field and occasion are extensive in the prior art.
Description
Technical field
The present invention relates to field of adhesive technology, and in particular to a kind of decorative wall paper paste with environmentally friendly corrosion resistant adhesive and its
Preparation method.
Background technology
Wallpaper needs to paste wallpaper on metope using adhesive in decoration process, and the paving effect of wallpaper is also whole
The embodiment of a finishing effect, clings the basic function that wallpaper is wallpaper adhesive for a long time.
Interior decoration wallpaper adhesive can be divided into following two at present;
(1) non-environmental protection type wallpaper adhesive:Phenolic resin, Lauxite, Pioloform, polyvinyl acetal have been used in raw material mostly
Equal ingredients, thus obtained adhesive always carries remaining free formaldehyde, and formaldehyde is a kind of poisonous and hazardous substance, it can make
At serious air pollution, great injury is brought to human body;
(2) environment-friendly type wallpaper adhesive:Mostly using starch, potato powder, glutinous rice flour as the grain system of raw material, this kind of grain in raw material
It is that adhesive is although formaldehydeless, it is more environmentally friendly, but cementability is poor, it is easy to make moist, mouldy corruption, influences the paving effect of wallpaper
Fruit leads to its jaundice, blackening, plays drum, alice, or even pierces because of corruption, and service life is short, and application prospect is not fine.
Invention content
For problems of the prior art, the present invention provides a kind of decorative wall papers to paste with environmentally friendly corrosion resistant adhesive
And preparation method thereof, this kind of adhesive prepares simple and convenient, environment friendly corrosion protection, high comprehensive performance.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of decorative wall paper stickup environmentally friendly corrosion resistant adhesive, including two kinds of components of following A, B:
Component A includes following raw material by weight:10-15 parts of Chinese yam rhizome slurries, 12-16 parts of vinylacetate, pine
Set 8-12 parts of slurries, 10-20 parts of polyvinyl alcohol, 3-5 parts of hydrogenated rosin, 0.4-0.6 parts of N- n-butoxy methyl acrylamides, first
0.6-1 parts of base glycidyl acrylate, isoprene -2-3 parts of styrene body, 1.5-2.5 parts of crosslinking agent, idol
Join 1-1.5 parts of 2-3 parts of agent, 1-2 parts of accelerating agent and antioxidant;
B component includes following raw material by weight:3-5 parts of fibrous plaster, 2-3 parts of chlorite of expansion, Tengchong In Yunnan Province
1-2 parts of 4-6 parts of volcanic ash and palygorskite;
Above-mentioned crosslinking agent is using any one of polyethylene glycol, polypropylene glycol or trimethylolpropane;
Above-mentioned coupling agent uses silane coupling agent or aluminate coupling agent;
Above-mentioned accelerating agent uses Vulcanization accelerator TMTD or diphenylguanidine PTT;
Above-mentioned antioxidant is using antioxidant 1010 or the composition of irgasfos 168 and tert-butyl hydroquinone;
Further, above-mentioned component A includes following raw material by weight:12 parts of Chinese yam rhizome slurries, vinylacetate
14 parts, 10 parts of pine tree slurries, 15 parts of polyvinyl alcohol, 4 parts of hydrogenated rosin, 0.5 part of N- n-butoxy methyl acrylamides, methyl-prop
0.8 part of olefin(e) acid ethylene oxidic ester, isoprene -2.5 parts of styrene body, 2.5 parts of coupling agent, promote 2 parts of crosslinking agent
Into 1.2 parts of 1.5 parts of agent and antioxidant;
B component includes following raw material by weight:4 parts of fibrous plaster, 2.5 parts of chlorite of expansion, Tengchong In Yunnan Province fire
1.5 parts of 5 parts of mountain ash and palygorskite.
Preferably, above-mentioned crosslinking agent uses trimethylolpropane.
Preferably, above-mentioned coupling agent uses anti-settling aluminate coupling agent ASA.
Preferably, above-mentioned accelerating agent uses diphenylguanidine PTT.
Preferably, above-mentioned antioxidant uses the composition of irgasfos 168 and tert-butyl hydroquinone.
Further, above-mentioned antioxidant is irgasfos 168, tert-butyl hydroquinone in mass ratio 1:1 or 2:1 composition mixes
Close object.
A kind of above-mentioned decorative wall paper pastes the preparation method with environmentally friendly corrosion resistant adhesive, follows the steps below:
(1) raw material is weighed by above-mentioned weight;
(2) it is 10-15 microns fibrous plaster, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite to be milled to fineness,
Dry 1.5-2h under the conditions of temperature is 70-80 DEG C again, obtains inorganic powder;
(3) by Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N- n-butoxy methyl
Acrylamide, isoprene-styrene body and accelerating agent are added in reaction kettle, are 0.01- in vacuum degree
It is heated to 85-95 DEG C under conditions of 0.02MPa, 20-30min is mixed;
(4) inorganic powder, glycidyl methacrylate and coupling agent are added in reaction kettle, are in vacuum degree
It is heated to 95-105 DEG C under conditions of 0.01-0.02MPa, 30-40min is mixed;
(5) remaining other raw materials are added in reaction kettle, are heated under conditions of vacuum degree is 0.01-0.02MPa
92-96 DEG C, 10-15min is mixed.
The present invention has following advantageous effect:
(1) adhesive of the invention is prepared simple and convenient, and production efficiency is high, low raw-material cost, compatibility performance between raw material
Good, easy to use, smearable facade does not trickle;In process of manufacture, no discharge, pollution-free, have no irritating odor generation, at
Product adhesive is environmentally protective, and stability is good, easily stores;
(2) adhesive of the invention is by the selection processing and the improvement of technique to production and processing raw material, make it is obtained at
The crosslinking of macromolecular framework tissue is fine and close inside product adhesive, and structural stability can is good, is not easy to shrink, and adhesive property is strong, tack
Can be good, after realizing wallpaper bonding solidification, can have good quality and elastic property, feel is all good, in conjunction in adhesive linkage
A large amount of fine foaming that portion is evenly distributed with are closed micropore, can effectively improve the heat preservation and soundproof and electromagnetic screen of decorative wall paper
Covering property, has achieved the purpose that noise-reduction energy-saving, has effectively completely cut off outdoor environment to indoor interference and influence;
(3) the colloform texture tensile strength after adhesive of the invention solidification is big, and physicochemical property is stablized excellent, has following
Characteristic:High temperature resistant can inhibit the burning of wallpaper, flame retardant property good;Moisture absorption is freeze proof, can absorb and be mingled with pernicious gas in air
(such as:Formaldehyde), the moisture of dust etc., purify the air of a room quality, and moisture evaporation speed is fast, not will produce mouldy, the tool that makes moist
There is the good mould antibacterial insect resistance of suppression;The chemical compositions such as acidproof alkali salt are corroded, weather-proof anti-aging, resistance to radiation, service life
Long, using effect is good, solves the problems, such as that it is bad the quality such as jaundice, blackening, drum, alice occur for wallpaper in the prior art, can
The field of application and occasion are extensive.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of environmentally friendly corrosion resistant adhesive of decorative wall paper stickup, weighs two kinds of component raw materials of following A, B:
Component A:Chinese yam rhizome slurries 10kg, vinylacetate 12kg, pine tree slurries 8kg, polyvinyl alcohol 10kg, hydrogenated rosin
3kg, N- n-butoxy methyl acrylamide 0.4kg, glycidyl methacrylate 0.6kg, isoprene-styrene are embedding
Section copolymer 2kg, crosslinking agent 1.5kg, coupling agent 2kg, accelerating agent 1kg and antioxidant 1kg;
B component:Fibrous plaster 3kg, expansion chlorite 2kg, Tengchong In Yunnan Province volcanic ash 4kg and palygorskite 1kg;
The selection of above-mentioned auxiliary agent see the table below shown in 1:
Table 1
Above-mentioned decorative wall paper is pasted as follows with the preparation method of environmentally friendly corrosion resistant adhesive:
(1) first the above-mentioned fibrous plaster weighed, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite are milled to
Fineness is 10 microns, then dry 2h under the conditions of temperature is 70 DEG C, obtains inorganic powder;
(2) again by Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N- n-butoxy first
Base acrylamide, isoprene-styrene body and accelerating agent are added in reaction kettle, are in vacuum degree
It is heated to 85 DEG C under conditions of 0.01MPa, 30min is mixed;
(3) inorganic powder, glycidyl methacrylate and coupling agent are added in reaction kettle after, in vacuum degree
To be heated to 95 DEG C under conditions of 0.01MPa, 30min is mixed;
(4) finally remaining other raw materials are added in reaction kettle, 92 is heated under conditions of vacuum degree is 0.01MPa
DEG C, 15min is mixed.
Embodiment 2
A kind of environmentally friendly corrosion resistant adhesive of decorative wall paper stickup, weighs two kinds of component raw materials of following A, B:
Component A:Chinese yam rhizome slurries 12kg, vinylacetate 14kg, pine tree slurries 10kg, polyvinyl alcohol 15kg, hydrogenation pine
Fragrant 4kg, N- n-butoxy methyl acrylamide 0.5kg, glycidyl methacrylate 0.8kg, isoprene-styrene
Block interpolymers 2.5kg, crosslinking agent 2kg, coupling agent 2.5kg, accelerating agent 1.5kg and antioxidant 1.2kg;
B component:Fibrous plaster 4kg, expansion chlorite 2.5kg, Tengchong In Yunnan Province volcanic ash 5kg and palygorskite 1.5kg;
The selection of above-mentioned auxiliary agent see the table below shown in 2:
Table 2
Serial number | Component | Ingredient |
1 | Crosslinking agent | Trimethylolpropane |
2 | Coupling agent | Anti-settling aluminate coupling agent ASA |
3 | Accelerating agent | Diphenylguanidine PTT |
4 | Antioxidant | Irgasfos 168, tert-butyl hydroquinone in mass ratio 1:1 |
Above-mentioned decorative wall paper is pasted as follows with the preparation method of environmentally friendly corrosion resistant adhesive:
(1) first the above-mentioned fibrous plaster weighed, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite are milled to
Fineness is 12 microns, then dry 1.8h under the conditions of temperature is 75 DEG C, obtains inorganic powder;
(2) again by Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N- n-butoxy first
Base acrylamide, isoprene-styrene body and accelerating agent are added in reaction kettle, are in vacuum degree
It is heated to 90 DEG C under conditions of 0.015MPa, 25min is mixed;
(3) inorganic powder, glycidyl methacrylate and coupling agent are added in reaction kettle after, in vacuum degree
To be heated to 100 DEG C under conditions of 0.015MPa, 35min is mixed;
(4) finally remaining other raw materials are added in reaction kettle, are heated under conditions of vacuum degree is 0.015MPa
94 DEG C, 12min is mixed.
Embodiment 3
A kind of environmentally friendly corrosion resistant adhesive of decorative wall paper stickup, weighs two kinds of component raw materials of following A, B:
Component A:Chinese yam rhizome slurries 15kg, vinylacetate 16kg, pine tree slurries 12kg, polyvinyl alcohol 20kg, hydrogenation pine
Fragrant 5kg, N- n-butoxy methyl acrylamide 0.6kg, glycidyl methacrylate 1kg, isoprene-styrene are embedding
Section copolymer 3kg, crosslinking agent 2.5kg, coupling agent 3kg, accelerating agent 2kg and antioxidant 1.5kg;
B component:Fibrous plaster 5kg, expansion chlorite 3kg, Tengchong In Yunnan Province volcanic ash 6kg and palygorskite 2kg;
The selection of above-mentioned auxiliary agent see the table below shown in 3:
Table 3
Serial number | Component | Ingredient |
1 | Crosslinking agent | Polypropylene glycol |
2 | Coupling agent | Anti-settling aluminate coupling agent ASA |
3 | Accelerating agent | Diphenylguanidine PTT |
4 | Antioxidant | Irgasfos 168, tert-butyl hydroquinone in mass ratio 2:1 |
Above-mentioned decorative wall paper is pasted as follows with the preparation method of environmentally friendly corrosion resistant adhesive:
(1) first the above-mentioned fibrous plaster weighed, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite are milled to
Fineness is 15 microns, then dry 1.5h under the conditions of temperature is 80 DEG C, obtains inorganic powder;
(2) again by Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N- n-butoxy first
Base acrylamide, isoprene-styrene body and accelerating agent are added in reaction kettle, are in vacuum degree
It is heated to 95 DEG C under conditions of 0.02MPa, 20min is mixed;
(3) inorganic powder, glycidyl methacrylate and coupling agent are added in reaction kettle after, in vacuum degree
To be heated to 105 DEG C under conditions of 0.02MPa, 30min is mixed;
(4) finally remaining other raw materials are added in reaction kettle, 96 is heated under conditions of vacuum degree is 0.02MPa
DEG C, 10min is mixed.
Comparative example 4
A kind of decorative wall paper stickup adhesive, production and processing raw material used and its component proportioning are same as Example 2,
But preparation method is:By the above-mentioned fibrous plaster weighed, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite ball milling
It is 60 microns to fineness, then dry 45min under the conditions of temperature is 85 DEG C, obtains inorganic powder, then by inorganic powder and other institutes
There is raw material to be added in reaction kettle jointly, 2.5h is mixed under the conditions of normal pressure, temperature are 105 DEG C.
Comparative example 5
A kind of decorative wall paper stickup adhesive, including following raw material by weight:50 parts of Lauxite, ethylene-
15 parts of acetate ethylene copolymer, 8 parts of organophosphorus ester, 5 parts of nano-sized magnesium hydroxide, 2.5 parts of sodium bentonite, 3 parts of polypropylene glycol,
0.5 part of 1.5 parts of polyacrylamide, 2 parts of cornstarch of gelatinization, KH-5600.3 parts of silane coupling agent and altax.It is prepared
Method is to be added to all raw materials in reaction kettle jointly, and 2.5h is mixed under the conditions of normal pressure, temperature are 105 DEG C.
Performance detection
By adhesive applications made from above-described embodiment 1-3 and comparative example 4-5 in the stickup of chamber wall paper, the phase of performance
It is as shown in table 4 below to close performance parameter:
Table 4
By upper table 4 it is found that the decorative wall paper stickup of the present invention is all with performance on environmentally friendly corrosion resistant adhesive in all respects performance
It is good, have and significantly promoted, can meet the needs of market significantly, in addition under comparison, Adhensive performance made from embodiment 2 is most
Excellent, it is preferred plan to be formulated dosage and preparation method accordingly.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of decorative wall paper is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that including two kinds of components of following A, B:
Component A includes following raw material by weight:10-15 parts of Chinese yam rhizome slurries, 12-16 parts of vinylacetate, pine tree slurry
8-12 parts of liquid, 10-20 parts of polyvinyl alcohol, 3-5 parts of hydrogenated rosin, 0.4-0.6 parts of N- n-butoxy methyl acrylamides, methyl-prop
0.6-1 parts of olefin(e) acid ethylene oxidic ester, isoprene -2-3 parts of styrene body, 1.5-2.5 parts of crosslinking agent, coupling agent
1-1.5 parts of 2-3 parts, 1-2 parts of accelerating agent and antioxidant;
B component includes following raw material by weight:3-5 parts of fibrous plaster, 2-3 parts of chlorite of expansion, Tengchong In Yunnan Province volcano
Grey 4-6 parts and 1-2 parts of palygorskite;
The crosslinking agent is any one of polyethylene glycol, polypropylene glycol or trimethylolpropane;
The coupling agent is silane coupling agent or aluminate coupling agent;
The accelerating agent is Vulcanization accelerator TMTD or diphenylguanidine PTT;
The antioxidant is the composition of antioxidant 1010 or irgasfos 168 and tert-butyl hydroquinone.
2. a kind of decorative wall paper according to claim 1 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that
The component A includes following raw material by weight:12 parts of Chinese yam rhizome slurries, 14 parts of vinylacetate, pine tree slurries
10 parts, 15 parts of polyvinyl alcohol, 4 parts of hydrogenated rosin, 0.5 part of N- n-butoxy methyl acrylamides, methyl propenoic acid glycidyl
0.8 part of ester, isoprene -2.5 parts of styrene body, 2 parts of crosslinking agent, 2.5 parts of coupling agent, 1.5 parts of accelerating agent and
1.2 parts of antioxidant;
B component includes following raw material by weight:4 parts of fibrous plaster, 2.5 parts of chlorite of expansion, Tengchong In Yunnan Province volcanic ash 5
1.5 parts of part and palygorskite.
3. a kind of decorative wall paper according to claim 1 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that the crosslinking
Agent is trimethylolpropane.
4. a kind of decorative wall paper according to claim 1 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that the coupling
Agent is anti-settling aluminate coupling agent ASA.
5. a kind of decorative wall paper according to claim 1 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that the promotion
Agent is diphenylguanidine PTT.
6. a kind of decorative wall paper according to claim 1 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that the antioxygen
Agent is the composition of irgasfos 168 and tert-butyl hydroquinone.
7. a kind of decorative wall paper according to claim 6 is pasted with environmentally friendly corrosion resistant adhesive, which is characterized in that the antioxygen
Agent is irgasfos 168, tert-butyl hydroquinone in mass ratio 1:1 or 2:The mixture of 1 composition.
8. a kind of preparation method pasted according to claim 1-7 any one of them decorative wall papers with environmentally friendly corrosion resistant adhesive,
It is characterized by comprising the following steps:
(1) raw material is weighed by the weight;
(2) it is 10-15 microns fibrous plaster, expansion chlorite, Tengchong In Yunnan Province volcanic ash and palygorskite to be milled to fineness, then
Temperature dry 1.5-2h under the conditions of being 70-80 DEG C, obtains inorganic powder;
(3) by Chinese yam rhizome slurries, vinylacetate, pine tree slurries, polyvinyl alcohol, hydrogenated rosin, N- n-butoxy metering systems
Amide, isoprene-styrene body and accelerating agent are added in reaction kettle, are 0.01-0.02MPa in vacuum degree
Under conditions of be heated to 85-95 DEG C, 20-30min is mixed;
(4) inorganic powder, glycidyl methacrylate and coupling agent are added in reaction kettle, are 0.01- in vacuum degree
It is heated to 95-105 DEG C under conditions of 0.02MPa, 30-40min is mixed;
(5) remaining other raw materials are added in reaction kettle, 92-96 is heated under conditions of vacuum degree is 0.01-0.02MPa
DEG C, 10-15min is mixed.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001049581A (en) * | 1999-08-05 | 2001-02-20 | Yuken Chemical Kk | Coating material for sewn product, production of coating material for sewn product and processing of sewn product |
CN1590493A (en) * | 2003-08-04 | 2005-03-09 | 赛拉尼斯乳胶有限公司 | Water-resistant adhesives, their preparation and use |
CN102585736A (en) * | 2012-01-12 | 2012-07-18 | 浙江顶立胶业有限公司 | Hot-pressing veneer adhesive and preparation method thereof |
CN107936856A (en) * | 2017-11-30 | 2018-04-20 | 明光市裕阳新材料有限公司 | A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof |
-
2018
- 2018-05-04 CN CN201810417929.2A patent/CN108485541A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001049581A (en) * | 1999-08-05 | 2001-02-20 | Yuken Chemical Kk | Coating material for sewn product, production of coating material for sewn product and processing of sewn product |
CN1590493A (en) * | 2003-08-04 | 2005-03-09 | 赛拉尼斯乳胶有限公司 | Water-resistant adhesives, their preparation and use |
CN102585736A (en) * | 2012-01-12 | 2012-07-18 | 浙江顶立胶业有限公司 | Hot-pressing veneer adhesive and preparation method thereof |
CN107936856A (en) * | 2017-11-30 | 2018-04-20 | 明光市裕阳新材料有限公司 | A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof |
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Title |
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尹作瑞 等: "淀粉接枝共混壁纸胶粘剂", 《化学建材》 * |
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