CN108485502A - A kind of anti-static coating material and its application on gum PVC products - Google Patents
A kind of anti-static coating material and its application on gum PVC products Download PDFInfo
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- CN108485502A CN108485502A CN201810436004.2A CN201810436004A CN108485502A CN 108485502 A CN108485502 A CN 108485502A CN 201810436004 A CN201810436004 A CN 201810436004A CN 108485502 A CN108485502 A CN 108485502A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of anti-static coating material and its application on gum PVC products, this anti-static coating material is made of following raw material by weight：40 54 parts of polyurethane；5 20 parts of tackifying resin；24 parts of antifoaming agent；13 parts of water-soluble polyaniline；13 parts of nano-silica powder；13 parts of nanometer titanium dioxide zinc powder；5 15 parts of polyvinyl alcohol resin, 13 parts of crosslinking agent, 13 parts of dispersant, 24 parts of initiator；50 65 parts of water.The present invention not only increases the antistatic performance of coating, while coating also has excellent water resistance using nano particle is evenly spread in PVA resins；Even if the addition of nano particle entirely to be coated with liquid system under weakly acidic condition in addition, coating also can Quick cross-linking film forming, alleviate the self-crosslinking tendency of coating fluid during storage significantly, system viscosity keeps stable for a long time.
Description
Technical field
The invention belongs to the antistatic technology fields of PVC, and in particular to a kind of anti-static coating material and preparation method thereof
And its application on gum PVC products.
Background technology
In mid-twentieth century, with the rapid popularization and application of industrial high speed development and high molecular material, one
Aspect, the extensive use of the product of some resistivity very high high molecular material such as plastics, rubber etc. and present-day procedure
High speed so that electrostatic energy runs up to very high degree, on the other hand, the production and use of electrostatic sensitive material, such as lightweight
Oil product, gunpowder, solid electronic device etc., department of industrial and mining enterprises is also more and more prominent by the harm of electrostatic, and electrostatic hazard causes
Quite serious consequence and loss.Once so that the loss of electronics industry year is caused to reach multi-billion dollar, this does not also include potential damage
It loses.In aerospace industry, static discharge causes rocket and satellite launch to fail, and interferes the operation of aerospace craft.In petrochemical industry,
The U.S. is from nineteen sixty to the fire explosion caused by electrostatic in 1975 up to 116.The end of the year 1969 are less than one month
The electrostatic generated when three Holland, Norway, Britain 200,000 tons of supertanker washings of tanks in time causes after exploding in succession, draws
Concern of the World Science man to electrostatic protection is played.In petroleum chemical enterprise more than 30 larger electrostatic thing once occurred for China in recent years
Therefore wherein losing up to million yuan or more has several.Such as the 2000m3 toluene tanks of Shanghai petro-chemical corporation, Shandong petrochemical industry are public
The glue residue tank of department, boat coal tank of Fushun petro-chemical corporation etc. is all because electrostatic causes serious fire explosion.The secondary world is big
Many industrially developed country all establish electrostatic research institution after the war.
Electrostatic hazard is due to electrostatic force and electrostatic spark, and the static discharge of most serious causes combustible in electrostatic hazard
On fire and explosion.It has often been said that preventing trouble before it happens, prevent that the measure of electrostatic is typically all, the strong technique of transformation electrification
Link, using the less equipment and materials etc. that electrifies.Most simple and most reliable method is with conducting wire equipment ground, in this way can be with
Charge is induced one greatly, to avoid accumulation of static electricity.Careful passenger can probably have found；In the both sides wing tip of aircraft and the tail portion of aircraft
It is equipped with discharge brush, when aircraft landing, is electrically shocked when flying under passenger in order to prevent, is mostly connect using special on undercarriage
Ground tire or ground wire；With aircraft generated electrostatic charge in the air of releasing.It drags the tail portion that we are also frequently seen oil truck
One iron chains, here it is the ground wires of vehicle.The appropriate humidity for increasing working environment, allows charge to release at any time, it is possibility to have effect ground
Eliminate electrostatic.Want some doing electrostatic is tested in wet weather, is exactly this reason.The antistatic agent of scientific research personnel's research,
The electrostatic inside insulator can be then eliminated well.
PVC gums product is all to store in rolls during manufacture, storage, transport and use, all can in rolling up solution preocess
Electric spark is generated, has prodigious risk to cause fire or explosion, therefore, it is urgently to be resolved hurrily to make the PVC gum products of antistatic
The technical issues of.However, in use, using general cationic antistatic agent, anionic antistatic agents or nonionic
Type antistatic agent is easy to react with other basic ingredients, has easily caused the problems such as sticky insufficient, antistatic property is weak, from
And influence the quality of product.
Invention content
The goal of the invention of the present invention is to provide for a kind of anti-static coating material.With solve the prior art it is above-mentioned not
Foot.
It is a further object of the present invention to provide a kind of this preparation methods of anti-static coating material.
Application of the anti-static coating material of the present invention on gum PVC products.
The purpose of the present invention can be achieved through the following technical solutions.
A kind of anti-static coating material is made of following raw material by weight：40-54 parts of polyurethane；Tackifying resin
5-20 parts；2-4 parts of antifoaming agent；1-3 parts of water-soluble polyaniline；1-3 parts of nano-silica powder；1-3 parts of nanometer titanium dioxide zinc powder；
5-15 parts of polyvinyl alcohol resin, 1-3 parts of crosslinking agent, 1-3 parts of dispersant, 2-4 parts of initiator；50-65 parts of water.
The tackifying resin is disproportionated rosin ester.
The antifoaming agent is dimethyl silicone polymer.
The crosslinking agent is one or more of amino resins, silane coupling agent, boric acid, urea etc. arbitrary proportion
Mixture.
The dispersant is acrylic compounds or maleic acid family macromolecule dispersant.
The initiator is the mixture of one or more kinds of arbitrary proportions such as hydrochloric acid, sulfuric acid, phosphoric acid.Concentration is less than
1mol/L, preferably shorter than 0.1mol/L.
The preparation method of above-mentioned anti-static coating material：
(3) each component is weighed in proportion；
(4) polyvinyl alcohol resin, water, antifoaming agent are uniformly mixed, are heated to 95~100 DEG C, constant temperature keeps resin fully molten
Solution, is cooled to room temperature, obtains poly-vinyl alcohol solution；
(3) nano-silica powder, nanometer titanium dioxide zinc powder and dispersant are placed in suitable quantity of water, are stirred to full and uniform
Dispersion, obtains nano dispersion fluid；
(4) successively by water-soluble polyaniline, crosslinking agent, initiator, polyurethane, tackifying resin be added it is above-mentioned prepare it is poly-
In glycohol solution and nano dispersion fluid, modified coating fluid is obtained after evenly mixing.
Above-mentioned anti-static coating material is coated in gum PVC material, prepares the gum PVC of antistatic.
The present invention not only increases the antistatic performance of coating, together using nano particle is evenly spread in PVA resins
When coating also have excellent water resistance；Even if the addition of nano particle entirely to be coated with liquid system in weakly acidic condition in addition
Under, coating also can Quick cross-linking film forming, alleviate significantly coating fluid during storage self-crosslinking tendency, when system viscosity is long
Between keep stablize.
Specific implementation mode
With reference to the specific embodiment technical characterstic that the present invention is further explained.
Product used in the embodiment of the present invention is commercially available.
Embodiment 1-5 is prepared using following preparation method：
Prepare poly-vinyl alcohol solution：Polyvinyl alcohol resin, water, antifoaming agent are uniformly mixed, are heated to 95~100 DEG C, perseverance
So that resin is fully dissolved, be cooled to room temperature, obtains poly-vinyl alcohol solution；
Prepare nano dispersion fluid：Nano-silica powder, nanometer titanium dioxide zinc powder and dispersant are placed in suitable quantity of water, stirred
It mixes to full and uniform dispersion, obtains nano dispersion fluid；
The above-mentioned poly- second prepared is added in water-soluble polyaniline, crosslinking agent, initiator, polyurethane, tackifying resin successively
In enolate solution and nano dispersion fluid, modified coating fluid is obtained after evenly mixing.
Embodiment 1
It is made of following raw material by weight：40 parts of polyurethane；10 parts of tackifying resin；3 parts of antifoaming agent；Water-soluble poly
1 part of aniline；3 parts of nano-silica powder；1 part of nanometer titanium dioxide zinc powder；5 parts of polyvinyl alcohol resin, 1 part of crosslinking agent, dispersant 1
Part, 2 parts of initiator；65 parts of water.
Embodiment 2
It is made of following raw material by weight：45 parts of polyurethane；10 parts of tackifying resin；3 parts of antifoaming agent；Water-soluble poly
1 part of aniline；3 parts of nano-silica powder；1 part of nanometer titanium dioxide zinc powder；10 parts of polyvinyl alcohol resin, 1 part of crosslinking agent, dispersant
1 part, 2 parts of initiator；50 parts of water.
Embodiment 3
It is made of following raw material by weight：50 parts of polyurethane；20 parts of tackifying resin；4 parts of antifoaming agent；Water-soluble poly
2 parts of aniline；2 parts of nano-silica powder；2 parts of nanometer titanium dioxide zinc powder；10 parts of polyvinyl alcohol resin, 2 parts of crosslinking agent, dispersant
2 parts, 2 parts of initiator；60 parts of water.
Embodiment 4
It is made of following raw material by weight：54 parts of polyurethane；5 parts of tackifying resin；3 parts of antifoaming agent；Water-soluble poly
2 parts of aniline；3 parts of nano-silica powder；3 parts of nanometer titanium dioxide zinc powder；15 parts of polyvinyl alcohol resin, 3 parts of crosslinking agent, dispersant
3 parts, 2 parts of initiator；50 parts of water.
Embodiment 5
It is made of following raw material by weight：45 parts of polyurethane；15 parts of tackifying resin；2 parts of antifoaming agent；Water-soluble poly
3 parts of aniline；3 parts of nano-silica powder；3 parts of nanometer titanium dioxide zinc powder；15 parts of polyvinyl alcohol resin, 1 part of crosslinking agent, dispersant
3 parts, 3 parts of initiator；65 parts of water.
Comparative example 1
It is made of following raw material by weight：50 parts of polyurethane；20 parts of tackifying resin；4 parts of antifoaming agent；Water-soluble poly
2 parts of aniline；4 parts of nano-silica powder；10 parts of polyvinyl alcohol resin, 2 parts of crosslinking agent, 2 parts of dispersant, 2 parts of initiator；Water 60
Part.
Comparative example 2
It is made of following raw material by weight：50 parts of polyurethane；20 parts of tackifying resin；4 parts of antifoaming agent；Water-soluble poly
2 parts of aniline；4 parts of nanometer titanium dioxide zinc powder；10 parts of polyvinyl alcohol resin, 2 parts of crosslinking agent, 2 parts of dispersant, 2 parts of initiator；Water 60
Part.
Comparative example 3
It is made of following raw material by weight：50 parts of polyurethane；20 parts of tackifying resin；4 parts of antifoaming agent；Water-soluble poly
2 parts of aniline；10 parts of polyvinyl alcohol resin, 2 parts of crosslinking agent, 2 parts of dispersant, 2 parts of initiator；60 parts of water.
Peeling force and surface resistivity test：
The said goods are spread evenly across PVC on pieces, are then tested according to following test mode：
1, peeling force：180 ° of peeling forces are tested by GB/2792-1998；(stripping is measured using electron detachment machine
Rate is 250mm/min).
2, surface resistivity：It is measured according to GB50174-2008.
It can see by 3 test data of embodiment and comparative example 1, comparative example 2, the comparison of the test data of comparative example 3：Nanometer
The synergistic effect of silicon dioxide powder and nanometer titanium dioxide zinc powder, than single use nano-silica powder and nanometer titanium dioxide zinc powder
Peel strength it is suitable, but electrical conductivity have very big difference, differed nearly 2 orders of magnitude.
The above is presently preferred embodiments of the present invention, but the present invention should not be limited to disclosed in the embodiment
Content.So every do not depart from the lower equivalent or modification completed of spirit disclosed in this invention, the model that the present invention protects is both fallen within
It encloses.
Claims (9)
1. a kind of anti-static coating material, it is characterised in that：It is made of following raw material by weight：40-54 parts of polyurethane；
5-20 parts of tackifying resin；2-4 parts of antifoaming agent；1-3 parts of water-soluble polyaniline；1-3 parts of nano-silica powder；Nano zinc dioxide impact-resistant
1-3 parts of powder；5-15 parts of polyvinyl alcohol resin, 1-3 parts of crosslinking agent, 1-3 parts of dispersant, 2-4 parts of initiator；50-65 parts of water.
2. a kind of anti-static coating material according to claim 1, it is characterised in that：The tackifying resin is disproportionation pine
Fragrant ester.
3. a kind of anti-static coating material according to claim 1, it is characterised in that：The antifoaming agent is poly dimethyl
Siloxanes.
4. a kind of anti-static coating material according to claim 1, it is characterised in that：The crosslinking agent be amino resins,
The mixture of one or more of silane coupling agent, boric acid, urea etc. arbitrary proportion.
5. a kind of anti-static coating material according to claim 1, it is characterised in that：The dispersant be acrylic compounds or
Maleic acid family macromolecule dispersant.
6. a kind of anti-static coating material according to claim 1, it is characterised in that：The initiator be hydrochloric acid, sulfuric acid,
The mixture of the one or more arbitrary proportion such as phosphoric acid；Concentration is less than 1mol/L.
7. a kind of anti-static coating material according to claim 6, it is characterised in that：The concentration of the initiator is less than
0.1mol/L。
8. the preparation method of one of the arbitrary anti-static coating materials of claim 1-7, it is characterised in that：Its step is：
(1) each component is weighed in proportion；
(2) polyvinyl alcohol resin, water, antifoaming agent are uniformly mixed, are heated to 95~100 DEG C, constant temperature makes resin fully dissolve, cold
But to room temperature, poly-vinyl alcohol solution is obtained；
(3) nano-silica powder, nanometer titanium dioxide zinc powder and dispersant are placed in suitable quantity of water, are stirred to full and uniform point
It dissipates, obtains nano dispersion fluid；
(4) the above-mentioned polyethylene prepared is added in water-soluble polyaniline, crosslinking agent, initiator, polyurethane, tackifying resin successively
In alcoholic solution and nano dispersion fluid, modified coating fluid is obtained after evenly mixing.
9. one of the arbitrary anti-static coating materials of claim 1-7, it is characterised in that：The anti-static coating material coating
In the gum PVC in gum PVC material, preparing antistatic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810436004.2A CN108485502A (en) | 2018-05-09 | 2018-05-09 | A kind of anti-static coating material and its application on gum PVC products |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810436004.2A CN108485502A (en) | 2018-05-09 | 2018-05-09 | A kind of anti-static coating material and its application on gum PVC products |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109237434A (en) * | 2018-09-29 | 2019-01-18 | 江苏锐阳照明电器设备有限公司 | A kind of dust-proof coating of mining illuminating lamp tool |
| WO2020238083A1 (en) * | 2019-05-24 | 2020-12-03 | 浙江欧仁新材料有限公司 | Solvent-resistant antistatic film |
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|---|---|---|---|---|
| CN109237434A (en) * | 2018-09-29 | 2019-01-18 | 江苏锐阳照明电器设备有限公司 | A kind of dust-proof coating of mining illuminating lamp tool |
| WO2020238083A1 (en) * | 2019-05-24 | 2020-12-03 | 浙江欧仁新材料有限公司 | Solvent-resistant antistatic film |
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