CN108483963A - A kind of pretreatment of particles technique for packing reducing haydite water absorption rate - Google Patents

A kind of pretreatment of particles technique for packing reducing haydite water absorption rate Download PDF

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Publication number
CN108483963A
CN108483963A CN201810286850.0A CN201810286850A CN108483963A CN 108483963 A CN108483963 A CN 108483963A CN 201810286850 A CN201810286850 A CN 201810286850A CN 108483963 A CN108483963 A CN 108483963A
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CN
China
Prior art keywords
haydite
water
sulphate aluminium
aluminium cement
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810286850.0A
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Chinese (zh)
Inventor
张文华
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Nanjing Forestry University
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Nanjing Forestry University
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Application filed by Nanjing Forestry University filed Critical Nanjing Forestry University
Priority to CN201810286850.0A priority Critical patent/CN108483963A/en
Publication of CN108483963A publication Critical patent/CN108483963A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/027Lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/12Multiple coating or impregnating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a kind of pretreatment of particles technique for packing reducing haydite water absorption rate, include the following steps:The first step:2 parts of surfactants and 100 parts of water are uniformly mixed into the mixture of surfactant and water;Second step:The mixture of surfactant and water is sprayed on haydite particles surface, haydite particles is made tentatively to moisten;Third walks:Sulphate aluminium cement is stirred into flowing water slurry body according to match ratio:4th step:By cement slurry be sprayed on haydite particles to completely be wrapped after discharge;5th step:It conserves 6 hours at ambient temperature, after sulphate aluminium cement condenses hardening completely, forms the wrapping layer that uniform, thickness is 1~2mm outside haydite.The strong sulphate aluminium cement shell of a floor height is wrapped up on the haydite surface that the present invention keeps water absorption rate big, and the haydite after package has higher-strength, and the water absorbing properties of particle can be obviously reduced, and water absorption rate is only 0.5% within 1 hour.

Description

A kind of pretreatment of particles technique for packing reducing haydite water absorption rate
Technical field
The invention belongs to building material technical fields, and in particular to a kind of pretreatment of particles package reducing haydite water absorption rate Technology, the heat-insulation wall plate for being mainly used for the assembled architectures such as residential houses, office building make.
Background technology
Haydite wall heat insulation material have many advantages, such as heat insulation property it is good, etc. it is cheap, easy for construction, be China building The developing direction of energy-saving wall material.
However, haydite has the characteristics that porosity is high, water absorption rate is big, water consumption increases in whipping process, destroys sand The solidification cycle of slurry so that the mechanical property of mortar substantially reduces, and easily generates hollowing, cracking, seriously affects entire heat preservation system The thermal property and durability of system.Disadvantages mentioned above limits large-scale popularization application of the haydite heat-insulation wall plate in building field, however There is presently no relevant solutions.Therefore it is badly in need of being surface-treated haydite particles, realizing reduces water absorption rate, raising The purpose of grain intensity.
The particle encapsulation technology for researching and developing haydite, porosity is big, shaggy haydite surface wrap up one layer it is fast hard, high-strength Shell layer significantly reduce its water absorbing properties while improving haydite integral strength, increase substantially assembled haydite heat preservation The intensity of wallboard improves the effect of building thermal-insulation energy-saving for accelerating the development of China's assembled architecture, have most important theories and Realistic meaning.
Invention content
The present invention is to provide a kind of drop for the deficiency that porosity rate existing in the prior art is big, water absorption rate is high The pretreatment of particles technique for packing of low haydite water absorption rate, the haydite made using this technology, it is strong that a floor height has been wrapped up on surface Sulphate aluminium cement shell layer, have the characteristics that intensity is high, water absorption rate is low, the strong of assembling thermal-insulating wall board can be significantly improved Degree, suitable for requiring the buildings such as high house, office building heat preservation, heat-insulated, sound insulation.
The specific technical solution of the present invention is as follows:
It is a kind of reduce haydite water absorption rate pretreatment of particles technique for packing, the technology processing procedure in five steps:
The first step:2 parts of surfactants and 100 parts of water are uniformly mixed into the mixture of surfactant and water;
Second step:The mixture of surfactant and water is sprayed on haydite particles surface, haydite particles is made to be sufficiently humidified so as to;
Third walks:Sulphate aluminium cement is stirred into flowing water slurry body according to match ratio:
4th step:Haydite after moistening is poured into blender to be stirred, aluminium sulfate water is sprayed during stirring Slurry body controls the thickness of wrapping layer, stir and is sprayed to haydite quilt completely by spraying the amount of sulphate aluminium cement slurry It discharges after sulphate aluminium cement package;
5th step:It conserves 6 hours at ambient temperature, after sulphate aluminium cement condenses hardening completely, outside haydite Form the wrapping layer that uniform, thickness is 1~2mm.
Contain carboxylic acid, sulfonic acid, sulfuric acid, amino or amido polar hydrophilic group in the molecular structure of the surfactant, After being mixed with water and moistening haydite surface, the hydrophilic ability of haydite can be improved, improves the bonding with sulphate aluminium cement.
The sulphate aluminium cement is the rapid hardening high-strength sulphate aluminium cement that strength grade is 62.5.
The cement slurry setting time can be controlled within 30 minutes, and intensity reaches 80MPa after hardening, can rapidly exist It is wrapped to form high-strength shell outside big, the coarse haydite of porosity, significantly reduces water absorption rate, water absorption rate is only within 1 hour 0.5%.Include following substance by mass percentage by match ratio:
The sulphate aluminium cement has good adhesive property with Portland cement, and by this technology, treated Haydite can significantly improve the compression strength of assembling thermal-insulating wall board.
Compared to the prior art the present invention, has the following advantages that:
(1) haydite particles encapsulation technology provided by the invention is used, it can be rapidly in the pottery that porosity is big, water absorption rate is high Grain periphery package last layer sulphate aluminium cement shell, compared with before package, the haydite after package has higher cylindrical compress strength Very low water absorption, to significantly improve the intensity of assembled haydite heat-insulation wall plate;
(2) sulphate aluminium cement used in the present invention is conventional building material, and raw material are easy to get, and cheap;
(3) present invention's is technically simple easy, fully utilizes a large amount of silicon ashes, flyash equal industrial residue, also has green The characteristics of colour circle is protected.
Specific implementation mode
A kind of pretreatment of particles technique for packing reducing haydite water absorption rate, including five steps:
The first step:2 parts of surfactants and 100 parts of water are uniformly mixed into the mixture of surfactant and water;
Second step:The mixture of surfactant and water is sprayed on haydite particles surface, haydite particles is made to be sufficiently humidified so as to;
Third walks:Sulphate aluminium cement is stirred into flowing water slurry body according to match ratio:
4th step:Haydite after moistening is poured into blender to be stirred, aluminium sulfate water is sprayed during stirring Slurry body controls the thickness of wrapping layer, stir and is sprayed to haydite quilt completely by spraying the amount of sulphate aluminium cement slurry It discharges after sulphate aluminium cement package;
5th step:It conserves 6 hours at ambient temperature, after sulphate aluminium cement condenses hardening completely, outside haydite Form the wrapping layer that uniform, thickness is 1~2mm.
Embodiment 1
A kind of pretreatment of particles technique for packing reducing haydite water absorption rate, implementation process are as follows:
(1) 2 parts of surfactants and 100 parts of water are uniformly mixed into the mixture of surfactant and water;
(2) mixture of surfactant and water is sprayed on haydite particles surface, haydite particles is made to be sufficiently humidified so as to;
(3) material is good by following quality weighing:
Sulphate aluminium cement is stirred into flowing water slurry body according to match ratio.
(4) haydite after moistening is poured into blender to be stirred, sulphate aluminium cement slurry is sprayed during stirring Body controls the thickness of wrapping layer, stir and is sprayed to haydite completely by sulphur aluminium by spraying the amount of sulphate aluminium cement slurry It discharges after acid salt cement package;
(5) it conserves 6 hours, after sulphate aluminium cement condenses hardening completely, is formed outside haydite at ambient temperature Uniformly, thickness is the wrapping layer of 1~2mm, and the haydite cylindrical compress strength after package reaches 2.5MPa, and water absorption rate is only 0.5% within 1 hour.

Claims (7)

1. a kind of pretreatment of particles technique for packing reducing haydite water absorption rate, it is characterised in that its processing procedure is in five steps:
The first step:2 parts of surfactants and 100 parts of water are uniformly mixed into the mixture of surfactant and water;
Second step:The mixture of surfactant and water is sprayed on haydite particles surface, haydite particles is made to be sufficiently humidified so as to;
Third walks:Sulphate aluminium cement is stirred into flowing water slurry body according to match ratio:
4th step:Haydite after moistening is poured into blender to be stirred, sulphate aluminium cement slurry is sprayed during stirring Body controls the thickness of wrapping layer, stir and is sprayed to haydite completely by sulphur aluminium by spraying the amount of sulphate aluminium cement slurry It discharges after acid salt cement package;
5th step:It conserves 6 hours, after sulphate aluminium cement condenses hardening completely, is formed outside haydite at ambient temperature Uniformly, thickness is the wrapping layer of 1~2mm.
2. pretreatment technique for packing according to claim 1, it is characterised in that haydite is spheric granules, grain diameter between 5~20mm, bulk density is between 300kg/m3~900kg/m3
3. particle encapsulation technology according to claim 1, it is characterised in that contain carboxylic in the molecular structure of surfactant Acid, sulfonic acid, sulfuric acid, amino or amido polar hydrophilic group.
4. pretreatment technique for packing according to claim 1, it is characterised in that the sulphate aluminium cement is strength grade For 62.5 rapid hardening high-strength sulphate aluminium cement.
5. pretreatment technique for packing according to claim 1, it is characterised in that the cement slurry setting time is at 30 points Within clock, intensity reaches 75MPa intensity after hardening, includes following substance by mass percentage by match ratio:
6. particle encapsulation technology according to claim 1, it is characterised in that be formed by sulphate aluminium cement shell thickness Degree is 1~2mm, has good adhesive property with Portland cement, and can prevent outside during stirring molding Moisture enters the inside of haydite, significantly reduces the water absorption rate of haydite.
7. particle encapsulation technology according to claim 1, it is characterised in that blender is self-falling mixer, whipping process At 10 revs/min, rotating speed is excessively high to be unfavorable for package of the sulphate aluminium cement to haydite for middle rotating speed control.
CN201810286850.0A 2018-03-27 2018-03-27 A kind of pretreatment of particles technique for packing reducing haydite water absorption rate Withdrawn CN108483963A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810286850.0A CN108483963A (en) 2018-03-27 2018-03-27 A kind of pretreatment of particles technique for packing reducing haydite water absorption rate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810286850.0A CN108483963A (en) 2018-03-27 2018-03-27 A kind of pretreatment of particles technique for packing reducing haydite water absorption rate

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CN108483963A true CN108483963A (en) 2018-09-04

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109534785A (en) * 2018-12-27 2019-03-29 东北大学 A kind of Ceramic Composite sand of artificial spherical shape
CN110526609A (en) * 2019-08-31 2019-12-03 武汉理工大学 A kind of hud typed sulphoaluminate cement base high-strength light aggregate and preparation method thereof
CN113603381A (en) * 2021-09-17 2021-11-05 哈尔滨工业大学(深圳) Cement shell-making sludge ceramsite and preparation method and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109534785A (en) * 2018-12-27 2019-03-29 东北大学 A kind of Ceramic Composite sand of artificial spherical shape
CN110526609A (en) * 2019-08-31 2019-12-03 武汉理工大学 A kind of hud typed sulphoaluminate cement base high-strength light aggregate and preparation method thereof
CN113603381A (en) * 2021-09-17 2021-11-05 哈尔滨工业大学(深圳) Cement shell-making sludge ceramsite and preparation method and application thereof

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Application publication date: 20180904