CN108483940A - A kind of building glass with good heat insulation - Google Patents

A kind of building glass with good heat insulation Download PDF

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Publication number
CN108483940A
CN108483940A CN201810364956.8A CN201810364956A CN108483940A CN 108483940 A CN108483940 A CN 108483940A CN 201810364956 A CN201810364956 A CN 201810364956A CN 108483940 A CN108483940 A CN 108483940A
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Prior art keywords
glass
parts
agent
building
insulation layer
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Inventor
魏芳芳
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Hefei Xieyao Glassware Co Ltd
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Hefei Xieyao Glassware Co Ltd
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Priority to CN201810364956.8A priority Critical patent/CN108483940A/en
Publication of CN108483940A publication Critical patent/CN108483940A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2231Oxides; Hydroxides of metals of tin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to glassmaking arts, and in particular to a kind of building glass with good heat insulation.The building glass includes heat safe reinforced glass substrate, the thermal isolation film being attached to outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;The thermal insulation layer is the hollow glass micropearl layer in glass baseplate surface by baking-curing;The raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion, nano-indium stannum oxide, Nanometer gallium oxide, dispersant, coupling agent, levelling agent, coalescents and wetting agent.Wherein, coupling agent is silane coupling agent;Levelling agent is virgin pp acid esters levelling agent;Coalescents are propandiol butyl ether;Wetting agent is poly- carboxylic esters.The building glass has good thermal and insulating performance, can keep stablizing relatively for indoor temperature, reduce the power consumption of building, be more energy-saving and environmentally friendly.

Description

A kind of building glass with good heat insulation
Technical field
The present invention relates to glassmaking arts, and in particular to a kind of building glass with good heat insulation.
Background technology
With the continuous variation of production technology being constantly progressive with the market demand, the molding of glass and processing technology There is new development.People have had developed interlayer, tempering, ion exchange, glaze decorating, chemistry thermal decomposition and cathodic sputtering etc. New technology glass, this makes the intensity of glass material higher and higher, and hardness is better, and the dosage of glass under construction is also rapid therewith Increase, becomes the third-largest construction material after cement and steel.Due to its light penetration outstanding and easy to process Characteristic, either on the glass partition of the glass curtain wall of building external or building interior, glass material all has extensive Using.
The function of building glass is not only to meet daylighting requirement, and to have can light regulating, safe, shellproof, anti- The characteristics such as robber, fire prevention, radiation protection, anti electromagnetic wave interference, artistic decoration.But the physical characteristic of glass material itself determines glass The heat conductivility of glass is relatively preferable, as building glass in use, material thermal and insulating performance also just it is relatively poor, this makes Cold season, the heat of building interior are particularly easy to scatter and disappear, and hot season indoor temperature is easy to quickly increase;It is this Situation will increase energy consumption of the building interior for temperature adjusting.
Invention content
For problems of the prior art, the present invention provides a kind of building glass with good heat insulation, The building glass has good thermal and insulating performance, can keep stablizing relatively for indoor temperature, reduce the power consumption of building, more Add energy conservation and environmental protection.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of building glass with good heat insulation, which includes heat safe reinforced glass substrate, attached The thermal isolation film outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;Thermal insulation layer is by baking-curing in glass substrate The hollow glass micropearl layer on surface;According to mass fraction, the raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion 40-50 parts, 10-13 parts of nano-indium stannum oxide, 0.5-1.2 parts of Nanometer gallium oxide, 7-9 parts of dispersant, 0.2-0.5 parts of coupling agent, 1-2 parts of levelling agent, 1-3 parts of coalescents, 0.5-1 parts of wetting agent.
Preferably, according to mass fraction, the raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion 46-47 Part, 11-12 parts of nano-indium stannum oxide, 0.8-0.9 parts of Nanometer gallium oxide, 8-9 parts of dispersant, 0.3-0.4 parts of coupling agent, levelling agent 1.3-1.5 parts, 2-3 parts of coalescents, 0.7-0.8 parts of wetting agent.
Preferably, dispersant be perfluor yl carboxylic acid and 1,2-PD etc. quality than mixture or perfluoropolyether diol and 1,2- Propylene glycol etc. quality compare mixture.
Preferably, coupling agent is silane coupling agent.
Preferably, levelling agent is virgin pp acid esters levelling agent.
Preferably, coalescents are propandiol butyl ether;Wetting agent is poly- carboxylic esters.
The preparation method of thermal insulation layer in the present invention is:According to mass fraction, it is 15-20 μm to prepare 80-90 parts of grain sizes Glass microballoon is surface-treated by borosilicate hollow glass micropearl with 4-6 parts of silane coupler solution, treated glass Glass microballon and titanium dioxide are according to 2:Then 3 mass ratio mixing is added acetone solvent and coating is made, by coating even application and clearly Surface of plate glass after clean, spray film thickness is 90-120 μm, and then glass is sent in continuous tunnel stove and is toasted, and is dried Roasting temperature is 580-600 DEG C, is taken out from continuous tunnel furnace after toasting 15-20min, after coating cooling and solidifying, obtains required glass Glass substrate thermal insulation layer.
The preparation method of thermal isolation film is as follows in the present invention:According to mass fraction, by organosilicon-modified acrylic polymer breast Liquid and dispersant, which are added in Scattered Kettle, to be stirred, then by nano-indium stannum oxide, Nanometer gallium oxide and coupling agent add Enter into Scattered Kettle, decentralized processing carried out with the rotating speed of 650-700r/min, processing time 8-10min, then by levelling agent, Wetting agent, coalescents are added sequentially in Scattered Kettle, continue to disperse 5-7min, obtain required heat-insulated coating, will be heat-insulated The thermal insulation layer surface of coating even application and glass substrate is placed at room temperature to coating and is spontaneously dried, then will be after drying Glass substrate be sent in continuous tunnel furnace 8-10min toasted with 130-140 DEG C of temperature, take out, it is cooling after obtain required building Glass.
The present invention has following advantageous effect:
The glass baseplate surface of the type building glass is equipped with hollow glass micropearl layer, and soot layer uses hollow Borosilicate glass microballon, the microballon are solidificated in glass baseplate surface after high temperature is baked, therefore form one layer and carry cavity Protective coating, which can improve the heat-insulating property of glass substrate.
Outside hollow glass micro-bead thermal layer, it is also provided with the organic coating with heat-insulating property, the coating is with resin breast Liquid is matrix, and added with the nano-indium stannum oxide and Nanometer gallium oxide that can promote glass heat-insulating performance, which can not only change The thermal and insulating performance of kind building glass, moreover it is possible to improve the automatically cleaning effect of glass, reduce attachment of the spot in glass surface.
After the thermal and insulating performance of the building glass improves, can make using the building of the material heat-insulating property more It is good, the energy consumption during building use is reduced, there is more environmentally-friendly energy-efficient characteristic.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of building glass with good heat insulation, which includes heat safe reinforced glass substrate, attached The thermal isolation film outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;Thermal insulation layer is by baking-curing in glass substrate The hollow glass micropearl layer on surface;According to mass fraction, the raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion 40 parts, 10 parts of nano-indium stannum oxide, 0.5 part of Nanometer gallium oxide, 7 parts of dispersant, 0.2 part of coupling agent, 1 part of levelling agent, film forming helps 1 part of agent, 0.5 part of wetting agent.
Wherein, dispersant be perfluor yl carboxylic acid and 1,2-PD etc. quality compare mixture.Coupling agent is silane coupled Agent;Levelling agent is virgin pp acid esters levelling agent;Coalescents are propandiol butyl ether;Wetting agent is poly- carboxylic esters.
The preparation method of thermal insulation layer is in the present embodiment:According to mass fraction, prepare the borosilicate that 80 parts of grain sizes are 15-20 μm Glass microballoon is surface-treated by hydrochlorate hollow glass micropearl with 4 parts of silane coupler solution, treated glass microballoon With titanium dioxide according to 2:Then 3 mass ratio mixing is added acetone solvent and coating is made, after coating even application and cleaning Surface of plate glass, spray film thickness is 90 μm, and then glass is sent in continuous tunnel stove and is toasted, the temperature of baking is It 580 DEG C, is taken out from continuous tunnel furnace after toasting 15min, after coating cooling and solidifying, obtains required glass substrate thermal insulation layer.
The preparation method of thermal isolation film is as follows in the present embodiment:According to mass fraction, by organosilicon-modified acrylic polymer Lotion and dispersant, which are added in Scattered Kettle, to be stirred, then by nano-indium stannum oxide, Nanometer gallium oxide and coupling agent It is added in Scattered Kettle, decentralized processing, processing time 8min, then by levelling agent, wetting is carried out with the rotating speed of 650r/min Agent, coalescents are added sequentially in Scattered Kettle, continue to disperse 5min, obtain required heat-insulated coating, will be by heat-insulated coating The thermal insulation layer surface of even application and glass substrate is placed at room temperature to coating and is spontaneously dried, then by the glass after drying Substrate is sent in continuous tunnel furnace and toasts 8min with 130 DEG C of temperature, takes out, obtains required building glass after cooling.
Embodiment 2
A kind of building glass with good heat insulation, which includes heat safe reinforced glass substrate, attached The thermal isolation film outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;Thermal insulation layer is by baking-curing in glass substrate The hollow glass micropearl layer on surface;According to mass fraction, the raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion 50 parts, 13 parts of nano-indium stannum oxide, 1.2 parts of Nanometer gallium oxide, 9 parts of dispersant, 0.5 part of coupling agent, 2 parts of levelling agent, film forming helps 3 parts of agent, 1 part of wetting agent.
Wherein, dispersant be perfluoropolyether diol and 1,2-PD etc. quality compare mixture.Coupling agent is silane coupling agent;Stream Flat agent is virgin pp acid esters levelling agent;Coalescents are propandiol butyl ether;Wetting agent is poly- carboxylic esters.
The preparation method of thermal insulation layer is in the present embodiment:According to mass fraction, prepare the borosilicate that 90 parts of grain sizes are 15-20 μm Glass microballoon is surface-treated by hydrochlorate hollow glass micropearl with 6 parts of silane coupler solution, treated glass microballoon With titanium dioxide according to 2:Then 3 mass ratio mixing is added acetone solvent and coating is made, after coating even application and cleaning Surface of plate glass, spray film thickness is 120 μm, and then glass is sent in continuous tunnel stove and is toasted, the temperature of baking It is 600 DEG C, is taken out from continuous tunnel furnace after toasting 20min, after coating cooling and solidifying, obtains required glass substrate thermal insulation layer.
The preparation method of thermal isolation film is as follows in the present embodiment:According to mass fraction, by organosilicon-modified acrylic polymer Lotion and dispersant, which are added in Scattered Kettle, to be stirred, then by nano-indium stannum oxide, Nanometer gallium oxide and coupling agent It is added in Scattered Kettle, decentralized processing, processing time 10min, then by levelling agent, wetting is carried out with the rotating speed of 700r/min Agent, coalescents are added sequentially in Scattered Kettle, continue to disperse 7min, obtain required heat-insulated coating, will be by heat-insulated coating The thermal insulation layer surface of even application and glass substrate is placed at room temperature to coating and is spontaneously dried, then by the glass after drying Substrate is sent in continuous tunnel furnace and toasts 10min with 140 DEG C of temperature, takes out, obtains required building glass after cooling.
Embodiment 3
A kind of building glass with good heat insulation, which includes heat safe reinforced glass substrate, attached The thermal isolation film outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;Thermal insulation layer is by baking-curing in glass substrate The hollow glass micropearl layer on surface;According to mass fraction, the raw material of thermal isolation film includes:Organosilicon-modified acrylic polymer emulsion 45 parts, 12 parts of nano-indium stannum oxide, 0.9 part of Nanometer gallium oxide, 8 parts of dispersant, 0.3 part of coupling agent, 1.5 parts of levelling agent, film forming 2 parts of auxiliary agent, 0.8 part of wetting agent.
Wherein, dispersant be perfluor yl carboxylic acid and 1,2-PD etc. quality compare mixture.Coupling agent is silane coupled Agent;Levelling agent is virgin pp acid esters levelling agent;Coalescents are propandiol butyl ether;Wetting agent is poly- carboxylic esters.
The preparation method of thermal insulation layer is in the present embodiment:According to mass fraction, prepare the borosilicate that 85 parts of grain sizes are 15-20 μm Glass microballoon is surface-treated by hydrochlorate hollow glass micropearl with 5 parts of silane coupler solution, treated glass microballoon With titanium dioxide according to 2:Then 3 mass ratio mixing is added acetone solvent and coating is made, after coating even application and cleaning Surface of plate glass, spray film thickness is 100 μm, and then glass is sent in continuous tunnel stove and is toasted, the temperature of baking It is 590 DEG C, is taken out from continuous tunnel furnace after toasting 17min, after coating cooling and solidifying, obtains required glass substrate thermal insulation layer.
The preparation method of thermal isolation film is as follows in the present embodiment:According to mass fraction, by organosilicon-modified acrylic polymer Lotion and dispersant, which are added in Scattered Kettle, to be stirred, then by nano-indium stannum oxide, Nanometer gallium oxide and coupling agent It is added in Scattered Kettle, decentralized processing, processing time 9min, then by levelling agent, wetting is carried out with the rotating speed of 670r/min Agent, coalescents are added sequentially in Scattered Kettle, continue to disperse 6min, obtain required heat-insulated coating, will be by heat-insulated coating The thermal insulation layer surface of even application and glass substrate is placed at room temperature to coating and is spontaneously dried, then by the glass after drying Substrate is sent in continuous tunnel furnace and toasts 9min with 135 DEG C of temperature, takes out, obtains required building glass after cooling.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of building glass with good heat insulation, it is characterised in that:The building glass includes heat safe tempering Glass substrate, the thermal isolation film being attached to outside the thermal insulation layer and thermal insulation layer of glass baseplate surface;The thermal insulation layer is through overbaking It is solidificated in the hollow glass micropearl layer of glass baseplate surface;According to mass fraction, the raw material of thermal isolation film includes:Organic-silicon-modified third 40-50 parts of olefin(e) acid polymer emulsion, 10-13 parts of nano-indium stannum oxide, 0.5-1.2 parts of Nanometer gallium oxide, 7-9 parts of dispersant are even Join 0.2-0.5 parts of agent, 1-2 parts of levelling agent, 1-3 parts of coalescents, 0.5-1 parts of wetting agent.
2. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:According to mass parts Number, the raw material of the thermal isolation film include:46-47 parts of organosilicon-modified acrylic polymer emulsion, nano-indium stannum oxide 11-12 Part, 0.8-0.9 parts of Nanometer gallium oxide, 8-9 parts of dispersant, 0.3-0.4 parts of coupling agent, 1.3-1.5 parts of levelling agent, coalescents 2- 3 parts, 0.7-0.8 parts of wetting agent.
3. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The dispersant For perfluor yl carboxylic acid and 1,2-PD etc. quality mixed with the equal mass ratioes of 1,2-PD than mixture or perfluoropolyether diol Object.
4. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The coupling agent For silane coupling agent.
5. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The levelling agent For virgin pp acid esters levelling agent.
6. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The film forming helps Agent is propandiol butyl ether;Wetting agent is poly- carboxylic esters.
7. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The thermal insulation layer Preparation method be:According to mass fraction, prepare the borosilicate hollow glass micropearl that 80-90 parts of grain sizes are 15-20 μm, by glass Glass microballon is surface-treated with 4-6 parts of silane coupler solution, and treated glass microballoon and titanium dioxide are according to 2:3 matter Then amount is added acetone solvent and coating is made, by coating even application and the surface of plate glass after cleaning, spray film thickness than mixing Degree is 90-120 μm, and then glass is sent in continuous tunnel stove and is toasted, and the temperature of baking is 580-600 DEG C, baking It is taken out from continuous tunnel furnace after 15-20min, after coating cooling and solidifying, obtains required glass substrate thermal insulation layer.
8. a kind of building glass with good heat insulation according to claim 1, it is characterised in that:The thermal isolation film Preparation method it is as follows:According to mass fraction, organosilicon-modified acrylic polymer emulsion and dispersant are added to Scattered Kettle It inside stirs, then by nano-indium stannum oxide, Nanometer gallium oxide and coupling agent are added in Scattered Kettle, with 650- The rotating speed progress decentralized processing of 700r/min, processing time 8-10min, then successively by levelling agent, wetting agent, coalescents It is added in Scattered Kettle, continues to disperse 5-7min, obtain required heat-insulated coating, it will be by heat-insulated coating even application and glass The thermal insulation layer surface of substrate is placed at room temperature to coating and is spontaneously dried, the glass substrate after drying is then sent to tunnel 8-10min is toasted with 130-140 DEG C of temperature in stove, takes out, obtain required building glass after cooling.
CN201810364956.8A 2018-04-23 2018-04-23 A kind of building glass with good heat insulation Withdrawn CN108483940A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN112408763A (en) * 2020-11-23 2021-02-26 徐州创合新材料科技有限公司 Toughened glass heat-insulating coating and preparation method thereof

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CN107267010A (en) * 2017-07-27 2017-10-20 莱恩创科(北京)科技有限公司 A kind of multifunctional and composite type nanometer reflection heat insulating coatings and preparation method thereof
US10401542B2 (en) * 2014-12-22 2019-09-03 Mitsubishi Materials Corporation Infrared light shielding laminate and infrared light shielding material using same

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Publication number Priority date Publication date Assignee Title
CN101851068A (en) * 2010-06-12 2010-10-06 重庆龙者低碳环保科技有限公司 Method for spraying and coating heat insulation film on surface of glass
CN103042781A (en) * 2012-12-26 2013-04-17 武汉羿阳科技有限公司 Heat-insulating ceramic membrane and window membrane prepared from same
CN103113027A (en) * 2013-01-30 2013-05-22 上海翔实玻璃有限公司 Plate glass preparation method capable of enhancing heat-insulating property
US10401542B2 (en) * 2014-12-22 2019-09-03 Mitsubishi Materials Corporation Infrared light shielding laminate and infrared light shielding material using same
CN107267010A (en) * 2017-07-27 2017-10-20 莱恩创科(北京)科技有限公司 A kind of multifunctional and composite type nanometer reflection heat insulating coatings and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112408763A (en) * 2020-11-23 2021-02-26 徐州创合新材料科技有限公司 Toughened glass heat-insulating coating and preparation method thereof
CN112408763B (en) * 2020-11-23 2021-11-05 徐州创合新材料科技有限公司 Toughened glass heat-insulating coating and preparation method thereof

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