CN108483914A - A kind of formula of blackish green colour glaze - Google Patents
A kind of formula of blackish green colour glaze Download PDFInfo
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- CN108483914A CN108483914A CN201810730616.2A CN201810730616A CN108483914A CN 108483914 A CN108483914 A CN 108483914A CN 201810730616 A CN201810730616 A CN 201810730616A CN 108483914 A CN108483914 A CN 108483914A
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- blackish green
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- oxide
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of formulas of blackish green colour glaze, include according to parts by weight composition:50~80 parts of silica, 5~15 parts of alundum (Al2O3), 5~10 parts of calcium phosphate calcium, 3~5 parts of titanium dioxide, 1.5~3.5 parts of potassium oxide, 0.1~0.5 part of lithia, 0.2~0.8 part of sodium fluoride, 3~5 parts of blackish green pigment, wherein, the blackish green pigment is the mixture of ferroso-ferric oxide and chrome green, and the weight ratio of the ferroso-ferric oxide and the chrome green is 1:3~10.Blackish green glaze formula in the present invention is simple, easy to operate, at low cost, has broad application prospects.
Description
Technical field
The present invention relates to glaze technical fields, more particularly to a kind of formula of blackish green colour glaze.
Background technology
Ceramics development history be Chinese civilization history an important component part, China as four major acids ancient country it
One, remarkable contribution is made that for mankind's social progress and development, wherein the invention and development of ceramics have more unique meaning
Justice, each Chao Gedai has different artistic styles and different technical characteristics on Chinese history." china " in English existing China
The meaning, and have the meaning of ceramics, clearly demonstrate that China is exactly " native places of ceramics ".Porcelain, which is grasped, early in European manufactures skill
As soon as before art more than thousand years, Han nationality has produced very exquisite ware.China is the country for applying pottery earliest in the world
One, and Chinese porcelain receives the high praise of common people because of its high practicability and artistry.
An ancient unit of weight kiln of Yuzhou of Henan is northern celadon kiln system, still has prodigious achievement at present, generally uses bavin, coal, charcoal
It is fired with natural gas, the glaze color change that different burning process generates is also different.Outside is glaze by being produced when high-temperature fusion
Raw gorgeous colorful variation, for reason mainly in the formula of glaze, this is an important factor for influencing pottery finished product exogenic color, simultaneously
And cause pottery to enter kiln is of the same colour, the color key factor of kiln discharge ten thousand.
Glaze is exactly one layer of decorative layer on pottery surface, is the principal element for determining pottery glaze colours and being formed.Using natural
Raw mineral materials or the certain industrial chemicals of addition coordinate according to a certain percentage, are melted under high temperature reducing atmospheres effect and are covered in embryo
Moisten gloss and colorful vitreum layer rich in jade-like stone in body surface face.With abundant dicoration, increase pottery natural trend
Aesthetic feeling makes pottery have certain artistic value and enjoying value.
Invention content
The purpose of the present invention is to provide a kind of formulas of blackish green colour glaze.
To achieve the above object, the present invention provides the following technical solutions:
A kind of formula of blackish green colour glaze, according to parts by weight composition include:50~80 parts of silica, alundum (Al2O3) 5
~15 parts, 5~10 parts of calcium phosphate calcium, 3~5 parts of titanium dioxide, 1.5~3.5 parts of potassium oxide, 0.1~0.5 part of lithia, fluorination
0.2~0.8 part of sodium, 3~5 parts of blackish green pigment, wherein the blackish green pigment is the mixed of ferroso-ferric oxide and chrome green
The weight ratio of conjunction object, the ferroso-ferric oxide and the chrome green is 1:3~10.
Preferably, the weight ratio of the ferroso-ferric oxide and the chrome green is 1:3~5.
Preferably, the weight ratio of the ferroso-ferric oxide and the chrome green is 1:4.
Preferably, include according to parts by weight composition:60~80 parts of silica, 7.5~15 parts of alundum (Al2O3), calcium phosphate
6~10 parts of calcium, 3.5~5 parts of titanium dioxide, 2~3.5 parts of potassium oxide, 0.2~0.5 part of lithia, 0.4~0.8 part of sodium fluoride,
3.5~5 parts of blackish green pigment.
Preferably, include according to parts by weight composition:70~80 parts of silica, 12.5~15 parts of alundum (Al2O3), phosphoric acid
8~10 parts of calcium calcium, 4.25~5 parts of titanium dioxide, 2.75~3.5 parts of potassium oxide, 0.35~0.5 part of lithia, sodium fluoride 0.6~
0.8 part, 4~5 parts of blackish green pigment.
Preferably, further include parts by weight it is 0.5~2 part of compound antibacterial powder, the compound antibacterial powder includes that weight ratio is
1:1 zinc oxide and copper oxide.
Compared with the prior art, the advantages of the present invention are as follows:Blackish green glaze formula in the present invention is simple, operation side
Just, at low cost, it has broad application prospects.
Specific implementation mode
The present invention is described further by the following example:According to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of formula of blackish green colour glaze, includes according to parts by weight composition:50~80 parts of silica, three
5~15 parts of Al 2 O, 5~10 parts of calcium phosphate calcium, 3~5 parts of titanium dioxide, 1.5~3.5 parts of potassium oxide, lithia 0.1~
0.5 part, 0.2~0.8 part of sodium fluoride, 3~5 parts of blackish green pigment, wherein the blackish green pigment is ferroso-ferric oxide and three oxygen
Change the mixture of two chromium, the weight ratio of the ferroso-ferric oxide and the chrome green is 1:3~10.
Wherein, further include parts by weight it is 0.5~2 part of compound antibacterial powder, the compound antibacterial powder includes that weight ratio is 1:1
Zinc oxide and copper oxide.
Following blackish green colour glazes illustrated with specifically embodiment in the present invention.
Embodiment 1
Include according to parts by weight composition:50 parts of silica, 5 parts of alundum (Al2O3), 5 parts of calcium phosphate calcium, titanium dioxide 3
Part, 1.5 parts of potassium oxide, 0.1 part of lithia, 0.2 part of sodium fluoride, 3 parts of blackish green pigment, wherein the blackish green pigment is four
The weight ratio of the mixture of Fe 3 O and chrome green, the ferroso-ferric oxide and the chrome green is 1:3.
Embodiment 2
Include according to parts by weight composition:60 parts of silica, 7.5 parts of alundum (Al2O3), 6 parts of calcium phosphate calcium, titanium dioxide
3.5 parts, 2 parts of potassium oxide, 0.2 part of lithia, 0.4 part of sodium fluoride, 3.5 parts of blackish green pigment, wherein the blackish green pigment is
The weight ratio of the mixture of ferroso-ferric oxide and chrome green, the ferroso-ferric oxide and the chrome green is 1:4.
Embodiment 3
Include according to parts by weight composition:70 parts of silica, 12.5 parts of alundum (Al2O3), 8 parts of calcium phosphate calcium, titanium dioxide
4.25 parts, 2.75 parts of potassium oxide, 0.35 part of lithia, 0.6 part of sodium fluoride, 4 parts of blackish green pigment, wherein the blackish green face
Material is the mixture of ferroso-ferric oxide and chrome green, and the weight ratio of the ferroso-ferric oxide and the chrome green is
1:5。
Embodiment 4
Include according to parts by weight composition:80 parts of silica, 15 parts of alundum (Al2O3), 10 parts of calcium phosphate calcium, titanium dioxide 5
Part, 3.5 parts of potassium oxide, 0.5 part of lithia, 0.8 part of sodium fluoride, 5 parts of blackish green pigment, wherein the blackish green pigment is four
The weight ratio of the mixture of Fe 3 O and chrome green, the ferroso-ferric oxide and the chrome green is 1:10.
Blackish green glaze formula in the present invention is simple, can reach good, lasting antibiotic property.By above-described embodiment
After blackish green colour glaze in 1~4 is coated onto porcelain surface and fires successfully, at 25 DEG C act under 30min, germicidal efficiency be 54~
58%.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that including a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (6)
1. a kind of formula of blackish green colour glaze, which is characterized in that include according to parts by weight composition:50~80 parts of silica, three
5~15 parts of Al 2 O, 5~10 parts of calcium phosphate calcium, 3~5 parts of titanium dioxide, 1.5~3.5 parts of potassium oxide, lithia 0.1~
0.5 part, 0.2~0.8 part of sodium fluoride, 3~5 parts of blackish green pigment, wherein the blackish green pigment is ferroso-ferric oxide and three oxygen
Change the mixture of two chromium, the weight ratio of the ferroso-ferric oxide and the chrome green is 1:3~10.
2. the formula of blackish green colour glaze according to claim 1, which is characterized in that the ferroso-ferric oxide and three oxygen
The weight ratio for changing two chromium is 1:3~5.
3. the formula of blackish green colour glaze according to claim 2, which is characterized in that the ferroso-ferric oxide and three oxygen
The weight ratio for changing two chromium is 1:4.
4. the formula of blackish green colour glaze according to claim 1, which is characterized in that include according to parts by weight composition:Dioxy
60~80 parts of SiClx, 7.5~15 parts of alundum (Al2O3), 6~10 parts of calcium phosphate calcium, 3.5~5 parts of titanium dioxide, potassium oxide 2~
3.5 parts, 0.2~0.5 part of lithia, 0.4~0.8 part of sodium fluoride, 3.5~5 parts of blackish green pigment.
5. the formula of blackish green colour glaze according to claim 4, which is characterized in that include according to parts by weight composition:Dioxy
70~80 parts of SiClx, 12.5~15 parts of alundum (Al2O3), 8~10 parts of calcium phosphate calcium, 4.25~5 parts of titanium dioxide, potassium oxide
2.75~3.5 parts, 0.35~0.5 part of lithia, 0.6~0.8 part of sodium fluoride, 4~5 parts of blackish green pigment.
6. the formula of blackish green colour glaze according to claim 1, which is characterized in that further include parts by weight be 0.5~2 part
Compound antibacterial powder, the compound antibacterial powder include that weight ratio is 1:1 zinc oxide and copper oxide.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110204206A (en) * | 2019-05-23 | 2019-09-06 | 醴陵陶润实业发展有限公司 | Blackish green furnace transmutation glaze of cobalt nickel and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102161569A (en) * | 2010-12-28 | 2011-08-24 | 南昌航空大学 | Formula of enamel glass glaze with high anticorrosion performance for glyphosate production equipment and preparation method of enamel glass glaze with high anticorrosion performance |
CN106336120A (en) * | 2016-08-18 | 2017-01-18 | 温书强 | Jun porcelain cyanine glaze |
CN107902906A (en) * | 2017-10-12 | 2018-04-13 | 福建省德化云水窑陶瓷有限公司 | The production method of cloud glaze and its cloud glaze ceramics |
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2018
- 2018-07-05 CN CN201810730616.2A patent/CN108483914A/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102161569A (en) * | 2010-12-28 | 2011-08-24 | 南昌航空大学 | Formula of enamel glass glaze with high anticorrosion performance for glyphosate production equipment and preparation method of enamel glass glaze with high anticorrosion performance |
CN106336120A (en) * | 2016-08-18 | 2017-01-18 | 温书强 | Jun porcelain cyanine glaze |
CN107902906A (en) * | 2017-10-12 | 2018-04-13 | 福建省德化云水窑陶瓷有限公司 | The production method of cloud glaze and its cloud glaze ceramics |
Non-Patent Citations (2)
Title |
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周晓燕等: "《陶瓷坯釉料制备技术》", 31 August 2017, 江西高校出版社 * |
布莱恩•泰勒等编: "《釉料及陶瓷颜色配制手册》", 31 October 2015, 上海科学技术出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110204206A (en) * | 2019-05-23 | 2019-09-06 | 醴陵陶润实业发展有限公司 | Blackish green furnace transmutation glaze of cobalt nickel and preparation method thereof |
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Application publication date: 20180904 |