CN108467318A - The new application of organic fertilizer, the organic fertilizer and preparation method that control heavy metal in soil can be dropped - Google Patents

The new application of organic fertilizer, the organic fertilizer and preparation method that control heavy metal in soil can be dropped Download PDF

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Publication number
CN108467318A
CN108467318A CN201710987889.0A CN201710987889A CN108467318A CN 108467318 A CN108467318 A CN 108467318A CN 201710987889 A CN201710987889 A CN 201710987889A CN 108467318 A CN108467318 A CN 108467318A
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CN
China
Prior art keywords
organic fertilizer
heavy metal
soil
parts
control heavy
Prior art date
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Pending
Application number
CN201710987889.0A
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Chinese (zh)
Inventor
吴自明
宋平
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Jiangxi Lian Pu People Agricultural Development Co Ltd
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Jiangxi Lian Pu People Agricultural Development Co Ltd
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Priority to CN201710987889.0A priority Critical patent/CN108467318A/en
Publication of CN108467318A publication Critical patent/CN108467318A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The organic fertilizer and preparation method that the present invention discloses a kind of new application of organic fertilizer, can drop control heavy metal in soil, new application refer to this organic fertilizer for isolation heavy metal in proportion of crop planting and prevent the absorptions of crops;The organic fertilizer that control heavy metal in soil can be dropped, is counted, it includes in parts by weight:45 60 parts of humic acid;8 12 parts of total nutrient;68 parts of trace element;20 41 parts of Amino acid;The present invention is used in soil, can prevent absorption of the crops to heavy metal, reduces the content of heavy metal in crops, meanwhile, it can also increase the yield of crop, there is huge application prospect.

Description

The new application of organic fertilizer, the organic fertilizer that control heavy metal in soil can be dropped and preparation Method
Technical field
The present invention relates to organic fertilizer technical field more particularly to a kind of new application of organic fertilizer, can drop in control soil The organic fertilizer and preparation method of heavy metal.
Background technology
In China, startling stage has been arrived in heavy metals in farmland pollution, and national heavy metals in farmland pollution is annual dirty Contaminate 12,000,000 ton-grain food;Heavy metals in farmland pollution is heavy metal soil pollution caused by excess deposition in the soil, pollutes agriculture The heavy metal of field soil includes mainly the significant elements of bio-toxicities such as mercury, cadmium, lead, chromium and metalloid arsenic, and has certain poison The elements such as zinc, copper, the nickel of property;Heavy metal contaminants mobility very little in the soil, is not easy with water leaching, is not microorganism drop Solution, excessive heavy metal can cause physiological function of plants disorder, trophic disturbance, after entering human body by food chain, potential hazard pole Greatly, it should be specifically noted that preventing pollution of the heavy metal to agricultural land soil.
Currently, countries in the world include mainly physics, chemistry, biology, agricultural to farmland soil heavy metals pollution remediation technology Ecology and combined remediation technology etc.;Peripheral doses technology is mainly digged including soil moved in improve the original, soil removal and replacement and deep ploughing;Chemical remediation technology packet Electro reclamation, elution technique, stabilization/solidification recovery technique etc. are included, bioremediation technology refers to using specific bio-absorbable, turns Change, remove or degradation environmental contaminants, realize the depollution of environment, ecological effect restore biological control measure, mainly include phytoremediation, Microorganism remediation and animal reparation.This method is because big at low cost, easy to operate, non-secondary pollution, high treating effect and energy Its mechanism study of the advantages that area promotes and applies and application prospect are concerned.
Invention content
The organic fertilizer that it is an object of the invention to disclose a kind of new application of organic fertilizer, can drop control heavy metal in soil And preparation method.
In order to achieve the object of the present invention, the technical solution adopted in the present invention is:
A kind of new application of organic fertilizer is disclosed, this organic fertilizer is used for isolation heavy metal in proportion of crop planting and prevents crops Absorption, this organic fertilizer can be selected commercially available organic fertilizer, or use organic fertilizer disclosed in this invention.
Further, invention additionally discloses a kind of organic fertilizers realized purpose as described above and can drop control heavy metal in soil Material, is counted, it includes in parts by weight:
45-60 parts of humic acid;
8-12 parts of total nutrient;
It is 6-8 parts micro-;
20-41 parts of Amino acid.
Further, it is described trace element include at least copper, molybdenum, silicon,Zinc;By weight percentage, the copper, molybdenum, Silicon,The gross mass of zinc accounts for the 2-3% of micro- gross mass.
Further, further include 0.5-1.0 parts of fulvic acid.
Further, further include 1.5-2.0 parts of surfactant.
Further, further include 0.5-1.0 parts of acidic activator.
Further, the organic fertilizer is liquid.
Further, the organic fertilizer is solid-state.
Further, the invention also discloses a kind of are used to prepare can drop the organic fertilizer for controlling heavy metal in soil as described above Expect the preparation method of (solid fertilizer), it includes the following steps:
(1) raw material mixed powder is broken;
(2) ripening;
(3) it is granulated;
In step (1), each component raw material is mixed by blender, 50 DEG C of the reaction temperature-when stirring when control stirring 53 DEG C, reaction time 40-50 minute.
Further, the invention also discloses a kind of are used to prepare can drop the organic fertilizer for controlling heavy metal in soil as described above Expect the preparation method of (liquid fertilizer), it includes the following steps:
(1) raw material carries out co-grinding, grinding successively;
(2) plus water mixing continues to stir;
(3) filtering and removing slag;
(4) it dilutes.
In step (1), raw material is ground to micron order.
The beneficial effects of the present invention are:
The present invention is used in soil, can prevent absorption of the crops to heavy metal, reduces the content of heavy metal in crops, together When, it can also increase the yield of crop, there is huge application prospect.
Description of the drawings
Fig. 1 is that organic fertilizer of the present invention is used in the paddy examining report title page on paddy;
Fig. 2 is that organic fertilizer of the present invention is used in the paddy examining report on paddy;
Fig. 3 is that organic fertilizer of the present invention is used in the paddy examining report on paddy;
Fig. 4 is that organic fertilizer of the present invention is used in the black tea examining report on black tea;
Fig. 5 is that organic fertilizer of the present invention is used in the green tea examining report on green tea;
Fig. 6 is that organic fertilizer of the present invention is used in another batch green tea examining report on green tea.
Specific implementation mode
With reference to embodiment and attached drawing, the present invention is further described:
Embodiment 1:A kind of new application of organic fertilizer, this organic fertilizer are used for isolation heavy metal in proportion of crop planting and prevent agriculture Commercially available organic fertilizer can be selected in the absorption of crop, this organic fertilizer, or using the organic fertilizer disclosed in following examples of the present invention Material.
The crops are preferably rice.
Embodiment 2, a kind of organic fertilizer for dropping control heavy metal in soil for realizing purpose as described in Example 1, by weight Number meter is measured, it includes:
60 parts of humic acid;12 parts of total nutrient;8 parts of trace element;41 parts of Amino acid.
Total nutrient described above refers to nitrogen (N), phosphorus (P2O5), potassium (K2O), nitrogen (N), phosphorus (P2O5), potassium in total nutrient (K2O) proportioning is executed according to national regulation.
Trace element described above include at least copper, molybdenum, silicon,Zinc, by weight percentage, the copper, molybdenum, silicon,The gross mass of zinc accounts for the 3% of micro- gross mass.
Further include 1.0 parts of fulvic acid, 2.0 parts of surfactant, 1.0 parts of acidic activator.
The organic fertilizer in the present embodiment can be liquid, while may be solid-state, and when for liquid, this is organic Fertilizer can be used as foliar fertilizer use, and when for solid-state, this organic fertilizer can be mixed in fertilizer (composite fertilizer, urea etc.) according to a certain percentage It is middle to be used as base fertilizer.
Embodiment 3, a kind of organic fertilizer dropping control heavy metal in soil, place same as Example 2 repeat no more, no It is with place:
45 parts of the humic acid;8 parts of total nutrient;6 parts of trace element;20 parts of Amino acid.
The copper, molybdenum, silicon,The gross mass of zinc accounts for the 2% of micro- gross mass.
0.5 part of the fulvic acid;1.5 parts of surfactant;0.5 part of acidic activator.
Embodiment 4, a kind of organic fertilizer dropping control heavy metal in soil, place same as Example 2 repeat no more, no It is with place:
50 parts of the humic acid;10 parts of total nutrient;7 parts of trace element;30 parts of Amino acid.
The copper, molybdenum, silicon,The gross mass of zinc accounts for the 2.5% of micro- gross mass.
0.8 part of the fulvic acid;1.7 parts of surfactant;0.8 part of acidic activator.
Embodiment 5, a kind of organic fertilizer dropping control heavy metal in soil, place same as Example 2 repeat no more, no It is with place:
55 parts of the humic acid;9 parts of total nutrient;6 parts of trace element;25 parts of Amino acid.
The copper, molybdenum, silicon,The gross mass of zinc accounts for the 2.5% of micro- gross mass.
0.7 part of the fulvic acid;1.6 parts of surfactant;0.9 part of acidic activator.
Embodiment 6, weight in control soil can be dropped by being used to prepare as described in embodiment 2 to 5 is any the invention also discloses one kind The preparation method of the organic fertilizer of metal, this method refer mainly to the preparation method of solid fertilizer, it includes the following steps:
(1) raw material mixed powder is broken;(2) ripening;(3) it is granulated.
In above-mentioned steps (1), each component raw material is mixed by blender, reaction temperature when stirring when control stirring 50 DEG C -53 DEG C of degree, reaction time 40-50 minute.
In the present embodiment the method, does not state and statement in detail is implemented according to existing method, the present embodiment is no longer Excessive explanation is done to it.
Embodiment 7, weight in control soil can be dropped by being used to prepare as described in embodiment 2 to 5 is any the invention also discloses one kind The preparation method of the organic fertilizer of metal, this method refer mainly to the preparation method of liquid fertilizer, it includes the following steps:
(1) raw material carries out co-grinding, grinding successively;(2) plus water mixing continues to stir;(3) filtering and removing slag;(4) it dilutes.
In step (1), raw material is ground to micron order.
In the present embodiment the method, does not state and statement in detail is implemented according to existing method, the present embodiment is no longer Excessive explanation is done to it.
The real effectiveness of this organic fertilizer is verified for detection and the drop control of heavy metal in soil is acted on, the present inventor institute It is tested in 500 mu of big Tanakas of early rice in the support institute of agricultural sciences of unit special commission, test result is as follows:
Manure use material type:Commercially available brand solid, Liquid organic fertilizer (control group), organic fertilizer of the invention (experiment Group).
Test group:Experiment carries out in 500 mu of early rice experimental plots of live streaming, in the solid of 60 kilograms of straight preplant treatment/per acre This validation group organic fertilizer makees base fertilizer;Then, respectively at rice seedling, tillering stage and boot stage, this verification is used in three times Group organic fertilizer is used as foliar fertilizer, every time 100 milliliter/time, is watered 15 kilograms of progress foliar sprays every time;Other field pipes Reason method drops the effect of control heavy metal with common crop field, later check test group organic fertilizer in large area Rice Production.
Control group:Control group carries out in 500 mu of early rice experimental plots being broadcast live with experimental group areal, is applied before live streaming With 60 kilograms/per acre the commercially available machine fertilizer of solid make base fertilizer;Then, respectively at rice seedling, tillering stage and boot stage, in three times It is used using commercially available machine fertilizer as foliar fertilizer, every time 100 milliliter/time, is watered 15 kilograms of progress foliar sprays every time;Other fields Between management method with common crop field, examine the commercially available machine fertilizer of this control group to drop in large area Rice Production control heavy metal later Effect.
Above-mentioned test group and China Resources collective inspection test center of control group produced paddy inspection China are detected, inspection It is as follows to survey result:
Control group and test group submitted sample are respectively divided into three parts of inspections.
First part:
Submitted sample one (test group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.14mg/kg.
Submitted sample two (control group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.19mg/kg.
Decline 26.3% than control group using the cadmium metal content in the produced paddy of organic fertilizer of the present invention.
Second part:
Submitted sample one (test group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.15mg/kg.
Submitted sample two (control group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.32mg/kg.
Decline 52.1% than control group using the cadmium metal content in the produced paddy of organic fertilizer of the present invention;
Third part:
Submitted sample one (test group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.14mg/kg.
Submitted sample two (control group) predominantly detects heavy metal every 1, and wherein cadmium content (in terms of Cd) is 0.30mg/kg.
Decline 53.3% than control group using the cadmium metal content in the produced paddy of organic fertilizer of the present invention.
By above-mentioned three parts of detection data it is found that using the cadmium content mean reduction 43.9% in the produced paddy of the present invention.
And from the point of view of the output value of harvested per mu yield paddy, the average yield per mu value of experimental group is 1261.4 yuan, control group Average yield per mu value is 1239.3 yuan, is higher than the per mu yield value of control group.
Apart from the above, " Ministry of Agriculture's rice and quality of item have also been sent to using the produced paddy of organic fertilizer of the present invention Supervision and inspection center " is detected heavy metal therein, and the data after test can be found in shown in Fig. 1 to 2.
From test result it is found that the cadmium (in terms of Cd) in this sample presentation Paddy Products is 0.16mg/kg, chromium 0.19mg/kg, mercury It is not detected in the sample, lead 0.05mg/kg, arsenic 0.012mg/kg.
Other testing results can be found in shown in attached drawing 3.
Using the examining report of organic fertilizer institute's product in Tea planting of the invention as shown in figure to 4 to 6.
Based on described above, the present invention has broad application prospects, and has huge promotional value.
What the embodiment of the present invention was announced is preferred embodiment, and however, it is not limited to this, the ordinary skill people of this field Member understands the spirit of the present invention easily according to above-described embodiment, and makes different amplification and variation, but as long as not departing from this The spirit of invention, all within the scope of the present invention.

Claims (10)

1. a kind of new application of organic fertilizer, it is characterised in that:The organic fertilizer is used to that heavy metal to be isolated in proportion of crop planting And prevent the absorption of crops.
2. a kind of organic fertilizer realized purpose as described in claim 1 and can drop control heavy metal in soil, it is characterised in that:By weight Number meter is measured, it includes:
45-60 parts of humic acid;
8-12 parts of total nutrient;
It is 6-8 parts micro-;
20-41 parts of Amino acid.
3. the organic fertilizer of control heavy metal in soil can be dropped as claimed in claim 2, it is characterised in that:The trace element is extremely Less include copper, molybdenum, silicon,Zinc;By weight percentage, the copper, molybdenum, silicon,The gross mass of zinc accounts for the total matter of trace element The 2-3% of amount.
4. the organic fertilizer of control heavy metal in soil can be dropped as claimed in claim 2, it is characterised in that:It further include fulvic acid 0.5-1.0 parts.
5. the organic fertilizer of control heavy metal in soil can be dropped as claimed in claim 2, it is characterised in that:It further include surface-active 1.5-2.0 parts of agent.
6. the organic fertilizer of control heavy metal in soil can be dropped as claimed in claim 2, it is characterised in that:Further include acidic activated 0.5-1.0 parts of agent.
7. the organic fertilizer for dropping control heavy metal in soil as described in claim 2-6 is any, it is characterised in that:It is described organic Fertilizer is liquid.
8. the organic fertilizer for dropping control heavy metal in soil as described in claim 2-6 is any, it is characterised in that:It is described organic Fertilizer is solid-state.
9. a kind of preparation method being used to prepare the organic fertilizer that can drop control heavy metal in soil as claimed in claim 7, special Sign is:It includes the following steps:
(1) raw material mixed powder is broken;
(2) ripening;
(3) it is granulated;
In step (1), each component is mixed by blender, 50 DEG C -53 DEG C of reaction temperature when stirring when control stirring, Reaction time 40-50 minute.
10. a kind of preparation method being used to prepare the organic fertilizer that can drop control heavy metal in soil as claimed in claim 8, It is characterized in that:It includes the following steps:
(1) raw material carries out co-grinding, grinding successively;
(2) plus water mixing continues to stir;
(3) filtering and removing slag;
(4) it dilutes.
In step (1), raw material is ground to micron order.
CN201710987889.0A 2017-10-21 2017-10-21 The new application of organic fertilizer, the organic fertilizer and preparation method that control heavy metal in soil can be dropped Pending CN108467318A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112409089A (en) * 2021-01-25 2021-02-26 江西联普人农业科技有限公司 Mixing method of bio-organic fertilizer for reducing and controlling heavy metals
CN114902919A (en) * 2022-06-07 2022-08-16 广东省农业科学院水稻研究所 Silk seedling rice planting and cultivating method

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112409089A (en) * 2021-01-25 2021-02-26 江西联普人农业科技有限公司 Mixing method of bio-organic fertilizer for reducing and controlling heavy metals
CN114902919A (en) * 2022-06-07 2022-08-16 广东省农业科学院水稻研究所 Silk seedling rice planting and cultivating method

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Application publication date: 20180831