CN108441269A - A kind of compound hydrogen fuel and preparation method thereof - Google Patents
A kind of compound hydrogen fuel and preparation method thereof Download PDFInfo
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- CN108441269A CN108441269A CN201810158955.8A CN201810158955A CN108441269A CN 108441269 A CN108441269 A CN 108441269A CN 201810158955 A CN201810158955 A CN 201810158955A CN 108441269 A CN108441269 A CN 108441269A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/08—Inhibitors
- C10L2230/081—Anti-oxidants
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- General Chemical & Material Sciences (AREA)
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- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to chemical material technical fields, specifically, being related to a kind of compound hydrogen fuel and preparation method thereof.It is made of the raw material of following weight percent:Refined methanol 85%, the tert-butyl alcohol 5%, n-butanol 2%, dimethoxym ethane 0.5%, dimethyl ether 0.5%, petroleum ether 0.5%, n-hexane 1%, naphtha 0.5%, compound hydrogen additive 5%.The advantage of the invention is that:1, the capability of antidetonance is good, and evaporating temperature is relatively low, has good acceleration;2, induction period is longer, and gasoline stability is good, and the content of various objectionable impurities is all relatively low;3, high oxygen content, exhaust emissions cleaning;4, normal temperature and pressure can be prepared, and preparation process is simple, and additive derives from a wealth of sources, is cheap;5, it can directly substitute existing gasoline to use, be reequiped without to existing automotive oil tank, engine or other components need not also be reequiped;6, it can also be dissolved each other use with arbitrary proportion with existing gasoline, it is adaptable.
Description
Technical field
The present invention relates to chemical material technical fields, specifically, being related to a kind of compound hydrogen fuel and preparation method thereof.
Background technology
In recent years, with economic rapid development, popularity rate of the motor vehicles in China is higher and higher.Motor vehicle number
Surging causes the demand of gasoline to increase.Currently, gasoline mostly be using oil be raw material in multiple tracks complicated technology and special equipment
Under the action of be made.Due to the limitation of this preparation method, cause in motor vehicle exhaust emission containing hundreds of different chemical combination
Object, pollutant therein have solid aerosol, carbon monoxide, carbon dioxide, hydrocarbon, oxynitrides, lead and sulphur
Oxygen compound etc..Vehicle exhaust can also exert far reaching influence to the environment of human lives while being directly detrimental to health.
Sulfur dioxide in vehicle exhaust has strong impulse smell, and the generation of " acid rain " is easy to cause when reaching a certain concentration, is made
It is acidified at soil and water source, influences the growth of crops and forest.In the last hundred years, greenhouse effects have become the great misfortune of the mankind
Suffer from, Melting Glacierss, sea level rise, EI Nino phenomenon, La Nina Phenomenon etc. all the existence of the mankind is brought it is extremely severe
Challenge, and carbon dioxide is then the arch-criminal for leading to greenhouse effects.In addition, oil is as non-renewable energy resources, in the whole world
It is increasingly deficienter in range.Therefore, it is increasingly reduced to alleviate petroleum resources, petroleum product price goes up and vehicle exhaust
The pollution of environment is destroyed, a large amount of fuel substitutes come into being, to solve the oil and severe environmental pollution that are increasingly dependent on
The problem of.
Invention content
The object of the present invention is to provide a kind of compound hydrogen fuels and preparation method thereof may replace gasoline, in solution
The technical issues of stating.
To achieve the above object, the technical solution adopted in the present invention is:
A kind of compound hydrogen fuel, it is characterised in that:It is made of the raw material of following weight percent:Refined methanol 85%, uncle
Butanol 5%, n-butanol 2%, dimethoxym ethane 0.5%, dimethyl ether 0.5%, petroleum ether 0.5%, n-hexane 1%, naphtha 0.5%,
Compound hydrogen additive 5%;The compound hydrogen additive be by anti-corrosion expansion inhibiting agent, anti-knock agent, stabilizer, dissolving antioxidizing and antigum agent by
1: 1: 1: 2 ratio is formulated.
Preferably:The anti-corrosion expansion inhibiting agent is with 1- propyl -2-Pyrrolidone by the double octyl basic zinc salts of sulfonic acid ammonia according to 1
: 1 ratio is formulated.
Preferably:The anti-knock agent is methyl tertiary butyl ether(MTBE).
Preferably:The stabilizer be by oleic acid, aphthenic acids, diethylamine, lead salt according to its for 1: 1: 5: 3 ratios prepare and
At.
Preferably:The dissolving antioxidizing and antigum agent is by 2,6-di-tert-butyl p-cresol, low-carbon ferromanganese, n-octyl alcohol, positive ten
Glycol is formulated according to 3: 3: 2: 2 ratio.
The preparation method of the compound hydrogen fuel, it is characterised in that:Include the following steps:
1, according to refined methanol 85%, the tert-butyl alcohol 5%, n-butanol 2%, dimethoxym ethane 0.5%, dimethyl ether 0.5%, petroleum ether
0.5%, the composition of raw materials of n-hexane 1%, naphtha 0.5%, compound hydrogen additive 5%, gets all the various raw materials ready;
2, refined methanol is pumped into oil transportation in retort;
3, the tert-butyl alcohol, n-butanol, dimethoxym ethane, dimethyl ether, petroleum ether, n-hexane, naphtha, compound hydrogen additive are distinguished
It is added in retort, stirs 30 minutes;Make various raw materials fully emulsified in retort under room temperature, normal pressure, becomes synthesis
Liquid;
4, by Synthesis liquid made from filter filtration step 3, the mesh of filter is 120-180 mesh;
5, filling bucket is put in storage after the assay was approved, obtains finished product.
Advantageous effect:Compared with the prior art, the advantages of the present invention are as follows:1, the capability of antidetonance is good, and evaporating temperature
It is relatively low, it has good acceleration;2, induction period is longer, and gasoline stability is good, and the content of various objectionable impurities is all relatively low,
Conventional gasoline can be substituted well;3, high oxygen content, and the pollutants such as aromatic hydrocarbons are practically free of, therefore, exhaust emissions cleaning;4、
Normal temperature and pressure can be prepared, and preparation process is simple, and additive derives from a wealth of sources, is cheap;5, existing gasoline can directly be substituted
It uses, is reequiped without to existing automotive oil tank, engine or other components need not also be reequiped;It 6, can be with
It is dissolved each other use with arbitrary proportion with existing gasoline, it is adaptable.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment:Prepare the compound hydrogen fuels of 1000L
Prepare main raw material(s) refined methanol 850L;Prepare auxiliary raw material:Tert-butyl alcohol 50L, n-butanol 20L, dimethoxym ethane 5L,
Dimethyl ether 5L, petroleum ether 5L, n-hexane 10L, naphtha 5L;Prepare compound hydrogen additive 50L, wherein anti-corrosion expansion inhibiting agent 10L,
Anti-knock agent 10L, stabilizer 10L, dissolving antioxidizing and antigum agent 20L.The double octyl basic zinc salts of ammonia containing sulfonic acid in the anti-corrosion expansion inhibiting agent
5L, 1- propyl -2-Pyrrolidone 5L;Anti-knock agent is methyl tertiary butyl ether(MTBE) (MTBE) 10L;1L containing oleic acid, ring in the stabilizer
Alkanoic acid 1L, diethylamine 5L, lead salt 3L;6L containing 2,6-di-tert-butyl p-cresol in the dissolving antioxidizing and antigum agent, low-carbon ferromanganese 6L,
N-octyl alcohol 4L, n-dodecanol 4L.
First refined methanol is pumped into oil transportation in retort;Again by the tert-butyl alcohol, n-butanol, dimethoxym ethane, dimethyl ether, oil
Ether, n-hexane, naphtha, compound hydrogen additive are added separately in retort;Stirring 30 minutes makes each under room temperature, normal pressure
Kind raw material is fully emulsified in retort, becomes Synthesis liquid;Pass through Synthesis liquid, filter made from filter filtration step 3 again
Mesh be 120-180 mesh;Finally, filling bucket is put in storage after the assay was approved, obtains finished product.
After testing, compound hydrogen fuel made from the present embodiment is functional, and the pollutant emission in tail gas is obviously low
In traditional 93# gasoline, belong to clean energy resource.
Compound hydrogen fuel of the present invention has following characteristic:1, using methanol purity more than 99.9% refined methanol as lead
Raw material, the highest content of methanol can reach 90% in finished product, and therefore, oxygen content is very high, can fully burn, not only flammability
Can be good, and reduce solid aerosol, carbon monoxide, carbon dioxide, hydrocarbon, oxynitrides, lead and sulphur oxygen
The discharge of the polluted gas such as compound;2, used compound hydrogen additive be for methanol chemical characteristic and with gasoline tune
The well-designed a variety of chemical substances of the process characteristic of timing, compounding is modified to methanol, solve meet water be easily layered, low temperature
The problems such as cold starting property, oil consumption height, power dropping, addition anti-corrosion expansion inhibiting agent, anti-knock agent, stabilizer and dissolving antioxidizing and antigum agent etc.
Functional materials solve the problems such as corrosivity, swellability;3, the raw material used is extensive, cheap, and production technology is advanced,
Production cost is low, with good economic efficiency.
The better embodiment of the present invention is illustrated above, but the present invention is not limited to the embodiment,
Those skilled in the art can also make various equivalent modifications or replacement under the premise of without prejudice to spirit of that invention, this
Equivalent modification or replacement are all contained in the application claim limited range a bit.
Claims (6)
1. a kind of compound hydrogen fuel, it is characterised in that:It is made of the raw material of following weight percent:Refined methanol 85%, tertiary fourth
Alcohol 5%, dimethoxym ethane 0.5%, dimethyl ether 0.5%, petroleum ether 0.5%, n-hexane 1%, naphtha 0.5%, is answered at n-butanol 2%
Close hydrogen additive 5%;The compound hydrogen additive is by anti-corrosion expansion inhibiting agent, anti-knock agent, stabilizer, dissolving antioxidizing and antigum agent by 1:
1: 1: 2 ratio is formulated.
2. compound hydrogen fuel according to claim 1, it is characterised in that:The anti-corrosion expansion inhibiting agent is by the double octyls of sulfonic acid ammonia
Basic zinc salt and 1- propyl -2-Pyrrolidone are formulated according to 1: 1 ratio.
3. compound hydrogen fuel according to claim 1, it is characterised in that:The anti-knock agent is methyl tertiary butyl ether(MTBE).
4. compound hydrogen fuel according to claim 1, it is characterised in that:The stabilizer is by oleic acid, aphthenic acids, diethyl
Amine, lead salt are formulated according to it for 1: 1: 5: 3 ratios.
5. compound hydrogen fuel according to claim 1, it is characterised in that:The dissolving antioxidizing and antigum agent is by 2,6-, bis- uncles
Butyl paracresol, low-carbon ferromanganese, n-octyl alcohol, n-dodecanol are formulated according to 3: 3: 2: 2 ratio.
6. the preparation method of compound hydrogen fuel as described in claim 1, it is characterised in that:Include the following steps:
(1) according to refined methanol 85%, the tert-butyl alcohol 5%, n-butanol 2%, dimethoxym ethane 0.5%, dimethyl ether 0.5%, petroleum ether
0.5%, the composition of raw materials of n-hexane 1%, naphtha 0.5%, compound hydrogen additive 5%, gets all the various raw materials ready;
(2) refined methanol is pumped into oil transportation in retort;
(3) tert-butyl alcohol, n-butanol, dimethoxym ethane, dimethyl ether, petroleum ether, n-hexane, naphtha, compound hydrogen additive are added respectively
Enter into retort, stirs 30 minutes;Make various raw materials fully emulsified in retort under room temperature, normal pressure, becomes Synthesis liquid;
(4) by Synthesis liquid made from filter filtration step (3), the mesh of filter is 120-180 mesh;
(5) filling bucket is put in storage after the assay was approved, obtains finished product.
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CN201810158955.8A CN108441269A (en) | 2018-02-09 | 2018-02-09 | A kind of compound hydrogen fuel and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109337720A (en) * | 2018-09-26 | 2019-02-15 | 侍淑丽 | A kind of hydrogen-rich power fluid |
CN109370665A (en) * | 2018-10-22 | 2019-02-22 | 辛志军 | A kind of low-carbon hybrid fuel and preparation method thereof |
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CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
CN102634385A (en) * | 2011-02-12 | 2012-08-15 | 湖南红宝科技开发有限公司 | Methanol gasoline |
CN102690674A (en) * | 2012-06-09 | 2012-09-26 | 龚坤 | Production method for hydrocarbon oil for vehicles |
CN103254947A (en) * | 2013-05-10 | 2013-08-21 | 辽宁鼎瀚能源开发有限公司 | Hydrocarbon oil for spark-ignition engine and preparation method thereof |
CN105154145A (en) * | 2015-07-14 | 2015-12-16 | 贵州天鼎新能源有限公司 | M100 methanol fuel |
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CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
CN102634385A (en) * | 2011-02-12 | 2012-08-15 | 湖南红宝科技开发有限公司 | Methanol gasoline |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109337720A (en) * | 2018-09-26 | 2019-02-15 | 侍淑丽 | A kind of hydrogen-rich power fluid |
CN109370665A (en) * | 2018-10-22 | 2019-02-22 | 辛志军 | A kind of low-carbon hybrid fuel and preparation method thereof |
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Application publication date: 20180824 |