A kind of rich water tunnel grouting serous fluid and grouting process
Technical field
The present invention relates to rich water tunnel slurry injection technique field more particularly to a kind of rich water tunnel grouting serous fluids and Cementer
Skill.
Background technology
Water-conveyance tunnel belongs to great burying high artesian Tunnel Engineering, and tunnel median year flowing water, country rock underground water is mainly base
Rock crevice water and artesian water, individual lot can also have rock crusher, and there are fault-layer-phenomenons, have a significant impact to engineering.This is disconnected
Layer is higher with interior landwaste, shale content, it may occur however that prominent water burst, prominent mud disaster, grouting for water blocking reinforcing is a kind of effective and feasible
Engineering measure.Current injecting paste material is various, and cement-water-clay system (also known as cs slurries) is current various grouting and reinforcing engineerings
In a kind of common compound slurry, but slurry viscosity is generally not easy to control, and it is strong that water dissipates property, especially in two fluid grouting, in water burst
Measure it is bigger in the case of easily broken up, the stability of slurries is poor, has seriously affected slip casting effect.
Invention content
Not easy to control for the slurry viscosity of existing cement-water-clay system, water dissipates the problems such as property is strong, and stability is poor, this
Invention provides a kind of rich water tunnel grouting serous fluid.And the rich water tunnel grouting process being adapted therewith.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
A kind of rich water tunnel grouting serous fluid, as single hole water yield > 10m3/ h or rich water tunnel are there are when solution cavity, the note
It includes component A and B component to starch slurries;Wherein:
Component A is starched for cement mixing, including cement, water, coagulant and water-reducing agent, and the ratio of mud of the water and cement is
(0.8-1):1, it is coagulant in terms of 100% by the quality of water in component A:1~1.5%, water-reducing agent:1-3%;B component is water glass
Glass, by cement mixing starch in water quality be 100% in terms of, waterglass:10~20%;
When single hole water yield is > 5m3/ h, and≤10m3When/h, the grouting serous fluid includes component C, D components and component E;
Wherein:
Component C is starched for cement list, including the ratio of mud is (0.8-1):1 water and cement;D groups are divided into cement mixing slurry, packet
Include cement, water and retarder, the ratio of mud of the water and cement is (0.8-1):1, with the gross mass of water in component C and D components
For 100% meter, retarder:0.6-0.8%;Component E is waterglass, by the gross mass of water in component C and D components be 100% in terms of,
Waterglass:14.5-15.5%;
When single hole water yield is > 2m3/ h, and≤5m3/ h, the grouting serous fluid include F components and G components, wherein F components
It is starched for cement mixing, including cement, water and retarder, the ratio of mud of the water and cement is (0.8-1):1, with water in F components
Quality be 100% meter, retarder:0.7%-1%;G groups are divided into waterglass, are water in terms of 100% by the quality of water in F components
Glass:14.5-15.5%.
Compared with the existing technology, rich water tunnel grouting serous fluid provided by the invention, has the advantage that:
The present invention matches according to the slurries of the engineerings situation reasonable designs such as size, the rock crusher degree of rich water tunnel gushing amount
Than changing size performance, adapting to the needs of engineering.When single hole water yield is more than 10m3/ h or rich water tunnel are needed there are when solution cavity
Grouting serous fluid is wanted to complete condensation within the injection short period, grouting serous fluid provided by the invention is suitable for big water yield, and gushing water is prominent
Mud, the slip casting under the conditions of karst etc., accelerated clotting time are can be controlled in 30s~60s.When single hole water yield is > 5m3/ h, and≤
10m3When/h, grouting serous fluid provided by the invention is suitable for larger water yield, and the slip casting under the conditions of multiply multiple spot water burst promotees solidifying
Time can be controlled in 60s-120s.When single hole water yield is > 2m3/ h, and≤5m3When/h, grouting serous fluid provided by the invention,
General suitable for water yield, country rock can be controlled in 120s or more compared with the slip casting under broken condition, accelerated clotting time.
Rich water tunnel grouting serous fluid provided by the invention, controllability is good, is not easy by broken off by water flush, and the property noted is strong, effectively
Solve the disadvantage that slurries are easily broken up under the conditions of big water yield.
The coagulant is one kind in polyacrylamide or calcium aluminate, preferably polyacrylamide.
Polyacrylamide amine molecule is in the continuous phase of cement granules, and cement granules are because absorbing the moisture of polyacrylamide due to water
Change (this process will be faster than simple hydration process), generates each macromolecule reticular structure to tension, effectively compensate for cement knot
While there is crack in stone body, due to the package action of macromolecule reticular structure, it is allowed to and the mixture of cement macroscopic view
On show to be not easy by the property of broken off by water flush.
The water-reducing agent is naphthalene water reducer.
Have the function of keeping slurry fluidity, mechanism as follows:
After hydrated cementitious, since interionic van der Waals interaction and cement essential mineral band in hydration process are different
Charge and generate cohesion, and then generate flocculent structure.High efficiency water reducing agent belongs to anionic surfactant mostly, is incorporated into cement
In after, anion in water-reducing agent can be adsorbed in cement particle surface under the effect of the positive charge of cement particle, form diffusion
Electric double layer makes cement particle disperse under electrostatic repulsion effect, in the space grid structure formed in cement hydration process
Irreducible water releases, being caused to flow.
The retarder is one kind in phosphate or metaphosphate, is selected as sodium dihydrogen phosphate.
The retardation mechanism of disodium bicarbonate includes two aspects:Disodium hydrogen phosphate is a kind of electrolyte salt first, can be
A variety of charged particles are ionized out in water, the presence of these charged particles has delayed cement setting;Secondly in Portland cement
Containing calcium hydroxide, disodium hydrogen phosphate generates calcium phosphate not soluble in water with calcium hydroxide reaction, and is wrapped in cement granules table
Face, prevents its contact with water, and retarding action is played to hydrated reaction of cement.
The Baume degrees of the waterglass is 25-40Be', modulus 3.1-3.4.
The present invention also provides a kind of rich water tunnel grouting process, as single hole water yield > 10m3There are molten for/h or rich water tunnel
When hole, bi-slurry grouting method is taken, is starched all the way for component A cement mixing, is all the way B component waterglass, slip casting initial pressure is
0.9-1MPa。
When single hole water yield is > 5m3/ h, and≤10m3When/h, first carries out component C cement list and starch slip casting, continue 25-
Then 35min is changed to two fluid grouting, be all the way D component cement mixing slurries, be all the way component E waterglass, control single slurry slip casting with
The grouting pressure of two fluid grouting is identical, and slip casting initial pressure is 0.9-1MPa.
It is > 5m in above-mentioned single hole water yield3/ h, and≤10m3Segmenting slip casting, initial list liquid note are used during/h slip castings
Slurry:Keep single slurry slip casting identical as the grouting pressure of two fluid grouting, cement list starches good fluidity, and consistency is low, only need to control single slurry
Slip casting 25-35min, you can filling tunnel distal end country rock tiny crack, it is preliminary to reinforce distal end rock mass;Two fluid grouting:Reinforce water blockoff
Effect is filled rock cranny within the scope of 3 to 5 meters of tunnel, and slip casting effect is more notable.
When single hole water yield is > 2m3/ h, and≤5m3When/h, using bi-slurry grouting method, mixed all the way for F component cements
Slurry, is all the way G component waterglass.
Specifically, it is preferable that as single hole water yield > 10m3/ h or rich water tunnel are there are when solution cavity, slip casting during slip casting
Pressure is no more than 5.5MPa.
Preferably, when single hole water yield is > 5m3/ h, and≤10m3When/h, grouting pressure is no more than during slip casting
4.5MPa。
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
The present invention is limited, another following lift all relies on laboratory test, principle of orthogonal test.
Embodiment 1
The present invention is that embodiment provides a kind of rich water tunnel grouting serous fluid, as single hole water yield > 10m3/ h or rich water tunnel
There are when solution cavity, the proportioning of grouting serous fluid is as shown in table 1 below.
The grouting serous fluid of 1 serial number 1-9 of table matches
Serial number |
The ratio of mud |
Waterglass |
Coagulant |
Water-reducing agent |
1 |
1:1 |
10% |
1% |
1% |
2 |
1:1 |
10% |
1.25% |
2% |
3 |
1:1 |
10% |
1.50% |
3% |
4 |
1:1 |
15% |
1% |
2% |
5 |
1:1 |
15% |
1.25% |
3% |
6 |
1:1 |
15% |
1.50% |
1% |
7 |
1:1 |
20% |
1% |
3% |
8 |
1:1 |
20% |
1.25% |
1% |
9 |
1:1 |
20% |
1.50% |
2% |
Above-mentioned coagulant is polyacrylamide;Above-mentioned water-reducing agent is poly- naphthalene formaldehyde sulfonate salt.
The grouting process of above-mentioned rich water tunnel grouting serous fluid, takes bi-slurry grouting method, is all the way waterglass, is all the way water
The cement mixing slurry of mud, coagulant, water-reducing agent, slip casting initial pressure is 0.9-1MPa, and grouting pressure is no more than during slip casting
5.5MPa。
The grouting serous fluid of above-mentioned serial number 1-9 carries out laboratory test performance detection, and testing result is as shown in table 2 below.
2 performance test results of table
Serial number |
Gelling time/s |
14d compression strength/MPa |
1 |
21.275 |
3.25 |
2 |
25.613 |
3.18 |
3 |
28.715 |
2.53 |
4 |
20.475 |
3.25 |
5 |
24.126 |
3.99 |
6 |
20.920 |
3.00 |
7 |
24.743 |
3.60 |
8 |
26.665 |
3.76 |
9 |
24.148 |
4.15 |
By table 2, it is apparent that provided by the invention work as single hole water yield > 10m3There are solution cavities for/h or rich water tunnel
When, grouting serous fluid is in 30s~60s inner gels, and compression strength is high, reaches requirement of engineering.
Embodiment 2
The present invention is that embodiment provides a kind of rich water tunnel grouting serous fluid, when single hole water yield is > 5m3/ h, and≤10m3/
When h, the proportioning of grouting serous fluid is as shown in table 3 below.
The grouting serous fluid of 3 serial number 10-12 of table matches
Serial number |
The ratio of mud |
Waterglass |
Retarder |
10 |
1:1 |
14.5% |
0.60% |
11 |
1:1 |
15% |
0.70% |
12 |
1:1 |
15.5% |
0.80% |
Above-mentioned retarder is disodium bicarbonate.
The grouting process of above-mentioned rich water tunnel grouting serous fluid first carries out cement list and starches slip casting, continues 30min, be then changed to
Two fluid grouting is all the way waterglass, is all the way cement, the cement mixing of retarder slurry, controls single slurry slip casting and two fluid grouting
Grouting pressure is identical, and slip casting initial pressure is 0.9-1MPa, and grouting pressure is no more than 4.5MPa during slip casting.
The grouting serous fluid of above-mentioned serial number 10-12 carries out performance detection after slip casting, and testing result is as shown in table 4 below.
4 performance test results of table
Serial number |
Gelling time/s |
14d compression strength/MPa |
10 |
110.375 |
3.14 |
11 |
102.358 |
3.25 |
12 |
109.681 |
3.19 |
By table 4, it is apparent that single hole water yield provided by the invention is > 5m3/ h, and≤10m3When/h, slip casting slurry
Liquid is in 60s-120s inner gels, and compression strength is high, reaches requirement of engineering.
Embodiment 3
The present invention is that embodiment provides a kind of rich water tunnel grouting serous fluid, when single hole water yield is > 2m3/ h, and≤5m3/h
When, the proportioning of grouting serous fluid is as shown in table 5 below.
The grouting serous fluid of 5 serial number 13-15 of table matches
Serial number |
The ratio of mud |
Waterglass |
Retarder |
13 |
1:1 |
14.5% |
0.70% |
14 |
1:1 |
15% |
0.90% |
15 |
1:1 |
15.5% |
1.00% |
Above-mentioned retarder is disodium bicarbonate.
The grouting process of above-mentioned rich water tunnel grouting serous fluid is all the way waterglass using bi-slurry grouting method, is all the way water
The cement mixing slurry of mud, retarder.
The grouting serous fluid of above-mentioned serial number 13-15 carries out performance detection after slip casting, and testing result is as shown in table 6 below.
6 performance test results of table
Serial number |
Gelling time/s |
14d compression strength/MPa |
13 |
121.352 |
3.15 |
14 |
126.487 |
3.27 |
15 |
123.684 |
3.26 |
It is by table 6, it is apparent that provided by the invention when single hole water yield is > 2m3/ h, and≤5m3When/h, slip casting slurry
Liquid is in 120s or more gels, and compression strength is high, reaches requirement of engineering.
Embodiment 4
The present invention is that embodiment provides a kind of rich water tunnel grouting serous fluid, as single hole water yield > 10m3/ h or rich water tunnel
There are when solution cavity, the proportioning of grouting serous fluid is as shown in table 7 below.
The grouting serous fluid of 7 serial number 16-18 of table matches
Serial number |
The ratio of mud |
Waterglass |
Polyacrylamide |
Water-reducing agent |
16 |
1:1 |
15% |
1% |
2% |
17 |
1:1 |
15% |
1.25% |
2% |
18 |
1:1 |
15% |
1.50% |
2% |
Above-mentioned water-reducing agent is poly- naphthalene formaldehyde sulfonate salt.
The grouting process of above-mentioned rich water tunnel grouting serous fluid, takes bi-slurry grouting method, is all the way waterglass, is all the way water
The cement mixing slurry of mud, coagulant, water-reducing agent, slip casting initial pressure is 0.9-1MPa, and grouting pressure is no more than during slip casting
5.5MPa。
Embodiment 5
The present invention is that embodiment provides a kind of rich water tunnel grouting serous fluid, as single hole water yield > 10m3/ h or rich water tunnel
There are when solution cavity, the proportioning of grouting serous fluid is as shown in table 8 below.
The grouting serous fluid of 8 serial number 19-21 of table matches
Serial number |
The ratio of mud |
Waterglass |
Calcium aluminate |
Water-reducing agent |
19 |
1:1 |
15% |
1% |
2% |
20 |
1:1 |
15% |
1.25% |
2% |
21 |
1:1 |
15% |
1.50% |
2% |
Above-mentioned water-reducing agent is poly- naphthalene formaldehyde sulfonate salt.
The grouting serous fluid of serial number 16-21 is subjected to performance detection after slip casting, testing result is as shown in table 9 below.
9 performance test results of table
From table 9, it is apparent that polyacrylamide coagulates significant effect than the rush of calcium aluminate.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.