CN108439919A - A kind of fibre-reinforced infiltration crystallization type concrete - Google Patents

A kind of fibre-reinforced infiltration crystallization type concrete Download PDF

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Publication number
CN108439919A
CN108439919A CN201810535140.7A CN201810535140A CN108439919A CN 108439919 A CN108439919 A CN 108439919A CN 201810535140 A CN201810535140 A CN 201810535140A CN 108439919 A CN108439919 A CN 108439919A
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parts
fibre
reinforced
crystallization type
type concrete
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Inventor
陈万昕
李静
甘振先
陈连佳
李泽玉
吕宏鑫
李小雨
高嘉欣
戚桠童
冯伟浩
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South China University of Technology SCUT
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Priority to CN201810535140.7A priority Critical patent/CN108439919A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/021Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of fibre-reinforced infiltration crystallization type concretes, and by weight, raw material includes following components:120 130 parts of cement, 55 65 parts of flyash, 332 359 parts of fine aggregate, 500 560 parts of coarse aggregate, 50.5 59.5 parts of water, 0.3 0.9 parts of cellulose fibre, 3.3 3.48 parts of water-reducing agent, 22.5 27 parts of swelling agent, penetrant crystalline material 39.The present invention can realize while be promoted the working performance and basic mechanical performance of concrete, and improvement improves the economy of concrete to the inhibiting effect of certain performance when singly mixing cellulose fibre or penetrant crystalline material to expand the scope of application of engineering concrete.

Description

A kind of fibre-reinforced infiltration crystallization type concrete
Technical field
The present invention relates to building material fields, and in particular to fiber increasing that is a kind of while ensureing mechanical property and working performance Strong infiltration crystallization type concrete.
Background technology
Cement-base infiltration crystallization material is a kind of novel rigid material, and active chemistry therein can penetrate into coagulation It is native internal, it reacts with unhydrated cement granules, generates insoluble crystalline material, be filled in distress in concrete or gap In, play the role of air-free concrete, improve intensity, improve the performance of concrete, extend its service life, is improved in engineering Mechanical performance of concrete and the common additive of waterproof impervious characteristic.
It is the means that concrete performance is commonly improved in engineering that fiber is added in concrete, and the addition of fiber can change Kind concrete work, mechanics etc. performance.Cellulose fibre is new and high technology material of new generation, higher with elasticity modulus, The advantages that easily disperseing and be good with concrete bond performance.At present about cellulose fibre concrete early anti-cracking behavior and impermeability Can research it has been reported that but based on its superior structural and other additives interact in terms of the improvement to performance research compared with It is few.
Invention content
The technical problem to be solved by the present invention is in view of the above shortcomings of the prior art, provide one kind and make up singly mixing fiber To the incomplete shortcoming of performance improvement under cellulose fiber or penetrant crystalline material, while enhancing the working performance and mechanics of concrete Performance is realized and plays interaction facilitation while performance mutually makes up.
The present invention is realized using following scheme:
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 120-130 parts, 55-65 parts of flyash, 332-359 parts of fine aggregate, 500-560 parts of coarse aggregate, 50.5-59.5 parts of water, fiber 0.3-0.9 parts, 3.3-3.48 parts of water-reducing agent, 22.5-27 parts of swelling agent, 3-9 parts of penetrant crystalline material.
Further, the cement is PO42.5 class g cements.
Further, the flyash is I grade of flyash.
Further, the fine aggregate is sand in continuous grading.
Further, the coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.
Further, the fiber is cellulose fibre, length 2-3mm, elasticity modulus 8-10Gpa, tensile strength For 800-900MPa.
Further, the water-reducing agent is polycarboxylate superplasticizer mother liquor.
Further, the solid content of the polycarboxylate superplasticizer mother liquor is 40wt%.
Further, the swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.
Further, the penetrant crystalline material is activated silica penetrant crystalline masterbatch.
Compared with prior art, the invention has the advantages that:
1, the volume of permeable crystallization type material and cellulose fibre is positively correlated with concrete slump and negatively correlated respectively Relationship, i.e., cellulose fibre incorporation can to a certain degree reduce concrete slump;And penetrant crystalline material can increase coagulation The mobile performance of soil.When mixing both additives simultaneously in concrete, permeable crystallization type material can slow down cellulose fiber The reduction to concrete slump is tieed up, the defect that working performance is lost when being individually added into cellulose fibre is made up.
2, in the concrete sample of compound incorporation cellulose fiber peacekeeping penetrant crystalline material, the permeable crystallization type of appropriate volume Material can generate synergistic effect with cellulose fibre and be oozed that is, on the basis of cellulose fibre promotes concrete crushing strength Saturating crystalline materials improve cellulose fibre to mixing the humidification of test specimen compression strength again simultaneously again, the examination for both making to mix again Part has in compression strength to be promoted by a relatively large margin.
3, production process of the present invention is simple, can direct plunge into Practical Project.
Specific implementation mode
It to make the objectives, technical solutions, and advantages of the present invention more comprehensible, below will be by specific implementation, to this hair Bright to be described in further detail, embodiments of the present invention are not limited thereto.
The slump and resistance to compression axial compressive strength of following gained concrete are according to GB/T 50080-2002《It is common mixed Solidifying soil mixture method for testing performance standard》And GB/50081-2002《Standard for test methods of mechanical properties of ordinary concrete》Into Row experimental test.
Embodiment 1
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 130 parts, 65 parts of flyash, 350 parts of fine aggregate, 550 parts of coarse aggregate, 57 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.3 part of fiber, 3 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 2
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 130 parts, 65 parts of flyash, 350 parts of fine aggregate, 550 parts of coarse aggregate, 57 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.6 part of fiber, 3 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 3
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 130 parts, 65 parts of flyash, 350 parts of fine aggregate, 550 parts of coarse aggregate, 57 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.9 part of fiber, 3 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 4
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 125 parts, 60 parts of flyash, 340 parts of fine aggregate, 540 parts of coarse aggregate, 56 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.3 part of fiber, 6 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 5
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 125 parts, 60 parts of flyash, 340 parts of fine aggregate, 540 parts of coarse aggregate, 56 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.6 part of fiber, 6 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 6
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 125 parts, 60 parts of flyash, 340 parts of fine aggregate, 540 parts of coarse aggregate, 56 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.9 part of fiber, 6 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 7
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 120 parts, 55 parts of flyash, 335 parts of fine aggregate, 530 parts of coarse aggregate, 55 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.3 part of fiber, 9 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 8
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 120 parts, 55 parts of flyash, 335 parts of fine aggregate, 530 parts of coarse aggregate, 55 parts of water, 3.3 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.6 part of fiber, 9 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Embodiment 9
A kind of fibre-reinforced infiltration crystallization type concrete, by weight, which includes following components:Cement 120 parts, 55 parts of flyash, 335 parts of fine aggregate, 530 parts of coarse aggregate, 55 parts of water, 3.4 parts of water-reducing agent, 25 parts of swelling agent, cellulose 0.9 part of fiber, 9 parts of penetrant crystalline material.
The cement is PO42.5 class g cements.The flyash is I grade of flyash.The fine aggregate is in continuous grading Sand.The coarse aggregate is the continuous grading rubble that grain size is 5mm-15mm.The length of the cellulose fibre is 2-3mm, elasticity Modulus is 8-10Gpa, tensile strength 800-900MPa.The water-reducing agent is that the polycarboxylate water-reducer that solid content is 40wt% is female Liquid.The swelling agent is calcium sulphoaluminate-calcium oxide composite expanding agent.The penetrant crystalline material is activated silica penetrant crystalline Masterbatch, main component is high efficiency water reducing agent, early strength agent, active anion catalyst, special cement and quartz sand etc., by certain ratio Example is prepared.
Table 1:The performance test of case study on implementation 1-9
Table 1
The slump (mm) Axial compressive strength (N/mm2)
Case study on implementation 1 150 33.7
Case study on implementation 2 130 34.5
Case study on implementation 3 120 35.8
Case study on implementation 4 160 40.2
Case study on implementation 5 150 41.7
Case study on implementation 6 130 42.2
Case study on implementation 7 170 35.1
Case study on implementation 8 150 37.5
Case study on implementation 9 150 38.2
As shown in Table 1:
The permeable crystallization type material of concrete sample identical for cellulose fibre volume, 3 kinds of volumes improves fibre The slump of cellulose fiber concrete, promotion amplitude are improved with the increase of permeable crystallization type material;For different cellulose fibers Volume is tieed up, when permeable crystallization type material volume is identical, the promotion amplitude of the slump is almost the same.
When cellulose fibre volume is constant, concrete crushing strength increases with permeable crystallization type material volume and presents and first carry The process reduced after height, and compression strength is apparently higher than other two volumes when volume is appropriate;When permeable crystallization type material is mixed When amount remains unchanged, the volume correlation of concrete crushing strength and cellulose fibre, but cellulose fibre volume Increase little to the increase rate of compression strength.It is worth noting that, when permeable crystallization type material volume is low, no matter mix how much Cellulose fibre, compression strength is mixed test piece intensity with low-dosage permeable crystallization type bill of materials and is approached, and is below blank control Group and mix test specimen with the cellulose fibre list of volume;Test specimen compression strength and blank are mixed in answering for the permeable crystallization type material of high additive Group is close, and slightly above high additive permeable crystallization type bill of materials mixes test specimen, but still mixes examination less than the cellulose fibre list with volume Part;It is obviously improved when permeable crystallization type material volume where appropriate, mixing test specimen compression strength again, compression strength has been even more than together The cellulose fibre list of volume mixes test specimen.
The object, technical solutions and advantages of the present invention are further described in detail in present embodiment, should say Bright, the foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all spirit in the present invention Within principle, made by all any modification, equivalent and improvement etc., should be included within the scope of the present invention.

Claims (10)

1. a kind of fibre-reinforced infiltration crystallization type concrete, which is characterized in that by weight, which includes with the following group Point:120-130 parts of cement, 55-65 parts of flyash, 332-359 parts of fine aggregate, 500-560 parts of coarse aggregate, 50.5-59.5 parts of water, 0.3-0.9 parts of fiber, 3.3-3.48 parts of water-reducing agent, 22.5-27 parts of swelling agent, 3-9 parts of penetrant crystalline material.
2. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the cement For PO42.5 class g cements.
3. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the flyash For I grade of flyash.
4. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the fine aggregate For sand in continuous grading.
5. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the coarse aggregate It is the continuous grading rubble that grain size is 5mm-15mm.
6. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the fiber is Cellulose fibre, the length of 2-3mm, elasticity modulus 8-10Gpa, tensile strength 800-900MPa.
7. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the water-reducing agent It is polycarboxylate superplasticizer mother liquor.
8. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 7, which is characterized in that the polycarboxylic acids The solid content of water-reducing agent mother liquor is 40wt%.
9. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the expansion Agent is calcium sulphoaluminate-calcium oxide composite expanding agent.
10. a kind of fibre-reinforced infiltration crystallization type concrete according to claim 1, which is characterized in that the infiltration Crystalline material is activated silica penetrant crystalline masterbatch.
CN201810535140.7A 2018-05-30 2018-05-30 A kind of fibre-reinforced infiltration crystallization type concrete Pending CN108439919A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793884A (en) * 2018-07-24 2018-11-13 华南理工大学 A kind of infiltration crystallization type concrete of precenting chlorate corrosion
CN110668750A (en) * 2019-09-25 2020-01-10 中建西部建设北方有限公司 Special high-impermeability compensation shrinkage concrete for urban underground comprehensive pipe gallery and preparation method thereof
CN113006818A (en) * 2021-02-23 2021-06-22 福州大学 Novel stainless steel impervious segment and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104150813A (en) * 2014-08-21 2014-11-19 青岛骏泽盛泰智能科技有限公司 Anti-cracking anti-corrosion waterproof material
CN106495601A (en) * 2015-10-28 2017-03-15 浙江横店建筑工程有限公司 Injection Basalt fiber concrete and slope retaining surface construction method
CN107935466A (en) * 2017-11-13 2018-04-20 南通不二环境科技有限公司 A kind of impermeabilisation concrete

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CN104150813A (en) * 2014-08-21 2014-11-19 青岛骏泽盛泰智能科技有限公司 Anti-cracking anti-corrosion waterproof material
CN106495601A (en) * 2015-10-28 2017-03-15 浙江横店建筑工程有限公司 Injection Basalt fiber concrete and slope retaining surface construction method
CN107935466A (en) * 2017-11-13 2018-04-20 南通不二环境科技有限公司 A kind of impermeabilisation concrete

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793884A (en) * 2018-07-24 2018-11-13 华南理工大学 A kind of infiltration crystallization type concrete of precenting chlorate corrosion
CN110668750A (en) * 2019-09-25 2020-01-10 中建西部建设北方有限公司 Special high-impermeability compensation shrinkage concrete for urban underground comprehensive pipe gallery and preparation method thereof
CN113006818A (en) * 2021-02-23 2021-06-22 福州大学 Novel stainless steel impervious segment and preparation method thereof

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