CN108410302A - A kind of nano anti-corrosive thermal insulation coatings - Google Patents
A kind of nano anti-corrosive thermal insulation coatings Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C08K3/00—Use of inorganic substances as compounding ingredients
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- C08K3/20—Oxides; Hydroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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Abstract
The present invention proposes a kind of nano anti-corrosive thermal insulation coatings, and raw material includes following components by weight：45 65 parts of 52 65 parts of acrylic resin, 12 26 parts of alkyd resin, 5 12 parts of aerosil, 11 18 parts of nano ceramics hollow bead, modified 35 55 parts of oyster shell whiting, 25 parts of graphene, 39 parts of nano zircite, 38 parts of nano zine oxide, 6 17 parts of nano-titanium dioxide, 5 18 parts of auxiliary agent and water；The present invention has excellent heat-insulating property, while having good mechanical performance and impact resistance.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of nano anti-corrosive thermal insulation coatings.
Background technology
In recent years, with the rapid development that World Science technology and society produces, there is a growing awareness that environment and energy
Source problem has become 21 century urgent problem to be solved, and energy problem plays important work in world's development of all countries economy
With.Currently, national government not only to improve China the building that will be built build and following energy saving igniter, and
Also Energy-saving reformation is carried out in constructed original building.Thus the project of energy-saving heat-insulating has become today's society
One important topic of scientific circles.
Building wall uses painting insulating mold coating to ensure that there is building the method for energy-efficient performance to have obtained
It is more and more widely used, existing building insulating moulding coating mainly uses common portland cement, flyash, fiber etc.
Material is as thermal insulating filling, the heat-insulated of coating, heat resistance and the requirement that cannot meet society with the adhesive force of metope, up for
It improves.
In Research on Energy Saving, the EPS/XPS plate thin plastering outer heat preservation systems that China carries out at present, there is fire prevention
Performance is low, infiltration easy to crack even hollowing and obscission, and has buried hidden danger for serious white garbage pollution in the future；
Hard polyurethane foam paint finishing, fire protecting performance is poor, there is security risks；Polystyrene granule insulating mortar and vitrified micro-bead heat preserving
Mortar fades out market because applying thickness, long construction period, the reasons such as heat insulation effect difference.A kind of fire prevention of market in urgent need, safety, heat preservation
The aqueous insulation exterior wall coating of thin layer excellent, easy for construction, that cost performance is excellent of heat-proof quality.
Invention content
The present invention proposes a kind of nano anti-corrosive thermal insulation coatings, and thermal insulation is good, high temperature resistant, intensity are high, anti-pollution, is used for
The strong adhesive force of building wall and matrix, service life are long.
The present invention proposes a kind of nano anti-corrosive thermal insulation coatings, and raw material includes following components by weight：Acrylic acid tree
52-65 parts of fat, 12-26 parts of alkyd resin, 5-12 parts of aerosil, 11-18 parts of nano ceramics hollow bead, modified shellfish
35-55 parts of shell powder, 3-9 parts of nano zircite, 3-8 parts of nano zine oxide, 6-17 parts of nano-titanium dioxide, helps 2-5 parts of graphene
45-65 parts of 5-18 parts of agent and water；
The porosity of the aerosil is 90-95%, specific surface area 950-1100m2/g；
The grain size of the nano zircite is 35-50nm；
The grain size of the nano zine oxide is 50-80nm；
The grain size of the nano-titanium dioxide is 10-50nm.
Preferably, raw material includes following components by weight：55-60 parts of acrylic resin, 15-20 parts of alkyd resin,
8-11 parts of aerosil, modified 38-50 parts of oyster shell whiting, 3-5 parts of graphene, is received 13-16 parts of nano ceramics hollow bead
55-60 parts of 5-8 parts of zirconium oxide of rice, 5-7 parts of nano zine oxide, 8-15 parts of nano-titanium dioxide, 7-10 parts of auxiliary agent and water.
Preferably, 58 parts of acrylic resin, 18 parts of alkyd resin, 10 parts of aerosil, hollow of nano ceramics
15 parts of grain, modified 45 parts of oyster shell whiting, 4 parts of graphene, 6 parts of nano zircite, 6 parts of nano zine oxide, 12 parts of nano-titanium dioxide,
58 parts of 9 parts of auxiliary agent and water.
Preferably, the auxiliary agent includes the component of following mass fraction：
Dispersant 50400.4-0.8；
Wetting agent X4050.1-0.2；
Multifunction amine auxiliary agent A MP-950.1-0.2；
Antifoaming agent NXZ0.2-0.5；
Preservative LXE0.1-0.3；
Thickener TT9350.2-0.4；
Levelling agent RM-20200.3-0.5；
Preferably, the antifoaming agent is n-octyl alcohol, tributyl phosphate, triphenyl phosphate, emulsification methyl-silicone oil, emulsification benzyl silicon
The combination of one or more of oil.
The present invention makes the present invention have excellent heat-insulating property, together using acrylic resin, alkyd resin as film forming matter
When there is good mechanical performance and impact resistance, wherein alkyd resin low pole structural content is high, and dissolubility is good, makes this hair
It is bright that there is preferable gloss height, brushability, levelability；The addition of graphene, modified oyster shell whiting, nano ceramics hollow bead, greatly
It is big to improve the adhesive force and impact resistance of the present invention, and the cost of coating material is reduced, the present invention passes through various fillers
Synergistic effect, enhance the interface interaction of graphene and film forming matter, both make it is preferably compatible, in addition, modified graphene
In alkyl bond can fully be wound with film forming matter molecule, further improve the steady of " film forming matter-graphene " structure
It is qualitative so that the present invention, can be effectively by load transfer to the extremely strong modification stone of physical mechanical property when by outer force effect
On black alkene, to substantially increase the shock resistance of the present invention, there is certain static air in nano ceramics hollow bead
Layer can be made pottery among being evenly distributed in film forming matter together with modified oyster shell whiting by nano ceramics hollow bead and nanometer
There is a large amount of emission of ions with identical charges between porcelain hollow bead, nano ceramics hollow bead and modified oyster shell whiting
Electromagnetic wave, the conduction for effectively shielding thermal energy, preventing thermal energy, to substantially increase the heat-insulating property of the present invention.Specifically, two
Unique nano-pore and tridimensional network make it have extremely low thermal coefficient in silica aerogel, on the one hand, nano-pore
Aperture is close with the mean free path of phonon, and nano-pore can generate stronger scattering process to phonon, reduce being averaged certainly for phonon
By journey, reduce the efficiency of Gas-solid Coupling, on the one hand, nano-pore hole wall in aerosil can constantly to heat radiation into
Row reflection, refraction, make the heat that radiation is transmitted constantly decline, on the other hand, the pore-size and air of aerosil
The mean free path of molecule is close, and the gas molecule in nano-pore often loses the ability of free-flowing so that is in stomata
Vacuum state, the efficiency of convection current heat transfer is close to zero, to play heat-insulated effect；Nano zircite is added in coating, oxygen
Change zirconium has a good barriering effect to infrared ray, the tightly packed gap for applying interlayer of nano-particle, form complete air every
Thermosphere substantially increases the heat-proof quality of coating；The nano zine oxide of addition can be prevented obviously in the lower substrate of thermal cycle effect
It is thermally generated the formation of oxide, extends the thermal cycle life of coating；Nano-titanium dioxide can improve the resistance to soiling of coating, it
Automatic cleaning action is mainly to prevent pollutant in the deposition of coating surface, and under light illumination, nano-titanium dioxide is former according to photocatalysis
Reason constantly decomposes the organic matter for being gathered in coating surface, and the dust that coating surface adsorbs is made to lose the adhesive between coating,
To be easy to be removed, the cleaning of coating surface is kept, makes coating that there is long-term nalgene dirt effect.
Specific implementation mode
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent replacement etc. are in this hair
In bright protection domain.
The embodiment of the present invention provides a kind of nano anti-corrosive thermal insulation coatings, and raw material includes following components by weight：Third
52-65 parts of olefin(e) acid resin, 12-26 parts of alkyd resin, 5-12 parts of aerosil, 11-18 parts of nano ceramics hollow bead,
Modified 35-55 parts of oyster shell whiting, 2-5 parts of graphene, 3-9 parts of nano zircite, 3-8 parts of nano zine oxide, nano-titanium dioxide 6-
45-65 parts of 17 parts, 5-18 parts of auxiliary agent and water；
The porosity of the aerosil is 90-95%, specific surface area 950-1100m2/g；
The grain size of the nano zircite is 35-50nm；
The grain size of the nano zine oxide is 50-80nm；
The grain size of the nano-titanium dioxide is 10-50nm.
The acrylic resin, alkyd resin are the elasticity third of a kind of high solids content, low film formation temperature, ultraviolet-crosslinkable
Olefin(e) acid lotion is the film forming matter of nano-thermal-insulating coating；Its glass transition temperature is low, the low [0.06w/ of thermal coefficient（m·k）], bullet contracting
Property is good, lower temperature resistance is excellent, water impermeability is good, adhesive force is good.
The aerosil is a kind of light nanoporous amorphous solid material that thermal and insulating performance is very outstanding
Material, porosity are up to 80-99%, and the typical sizes of hole are 2-50nm, average pore size 20nm, specific surface area 600-
1000m2/ g, apparent density 0.003-0.35cm3/ g, room temperature thermal coefficient can be down to 0.013W/（m·k）Even if at 800 DEG C
Under high temperature, thermal coefficient is just 0.043W/（m·k）, and do not decomposed under high temperature, no pernicious gas is released, and is pure green environmental protection
Material.SiO2Aeroge insulation principle：
1）Solid thermal conduction SiO2Aeroge is to be connected with each other the nanometer three-dimensional network bone that aggregation is formed by several Si-0-Si groups
Frame structure, due to the presence of nearly infinite Donna metre hole, solid thermal transmission can only be transmitted along hole wall, and nearly infinite more air vent walls are constituted
It is bordering on " infinite long path " effect so that solid thermal conductance drops to almost lowest limit.
2）Convection current heat transfer：SiO2The mesopore size of aeroge is 2-50nm, when the hole diameter in material is less than 70nm
When, the air molecule in hole just loses the ability of free-flowing, is relatively attached on air vent wall, at this point, nano-pore is in
Near vacuum state, the cross-ventilation in material are attenuated to least limit.
3）Radiation thermal conduction：Conduct radiation heat is a kind of contactless heat transfer.Since aeroge is uniformly to receive
Rice stomata, and there is extremely low bulk density, so that material internal air vent wall number is tended to " infinite more ", and each air vent wall has
The effect of sunshading board is bordering on " infinite more sunshading boards " effect to generate, radiant heat transfer is made to drop to lowest limit.
The SiO2Although aeroge is good heat-insulating material, but its intensity is low, brittleness is big, compression strength is low, nanometer
Pore structure forces be easy to be crushed under power outside.In order to improve SiO2The mechanical property of aerogel heat-insulating coating, using thermal insulation
Performance is good, mechanical property is higher, the affected SiO of the diatomite of strong adsorption2The skeleton reinforcing material of aeroge；Work as SiO2Aeroge
After slurry is mixed with diatomite, then nanoporous aerogel particle is received by trepanning kieselguhr adsorption, part not to be adsorbed under condition of negative pressure
Rice aerogel particles are dispersed between the thicker filler gap of grain size, to improve SiO2The compression strength of aeroge.
The nano ceramics hollow bead is used as filler, and effect is in order to improve the mechanical property of insulating moulding coating, simultaneously
The thermal coefficient of film will not be increased substantially again；Nano ceramics hollow bead is the hollow and thin-walled ball made of special process
Powdery, the new lightweight material haveing excellent performance, have density is low, volume is big, thermal coefficient is low, compression strength is high, oil absorbency is low,
Auto-flowability is good, high and low temperature resistance and corrosion resistance, sound insulation, radiation protection, the advantages that water absorption rate is low, electrical insulating property is strong.
Using the modified oyster shell whiting of calcining, the filler that can be used as reflective heat-insulation paint replaces traditional nano-calcium carbonate, both carried
The high thermal insulation of coating material, resistance to ag(e)ing and wash-resistant property, and reduce the cost of coating material.
The auxiliary agent includes the component of following mass fraction：
Dispersant 50400.4-0.8
Wetting agent X4050.1-0.2
Multifunction amine auxiliary agent A MP-950.1-0.2
Antifoaming agent NXZ0.2-0.5
Preservative LXE0.1-0.3
Thickener TT9350.2-0.4
Levelling agent RM-20200.3-0.5.
The dispersant, wetting agent, antifoaming agent, thickener, preservative etc. are standard aqueous Coatings Additives, herein not
It repeats.
In the present invention, modified oyster shell whiting is prepared using following methods：
A. oyster shell whiting is calcined into 1-4h, the gas of calcining with the heating rate of 5 DEG C/min-30 DEG C/min between 400 DEG C -800 DEG C
Atmosphere is divided into inert atmosphere,
B., it is uniform that oyster shell whiting after calcining is carried out to first time grinding distribution at room temperature,
C. by the oyster shell whiting after grinding distribution, secondary clacining 1-4h, the atmosphere of calcining are divided into oxygen gas between 800 DEG C -1200 DEG C
Atmosphere,
D. the oyster shell whiting after secondary clacining is subjected to secondary grinding distribution at room temperature, until the oyster shell whiting grain size is less than 10
μm。
Wherein：
The inert atmosphere is argon gas atmosphere.
The first time grinding distribution refers to being ground with the speed of 500 ~ 1000r/min with grinding distribution blender
Stirring.
Second of grinding distribution refers to being ground with the speed of 1000 ~ 1500r/min with grinding distribution blender
Mill stirring.
Embodiment 1
Nano anti-corrosive thermal insulation coatings of the present invention, raw material include following components by weight：52 parts of acrylic resin, alkyd
26 parts of resin, 5 parts of aerosil, 11 parts of nano ceramics hollow bead, modified 35 parts of oyster shell whiting, graphene 5 part, nanometer
45 parts of 3 parts of zirconium oxide, 3 parts of nano zine oxide, 6 parts of nano-titanium dioxide, 5 parts of auxiliary agent and water；
Wherein, the porosity of the aerosil is 90%, specific surface area 950m2/g；The nano zircite
Grain size is 35nm；The grain size of the nano zine oxide is 80nm；The grain size of nano-titanium dioxide is 10nm；The antifoaming agent is just
Octanol.
Embodiment 2
Nano anti-corrosive thermal insulation coatings of the present invention, raw material include following components by weight：65 parts of acrylic resin, alkyd
12 parts of resin, 5 parts of aerosil, 11 parts of nano ceramics hollow bead, modified 35 parts of oyster shell whiting, graphene 2 part, nanometer
45 parts of 3 parts of zirconium oxide, 3 parts of nano zine oxide, 6 parts of nano-titanium dioxide, 5 parts of auxiliary agent and water；
Wherein, the porosity of the aerosil is 90%, specific surface area 950m2/g；The nano zircite
Grain size is 35nm；The grain size of the nano zine oxide is 80nm；The grain size of nano-titanium dioxide is 50nm；The antifoaming agent is just
Octanol.
Embodiment 3
Nano anti-corrosive thermal insulation coatings of the present invention, raw material include following components by weight：58 parts of acrylic resin, alkyd
18 parts of resin, 15 parts of nano ceramics hollow bead, modified 45 parts of oyster shell whiting, 4 parts of graphene, is received 10 parts of aerosil
58 parts of 6 parts of zirconium oxide of rice, 6 parts of nano zine oxide, 12 parts of nano-titanium dioxide, 9 parts of auxiliary agent and water.
Wherein, the porosity of the aerosil is 95%, specific surface area 1100m2/g；It is described nano oxidized
The grain size of zirconium is 50nm；The grain size of the nano zine oxide is 50nm；The grain size of nano-titanium dioxide is 15nm；The antifoaming agent
The combination of arbitrary weight ratio is pressed for tributyl phosphate, triphenyl phosphate, emulsification methyl-silicone oil.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (5)
1. a kind of nano anti-corrosive thermal insulation coatings, which is characterized in that its raw material includes following components by weight：Acrylic resin
52-65 parts, 12-26 parts of alkyd resin, 5-12 parts of aerosil, 11-18 parts of nano ceramics hollow bead, modified shell
35-55 parts of powder, 2-5 parts of graphene, 3-9 parts of nano zircite, 3-8 parts of nano zine oxide, 6-17 parts of nano-titanium dioxide, auxiliary agent
5-18 parts and 45-65 parts of water；
The porosity of the aerosil is 90-95%, specific surface area 950-1100m2/g；
The grain size of the nano zircite is 35-50nm；
The grain size of the nano zine oxide is 50-80nm；
The grain size of the nano-titanium dioxide is 10-50nm.
2. nano anti-corrosive thermal insulation coatings according to claim 1, which is characterized in that its raw material includes with the following group by weight
Point：55-60 parts of acrylic resin, 15-20 parts of alkyd resin, 8-11 parts of aerosil, nano ceramics hollow bead 13-
16 parts, modified 38-50 parts of oyster shell whiting, 3-5 parts of graphene, 5-8 parts of nano zircite, 5-7 parts of nano zine oxide, nanometer titanium dioxide
55-60 parts of 8-15 parts of titanium, 7-10 parts of auxiliary agent and water.
3. nano anti-corrosive thermal insulation coatings according to claim 1 or claim 2, which is characterized in that its raw material includes following by weight
Component：58 parts of acrylic resin, 10 parts of aerosil, 15 parts of nano ceramics hollow bead, is modified 18 parts of alkyd resin
45 parts of oyster shell whiting, 4 parts of graphene, 6 parts of nano zircite, 6 parts of nano zine oxide, 12 parts of nano-titanium dioxide, 9 parts of auxiliary agent and water
58 parts.
4. nano anti-corrosive thermal insulation coatings according to claim 1, which is characterized in that the auxiliary agent includes following mass fraction
Component：
Dispersant 50400.4-0.8；
Wetting agent X4050.1-0.2；
Multifunction amine auxiliary agent A MP-950.1-0.2；
Antifoaming agent NXZ0.2-0.5；
Preservative LXE0.1-0.3；
Thickener TT9350.2-0.4；
Levelling agent RM-20200.3-0.5.
5. nano anti-corrosive thermal insulation coatings according to claim 4, which is characterized in that the antifoaming agent is n-octyl alcohol, tricresyl phosphate
The combination of one or more of butyl ester, triphenyl phosphate, emulsification methyl-silicone oil, emulsification polymethylphenyl siloxane fluid.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321071A (en) * | 2018-08-22 | 2019-02-12 | 新昌县天姥园艺发展有限公司 | Outer wall heat-insulating coating and preparation method thereof |
| CN109504189A (en) * | 2018-11-15 | 2019-03-22 | 湖南上涂新材料有限公司 | A kind of automobile heat insulation coating and preparation method thereof |
| CN110183149A (en) * | 2019-05-30 | 2019-08-30 | 浙江莱邦新材料有限公司 | A kind of water-proof, heat-insulating, heat-preserving coating and its construction technology |
| CN114806342A (en) * | 2022-06-06 | 2022-07-29 | 青岛海源实业有限公司 | Sound-insulation anticorrosive paint, preparation method and application |
| CN115651511A (en) * | 2022-11-15 | 2023-01-31 | 广东电网有限责任公司 | Thermal insulation spraying material and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277633A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Nano insulating coating |
| CN104327644A (en) * | 2014-11-05 | 2015-02-04 | 侨健新能源科技（苏州）有限公司 | High-mechanical-property impact-resisting heat-preservation coating |
| CN106905790A (en) * | 2017-02-22 | 2017-06-30 | 东南大学 | A kind of reflective insulation coating material and preparation method thereof |
-
2018
- 2018-02-28 CN CN201810167435.3A patent/CN108410302A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277633A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Nano insulating coating |
| CN104327644A (en) * | 2014-11-05 | 2015-02-04 | 侨健新能源科技（苏州）有限公司 | High-mechanical-property impact-resisting heat-preservation coating |
| CN106905790A (en) * | 2017-02-22 | 2017-06-30 | 东南大学 | A kind of reflective insulation coating material and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321071A (en) * | 2018-08-22 | 2019-02-12 | 新昌县天姥园艺发展有限公司 | Outer wall heat-insulating coating and preparation method thereof |
| CN109504189A (en) * | 2018-11-15 | 2019-03-22 | 湖南上涂新材料有限公司 | A kind of automobile heat insulation coating and preparation method thereof |
| CN110183149A (en) * | 2019-05-30 | 2019-08-30 | 浙江莱邦新材料有限公司 | A kind of water-proof, heat-insulating, heat-preserving coating and its construction technology |
| CN114806342A (en) * | 2022-06-06 | 2022-07-29 | 青岛海源实业有限公司 | Sound-insulation anticorrosive paint, preparation method and application |
| CN115651511A (en) * | 2022-11-15 | 2023-01-31 | 广东电网有限责任公司 | Thermal insulation spraying material and preparation method and application thereof |
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