CN108410117A - A kind of babinet ABS composite material and preparation method thereof - Google Patents
A kind of babinet ABS composite material and preparation method thereof Download PDFInfo
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- CN108410117A CN108410117A CN201810367559.6A CN201810367559A CN108410117A CN 108410117 A CN108410117 A CN 108410117A CN 201810367559 A CN201810367559 A CN 201810367559A CN 108410117 A CN108410117 A CN 108410117A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of babinet ABS composite material and preparation method thereof, the raw material for preparing babinet ABS composite material includes by its parts by weight：60 parts~80 parts of ABS resin, 2 parts~8 parts of ABS high glue powders, 5 parts~15 parts of SBS resins, 1 part~6 parts of modification infusorial earth, 0.1 part~1.2 parts of nano zine oxide, 0.5 part~1.5 parts of polyethylene wax, 0.5 part~1.5 parts of antioxidant.The present invention improves the impact resistance of material using ABS resin as matrix resin, SBS resins are modified resin, the ductility and bearing capacity of reinforcing material, the tensile strength of the babinet ABS composite material of preparation is big, good impact resistance, bearing capacity are strong, the glossiness of product surface is high, and preparation method is simple, preparation process is easy to operate, is suitble to large-scale production and application.
Description
Technical field
The present invention relates to luggage case technical fields, and in particular to a kind of babinet ABS composite material and preparation method thereof.
Background technology
With people's the accelerating rhythm of life, the chance travelled outdoors is more and more, and portable luggage is also increasingly
As necessity.Existing all kinds of luggages generally comprise two kinds：It is another one is the soft case made of textile cloth or leather substance
Kind is hard babinet made of high molecular material.Hard babinet becomes people with its excellent performance and moderate price most often to be made
Luggage, wherein sell be widely ABS materials luggage, the ABS resin in luggage is by acrylonitrile (A), butadiene (B)
With the terpolymer of styrene (S) composition, styrene assigns resin rigidity, electrical property, workability and lustrous surface, fourth
Diene assigns resin toughness and low temperature impact performance, and acrylonitrile assigns resin chemical resistance, weatherability, heat resistance and tensile strength.
Chinese patent CN105542379A discloses a kind of high-impact and resists cold ABS tank materials and preparation method thereof, by with
The following group is grouped as：ABS resin, maleic anhydride grafting POE, ABS high glue powder, inorganic nano-particle, surface conditioning agent, antioxidant,
Lubricant, ABS tank materials squeeze out plastics sucking moulding by injection molding machine injection molding or by squeezing out Packing Machine, obtain ABS babinets.
This patent by the physics in terms of raw material, chemical method be combined and machining process in specific process parameter be modified
The tank material of ABS, preparation have higher shock resistance and cold-resistant function, but the patent system is for the bearing capacity of babinet
It is bad.
Chinese patent CN105492219A discloses a kind of preparation process of one-pass molding PC casees, includes the following steps：Step
Rapid one：PC is expected, after drying, dry PC material are made；Step 2：Colorant is deployed, first after sufficiently mixing, then through dry
After dry processing, allotment colorant is obtained；Step 3：By PC material, Styrene-co-acrylamide, basic zirconium phosphate, hydrotalcite, boric acid
Zinc, boric acid zirconium add the allotment colorant in step 2, PC raw materials are obtained after being sufficiently stirred after being sufficiently stirred；Step 4：It will step
Gained PC raw materials are directly molded into babinet in addition high-speed injection molding machine injection mold in rapid three；Step 5：By institute in step 4
It obtains babinet and is covered with PE guarantor's overlay films；Step 6：It is packed after the babinet obtained in step 5 is dehumidified.The patent obtain one at
The PC luggages of type have preferable high temperature resistant, resistance to Han Xing, also have preferable hardness at a low density, but the patent system is standby
Luggage shock resistance it is bad.
Therefore, it is badly in need of a kind of good impact resistance, the strong tank material and preparation method thereof of bearing capacity.
Invention content
The present invention is in view of the above-mentioned problems, provide a kind of babinet ABS composite material and preparation method thereof.
Technical solution is used by the present invention solves the above problems：A kind of babinet ABS composite material prepares babinet use
The raw material of ABS composite material includes by its parts by weight：60 parts~80 parts of ABS resin, 2 parts~8 parts of ABS high glue powders, SBS resins 5
Part~15 parts, 1 part~6 parts of modification infusorial earth, 0.1 part~1.2 parts of nano zine oxide, 0.5 part~1.5 parts of polyethylene wax, antioxygen
0.5 part~1.5 parts of agent.Wherein, the average molecular weight of ABS resin is 100,000~200,000；SBS resins are styrene and butadiene
Block copolymer has two phase structure, and the styrene dispersed phase with plastics performance becomes physical crosslinking point at normal temperatures, makes
SBS has the performance of general vulcanized rubber, is added in ABS resin and the high impact of ABS can be improved；Diatomite is one
Kind silicates substance, has abundant pore structure, the mechanical property of material can be improved after silane coupler modified；It is poly-
Ethylene waxes have excellent heat-resisting, wear-resisting, chemical resistance, are added in ABS resin, can improve production as lubricant
The gloss and processability of product.
Further, the melt index of ABS resin is 8g/10min~20g/10min.
Further, ABS high glue powders are the ABS rubber powders that glue content is 50wt%~75wt%.
Further, the content of styrene is 30wt%~40wt% in SBS resins.
Further, the preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 1 part~2 parts of silane coupling agent KH-560,100 parts of toluene by weight, will
Diatomite is put into 360 DEG C~450 DEG C of baking oven and is heat-treated 1.5 hours~2.5 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, ultrasonic disperse 15 minutes~30
Minute, the silane coupling agent KH-560 that the parts by weight are added continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 4 hours~6 hours, through centrifugation
Separation, vacuum drying, obtain modification infusorial earth.
Further, antioxidant is selected from any one of irgasfos 168, antioxidant 1010, antioxidant 264.
Further, the raw material for preparing babinet ABS composite material includes by its parts by weight：70 parts of ABS resin, ABS high
5 parts of rubber powder, 10 parts of SBS resins, 3.5 parts of modification infusorial earth, 0.6 part of nano zine oxide, 1.0 parts of polyethylene wax, antioxidant 1.0
Part.
Another goal of the invention of the present invention is to provide a kind of preparation method of babinet ABS composite material, including as follows
Step：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into baking oven, 1.5 hours~2.5 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder, extruded granulation by step S30, and babinet is made and uses
ABS composite material.
Further, in step S10, the temperature of baking oven is 80 DEG C~90 DEG C.
Further, in step S30, the running parameter of double screw extruder is：200 DEG C~270 DEG C of extrusion temperature, screw rod
300 revs/min~350 revs/min of rotating speed, screw slenderness ratio 1:35~40.
It is an advantage of the invention that：
1. the present invention, using ABS resin as matrix resin, SBS resins are modified resin, pass through chemical method and physical method
It is combined, improves the impact resistance of material, the ductility and bearing capacity of reinforcing material are added with silane coupler modified silicon
Diatomaceous earth can improve the mechanical property of material, improve the anti-pressure and abrasion-proof characteristic of babinet；It can be with reinforced ABS added with ABS high glue powders
The comixing compatibility of resin and SBS resins；
2. the tensile strength of babinet ABS composite material prepared by the present invention is big, good impact resistance, bearing capacity are strong, production
The glossiness on product surface is high, and preparation method is simple, and preparation process is easy to operate, is suitble to large-scale production and application.
Specific implementation mode
The embodiment of the present invention is described in detail below, but what the present invention can be defined by the claims and cover
Multitude of different ways is implemented.
Embodiment 1
A kind of babinet ABS composite material and preparation method thereof
The raw material for preparing babinet ABS composite material includes：ABS resin 60kg, ABS high glue powder 4kg, SBS resin 12kg,
Modification infusorial earth 1kg, nano zine oxide 1.0kg, polyethylene wax 0.7kg, irgasfos 168 0.5kg.
The preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 1 part of silane coupling agent KH-560,100 parts of toluene, by weight by diatomite
It is put into 360 DEG C of baking oven and is heat-treated 2.5 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, and ultrasonic disperse 30 minutes adds
The silane coupling agent KH-560 for entering the parts by weight continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 4 hours, are centrifuged, very
Sky is dry, obtains modification infusorial earth.
The preparation method of babinet ABS composite material, is prepared via a method which：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into 80 DEG C of baking oven, 2.5 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder by step S30, and 200 DEG C of extrusion temperature, screw rod turn
Fast 350 revs/min, screw slenderness ratio 1:35, extruded granulation, obtained babinet ABS composite material.
Embodiment 2
A kind of babinet ABS composite material and preparation method thereof
The raw material for preparing babinet ABS composite material includes：ABS resin 65kg, ABS high glue powder 2kg, SBS resin 15kg,
Modification infusorial earth 2kg, nano zine oxide 0.3kg, polyethylene wax 1.5kg, antioxidant 1010 1.3kg.
The preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 1.5 parts of silane coupling agent KH-560,100 parts of toluene, by weight by diatom
Soil is put into 380 DEG C of baking oven and is heat-treated 2.0 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, and ultrasonic disperse 15 minutes adds
The silane coupling agent KH-560 for entering the parts by weight continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 6 hours, are centrifuged, very
Sky is dry, obtains modification infusorial earth.
The preparation method of babinet ABS composite material, is prepared via a method which：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into 90 DEG C of baking oven, 1.5 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder by step S30, and 260 DEG C of extrusion temperature, screw rod turn
Fast 320 revs/min, screw slenderness ratio 1:40, extruded granulation, obtained babinet ABS composite material.
Embodiment 3
A kind of babinet ABS composite material and preparation method thereof
The raw material for preparing babinet ABS composite material includes：ABS resin 70kg, ABS high glue powder 5kg, SBS resin 10kg,
Modification infusorial earth 3.5kg, nano zine oxide 0.6kg, polyethylene wax 1.0kg, antioxidant 264 1.0kg.
The preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 2 parts of silane coupling agent KH-560,100 parts of toluene, by weight by diatomite
It is put into 420 DEG C of baking oven and is heat-treated 2.5 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, and ultrasonic disperse 20 minutes adds
The silane coupling agent KH-560 for entering the parts by weight continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 4.5 hours, be centrifuged,
Vacuum drying, obtains modification infusorial earth.
The preparation method of babinet ABS composite material, is prepared via a method which：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into 83 DEG C of baking oven, 2.5 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder by step S30, and 220 DEG C of extrusion temperature, screw rod turn
Fast 340 revs/min, screw slenderness ratio 1:36, extruded granulation, obtained babinet ABS composite material.
Embodiment 4
A kind of babinet ABS composite material and preparation method thereof
The raw material for preparing babinet ABS composite material includes：ABS resin 75kg, ABS high glue powder 8kg, SBS resin 5kg,
Modification infusorial earth 6kg, nano zine oxide 0.1kg, polyethylene wax 0.5kg, antioxidant 1.5kg.
The preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 2 parts of silane coupling agent KH-560,100 parts of toluene, by weight by diatomite
It is put into 450 DEG C of baking oven and is heat-treated 1.5 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, and ultrasonic disperse 25 minutes adds
The silane coupling agent KH-560 for entering the parts by weight continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 5.5 hours, be centrifuged,
Vacuum drying, obtains modification infusorial earth.
The preparation method of babinet ABS composite material, is prepared via a method which：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into 88 DEG C of baking oven, 2.3 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder by step S30, and 270 DEG C of extrusion temperature, screw rod turn
Fast 300 revs/min, screw slenderness ratio 1:39, extruded granulation, obtained babinet ABS composite material.
Embodiment 5
A kind of babinet ABS composite material and preparation method thereof
The raw material for preparing babinet ABS composite material includes：ABS resin 80kg, ABS high glue powder 6kg, SBS resin 8kg,
Modification infusorial earth 4kg, nano zine oxide 1.2kg, polyethylene wax 1.3kg, antioxidant 0.7kg.
The preparation method of modification infusorial earth includes：
Step i weighs up 4 parts of diatomite, 1.5 parts of silane coupling agent KH-560,100 parts of toluene, by weight by diatom
Soil is put into 400 DEG C of baking oven and is heat-treated 2.0 hours；
Step ii, by step i, treated that diatomite is put into the toluene of above-mentioned parts by weight, and ultrasonic disperse 25 minutes adds
The silane coupling agent KH-560 for entering the parts by weight continues ultrasonic disperse 5 minutes, obtains pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 5 hours, are centrifuged, very
Sky is dry, obtains modification infusorial earth.
The preparation method of babinet ABS composite material, is prepared via a method which：
Step S10 is weighed the raw material for preparing babinet ABS composite material by above-mentioned parts by weight, by the ABS of above-mentioned parts by weight
Resin, ABS high glue powders, SBS resins are put into 85 DEG C of baking oven, 2.0 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer by step S20,
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of above-mentioned parts by weight is added, is sufficiently mixed uniformly, is mixed
Material；
The obtained mixtures of step S20 are put into double screw extruder by step S30, and 240 DEG C of extrusion temperature, screw rod turn
Fast 330 revs/min, screw slenderness ratio 1:37, extruded granulation, obtained babinet ABS composite material.
Experimental example
Technological progress in order to further illustrate the present invention is now further illustrated using experiment.
Experiment material：The babinet that the commercially available, embodiment of the present invention 1~5 is produced is molded into standard sample with ABS composite material
Item.
Experimental method：Compare the properties of a variety of materials under square one.
The test result of babinet ABS composite material prepared by 1. Examples 1 to 5 of table
The experimental results showed that the tensile strength of babinet ABS composite material prepared by the embodiment of the present invention 1~5 is more than
50MPa, for impact strength between 190J/M~220J/M, bending modulus is more than 1700MPa, and elongation at break is more than 70%, this
The tensile strength of inventing the babinet ABS composite material prepared is big, good impact resistance, bearing capacity are strong, and service life is long.
It these are only the preferred embodiment of the present invention, be not intended to restrict the invention, for those skilled in the art
For member, the invention may be variously modified and varied.Any modification made by all within the spirits and principles of the present invention,
Equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of babinet ABS composite material, which is characterized in that the raw material for preparing the babinet ABS composite material is heavy by its
Measuring part includes：60 parts~80 parts of ABS resin, 2 parts~8 parts of ABS high glue powders, 5 parts~15 parts of SBS resins, 1 part of modification infusorial earth~
6 parts, 0.1 part~1.2 parts of nano zine oxide, 0.5 part~1.5 parts of polyethylene wax, 0.5 part~1.5 parts of antioxidant.
2. babinet ABS composite material according to claim 1, which is characterized in that the melt index of the ABS resin is
8g/10min~20g/10min.
3. babinet ABS composite material according to claim 1, which is characterized in that the ABS high glue powders are that glue content is
The ABS rubber powders of 50wt%~75wt%.
4. babinet ABS composite material according to claim 1, which is characterized in that styrene contains in the SBS resins
Amount is 30wt%~40wt%.
5. babinet ABS composite material according to claim 1, which is characterized in that the preparation side of the modification infusorial earth
Method includes：
Step i weighs up 4 parts of diatomite, 1 part~2 parts of silane coupling agent KH-560,100 parts of toluene, by weight by diatom
Soil is put into 360 DEG C~450 DEG C of baking oven and is heat-treated 1.5 hours~2.5 hours；
Step ii, by step i, treated that diatomite is put into the toluene of the parts by weight, 15 minutes~30 points of ultrasonic disperse
Clock, the silane coupling agent KH-560 that the parts by weight are added continue ultrasonic disperse 5 minutes, obtain pre-composition；
The obtained pre-compositions of step ii are put into 90 DEG C of thermostats by step iii, are kept for 4 hours~6 hours, be centrifuged,
Vacuum drying, obtains modification infusorial earth.
6. babinet ABS composite material according to claim 1, which is characterized in that the antioxidant is selected from antioxidant
168, any one of antioxidant 1010, antioxidant 264.
7. babinet ABS composite material according to claim 1, which is characterized in that prepare the babinet ABS composite woods
The raw material of material includes by its parts by weight：70 parts of ABS resin, 5 parts of ABS high glue powders, 10 parts of SBS resins, 3.5 parts of modification infusorial earth,
0.6 part of nano zine oxide, 1.0 parts of polyethylene wax, 1.0 parts of antioxidant.
8. a kind of preparation method of babinet ABS composite material according to any one of claims 1 to 7, feature exist
In including the following steps：
Step S10 is weighed the raw material for preparing babinet ABS composite material by the parts by weight, by the ABS trees of the parts by weight
Fat, ABS high glue powders, SBS resins are put into baking oven, 1.5 hours~2.5 hours dry；
ABS resin, ABS high glue powders and SBS resins after step S10 dryings is put into high-speed mixer, is added by step S20
Modification infusorial earth, nano zine oxide, polyethylene wax and the antioxidant of the parts by weight are sufficiently mixed uniformly, obtain mixture；
The obtained mixtures of step S20 are put into double screw extruder, extruded granulation by step S30, obtained babinet ABS
Composite material.
9. preparation method according to claim 8, which is characterized in that in step S10, the temperature of the baking oven is 80 DEG C~
90℃。
10. preparation method according to claim 8, which is characterized in that in step S30, the work of the double screw extruder
It is as parameter：200 DEG C~270 DEG C of extrusion temperature, 300 revs/min~350 revs/min of screw speed, screw slenderness ratio 1:35
~40.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810367559.6A CN108410117A (en) | 2018-04-23 | 2018-04-23 | A kind of babinet ABS composite material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810367559.6A CN108410117A (en) | 2018-04-23 | 2018-04-23 | A kind of babinet ABS composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108410117A true CN108410117A (en) | 2018-08-17 |
Family
ID=63136197
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810367559.6A Withdrawn CN108410117A (en) | 2018-04-23 | 2018-04-23 | A kind of babinet ABS composite material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409745A (en) * | 2020-12-01 | 2021-02-26 | 安徽理工大学 | Pencil surface material |
| CN113683859A (en) * | 2021-08-30 | 2021-11-23 | 浙江星耀箱包有限公司 | Preparation process of high-strength compression-resistant draw-bar box |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634161A (en) * | 2012-04-28 | 2012-08-15 | 广东省石油化工研究院 | Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof |
| JP5049229B2 (en) * | 2008-08-21 | 2012-10-17 | 有限会社エルアンドアール | Molding resin composition |
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
-
2018
- 2018-04-23 CN CN201810367559.6A patent/CN108410117A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5049229B2 (en) * | 2008-08-21 | 2012-10-17 | 有限会社エルアンドアール | Molding resin composition |
| CN102634161A (en) * | 2012-04-28 | 2012-08-15 | 广东省石油化工研究院 | Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof |
| CN105542379A (en) * | 2015-12-31 | 2016-05-04 | 祥兴(福建)箱包集团有限公司 | ABS box material with high impact resistance and cold resistance and preparing method and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409745A (en) * | 2020-12-01 | 2021-02-26 | 安徽理工大学 | Pencil surface material |
| CN113683859A (en) * | 2021-08-30 | 2021-11-23 | 浙江星耀箱包有限公司 | Preparation process of high-strength compression-resistant draw-bar box |
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Application publication date: 20180817 |