CN108410076A - A kind of flame retardant plastics - Google Patents

A kind of flame retardant plastics Download PDF

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Publication number
CN108410076A
CN108410076A CN201810232351.3A CN201810232351A CN108410076A CN 108410076 A CN108410076 A CN 108410076A CN 201810232351 A CN201810232351 A CN 201810232351A CN 108410076 A CN108410076 A CN 108410076A
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CN
China
Prior art keywords
parts
flame retardant
nano
retardant plastics
corvic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810232351.3A
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Chinese (zh)
Inventor
陆华平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Teflon Plastic Products Factory
Original Assignee
Suzhou New District Teflon Plastic Products Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Teflon Plastic Products Factory filed Critical Suzhou New District Teflon Plastic Products Factory
Priority to CN201810232351.3A priority Critical patent/CN108410076A/en
Publication of CN108410076A publication Critical patent/CN108410076A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2255Oxides; Hydroxides of metals of molybdenum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of flame retardant plastics, including:Trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire retardant, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, thermoplastic polyester and Corvic, parts by weight shared by each ingredient in the flame retardant plastics:5 10 parts of 10 15 parts of trithiophenyl phosphate, 15 20 parts of polystyrene, 5 10 parts of nano silicon dioxide, 20 25 parts of fire retardant, 15 parts of molybdenum trioxide, 15 parts of ammonium polyphosphate, 5 10 parts of nano-titanium dioxide, 10 15 parts of thermoplastic polyester and Corvic.By the above-mentioned means, flame retardant plastics provided by the invention, there is good flame retardant property, smoke amount is few when burning.

Description

A kind of flame retardant plastics
Technical field
The present invention relates to plastic applications, more particularly to a kind of flame retardant plastics.
Background technology
With science and technology and economic continuous development, the daily product generated by plastics plays more and more important in life Effect.But plastics easy firing, and burning velocity is fast, will produce a large amount of toxic gas, causes casualties and property loss. So plastic products is needed not burn, there is good flame retardant property, it is desirable that smoke degree of the plastics in big fire wants small.But mesh The preceding flame retardant plastics performance used cannot be met the requirements.
Invention content
The invention mainly solves the technical problem of providing a kind of flame retardant plastics, there is good flame retardant property, when burning Smoke amount is few.
In order to solve the above technical problems, one aspect of the present invention is:A kind of flame retardant plastics is provided, including: Trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire retardant, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, heat Plasticity polyester and Corvic, parts by weight shared by each ingredient in the flame retardant plastics:Trithiophenyl phosphate 10-15 Part, 15-20 parts of polystyrene, 5-10 parts of nano silicon dioxide, 20-25 parts of fire retardant, 1-5 parts of molybdenum trioxide, ammonium polyphosphate 1-5 Part, 5-10 parts of nano-titanium dioxide, 10-15 parts of thermoplastic polyester and 5-10 parts of Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate 10 parts of phenyl ester, 15 parts of polystyrene, 5 parts of nano silicon dioxide, 20 parts of fire retardant, 1 part of molybdenum trioxide, ammonium polyphosphate 1 part, nanometer 5 parts of 5 parts of titanium dioxide, 10 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate 11 parts of phenyl ester, 15 parts of polystyrene, 6 parts of nano silicon dioxide, 20 parts of fire retardant, 2 parts of molybdenum trioxide, ammonium polyphosphate 1 part, nanometer 5 parts of 6 parts of titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate 12 parts of phenyl ester, 16 parts of polystyrene, 6 parts of nano silicon dioxide, 21 parts of fire retardant, 2 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer 6 parts of 6 parts of titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate 13 parts of phenyl ester, 17 parts of polystyrene, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 3 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer 7 parts of 6 parts of titanium dioxide, 12 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate 14 parts of phenyl ester, 18 parts of polystyrene, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 4 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer 8 parts of 7 parts of titanium dioxide, 13 parts of thermoplastic polyester and Corvic.
The beneficial effects of the invention are as follows:A kind of flame retardant plastics that the present invention points out has good flame retardant property, when burning Smoke amount is few.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:
It weighs:10 kilograms of trithiophenyl phosphate, 15 kilograms of polystyrene, 5 kilograms of nano silicon dioxide, 20 kilograms of fire retardant, 1 kilogram of molybdenum trioxide, 1 kilogram of ammonium polyphosphate, 5 kilograms of nano-titanium dioxide, 10 kilograms of thermoplastic polyester and Corvic 5 Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's Flame retardant plastics.
Embodiment 2:
It weighs:11 kilograms of trithiophenyl phosphate, 15 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 20 kilograms of fire retardant, 2 kilograms of molybdenum trioxide, 1 kilogram of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 11 kilograms of thermoplastic polyester and Corvic 5 Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's Flame retardant plastics.
Embodiment 3:
It weighs:12 kilograms of trithiophenyl phosphate, 16 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 21 kilograms of fire retardant, 2 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 11 kilograms of thermoplastic polyester and Corvic 6 Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's Flame retardant plastics.
Embodiment 4:
It weighs:13 kilograms of trithiophenyl phosphate, 17 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 22 kilograms of fire retardant, 3 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 12 kilograms of thermoplastic polyester and Corvic 7 Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's Flame retardant plastics.
Embodiment 5:
It weighs:14 kilograms of trithiophenyl phosphate, 18 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 22 kilograms of fire retardant, 4 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 7 kilograms of nano-titanium dioxide, 13 kilograms of thermoplastic polyester and Corvic 8 Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's Flame retardant plastics.
Test case:Anti-flammability test is carried out to the flame retardant plastics of embodiment 1-5, test result is shown in Table 1.
Table 1:Flame retardant plastics flame retardant property tests table
Flue gas generating rate(m2 /s2
Test method GB/T 20284-2006
Embodiment 1 0.24
Embodiment 2 0.23
Embodiment 3 0.22
Embodiment 4 0.21
Embodiment 5 0.25
In conclusion a kind of flame retardant plastics that the present invention points out, there is good flame retardant property, smoke amount is few when burning.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of flame retardant plastics, which is characterized in that including:It is trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire-retardant Agent, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, thermoplastic polyester and Corvic, in the flame retardant plastics respectively at Parts by weight shared by point:It is 10-15 parts of trithiophenyl phosphate, 15-20 parts of polystyrene, 5-10 parts of nano silicon dioxide, fire-retardant 20-25 parts of agent, 1-5 parts of molybdenum trioxide, 1-5 parts of ammonium polyphosphate, 5-10 parts of nano-titanium dioxide, 10-15 parts of thermoplastic polyester and 5-10 parts of Corvic.
2. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics Number:10 parts of trithiophenyl phosphate, 5 parts of nano silicon dioxide, 20 parts of fire retardant, 1 part of molybdenum trioxide, gathers 15 parts of polystyrene 5 parts of 1 part of ammonium phosphate, 5 parts of nano-titanium dioxide, 10 parts of thermoplastic polyester and Corvic.
3. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics Number:11 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 20 parts of fire retardant, 2 parts of molybdenum trioxide, gathers 15 parts of polystyrene 5 parts of 1 part of ammonium phosphate, 6 parts of nano-titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
4. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics Number:12 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 21 parts of fire retardant, 2 parts of molybdenum trioxide, gathers 16 parts of polystyrene 6 parts of 2 parts of ammonium phosphate, 6 parts of nano-titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
5. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics Number:13 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 3 parts of molybdenum trioxide, gathers 17 parts of polystyrene 7 parts of 2 parts of ammonium phosphate, 6 parts of nano-titanium dioxide, 12 parts of thermoplastic polyester and Corvic.
6. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics Number:14 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 4 parts of molybdenum trioxide, gathers 18 parts of polystyrene 8 parts of 2 parts of ammonium phosphate, 7 parts of nano-titanium dioxide, 13 parts of thermoplastic polyester and Corvic.
CN201810232351.3A 2018-03-21 2018-03-21 A kind of flame retardant plastics Pending CN108410076A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150258A (en) * 2021-05-12 2021-07-23 江苏欣宝科技股份有限公司 Polyester resin for dry-mixed extinction powder coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829959A (en) * 2015-04-30 2015-08-12 王英英 Flame retardant plastic
CN106916403A (en) * 2015-12-25 2017-07-04 青岛城轨交通装备科技有限公司 A kind of flame retardant plastics
CN106995618A (en) * 2017-06-01 2017-08-01 东至县科创塑料制品有限公司 A kind of flame retardant plastics

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829959A (en) * 2015-04-30 2015-08-12 王英英 Flame retardant plastic
CN106916403A (en) * 2015-12-25 2017-07-04 青岛城轨交通装备科技有限公司 A kind of flame retardant plastics
CN106995618A (en) * 2017-06-01 2017-08-01 东至县科创塑料制品有限公司 A kind of flame retardant plastics

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150258A (en) * 2021-05-12 2021-07-23 江苏欣宝科技股份有限公司 Polyester resin for dry-mixed extinction powder coating and preparation method thereof
CN113150258B (en) * 2021-05-12 2024-03-26 江苏欣宝科技股份有限公司 Polyester resin for dry-mixed extinction powder coating and preparation method thereof

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Application publication date: 20180817