CN108410076A - A kind of flame retardant plastics - Google Patents
A kind of flame retardant plastics Download PDFInfo
- Publication number
- CN108410076A CN108410076A CN201810232351.3A CN201810232351A CN108410076A CN 108410076 A CN108410076 A CN 108410076A CN 201810232351 A CN201810232351 A CN 201810232351A CN 108410076 A CN108410076 A CN 108410076A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- nano
- retardant plastics
- corvic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of flame retardant plastics, including:Trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire retardant, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, thermoplastic polyester and Corvic, parts by weight shared by each ingredient in the flame retardant plastics:5 10 parts of 10 15 parts of trithiophenyl phosphate, 15 20 parts of polystyrene, 5 10 parts of nano silicon dioxide, 20 25 parts of fire retardant, 15 parts of molybdenum trioxide, 15 parts of ammonium polyphosphate, 5 10 parts of nano-titanium dioxide, 10 15 parts of thermoplastic polyester and Corvic.By the above-mentioned means, flame retardant plastics provided by the invention, there is good flame retardant property, smoke amount is few when burning.
Description
Technical field
The present invention relates to plastic applications, more particularly to a kind of flame retardant plastics.
Background technology
With science and technology and economic continuous development, the daily product generated by plastics plays more and more important in life
Effect.But plastics easy firing, and burning velocity is fast, will produce a large amount of toxic gas, causes casualties and property loss.
So plastic products is needed not burn, there is good flame retardant property, it is desirable that smoke degree of the plastics in big fire wants small.But mesh
The preceding flame retardant plastics performance used cannot be met the requirements.
Invention content
The invention mainly solves the technical problem of providing a kind of flame retardant plastics, there is good flame retardant property, when burning
Smoke amount is few.
In order to solve the above technical problems, one aspect of the present invention is:A kind of flame retardant plastics is provided, including:
Trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire retardant, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, heat
Plasticity polyester and Corvic, parts by weight shared by each ingredient in the flame retardant plastics:Trithiophenyl phosphate 10-15
Part, 15-20 parts of polystyrene, 5-10 parts of nano silicon dioxide, 20-25 parts of fire retardant, 1-5 parts of molybdenum trioxide, ammonium polyphosphate 1-5
Part, 5-10 parts of nano-titanium dioxide, 10-15 parts of thermoplastic polyester and 5-10 parts of Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate
10 parts of phenyl ester, 15 parts of polystyrene, 5 parts of nano silicon dioxide, 20 parts of fire retardant, 1 part of molybdenum trioxide, ammonium polyphosphate 1 part, nanometer
5 parts of 5 parts of titanium dioxide, 10 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate
11 parts of phenyl ester, 15 parts of polystyrene, 6 parts of nano silicon dioxide, 20 parts of fire retardant, 2 parts of molybdenum trioxide, ammonium polyphosphate 1 part, nanometer
5 parts of 6 parts of titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate
12 parts of phenyl ester, 16 parts of polystyrene, 6 parts of nano silicon dioxide, 21 parts of fire retardant, 2 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer
6 parts of 6 parts of titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate
13 parts of phenyl ester, 17 parts of polystyrene, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 3 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer
7 parts of 6 parts of titanium dioxide, 12 parts of thermoplastic polyester and Corvic.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the flame retardant plastics:Tri o cresyl thiophosphate
14 parts of phenyl ester, 18 parts of polystyrene, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 4 parts of molybdenum trioxide, ammonium polyphosphate 2 part, nanometer
8 parts of 7 parts of titanium dioxide, 13 parts of thermoplastic polyester and Corvic.
The beneficial effects of the invention are as follows:A kind of flame retardant plastics that the present invention points out has good flame retardant property, when burning
Smoke amount is few.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1:
It weighs:10 kilograms of trithiophenyl phosphate, 15 kilograms of polystyrene, 5 kilograms of nano silicon dioxide, 20 kilograms of fire retardant,
1 kilogram of molybdenum trioxide, 1 kilogram of ammonium polyphosphate, 5 kilograms of nano-titanium dioxide, 10 kilograms of thermoplastic polyester and Corvic 5
Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder
In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's
Flame retardant plastics.
Embodiment 2:
It weighs:11 kilograms of trithiophenyl phosphate, 15 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 20 kilograms of fire retardant,
2 kilograms of molybdenum trioxide, 1 kilogram of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 11 kilograms of thermoplastic polyester and Corvic 5
Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder
In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's
Flame retardant plastics.
Embodiment 3:
It weighs:12 kilograms of trithiophenyl phosphate, 16 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 21 kilograms of fire retardant,
2 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 11 kilograms of thermoplastic polyester and Corvic 6
Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder
In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's
Flame retardant plastics.
Embodiment 4:
It weighs:13 kilograms of trithiophenyl phosphate, 17 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 22 kilograms of fire retardant,
3 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 6 kilograms of nano-titanium dioxide, 12 kilograms of thermoplastic polyester and Corvic 7
Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder
In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's
Flame retardant plastics.
Embodiment 5:
It weighs:14 kilograms of trithiophenyl phosphate, 18 kilograms of polystyrene, 6 kilograms of nano silicon dioxide, 22 kilograms of fire retardant,
4 kilograms of molybdenum trioxide, 2 kilograms of ammonium polyphosphate, 7 kilograms of nano-titanium dioxide, 13 kilograms of thermoplastic polyester and Corvic 8
Kilogram, mixing machine is added, controls rotating speed at room temperature at 1300 revs/min, mixing is taken out after 15 minutes, adds screw extruder
In, extruding pelletization, it is 150 DEG C to squeeze out barrel temperature, 180 DEG C, screw speed 30r/min of head temperature, that is, obtains the present invention's
Flame retardant plastics.
Test case:Anti-flammability test is carried out to the flame retardant plastics of embodiment 1-5, test result is shown in Table 1.
Table 1:Flame retardant plastics flame retardant property tests table
Flue gas generating rate(m2 /s2) | |
Test method | GB/T 20284-2006 |
Embodiment 1 | 0.24 |
Embodiment 2 | 0.23 |
Embodiment 3 | 0.22 |
Embodiment 4 | 0.21 |
Embodiment 5 | 0.25 |
In conclusion a kind of flame retardant plastics that the present invention points out, there is good flame retardant property, smoke amount is few when burning.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (6)
1. a kind of flame retardant plastics, which is characterized in that including:It is trithiophenyl phosphate, polystyrene, nano silicon dioxide, fire-retardant
Agent, molybdenum trioxide, ammonium polyphosphate, nano-titanium dioxide, thermoplastic polyester and Corvic, in the flame retardant plastics respectively at
Parts by weight shared by point:It is 10-15 parts of trithiophenyl phosphate, 15-20 parts of polystyrene, 5-10 parts of nano silicon dioxide, fire-retardant
20-25 parts of agent, 1-5 parts of molybdenum trioxide, 1-5 parts of ammonium polyphosphate, 5-10 parts of nano-titanium dioxide, 10-15 parts of thermoplastic polyester and
5-10 parts of Corvic.
2. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics
Number:10 parts of trithiophenyl phosphate, 5 parts of nano silicon dioxide, 20 parts of fire retardant, 1 part of molybdenum trioxide, gathers 15 parts of polystyrene
5 parts of 1 part of ammonium phosphate, 5 parts of nano-titanium dioxide, 10 parts of thermoplastic polyester and Corvic.
3. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics
Number:11 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 20 parts of fire retardant, 2 parts of molybdenum trioxide, gathers 15 parts of polystyrene
5 parts of 1 part of ammonium phosphate, 6 parts of nano-titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
4. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics
Number:12 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 21 parts of fire retardant, 2 parts of molybdenum trioxide, gathers 16 parts of polystyrene
6 parts of 2 parts of ammonium phosphate, 6 parts of nano-titanium dioxide, 11 parts of thermoplastic polyester and Corvic.
5. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics
Number:13 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 3 parts of molybdenum trioxide, gathers 17 parts of polystyrene
7 parts of 2 parts of ammonium phosphate, 6 parts of nano-titanium dioxide, 12 parts of thermoplastic polyester and Corvic.
6. flame retardant plastics according to claim 1, which is characterized in that parts by weight shared by each ingredient in the flame retardant plastics
Number:14 parts of trithiophenyl phosphate, 6 parts of nano silicon dioxide, 22 parts of fire retardant, 4 parts of molybdenum trioxide, gathers 18 parts of polystyrene
8 parts of 2 parts of ammonium phosphate, 7 parts of nano-titanium dioxide, 13 parts of thermoplastic polyester and Corvic.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810232351.3A CN108410076A (en) | 2018-03-21 | 2018-03-21 | A kind of flame retardant plastics |
Applications Claiming Priority (1)
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CN201810232351.3A CN108410076A (en) | 2018-03-21 | 2018-03-21 | A kind of flame retardant plastics |
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Publication Number | Publication Date |
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CN108410076A true CN108410076A (en) | 2018-08-17 |
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CN201810232351.3A Pending CN108410076A (en) | 2018-03-21 | 2018-03-21 | A kind of flame retardant plastics |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113150258A (en) * | 2021-05-12 | 2021-07-23 | 江苏欣宝科技股份有限公司 | Polyester resin for dry-mixed extinction powder coating and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104829959A (en) * | 2015-04-30 | 2015-08-12 | 王英英 | Flame retardant plastic |
CN106916403A (en) * | 2015-12-25 | 2017-07-04 | 青岛城轨交通装备科技有限公司 | A kind of flame retardant plastics |
CN106995618A (en) * | 2017-06-01 | 2017-08-01 | 东至县科创塑料制品有限公司 | A kind of flame retardant plastics |
-
2018
- 2018-03-21 CN CN201810232351.3A patent/CN108410076A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104829959A (en) * | 2015-04-30 | 2015-08-12 | 王英英 | Flame retardant plastic |
CN106916403A (en) * | 2015-12-25 | 2017-07-04 | 青岛城轨交通装备科技有限公司 | A kind of flame retardant plastics |
CN106995618A (en) * | 2017-06-01 | 2017-08-01 | 东至县科创塑料制品有限公司 | A kind of flame retardant plastics |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113150258A (en) * | 2021-05-12 | 2021-07-23 | 江苏欣宝科技股份有限公司 | Polyester resin for dry-mixed extinction powder coating and preparation method thereof |
CN113150258B (en) * | 2021-05-12 | 2024-03-26 | 江苏欣宝科技股份有限公司 | Polyester resin for dry-mixed extinction powder coating and preparation method thereof |
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Application publication date: 20180817 |