CN108398505A - The device and its detection method that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected - Google Patents
The device and its detection method that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected Download PDFInfo
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- CN108398505A CN108398505A CN201810267259.0A CN201810267259A CN108398505A CN 108398505 A CN108398505 A CN 108398505A CN 201810267259 A CN201810267259 A CN 201810267259A CN 108398505 A CN108398505 A CN 108398505A
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- heating component
- heating
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- cigarette filter
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/126—Preparation by evaporation evaporating sample
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The present invention relates to a kind of device that the volatile ingredient to flavoring composite cigarette filter tip is detected and its detection methods comprising filter segment (4), control section (3) and the bringing-up section (2) being arranged in order；Wherein, the filter segment (4) is hollow cylinder, and the control section (3) includes heating control system, and the bringing-up section (2) includes the N number of heating component (1 being arranged in order from remote mouth end to nearly mouth endi), N >=2, i are the heating component number since remote mouth end, and i is the positive integer from 1 to N.The state that apparatus of the present invention are burnt by the way that bringing-up section is arranged come pipe tobacco when simulating smoker's smoking cigarette, it is heated by heated section of the cleaned air without smoke components of convection current, then the flavoring composite cigarette filter tip of filter segment is heated, so that odourant ingredients are not influenced by complicated flue gas in filter tip, chromatography test result subsequent in this way will be relatively more accurate.
Description
Technical field
The invention belongs to cigarette detection device fields, and in particular to a kind of volatile ingredient to flavoring composite cigarette filter tip
The device and its detection method being detected.
Background technology
As international smoking ban cry rises from all around and cigarette consumption person is to the growing interest of own health, low tar less harmful volume
Cigarette will be necessarily accompanied with cigarette flavor loss as the mainstream of future world cigarette, but while reducing tar and reducing harm and comfort level becomes
Difference, and perfuming cigarette charging can be set off, added volume cigarette perfume taste, increase flue gas concentration, improvement is jealous, removes and covers miscellaneous gas, subtract
Few irritation, can also assign the characteristic chicken flavor of product grace, the personalized style of prominent cigarette product, and perfuming cigarette charging is ground
Hair and application are just becoming one of the most key technology that cigarette fragrance is kept in work of reducing tar and reducing harm.In the past few decades
Between, domestic and international each cigarette manufacturer develops numerous flavoring technologies, such as tobacco perfuming, cigarette paper flavoring, forming paper flavoring, bonding
Agent flavoring and packaging material flavoring etc., filter tip flavoring are an important flavoring modes.Essence and flavoring agent is directly appended to cigarette filter
There is following advantage on mouth：One, fragrance escaping and being pyrolyzed in can avoid cigarette storage and aspiration procedure of burning；Two, it can keep away
During exempting from the quiet combustion of cigarette, the loss of fragrance；Three, the retention to fragrance such as pipe tobacco and filter tip can be reduced, transfer efficiency is increased；Four,
A variety of perfuming methods can be used.
Realize that perfuming cigarette is the popular solution route of a comparison by adding fragrance in composite cigarette filter tip.But
Method to analysis and the detection of composite filter tip flavoring is all to carry out flue gas trapping analysis using smoking machine, but contained in pipe tobacco
Chemical substance up to more than 3000 kind, and pipe tobacco it is shared in entire cigarette proportion it is very big, and odourant ingredients only account for seldom
Proportion, therefore if by pipe tobacco and odourant ingredients together heating evaporation, complicated smoke components certainly will be to odourant ingredients in pipe tobacco
Analysis makes a big impact.It further says, the complicated smoke components in pipe tobacco are very likely mixed with odourant ingredients, are caused
When being analyzed using chromatography, chromatographic peak large area overlaps, and can not tell odourant ingredients, this is caused very to follow-up chromatography
Big puzzlement.Therefore, how really and accurately filter tip perfuming component accurately analyze and detect becoming Tobacco Analysis field
Extremely important problem.
Invention content
The present invention provides a kind of device that the volatile ingredient to flavoring composite cigarette filter tip is detected and its detection side
Method solves the problems, such as that the analysis of composite cigarette filter tip perfuming component is influenced by complicated smoke components.
A kind of device that volatile ingredient to flavoring composite cigarette filter tip is detected comprising the filter tip being arranged in order
Section 4, control section 3 and bringing-up section 2；Wherein, the filter segment 4 is hollow cylinder, and the control section 3 includes computer heating control system
System, the bringing-up section 2 includes the N number of heating component 1 being arranged in order from remote mouth end to nearly mouth endi, N >=2, i are to be opened from remote mouth end
The heating component of beginning is numbered, and i is the positive integer from 1 to N, and air hole is offered on 4 axial direction of the filter segment.
Device described above, the heating component 1iShell including seal and fill the inert particle 5 in it, institute
State heating component 1iBoth ends open.Wherein inert particle refers to not released when being subjected to the temperature heating not higher than 600 DEG C
The particle of any hot volatility or pyrolytic substance.
Device described above, the inert particle 5 are ceramic particle or alumina particle.
A method of the volatile ingredient of flavoring composite cigarette filter tip is detected, which is characterized in that its right to use
Profit requires the device described in 1, and it includes the following steps：
A, the composite cigarette filter tip containing fragrance is put into the filter segment 4, then filter segment 4 is connected with smoking machine
It connects；
B, start the heating control system of the control section 3, open first heating component 11, start after a period of time
Two heating components 12, simultaneously close off first heating component 11, and so on, principle is when i-th of heating component 1 of startupi
When, i-1 heating component before being shut off；Air is from first heating component 11Opening enter detection device, and according to
It is secondary to pass through second heating component 12, and so on, eventually by i-th of heating component so that the air of heating flows through described
Composite cigarette filter tip containing fragrance simultaneously makes the fragrance in cigarette filter is heated to evaporate；
C, the fragrance component evaporated is trapped on cambridge filter, is then analyzed.
The key point of the present invention is：Design it is a kind of can simulating smoker's suction traditional cigarette device, design point
It is 3 sections：Filter segment 4, control section 3 and bringing-up section 2, wherein filter segment 4 are for accommodating the composite cigarette filter tip containing fragrance, bringing-up section
2 be to contain N number of (N >=2) heating component 1iCalandria, be put into filter segment 4 when by the composite cigarette filter tip for containing fragrance, and with
After smoking machine connection, according to the puff number and heating temperature of sample to be tested design, start control section 3, opens first heating
Component 11, then start second heating component 12, simultaneously close off first heating component 11, and so on, principle is when startup
I-th of heating component 1iWhen, i-1 heating component before being shut off；Air is from first heating component 11Opening enter
Detection device, and pass sequentially through second heating component 12, and so on, eventually by i-th of heating component so that heating
Air flows through the composite cigarette filter tip containing fragrance and makes fragrance therein is heated to evaporate.
Beneficial effects of the present invention are as follows：
1, develop it is a kind of can simulating smoker's suction traditional cigarette device, the device pass through start i-th of heating group
Part 1iWhen, i-1 heating component before being shut off；Air is from first heating component 11Opening enter detection device, and
Pass sequentially through second heating component 12, and so on, eventually by i-th of heating component so that heating is free of pipe tobacco cigarette
The cleaned air of gas ingredient flows through the composite cigarette filter tip containing fragrance, and makes the heated volatilization of the fragrance in composite cigarette filter tip
Out, invention emulates smokers when aspirating cigarette, and pipe tobacco constantly burns and the state of reduction, also simulates into filter tip
The higher and higher state of the temperature of the gas at end, more truly simulates the heated volatilization of fragrance under conventional smoking state and releases
It puts and migration characteristic.
2, the state that apparatus of the present invention are burnt by the way that bringing-up section is arranged come pipe tobacco when simulating smoker's smoking cigarette, by right
The cleaned air without smoke components for flowing through bringing-up section is heated, and is then carried out to the flavoring composite cigarette filter tip of filter segment
Heating so that odourant ingredients are not influenced by complicated flue gas in filter tip, and chromatography test result subsequent in this way will be relatively more accurate,
By the way that air hole is arranged in the axial direction, increase the contact area of filter tip and air, acceleration detection process improves detection effect
Rate.
Description of the drawings
Fig. 1 is the structural schematic diagram of apparatus of the present invention；
Fig. 2 is the perfuming component GC-MS analysis surveys that the composite cigarette filter tip containing fragrance is tested in apparatus of the present invention embodiment 1
Test result figure；
Fig. 3 is the perfuming component GC-MS analysis surveys that the composite cigarette filter tip containing fragrance is tested in apparatus of the present invention embodiment 2
Test result figure；
Reference numeral meaning is as follows in figure：
1- heating components；2- bringing-up sections；3- control sections；4- filter segments, 5- inert particles.
Specific implementation mode
The present invention is described in further details with attached drawing with reference to embodiments, embodiment is only limitted to illustrate the present invention,
Rather than limitation of the invention.
Embodiment 1
A kind of device that volatile ingredient to flavoring composite cigarette filter tip is detected comprising the filter tip being arranged in order
Section 4, control section 3 and bringing-up section 2；Wherein, the filter segment 4 is hollow cylinder, and the control section 3 includes computer heating control system
System, the bringing-up section 2 includes the N number of heating component 1 being arranged in order from remote mouth end to nearly mouth endi, N >=2, i are to be opened from remote mouth end
The heating component of beginning is numbered, and i is the positive integer from 1 to N, and air hole is offered on 4 axial direction of the filter segment.
Device described above, the heating component 1iShell including seal and fill the inert particle 5 in it, institute
State heating component 1iBoth ends open.Wherein inert particle refers to not released when being subjected to the temperature heating not higher than 600 DEG C
The particle of any hot volatility or pyrolytic substance.
Device described above, the inert particle 5 can be ceramic particle or alumina particle.
Fragrance in the present embodiment is fragrance A.
A method of the volatile ingredient of flavoring composite cigarette filter tip is detected comprising following steps：
A, the composite cigarette filter tip containing fragrance is put into the filter segment 4, then filter segment 4 is connected with smoking machine
It connects；
B, start the heating control system of the control section 3, open first heating component 11, then start second and add
Hot component 12, simultaneously close off first heating component 11, and so on, principle is when i-th of heating component 1 of startupiWhen, just close
I-1 heating component before closing；Air is from first heating component 11Opening enter detection device, and pass sequentially through
Two heating components 12, and so on, eventually by i-th of heating component so that the air of heating flows through described containing fragrance
Composite cigarette filter tip simultaneously makes the fragrance in cigarette filter is heated to evaporate；
C, the fragrance component evaporated is trapped on cambridge filter, is then analyzed.
The above-mentioned cambridge filter by after trapping carries out GC-MS analyses, chromatographic condition by being concentrated after methanol extraction：Sample introduction
Mouth temperature：250℃；Temperature programming：50 DEG C of initial temperature keeps 1min, rises to 220 DEG C with 5 DEG C/min, keeps 20min；Side
Formula：Split sampling, split ratio 20：1；Sampling volume：1μL；Mass Spectrometry Conditions：Ion source：The sources EI；Ionization energy：70eV；Ion source temperature
Degree：180℃；Transmission line temperature：220℃；Detection pattern：Full ion scan monitoring, mass scan range：50~550amu；It is molten
Agent postpones：2min.Analysis result is as shown in Figure 2.
Embodiment 2
A kind of device that volatile ingredient to flavoring composite cigarette filter tip is detected comprising the filter tip being arranged in order
Section 4, control section 3 and bringing-up section 2；Wherein, the filter segment 4 is hollow cylinder, and the control section 3 includes computer heating control system
System, the bringing-up section 2 includes the N number of heating component 1 being arranged in order from remote mouth end to nearly mouth endi, N >=2, i are to be opened from remote mouth end
The heating component of beginning is numbered, and i is the positive integer from 1 to N, and air hole is offered on 4 axial direction of the filter segment.
Device described above, the heating component 1iShell including seal and fill the inert particle 5 in it, institute
State heating component 1iBoth ends open.Wherein inert particle refers to not released when being subjected to the temperature heating not higher than 600 DEG C
The particle of any hot volatility or pyrolytic substance.
Device described above, the inert particle 5 can be ceramic particle or alumina particle.
Fragrance in the present embodiment is fragrance B.
A method of the volatile ingredient of flavoring composite cigarette filter tip is detected comprising following steps：
A, the composite cigarette filter tip containing fragrance is put into the filter segment 4, then filter segment 4 is connected with smoking machine
It connects；
B, start the heating control system of the control section 3, open first heating component 11, then start second and add
Hot component 12, simultaneously close off first heating component 11, and so on, principle is when i-th of heating component 1 of startupiWhen, just close
I-1 heating component before closing；Air is from first heating component 11Opening enter detection device, and pass sequentially through
Two heating components 12, and so on, eventually by i-th of heating component so that the air of heating flows through described containing fragrance
Composite cigarette filter tip simultaneously makes the fragrance in cigarette filter is heated to evaporate；
C, the fragrance component evaporated is trapped on cambridge filter, is then analyzed.
It is concentrated after cambridge filter after above-mentioned trapping is extracted by ethyl alcohol, carries out GC-MS analyses, chromatographic condition：Sample introduction
Mouth temperature：250℃；Temperature programming：50 DEG C of initial temperature keeps 1min, rises to 220 DEG C with 5 DEG C/min, keeps 20min modes：
Split sampling, split ratio 20：1；Sampling volume：1μL；Mass Spectrometry Conditions：Ion source：The sources EI；Ionization energy：70eV；Ion source temperature：
180℃；Transmission line temperature：220℃；Detection pattern：Full ion scan monitoring, mass scan range：50~550amu；Solvent prolongs
Late：2min.Analysis result is as shown in Figure 3.
Above-mentioned apparatus and method can effectively promote the filter tip analysis of the composite cigarette filter tip aroma component sample containing fragrance, make
The sensitivity for analysis of sample improves, and sample is not influenced by complicated flue gas, really reflects the ingredient of composite cigarette filter tip flavoring
And its Transport, and can effectively guide product exploitation and design.Method is feasible, easy to operate, accurate sensitive, has to promote and answer
With value.
Claims (4)
1. the device that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected, which is characterized in that it includes successively
Filter segment (4), control section (3) and the bringing-up section (2) of arrangement；Wherein, the filter segment (4) is hollow cylinder, the control
Section (3) includes heating control system, and the bringing-up section (2) includes the N number of heating component being arranged in order from remote mouth end to nearly mouth end
(1i), N >=2, i are the heating component number since remote mouth end, and i is the positive integer from 1 to N, and the filter segment (4) is axial
Air hole is offered on direction.
2. the apparatus according to claim 1, which is characterized in that the heating component (1i) include seal shell and fill out
Fill the inert particle (5) in it, the heating component (1i) both ends open.
3. the apparatus of claim 2, which is characterized in that the inert particle (5) is ceramic particle or aluminium oxide granule
Grain.
4. a kind of method that volatile ingredient to the rotary cigarette filter of flavoring is detected, which is characterized in that its right to use
Profit requires the device described in 1, and it includes the following steps：
A, the composite cigarette filter tip containing fragrance is put into the filter segment (4), then filter segment (4) is connected with smoking machine
It connects；
B, start the heating control system of the control section (3), open first heating component (11), start after a period of time
Two heating components (12), simultaneously close off first heating component (11), and so on, principle is when i-th of heating component of startup
(1i) when, (i-1) a heating component before being shut off；Air is from first heating component (11) opening enter detection dress
It sets, and passes sequentially through second heating component (12), and so on, eventually by i-th of heating component so that the air of heating
It flows through the composite cigarette filter tip containing fragrance and makes the fragrance in cigarette filter is heated to evaporate；
C, the fragrance component evaporated is trapped on cambridge filter, is then analyzed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810267259.0A CN108398505A (en) | 2018-03-28 | 2018-03-28 | The device and its detection method that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810267259.0A CN108398505A (en) | 2018-03-28 | 2018-03-28 | The device and its detection method that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108398505A true CN108398505A (en) | 2018-08-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810267259.0A Withdrawn CN108398505A (en) | 2018-03-28 | 2018-03-28 | The device and its detection method that a kind of volatile ingredient to flavoring composite cigarette filter tip is detected |
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| CN (1) | CN108398505A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205321194U (en) * | 2015-12-31 | 2016-06-22 | 山东中烟工业有限责任公司 | Sectional type electrical heating cigarette |
-
2018
- 2018-03-28 CN CN201810267259.0A patent/CN108398505A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN205321194U (en) * | 2015-12-31 | 2016-06-22 | 山东中烟工业有限责任公司 | Sectional type electrical heating cigarette |
Non-Patent Citations (1)
| Title |
|---|
| 蔡君兰等: "采用滤嘴分析法评估吸烟者的口腔烟气暴露量", 《中国烟草学会2016年度优秀论文汇编——烟草工业主题》 * |
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Application publication date: 20180814 |