CN108396437A - A kind of preparation method of woven carpet without gum technique - Google Patents
A kind of preparation method of woven carpet without gum technique Download PDFInfo
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- CN108396437A CN108396437A CN201810137346.4A CN201810137346A CN108396437A CN 108396437 A CN108396437 A CN 108396437A CN 201810137346 A CN201810137346 A CN 201810137346A CN 108396437 A CN108396437 A CN 108396437A
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- yarn
- clad
- carpet
- pile
- fiber
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D27/00—Woven pile fabrics
- D03D27/02—Woven pile fabrics wherein the pile is formed by warp or weft
- D03D27/04—Weft pile fabrics
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/60—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the warp or weft elements other than yarns or threads
- D03D15/68—Scaffolding threads, i.e. threads removed after weaving
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C27/00—Compound processes or apparatus, for finishing or dressing textile fabrics, not otherwise provided for
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/04—Floor or wall coverings; Carpets
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Carpets (AREA)
Abstract
The invention discloses a kind of preparation methods of the woven carpet without gum technique, the second clad is used as the long filament or spun yarn that are formed by meldable fibre, first clad is the fiber filament or spun yarn formed by terylene, second clad accounts for 20% the 50% of composite yarn gross mass, first clad accounts for 10% the 15% of composite yarn gross mass, and surplus is that the mode of heart yarn is made and hangs pile filling.When producing non-adhesive carpet as adhesives using hot melt copolyester fiber, and pile yams made of cooperation acrylic fiber, when hot melt copolyester fiber is melted when hot pressing process is heated to its fusing point or more, fiber Macromolecular chain configuration changes, pass through the transition of segment, entire macromolecular chain is set to slide, VISCOUS FLOW occurs, pile and weft yarn and weft yarn and warp thread are effectively consolidated after solidification, enhance the extraction strength and the conformality of carpet and the stability of size of pile, to which the gum process in carpet preparation process be omitted, keep carpet obtained more environmentally friendly.
Description
Technical field
The present invention relates to field of sanitary equipment more particularly to a kind of preparation methods of woven carpet without gum technique.
Background technology
With the raising of modern life level, to the comfort of part public place and house fitting-up, fashion, environmental protection
The requirements such as property are also higher and higher.The utilization rate of carpet accounts for greatly in part public place and house ornamentation.Carpet has
The function of warming adjusting, in large area place mat carpet can reduce indoor by ground dispersed heat, block ground cold air
Invasion make one to bask comfortable.There is sound absorption function simultaneously, the surface that the abundant quality of carpet is stood with lint cluster has well
Sound-absorbing effect, and can suitably reduce influence of noise, due to the fabric that carpet is high resilience fiber, have plentiful, thick and solid, soft
Quality, so above walk when will produce preferable screen resilience, be comfortable on softness.Carpet has both aesthetic function simultaneously,
Quality is plentiful, and ground can seem dignified gorgeous after the magnificent laying carpet of appearance, obtain fabulous decorative effect.
Carpet is had by type point：Wool carpet, chemical fibre carpet, cortex carpet, rubber carpet, natural fiber carpet etc..
Respectively there are the characteristics and advantages of oneself.
Carpet can be divided into woven carpet and hand-made carpet by production method difference.Woven carpet includes tufted carpet and machine again
Knit Wilden carpet, woven Axminster carpet.Woven Wilden carpet is interweaved by warp thread, weft yarn, pile yams, through upper
The later process such as glue, shorn velvet are arranged and are made, and warp thread, weft yarn, pile yams mechanical adhesion, woven Axminster carpet is made to be also
Interweaved by warp thread, weft yarn, pile yams, arranged by processes such as gluing, shorn velvets, wherein being needed using organic in gluing program
Solvent has the following problems by glue dissolved dilution, therefore in upper glue process：(1) during gluing, volatilization pernicious gas pollution
Environment influences worker's health；(2) gluing and dry solidification technological process are long, of long duration, limit speed of production, equipment accounts for
Big with space, glue consumption is big, high energy consumption, and then increases the production cost of carpet；(3) traditional carpet uses embryo blanket backsizing
Mode, glue need to infiltrate to pile yams by embryo blanket base cloth, due to the presence of embryo blanket base cloth, are easy to make pile yams by seldom glue
It is deadlocked, cause pile yams to extract strength insufficient, poor dimensional stability, it is yielding the problems such as.Meanwhile to reduce cost and raising
The stiffness of carpet, gluing during generally glue bond layer is used with together with calcium carbonate, this method but come problem be not
Easy reuse, and when burning waste, fire retardant filler material is contained in waste.
Therefore, the prior art needs further improvement and develops.
Invention content
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide one kind without the woven carpet of gum technique
Preparation method, ensure pile extract strength and omit coating process under the premise of, enhance the conformality and size of carpet
Stability, and reduce the lower machine broadwise crimp after braiding carpet.
In order to solve the above technical problems, the present invention program includes：
A kind of preparation method of woven carpet without gum technique, the carpet include base fabric, pile yams, weft yarn and warp
Yarn, wherein the weft yarn includes hanging pile filling and not hanging pile filling, and it is 1 to hang pile filling and do not hang the ratio of pile filling:
1-1:4, naturally it is also possible to it is suitably adjusted according to needs of production to hanging pile filling and not hanging the ratio of pile filling,
For example it can also cancel all using the above-mentioned weft yarn of pile filling composition is hung and do not hang pile filling, to further increase carpet
Properties.Pile yams be meet carpet needs cation-dyeable acrylic fibers made of fiber filament yarn, staple yarn or
One kind in staple blended yarn, the extension pile filling are composite yarn, and composite yarn is made of heart yarn and clad, which is to meet
The normal weft that carpet requires, the clad include the first clad and the second clad, and the second clad is by meldable fibre
The long filament or spun yarn of formation, the first clad are the fiber filament or spun yarn formed by terylene, and the second clad accounts for compound
The 20%-50% of yarn gross mass, the first clad account for the 10%-15% of composite yarn gross mass, and surplus is heart yarn；
Above-mentioned meldable fibre is hot melt copolyester fiber, which is composite fibre, the composite fibre
Including copolyester material, bonding additives and inorganic nano material, wherein copolyester material, bonding additives and inorganic nano material
Mass ratio be (85-98.5):(1-10)：(0.5-5)；
Using silane coupling agent, titanate coupling agent, aluminate coupling agent or phosphate coupling agent to inorganic nano material
Surface modification is carried out, the copolyester material for being then 85 DEG C -95 DEG C with fusing point presses matter with surface-modified inorganic nano material
Amount is than being (60-70)：The ratio melt blending of (30-40) is granulated, and the first master batch is made, the copolymerization for being 85 DEG C -95 DEG C with fusing point
Ester material is (50-60) in mass ratio with bonding additives：The ratio melt blending of (40-50) is granulated, and the second master batch is made, then
The copolyester material melt spinning for being 95 DEG C -130 DEG C with fusing point by the first master batch, the second master batch by design requirement, is made above-mentioned
Heat copolyester fiber.
The preparation method, wherein above-mentioned bonding additives be ethylene-maleic acid-methacrylic dehydrated glyceride,
Ethylene-methyl acrylate-glyceryl methacrylate, ethylene-ethylacrylate-glycidyl methacrylate, second
Alkene-n-butyl acrylate-glycidyl methacrylate, polypropylene grafted glycidyl methacrylate, polyethylene connect
Branch glycidyl methacrylate, ethylene/butylene copolymers graft glycidyl methacrylate, ethylene/octene copolymerization
Object graft glycidyl methacrylate, styrene/ethylene/butadiene block copolymer grafted methacrylic acid glycidol
It is one or more in ester；Above-mentioned inorganic nano material be silica, calcium carbonate, montmorillonite, one kind in titanium dioxide or
A variety of, inorganic nano material grain size is 15 nanometers -20 nanometers, and specific surface area is 150 ± l0m2/g。
The preparation method, wherein press the advance structure design of carpet, be made after pile yams, weft yarn and warp thread are interweaved
Embryo blanket makes the fusing flowing of the second clad to embryo blanket hot-pressing processing, through cooling and solidifying, bonding pile yams and weft yarn and weft yarn with
Warp thread, then above-mentioned carpet is obtained after subsequent processing.
The preparation method, wherein above-mentioned hot using being carried out after far infrared or hot-air preheating to embryo blanket hot-pressing processing
Roller pressurizes；Before embryo blanket enters heat roller tube surface, first far infrared or hot-air is used to preheat embryo blanket, on heat roller tube surface
It is provided with 1-3 pressure roller, heat roller tube is dynamic for main turn, and pressure roller is driven rotation, and embryo blanket is slave drive, hot-rolling drum surface temperature
It it is 120 DEG C -160 DEG C, embryo blanket carries out hot pressurization by different pressure rollers successively；Embryo blanket leaves to enter in heat preservation zone after hot-rolling and carry out etc.
Temperature crystallization.
The preparation method, wherein the composite yarn of above-mentioned extension pile filling is to be added using coating machine or Novelty twisters
Composite yarn made of work.
The preparation method, wherein with the fiber filament or spun yarn that are formed by terylene for the first clad, with hot melt
The long filament or spun yarn that copolyester fiber is formed are the second clad, coating machine or Novelty twisters when coating the first clad
Seal wire hook distance be 10 centimetres -20 centimetres, when coat the second clad the seal wire of coating machine or Novelty twisters hook distance
Be 1 centimetre -15 centimetres, and distance seal wire hook when coat than first layer that seal wire hooks when the second layer coats distance it is low 5 centimetres with
On；
First clad is wrapped in compact state on heart yarn, and the second clad is wrapped in the first clad in soft fluffy state
On surface, above-mentioned extension pile filling is made after carrying out first layer cladding and second layer cladding to the heart yarn for hanging pile filling.
The preparation method, wherein above-mentioned carpet is woven Wilden carpet or woven Axminster carpet.
A kind of preparation method of woven carpet without gum technique provided by the invention, hot melt copolyester fiber have nothing
The presence of setting-crystalline state structure, crystal region makes fiber have certain strength；And the presence of amorphous region makes big point of fiber
Subchain can move freely, and to make the property of fiber close to amorphous high polymer, have possessed by Amorphous Polymers
Some physical state features, thus it is heated when have glassy state, elastomeric state, viscous state, therefore heat copolyester fiber and can be melted
Melt processing, and there is after cooling and solidifying certain strength and flexibility again, using hot melt copolyester fiber as bonding
When material produces non-adhesive carpet, and pile yams made of cooperation acrylic fiber, when hot melt copolyester fiber adds in hot pressing process
It is melted when more than heat to its fusing point, fiber Macromolecular chain configuration changes, and by the transition of segment, makes entire macromolecular
Chain slides, and VISCOUS FLOW occurs, and by the capillarity of glued Inter-fiber voids and the surface tension effects of fiber, occurs
The melt of flowing sprawls infiltration in fiber surface, after cooling and solidifying again, passes through the work of mechanical adhesion power and diffusion interfacial molecular
Pile yams and weft yarn are firmly bonded, while weft yarn and warp thread are effectively consolidated after solidification, enhance the conformality and ruler of carpet
Very little stability keeps carpet obtained more environmentally friendly to which the gum process in carpet preparation process be omitted.
And weft yarn is divided into the normal weft for not hanging pile and hangs the composite yarn of pile, due to meldable fibre phase in composite yarn
To higher price, therefore selectivity uses composite yarn as weft yarn, can reduce meldable fibre dosage, is ensureing tuft withdrawal force
Under the premise of, the production cost of carpet is reduced, and the stiffness and conformality of carpet can be improved in the addition of inorganic nano material.With silicon
Alkane coupling agent, titanate coupling agent, aluminate coupling agent, phosphate coupling agent etc. carry out surface modification to inorganic nano material,
One layer of organic matter is covered on inorganic nano material surface, enhances compatibility and the bonding of inorganic nano material and copolyester material
Power, and dispersibility of the enhancing inorganic nano material in copolyester material；With fusing point be 85 DEG C -95 DEG C copolyester material with
Surface-modified inorganic nano material melt blending is granulated, and the first master batch is made, since fusing point is 85 DEG C -95 DEG C of copolyesters
Viscosity lazy flow is good when material molten, and inorganic nano material can be made to have preferable dispersibility in heating copolyester fiber,
It is processed conducive to follow-up spinning.
Meldable fibre is directly placed in embryo blanket using during carpet weaving, can effectively solve traditional carpet craft gum
The problem of glue is not easy to permeate in the process, while omitting traditional gum process.The weft yarn composite yarn for hanging pile covers shape using double-contracting
Formula, the first clad select with the common polyeseter filament fiber or spun yarn of meldable fibre homology, such as the made of terylene
One clad, fusing point are more than 250 DEG C, since its hot pressing temperature is between 120 DEG C -160 DEG C in hot pressing process, will not occur
Melting, is wound in heart yarn surface with fiber condition always, is firmly combined with heart yarn under the action of mechanical force；It heats when heated
Fibers melt, because meldable fibre and the first clad are same based material, molecular radical having the same, therefore with compatible very well
Property and cementability, the two can pass through the winding of macromolecular chain, intermolecular force, hydrogen bond etc. carry out it is strong bonded.Therefore first
Clad plays the role of preferable bridge joint during weft yarn and pile heat bonding.
And distance is hooked using big seal wire when the first clad cladding, the first clad fiber can be made used in big rotation
Property power under the action of heart yarn is fettered close, enhance the rigidity and stiffness of weft yarn, and then enhance the stiffness of carpet and conformal
Property.Meanwhile heart yarn be bound it is close after infiltration of the melt to heart yarn when can reduce meldable fibre heating melting, increase melt to suede
The infiltration capacity of head improves the extraction strength of carpet pile.First clad filament fiber or spun yarn are with side arranged in parallel
Formula is wound in heart yarn surface, and the regularity of arrangement is preferable, and regular arrangement can enhance the first clad filament fiber or spun yarn
Between and long filament or the interfibrous capillary effect of spun yarn, the Wicking of melt when being conducive to enhance meldable fibre heating melting
Effect increases the bonding force with the first clad after melt cures.
Second clad, i.e. clad made of meldable fibre hook distance when cladding using small seal wire, and when cladding rotates
Inertia is relatively low, the second clad fiber can be made to be coated on the first cover surface with more fluffy state, due to the second clad
More fluffy, its internal/external heating is more uniform when hot pressing, can make fiber while melt, and reduces the melting delay of inner fiber, contracting
Short hot pressing time improves hot pressing process production efficiency；Simultaneously because the second clad is more fluffy, meldable fibre is along perpendicular to core
The direction of yarn is more sprawled, and is conducive to increase the contact area of melt and pile after meldable fibre melts, enhancing melt is to pile
Infiltration infiltration increases the extraction strength of pile after solidification.
Due to containing ethylene-maleic acid-methacrylic dehydrated glyceride, ethylene-in selected hot melt copolyester fiber
Methyl acrylate-glycidyl methacrylate, ethylene-ethylacrylate-glycidyl methacrylate, ethylene-the third
Olefin(e) acid N-butyl-glycidyl methacrylate, polypropylene grafted glycidyl methacrylate, polycthylene grafted methyl
Glycidyl acrylate, ethylene/butylene copolymers graft glycidyl methacrylate, ethylene/octene grafting
In glycidyl methacrylate, styrene/ethylene/butadiene block copolymer graft glycidyl methacrylate
It is one or more, the similar flexible fat of flexible fat segment in polyester molecule chain together is contained in each bonding additives strand
Segment, therefore each bonding additives have preferable compatibility and binding force, especially ethylene-acrylic acid first with copolyester material
Ester-glycidyl methacrylate, ethylene-ethylacrylate-glycidyl methacrylate, the positive fourth of ethylene-acrylic acid
Contain ester group in ester-glycidyl methacrylate, ester friendship can be carried out with the ester group in copolyesters in the case where heating molten condition
Reaction is changed, further enhances its binding force with copolyester material, while containing chemical property in each bonding additives strand
Active epoxy group or anhydride group, in the granulation of the second master batch, copolyesters composite fiber spinning and carpet heat pressure adhesive hair
When raw high-temperature fusion, epoxy group or anhydride group on bonding additives strand can together the terminal hydroxy group on polyester molecule chain,
End carboxyl forms covalent bond or hydrogen bond, enhances the cementability of bonding additives and copolyester material.Furthermore the addition of bonding additives can
The surface tension for reducing copolyesters melt is conducive to infiltration of the copolyesters melt to pile yarn fiber in carpet heat pressure adhesive, increases
The contact area of big copolyesters melt and pile yarn fiber enhances the machinery with pile yarn fiber after copolyesters melt cools and solidifies
Binding force and diffusion interfacial molecular active force, and then increase the extraction strength of carpet pile.
Using composite yarn as weft yarn, tightens heart yarn enhancing in the first clad and the second clad cladding and hang pile filling rigidity
And while stiffness, enhance the stretch modulus of composite yarn, and then reduce the lower machine broadwise crimp after the weaving of embryo blanket, mitigates carpet
The working strength of weaving process designer, increases the carpet manufacture breadth of loom, mitigates that carpet weaving breadth is limited to be brought
Waste.
Since selected pile yams are cation-dyeable acrylic fiber filament yarn or staple fiber Pure Yarn or spun-blend,
Contain ester group, carboxyl, sulfonic group and cyano isoreactivity group in strand, in carpet hot pressing process, heats copolyester fiber
While heating melting becomes melt infiltration acrylic fiber, epoxy group or anhydride group in melt in bonding additives strand
Covalent bond and/or hydrogen bond can be formed with carboxyl, sulfonic group and the cyano in acrylic fibers strand, while molecular melt chain can be with stretching
The strand of pile yarn fiber is mutually wound, and carries out the machinery consolidation of molecule interchain.Work between pile yams and bonding additives
Firmly, the active force between the active force between bonding additives and copolyesters, the second clad and the first clad, the first cladding
Under the collective effect of active force between layer and heart yarn, the extraction strength of pile yams ensure that.Meanwhile pile yams after cutting off by
It is shorter in its length, and two head ends are free end, therefore easily voluntarily backtwisting, and then suede yarn is made to become fluffy, be conducive to melt and ooze
Thoroughly, be conducive to the increase of pile bonding strength after solidification.
And hot pressing process is carried out by the way of first preheating multiple tracks hot pressing again, the uniformity of embryo blanket heating can be improved in preheating,
And improve the processing efficiency of hot pressing process；Multiple tracks hot pressing can enhance the mobility of melt after meldable fibre melts and be oozed to pile
Permeability improves the extraction strength of pile, while after preceding road pressure roller hot pressing, during the melt after meldable fibre can be made to melt is with heart yarn
Heart flowing expansion, while under pressure close to the pile yams part for hanging pile filling, being formed by plane and becoming in melt
Shape flattens, and then increases the contact area of melt and pile；It is acted on simultaneously in pressure close to the pile yams part for hanging pile filling
Air is extruded discharge between lower fiber, after carpet leaves pressure roller, since pile yarn fiber has certain resilience, in rebound
Negative pressure is formed inside pile yams, and then enhances infiltration of the melt to pile yams, increases the extraction strength of pile yams after melt solidification.
Using meldable fibre without adding organic solvent, reduces environmental pollution, ensure that carpet manufacture personnel and carpet use
The health of personnel；The warp thread hung the weft yarn of pile and intersected therewith can be consolidated after meldable fibre melt-flow resolidification
Knot, and then enhance the conformality and dimensional stability of carpet；The heat preservation that certain time is carried out after hot pressing, can be improved high molecular material
Crystallinity, and then improve carpet pile extraction strength.
Description of the drawings
Fig. 1 is the structural schematic diagram of the heat roller tube in autoclaving process in the present invention.
Specific implementation mode
The present invention provides a kind of preparation methods of the woven carpet without gum technique, to make the purpose of the present invention, skill
Art scheme and effect are clearer, clear, and the present invention is described in more detail below.It should be appreciated that tool described herein
Body embodiment is only used to explain the present invention, is not intended to limit the present invention.
The present invention provides a kind of preparation method of the woven carpet without gum technique, which includes base fabric, pile
Yarn, weft yarn and warp thread, and the weft yarn includes hanging pile filling and not hanging pile filling, hang pile filling and do not hang pile filling
Ratio be 1:1-1:2, pile yams are meeting fiber filament yarn, staple fiber made of the cation-dyeable acrylic fibers of carpet needs
One kind in yarn or staple blended yarn, the extension pile filling are composite yarn, and composite yarn is made of heart yarn and clad, which is
Meet the normal weft of carpet requirement, which includes the first clad and the second clad, and the second clad is by heating
Fibroplastic long filament or spun yarn, the first clad are the fiber filament or spun yarn formed by terylene, and the second clad accounts for
The 20%-50% of composite yarn gross mass, the first clad account for the 10%-15% of composite yarn gross mass, and surplus is heart yarn；
Above-mentioned meldable fibre is hot melt copolyester fiber, which is composite fibre, the composite fibre
Including copolyester material, bonding additives and inorganic nano material, wherein copolyester material, bonding additives and inorganic nano material
Mass ratio be (85-98.5):(1-10)：(0.5-5)；
Using silane coupling agent, titanate coupling agent, aluminate coupling agent or phosphate coupling agent to inorganic nano material
Surface modification is carried out, the copolyester material for being then 85 DEG C -95 DEG C with fusing point presses matter with surface-modified inorganic nano material
Amount is than being (60-70)：The ratio melt blending of (30-40) is granulated, and the first master batch is made, the copolymerization for being 85 DEG C -95 DEG C with fusing point
Ester material is (50-60) in mass ratio with bonding additives：The ratio melt blending of (40-50) is granulated, and the second master batch is made, then
The copolyester material melt spinning for being 95 DEG C -130 DEG C with fusing point by the first master batch, the second master batch by design requirement, is made above-mentioned
Heat copolyester fiber.
Heating copolyester fiber, there is amorphous-crystalline state structure, the presence of crystal region fiber to be made to have certain strength；
And the presence of amorphous region makes the macromolecular chain of fiber can move freely, to make the property of fiber close to amorphous high poly-
Object, has some physical state features possessed by Amorphous Polymers, thus it is heated when have glassy state, elastomeric state, viscous state,
Therefore hot melt copolyester fiber can carry out melt-processed, and have certain strength and flexibility after cooling and solidifying again,
When producing non-adhesive carpet as adhesives using hot melt copolyester fiber, and pile yams made of cooperation acrylic fiber, when
Hot melt copolyester fiber is melted when hot pressing process is heated to its fusing point or more, and fiber Macromolecular chain configuration changes,
By the transition of segment, entire macromolecular chain is made to slide, VISCOUS FLOW occurs, passes through the capillarity of glued Inter-fiber voids
And the surface tension effects of fiber, the melt flowed sprawl infiltration in fiber surface, after cooling and solidifying again, pass through machine
The active force binder fibre of tool bonding force and diffusion interfacial molecular, weft yarn and warp thread are effectively consolidated after solidification, enhance ground
The conformality of blanket and the stability of size make carpet more ring obtained to which the gum process in carpet preparation process be omitted
It protects.
Further, above-mentioned bonding additives are ethylene-maleic acid-methacrylic dehydrated glyceride, ethylene-propylene
Sour methyl esters-glycidyl methacrylate, ethylene-ethylacrylate-glycidyl methacrylate, ethylene-acrylic acid
N-butyl-glycidyl methacrylate, polypropylene grafted glycidyl methacrylate, polycthylene grafted metering system
Acid glycidyl ester, ethylene/butylene copolymers graft glycidyl methacrylate, ethylene/octene are grafted methyl
One kind in glycidyl acrylate, styrene/ethylene/butadiene block copolymer graft glycidyl methacrylate
Or it is a variety of；Above-mentioned inorganic nano material is silica, calcium carbonate, montmorillonite, one or more in titanium dioxide, inorganic to receive
Rice material particle size is 15 nanometers -20 nanometers, and specific surface area is 150 ± l0m2/g.Due to the composite fibre of selected hot melt copolyesters
In containing ethylene-maleic acid-methacrylic dehydrated glyceride, ethylene-methyl acrylate-methyl propenoic acid glycidyl
Ester, ethylene-ethylacrylate-glycidyl methacrylate, ethylene/n-butyl acrylate-methyl propenoic acid glycidyl
Ester, polypropylene grafted glycidyl methacrylate, polyethylene to graft glycidyl methacrylate, ethylene/butylene are total
Polymers graft glycidyl methacrylate, ethylene/octene graft glycidyl methacrylate, styrene/
It is one or more in ethylene/butadiene block copolymer graft glycidyl methacrylate, each bonding additives strand
In contain the similar flexible fat segment of flexible fat segment in polyester molecule chain together, therefore each bonding additives with copolymerization
Ester material has preferable compatibility and binding force, especially ethylene-methyl acrylate-glyceryl methacrylate, ethylene-
Contain in ethyl acrylate-glycidyl methacrylate, ethylene/n-butyl acrylate-glycidyl methacrylate
Ester group can carry out ester exchange reaction with the ester group in copolyesters in the case where heating molten condition, further enhance itself and copolyesters material
The binding force of material, while containing the active epoxy group of chemical property or anhydride group in each bonding additives strand,
When high-temperature fusion occurs for the granulation of two master batches, copolyesters composite fiber spinning and carpet heat pressure adhesive, on bonding additives strand
Epoxy group or anhydride group the terminal hydroxy group on polyester molecule chain, end carboxyl can form covalent bond or hydrogen bond together, enhancing is viscous
Connect the cementability of auxiliary agent and copolyester material.Furthermore the addition of bonding additives can reduce the surface tension of copolyesters melt, on ground
When blanket heat pressure adhesive, it is conducive to infiltration of the copolyesters melt to pile yarn fiber, increase copolyesters melt connects with pile yarn fiber
Contacting surface is accumulated, and mechanical bonding force and diffusion interfacial molecular active force after copolyesters melt cools and solidifies with pile yarn fiber are enhanced,
And then increase the extraction strength of carpet pile.
And the advance structure design of carpet is pressed, embryo blanket is made after pile yams, weft yarn and warp thread are interweaved, at embryo blanket hot pressing
Reason makes clad fusing flowing, through cooling and solidifying, bonding pile yams and weft yarn and weft yarn and warp thread, then after subsequent processing
To above-mentioned carpet.
It in another preferred embodiment of the present invention, can be to embryo blanket hot pressing in order to further improve the performance of carpet
Processing is using progress hot-rolling pressurization after far infrared or hot-air preheating.As shown in Figure 1,1 table of heat roller tube can be entered in embryo blanket 3
In front, first far infrared or hot-air 4 is used to preheat embryo blanket, 1 surface of heat roller tube is provided with 1-3 pressure roller 2, heat roller tube
1 is dynamic for main turn, and pressure roller 2 is driven rotation, and embryo blanket 3 is slave drive, and 1 surface temperature of heat roller tube is 120 DEG C -160 DEG C, hot-rolling
Cylinder 1 generally uses 125 DEG C or 140 DEG C, further improves the bonding of carpet pile and composite weft after carpet hot pressing
The stiffness of degree and carpet.Embryo blanket 3 carries out hot pressurization by different pressure rollers 2 successively；Embryo blanket 3 is being pressed during hot pressing
Under the collective effect of roller 2 and heat roller tube 1, the seepage velocity and infiltration capacity after the second clad hot melt are further improved, is made
Second clad is more conducive to bonding pile yams and weft yarn and weft yarn and warp thread after melting resolidification, and bonding has been effectively ensured and has made
With.Embryo blanket 3 enters progress isothermal crystal in heat preservation zone after leaving hot-rolling, and the temperature of heat preservation zone is generally between 50 DEG C -90 DEG C.This
The hot pressing process of invention is carried out by the way of first preheating multiple tracks hot pressing again, and the uniformity of embryo blanket heating can be improved in preheating, and carries
The processing efficiency of high hot pressing process；Multiple tracks hot pressing can enhance the mobility of melt and the infiltration to pile after meldable fibre melts
Property, the extraction strength of pile is improved, while after preceding road pressure roller hot pressing, the melt after meldable fibre can be made to melt is centered on heart yarn
Flowing expansion, while under pressure close to the pile yams part for hanging pile filling, plane internal deformation is formed by melt
Flattening, and then increase the contact area of melt and pile；Simultaneously under pressure close to the pile yams part of extension pile filling
Air is extruded discharge between fiber, after carpet leaves pressure roller, since pile yarn fiber has certain resilience, and the suede in rebound
Negative pressure is formed inside gauze kerchief worn on a woman's head, and then enhances infiltration of the melt to pile yams, increases the extraction strength of pile yams after melt solidification.
And the composite yarn of above-mentioned extension pile filling is the composite yarn being machined into using coating machine or fancy twist yarn.Than
Such as with the fiber filament or spun yarn that are formed by terylene for the first clad, with the long filament for heating copolyester fiber formation or short fibre
Yarn is the second clad, and it is 10 centimetres -20 lis that when coating the first clad, the seal wire of coating machine or Novelty twisters, which hooks distance,
Rice, it is 1 centimetre -15 centimetres that when coating the second clad, the seal wire of coating machine or Novelty twisters, which hooks distance, and second layer packet
Low 5 centimetres of the distance or more that seal wire hooks when the distance that seal wire hooks when covering is coated than first layer；
First clad is wrapped in compact state on heart yarn, and the second clad is wrapped in the first clad in soft fluffy state
On surface, above-mentioned extension pile filling is made after carrying out first layer cladding and second layer cladding to the heart yarn for hanging pile filling.
The weft yarn composite yarn for hanging pile covers form using double-contracting, and the first clad is selected common poly- with meldable fibre homology
Ester filament fiber or spun yarn, such as the first clad made of terylene, fusing point be more than 250 DEG C, in hot pressing process by
It in its hot pressing temperature between 120 DEG C -160 DEG C, will not melt, heart yarn surface is wound in fiber condition always, in machine
It is firmly combined with heart yarn under the action of tool power；Meldable fibre melts when heated, because meldable fibre and the first clad are homology
Material, molecular radical having the same, therefore there is fine compatibility and cementability, the two can by the winding of macromolecular chain,
Intermolecular force, hydrogen bond etc. carry out strong bonded.Therefore the first clad weft yarn and pile heat bonding during play compared with
Good bridge joint effect.
And distance is hooked using big seal wire when the first clad cladding, the first clad fiber can be made used in big rotation
Property power under the action of heart yarn is fettered close, enhance the rigidity of weft yarn, and then enhance the stiffness and conformality of carpet.Meanwhile
Infiltration of the melt to heart yarn, increases infiltration of the melt to pile heart yarn can reduce meldable fibre heating melting after being bound closely when
Amount improves the extraction strength of carpet pile.First clad filament fiber or spun yarn are wound in a manner of arranged in parallel
The regularity on heart yarn surface, arrangement is preferable, and regular arrangement can enhance between the first clad filament fiber or spun yarn and long
Silk or the interfibrous capillary effect of spun yarn, the Wicking effect of melt, increases when being conducive to enhance meldable fibre heating melting
Bonding force after adding melt to cure with the first clad.
Second clad, i.e. clad made of meldable fibre hook distance when cladding using small seal wire, and when cladding rotates
Inertia is relatively low, the second clad fiber can be made to be coated on the first cover surface in the form of more fluffy, due to the second clad
More fluffy, its internal/external heating is more uniform when hot pressing, can make fiber while melt, and reduces the melting delay of inner fiber, contracting
Short hot pressing time improves hot pressing process production efficiency；Simultaneously because the second clad is more fluffy, meldable fibre is along perpendicular to core
The direction of yarn is more sprawled, and is conducive to increase the contact area of melt and pile after meldable fibre melts, enhancing melt is to pile
Infiltration infiltration increases the extraction strength of pile after solidification.
Certainly in preparation process, above-mentioned carpet can be woven Wilden carpet or woven Axminster carpet, certainly
Carpet made of other modes can also be applied.
Certainly, described above is only that presently preferred embodiments of the present invention is answered the present invention is not limited to enumerate above-described embodiment
When explanation, any technical person familiar with the field is all equivalent substitutes for being made, bright under the introduction of this specification
Aobvious variant, all falls within the essential scope of this specification, ought to be protected by the present invention.
Claims (7)
1. a kind of preparation method of woven carpet without gum technique, which includes base fabric, pile yams, weft yarn and warp thread,
It is characterized in that, the weft yarn includes hanging pile filling and not hanging pile filling, pile yams are the cation by meeting carpet needs
One kind in fiber filament yarn, staple yarn or staple blended yarn made of polyacrylic fiber dyeable, which is composite yarn, multiple
It closes yarn to be made of heart yarn and clad, which is the normal weft for meeting carpet requirement, which includes the first clad
With the second clad, the second clad is the long filament or spun yarn formed by meldable fibre, and the first clad is to be formed by terylene
Fiber filament or spun yarn, the second clad accounts for the 20%-50% of composite yarn gross mass, and the first clad accounts for the total matter of composite yarn
The 10%-15% of amount, surplus are heart yarn；
Above-mentioned meldable fibre is hot melt copolyester fiber, which is composite fibre, which includes
Copolyester material, bonding additives and inorganic nano material, wherein copolyester material, bonding additives and inorganic nano material matter
Amount is than being (85-98.5):(1-10)：(0.5-5)；
Inorganic nano material is carried out using silane coupling agent, titanate coupling agent, aluminate coupling agent or phosphate coupling agent
Surface is modified, the copolyester material for being then 85 DEG C -95 DEG C with fusing point with surface-modified inorganic nano material in mass ratio
For (60-70)：The ratio melt blending of (30-40) is granulated, and the first master batch is made, the copolyesters material for being 85 DEG C -95 DEG C with fusing point
Material is (50-60) in mass ratio with bonding additives：The ratio melt blending of (40-50) is granulated, and the second master batch is made, then by setting
The copolyester material melt spinning that it is 95 DEG C -130 DEG C with fusing point by the first master batch, the second master batch that meter, which is required, is made above-mentioned hot melt
Copolyester fiber.
2. preparation method according to claim 1, which is characterized in that above-mentioned bonding additives are ethylene-maleic acid-methyl
Acrylic acid dehydrated glyceride, ethylene-methyl acrylate-glyceryl methacrylate, ethylene-ethylacrylate-methyl-prop
Olefin(e) acid ethylene oxidic ester, ethylene/n-butyl acrylate-glycidyl methacrylate, the contracting of polypropylene grafted methacrylic acid
Water glyceride, polyethylene to graft glycidyl methacrylate, ethylene/butylene copolymers grafted methacrylic acid glycidol
Ester, ethylene/octene graft glycidyl methacrylate, styrene/ethylene/butadiene block copolymer are grafted first
It is one or more in base glycidyl acrylate；Above-mentioned inorganic nano material is silica, calcium carbonate, montmorillonite, two
One or more in titanium oxide, inorganic nano material grain size is 15 nanometers -20 nanometers, and specific surface area is 150 ± l0m2/g。
3. preparation method according to claim 1, which is characterized in that the advance structure design of carpet is pressed, by pile yams, weft yarn
Embryo blanket is made after interweaving with warp thread, so that the fusing flowing of the second clad is bonded pile yams through cooling and solidifying embryo blanket hot-pressing processing
With weft yarn and weft yarn and warp thread, then above-mentioned carpet is obtained after subsequent processing.
4. preparation method according to claim 3, which is characterized in that above-mentioned to use far infrared or heat to embryo blanket hot-pressing processing
Hot-rolling pressurization is carried out after air preheat again；Before embryo blanket enters heat roller tube surface, first use far infrared or hot-air to embryo blanket into
Row preheating is provided with 1-3 pressure roller on heat roller tube surface, and heat roller tube is dynamic for main turn, and pressure roller is driven rotation, and embryo blanket is driven
Transmission, hot-rolling drum surface temperature are 120 DEG C -160 DEG C, and embryo blanket carries out hot pressurization by different pressure rollers successively；Embryo blanket leaves hot-rolling
Enter afterwards and carries out isothermal crystal in heat preservation zone.
5. preparation method according to claim 1, which is characterized in that the composite yarn of above-mentioned extension pile filling is using cladding
The composite yarn that machine or fancy twist yarn are machined into.
6. preparation method according to claim 5, which is characterized in that be with the fiber filament or spun yarn that are formed by terylene
First clad, with heat copolyester fiber formation long filament or spun yarn be the second clad, when coating the first clad
It is 10 centimetres -20 centimetres that the seal wire of coating machine or Novelty twisters, which hooks distance, coating machine or fancy when coating the second clad
It is 1 centimetre -15 centimetres that the seal wire of twisting machine, which hooks distance, and seal wire when the distance that seal wire hooks when the second layer coats is coated than first layer
Low 5 centimetres of distance of hook or more；
First clad is wrapped in compact state on heart yarn, and the second clad is wrapped in the first cover surface in soft fluffy state
On, above-mentioned extension pile filling is made after carrying out first layer cladding and second layer cladding to the heart yarn for hanging pile filling.
7. preparation method according to claim 1, which is characterized in that above-mentioned carpet be woven Wilden carpet or woven Ah
Gram Munster carpet.
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