CN108385382A - A kind of antibacterial deodourizing crease-shedding finishing agent and its application - Google Patents
A kind of antibacterial deodourizing crease-shedding finishing agent and its application Download PDFInfo
- Publication number
- CN108385382A CN108385382A CN201810090464.4A CN201810090464A CN108385382A CN 108385382 A CN108385382 A CN 108385382A CN 201810090464 A CN201810090464 A CN 201810090464A CN 108385382 A CN108385382 A CN 108385382A
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- CN
- China
- Prior art keywords
- cotton
- crease
- antibacterial deodourizing
- blended fabric
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 11
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 7
- 239000004902 Softening Agent Substances 0.000 claims abstract description 7
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 7
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims abstract description 7
- 239000004814 polyurethane Substances 0.000 claims abstract description 7
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001116 FEMA 4028 Substances 0.000 claims abstract description 6
- 108010022355 Fibroins Proteins 0.000 claims abstract description 6
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960004853 betadex Drugs 0.000 claims abstract description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims abstract description 6
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 5
- 229920000742 Cotton Polymers 0.000 claims description 56
- 239000004744 fabric Substances 0.000 claims description 50
- 229920002101 Chitin Polymers 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 abstract description 5
- 230000001681 protective effect Effects 0.000 abstract description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007096 poisonous effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 17
- 238000001035 drying Methods 0.000 description 14
- -1 alkylbenzene sulfonate Chemical class 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 108090000790 Enzymes Proteins 0.000 description 9
- 102000004190 Enzymes Human genes 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000012224 working solution Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 238000002386 leaching Methods 0.000 description 8
- 230000003137 locomotive effect Effects 0.000 description 8
- 238000007670 refining Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 108010076876 Keratins Proteins 0.000 description 5
- 102000011782 Keratins Human genes 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 210000002268 wool Anatomy 0.000 description 5
- 108010059892 Cellulase Proteins 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000002752 cationic softener Substances 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 235000018927 edible plant Nutrition 0.000 description 4
- ZZGUZQXLSHSYMH-UHFFFAOYSA-N ethane-1,2-diamine;propanoic acid Chemical compound NCCN.CCC(O)=O.CCC(O)=O ZZGUZQXLSHSYMH-UHFFFAOYSA-N 0.000 description 4
- 125000001924 fatty-acyl group Chemical group 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- QLCAGXDTDCDEGN-UHFFFAOYSA-N 3-sulfanylcarbonylhexanedioic acid Chemical compound OC(=O)CCC(C(O)=S)CC(O)=O QLCAGXDTDCDEGN-UHFFFAOYSA-N 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 210000001724 microfibril Anatomy 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C9/00—Singeing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
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- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/40—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using enzymes
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of antibacterial deodourizing crease-shedding finishing agents, including following weight, 50 60g/L of citric acid, (100) 5 15g/L of polyethylene glycol, 2 5g/L of softening agent, 1 3g/L of antiseptic, 50 60g/L of beta cyclodextrin, 4 6g/L of sodium hypophosphite, 1 2g/L of penetrating agent JFC, 1.2 2.8g/L of aqueous polyurethane, 2 5g/L of methanol, 3 4g/L of triethanolamine, 5 6g/L of nano-titanium dioxide, 20 30g/L of fibroin, 9 11g/L of glutaraldehyde.The antibacterial deodourizing crease-shedding finishing agent of the present invention, it is environmentally protective, will not the poisonous and harmful substances such as release formaldehyde, safe and secure.
Description
The application is application No. is 2016102004631, and the applying date is on 04 01st, 2016, and invention and created name is
The divisional application of the patent of " antibacterial deodourizing and anti-crease finishing technique of cotton/silk blended fabric ".
Technical field
The present invention relates to a kind of fabric finishing process, the antibacterial deodourizing of especially a kind of cotton/silk blended fabric and anti-
Wrinkle finishing technique.
Background technology
Cotton and silk are all natural cellulose fibres, and the microstructure of wherein cotton is big by the cellulose of tens of chains
Molecule assembles the micro- fibril to be formed, and micro- fibril reassociates into the fibril of lateral dimension about 10-25nm, then is arranged in the sun wheel by fibril
Layer, the fiber eventually formed.The microscopic internal of cotton fiber is a kind of porous material.Due to the characteristic of itself, determine that it has
There are good ventilative, moisture-inhibiting and comfort outstanding, thus by the great kindness of consumers in general.Silk fiber is also good because having
Good ventilative, moisture pick-up properties and liked by consumer.Cotton/silk blended fabric is received and is disappeared due to its ventilative, frivolous feature
The favor taken, wide market.But in wearing process, due to cotton fiber self-characteristic, easily there is pleat in cotton fiber fabric
The problems such as wrinkle, deformation, appearance of fabrics is not only influenced, and be not durable.And cotton/silk blended fabric is chiefly used in summer dress, summer
Season, weather was sultry, and easily perspiration, face/silk blended yarn weaved fabric under such environment are also easy to produce stink and grow bacterium, be unfavorable for
The image and health of wearer.
To solve the above problems, people start to carry out antibacterial and deodouring and anti-crease finishing to cotton/silk blended fabric, city at present
What is mostly used on field is N- hydroxy kind finishing agents, such finishing agent can effectively improve the wrinkle resistance of cotton fabric, but it is arranged
Textile afterwards will produce free formaldehyde during taking, be harmful to human health.It can not promote the use of.
Therefore, work out a kind of antibiosis and deodorization effects it is good and can effectively ensure that cotton/silk blended fabric wrinkle resistance and
The finishing technique of environmentally protective cotton cotton/silk blended fabric be it is current need to solve it is important for one of topic.
Invention content
Goal of the invention:In view of the above-mentioned problems, the object of the present invention is to provide a kind of antibacterial deodourizings of cotton/silk blended fabric
And anti-crease finishing technique.
Technical solution:In order to achieve the above object, the antibacterial deodourizing of a kind of cotton/silk blended fabric provided by the invention and anti-
Wrinkle finishing technique, including step
(a) it singes:Cotton/silk blended fabric is sent into gassing frame and carries out two-sided processing of singing, speed of singing is 95-
100m/min;
(b) one-bath DSB:Cotton/silk blended fabric after singing carries out one-bath DSB method and handles, specifically
It is to immerse cotton/silk blended fabric in the wool keratin solution of 13-15% (volume fraction), further includes net in the solution
Cotton enzyme GX12-3g/L, hydrogen peroxide 15-20ml/L, TYR enzyme 0.3-0.5g/L, refining agent 3-5g/L, bath raio 1:30;PH value
For 8-9, treatment temperature is 70-80 DEG C, processing time 55-65min;
(c) antibacterial deodourizing and anti-crease finishing:It will boil drift cotton/silk blended fabric by moving back and be put into antibacterial deodourizing and crease-resistant
Two leachings two are carried out by padding machine in housekeeping liquid and roll processing, pad 150-180 DEG C of the temperature of working solution, padding machine when two leachings two are rolled
Rotating speed be 12-15r/min, pick-up 85-90%, the working solution that pads includes following weight:
Citric acid:50-60g/L;
Polyethylene glycol (100):5-15g/L;
Softening agent:2-5g/L;
Antiseptic:1-3g/L;
Beta-cyclodextrin:50-60g/L;
Sodium hypophosphite:4-6g/L;
Penetrating agent JFC:1-2g/L;
Aqueous polyurethane:1.2-2.8g/L;
Methanol:2-5g/L;
Triethanolamine:3-4g/L;
Nano-titanium dioxide:5-6g/L;
Fibroin:20-30g/L;
Glutaraldehyde:9-11g/L;
(d) preliminary drying:It will be put into dryer and dry by antibacterial deodourizing and cotton/silk blended fabric of crease-resistant processing
Processing, drying temperature are 90-100 DEG C, and locomotive speed is 10-12m/min;
(e) it bakes:Cotton/silk blended fabric that preliminary drying is crossed is put into baker and carries out baking processing, baking temperature is
130-160 DEG C, locomotive speed 13-15m/min;
(f) it washes:Baked cotton/silk blended fabric is washed in 20-30 DEG C of clear water;
(g) it dries.
Refining agent described in step b includes following weight:Cellulase 1-3g/L, acid pectase 2.1-2.5g/L,
Trimethylolpropane 1.1-1.3g/L, polyethylene glycol 1-2g/L, double fatty acyl group ethylene diamine dipropionic acid sodium 0.7-0.8g/L, hydrogen-oxygen
Change sodium 2-5g/L, calcium chloride 1-2g/L, alkylbenzene sulfonate 1.2-1.6g/L, oleoyl N-methyltaurine sodium 0.2-0.6g/L, it is sub-
Methyl double bitter edible plant sodium sulfonate 0.1-0.4g/L, alkyl phenol polyoxyethylene ether polyethenoxy ether 0.3-0.5g/L, the thio fourth of carboxyethyl two
Sour 0.5-0.7g/L, soap flakes 1-2g/L, rest part are deionized water.
Softening agent described in step c is Gemini cationic softeners.
Antiseptic described in step c is chitin.
Advantageous effect:Compared with prior art, the present invention has the following advantages:
1. arranging step to simplify:The present invention replaces original desizing, kiering, bleaching to walk by using one-bath DSB method
Suddenly, but will antibacterial, deodorization, the unification of wrinkle resistant triple effects in dressing liquid, effectively shorten finishing time, cost-effective 30-
40%;
2. whiteness and intensity are good:The present invention boils drift by being moved back using enzyme oxygen in one-bath DSB method technique, effectively reduces
Injury to cotton fiber and silk fiber ensures the soft feel and intensity of cotton fiber and silk fiber;Again since the present invention exists
It moves back to boil in drift working solution and adds wool keratin, the whiteness of cotton/silk blended fabric can be further ensured that, convenient for after fabric
It is continuous to arrange;
3. environmentally protective:The present invention is by by components such as citric acid, polyethylene glycol, aqueous polyurethane, beta-cyclodextrins
Rational proportion forms antibacterial deodourizing crease-shedding finishing agent, environmentally protective, will not the poisonous and harmful substances such as release formaldehyde, safe and secure;
And the present invention by finishing agent softening agent can be further ensured that the cotton of cotton fabric/silk blended fabric keeps soft constant
Shape, practicability improve;
4. the present invention by the stringent control to preliminary drying, baking temperature and drying rate, is further ensured that cotton/silk is mixed
The antibacterial deodourizing and anti-crease finishing effect, advantageous effect of textile fabric are apparent.
Specific implementation mode
With reference to specific embodiment, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate the present invention
Rather than limit the scope of the invention, after having read the present invention, various equivalences of the those skilled in the art to the present invention
The modification of form falls within the application range as defined in the appended claims.
Embodiment 1
A kind of antibacterial deodourizing and anti-crease finishing technique of cotton/silk blended fabric, including step
(a) it singes:Cotton/silk blended fabric is sent into gassing frame and carries out two-sided processing of singing, speed of singing is 95m/
min;
(b) one-bath DSB:Cotton/silk blended fabric after singing carries out one-bath DSB method and handles, specifically
It is to immerse cotton/silk blended fabric in the wool keratin solution of 13% (volume fraction), further includes net cotton in the solution
Enzyme GX12g/L, hydrogen peroxide 15ml/L, TYR enzyme 0.3g/L, refining agent 3g/L, bath raio 1:30;PH value is 8, treatment temperature
It is 70 DEG C, processing time 55min;
(c) antibacterial deodourizing and anti-crease finishing:It will boil drift cotton/silk blended fabric by moving back and be put into antibacterial deodourizing and crease-resistant
Two leachings two are carried out by padding machine in housekeeping liquid and roll processing, pad 150 DEG C of the temperature of working solution, padding machine turns when two leachings two are rolled
Speed is 12r/min, and pick-up 85%, the working solution that pads includes following weight:
Citric acid:50g/L;
Polyethylene glycol (100):5g/L;
Gemini cationic softeners:2g/L;
Chitin:1g/L;
Beta-cyclodextrin:50g/L;
Sodium hypophosphite:4g/L;
Penetrating agent JFC:1g/L;
Aqueous polyurethane:1.2g/L;
Methanol:2g/L;
Triethanolamine:3g/L;
Nano-titanium dioxide:5g/L;
Fibroin:20g/L;
Glutaraldehyde:9g/L;
(d) preliminary drying:It will be put into dryer and dry by antibacterial deodourizing and cotton/silk blended fabric of crease-resistant processing
Processing, drying temperature are 90 DEG C, and locomotive speed is 10m/min;
(e) it bakes:Cotton/silk blended fabric that preliminary drying is crossed is put into baker and carries out baking processing, baking temperature is
130-160 DEG C, locomotive speed 13m/min;
(f) it washes:Baked cotton/silk blended fabric is washed in 20-30 DEG C of clear water;
(g) it dries.
Refining agent described in step b includes following weight:Cellulase 1g/L, acid pectase 2.1g/L, three hydroxyl first
Base propane 1.1g/L, polyethylene glycol 1g/L, double fatty acyl group ethylene diamine dipropionic acid sodium 0.7g/L, sodium hydroxide 2g/L, calcium chloride
1g/L, alkylbenzene sulfonate 1.2g/L, oleoyl N-methyltaurine sodium 0.2g/L, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.1g/L, alkyl phenol
Polyoxyethylene ether polyethenoxy ether 0.3g/L, carboxyethyl thiosuccinic acid 0.5g/L, soap flakes 1g/L, rest part is deionization
Water.
Embodiment 2
A kind of antibacterial deodourizing and anti-crease finishing technique of cotton/silk blended fabric, including step
(a) it singes:Cotton/silk blended fabric is sent into gassing frame and carries out two-sided processing of singing, speed of singing is 98m/
min;
(b) one-bath DSB:Cotton/silk blended fabric after singing carries out one-bath DSB method and handles, specifically
It is to immerse cotton/silk blended fabric in the wool keratin solution of 14% (volume fraction), further includes net cotton in the solution
Enzyme GX12.5g/L, hydrogen peroxide 18ml/L, TYR enzyme 0.4g/L, refining agent 4g/L, bath raio 1:30;PH value is 8.5, processing
Temperature is 75 DEG C, processing time 60min;
(c) antibacterial deodourizing and anti-crease finishing:It will boil drift cotton/silk blended fabric by moving back and be put into antibacterial deodourizing and crease-resistant
Two leachings two are carried out by padding machine in housekeeping liquid and roll processing, pad 165 DEG C of the temperature of working solution, padding machine turns when two leachings two are rolled
Speed is 13r/min, and pick-up 88%, the working solution that pads includes following weight:
Citric acid:55g/L;
Polyethylene glycol (100):10g/L;
Gemini cationic softeners:3g/L;
Chitin:2.2g/L;
Beta-cyclodextrin:54g/L;
Sodium hypophosphite:5g/L;
Penetrating agent JFC:1.4g/L;
Aqueous polyurethane:1.2-2.8g/L;
Methanol:3.1g/L;
Triethanolamine:3.5g/L;
Nano-titanium dioxide:5.6g/L;
Fibroin:25g/L;
Glutaraldehyde:10g/L;
(d) preliminary drying:It will be put into dryer and dry by antibacterial deodourizing and cotton/silk blended fabric of crease-resistant processing
Processing, drying temperature are 95 DEG C, and locomotive speed is 11m/min;
(e) it bakes:Cotton/silk blended fabric that preliminary drying is crossed is put into baker and carries out baking processing, baking temperature is
150 DEG C, locomotive speed 14m/min;
(f) it washes:Baked cotton/silk blended fabric is washed in 26 DEG C of clear water;
(g) it dries.
Refining agent described in step b includes following weight:Cellulase 2g/L, acid pectase 2.3g/L, three hydroxyl first
Base propane 1.2g/L, polyethylene glycol 1.5g/L, double fatty acyl group ethylene diamine dipropionic acid sodium 0.75g/L, sodium hydroxide 3g/L, chlorination
Calcium 1.3g/L, alkylbenzene sulfonate 1.5g/L, oleoyl N-methyltaurine sodium 0.4g/L, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.3g/L, alkane
Base phenol polyethenoxy ether polyethenoxy ether 0.4g/L, carboxyethyl thiosuccinic acid 0.6g/L, soap flakes 1.4g/L, rest part are to go
Ionized water.
Embodiment 3
A kind of antibacterial deodourizing and anti-crease finishing technique of cotton/silk blended fabric, including step
(a) it singes:Cotton/silk blended fabric is sent into gassing frame and carries out two-sided processing of singing, speed of singing is 100m/
min;
(b) one-bath DSB:Cotton/silk blended fabric after singing carries out one-bath DSB method and handles, specifically
It is to immerse cotton/silk blended fabric in the wool keratin solution of 15% (volume fraction), further includes net cotton in the solution
Enzyme GX13g/L, hydrogen peroxide 20ml/L, TYR enzyme 0.5g/L, refining agent 3-5g/L, bath raio 1:30;PH value is 9, processing temperature
Degree is 80 DEG C, processing time 65min;
(c) antibacterial deodourizing and anti-crease finishing:It will boil drift cotton/silk blended fabric by moving back and be put into antibacterial deodourizing and crease-resistant
Two leachings two are carried out by padding machine in housekeeping liquid and roll processing, pad 180 DEG C of the temperature of working solution, padding machine turns when two leachings two are rolled
Speed is 15r/min, and pick-up 90%, the working solution that pads includes following weight:
Citric acid:60g/L;
Polyethylene glycol (100):15g/L;
Gemini cationic softeners:5g/L;
Chitin:3g/L;
Beta-cyclodextrin:60g/L;
Sodium hypophosphite:6g/L;
Penetrating agent JFC:2g/L;
Aqueous polyurethane:2.8g/L;
Methanol:5g/L;
Triethanolamine:4g/L;
Nano-titanium dioxide:6g/L;
Fibroin:30g/L;
Glutaraldehyde:11g/L;
(d) preliminary drying:It will be put into dryer and dry by antibacterial deodourizing and cotton/silk blended fabric of crease-resistant processing
Processing, drying temperature are 100 DEG C, and locomotive speed is 12m/min;
(e) it bakes:Cotton/silk blended fabric that preliminary drying is crossed is put into baker and carries out baking processing, baking temperature is
160 DEG C, locomotive speed 15m/min;
(f) it washes:Baked cotton/silk blended fabric is washed in 30 DEG C of clear water;
(g) it dries.
Refining agent described in step b includes following weight:Cellulase 3g/L, acid pectase 2.5g/L, three hydroxyl first
Base propane 1.3g/L, polyethylene glycol 2g/L, double fatty acyl group ethylene diamine dipropionic acid sodium 0.8g/L, sodium hydroxide 5g/L, calcium chloride
2g/L, alkylbenzene sulfonate 1.6g/L, oleoyl N-methyltaurine sodium 0.6g/L, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.4g/L, alkyl phenol
Polyoxyethylene ether polyethenoxy ether 0.5g/L, carboxyethyl thiosuccinic acid 0.7g/L, soap flakes 2g/L, rest part is deionization
Water.
Claims (4)
1. a kind of antibacterial deodourizing crease-shedding finishing agent, which is characterized in that including following weight, citric acid 50-60g/L, polyethylene glycol
(100) 5-15g/L, softening agent 2-5g/L, antiseptic 1-3g/L, beta-cyclodextrin 50-60g/L, sodium hypophosphite 4-6g/L, infiltration
Agent JFC 1-2g/L, aqueous polyurethane 1.2-2.8g/L, methanol 2-5g/L, triethanolamine 3-4g/L, nano-titanium dioxide 5-6g/
L, fibroin 20-30g/L, glutaraldehyde 9-11g/L.
2. antibacterial deodourizing crease-shedding finishing agent as described in claim 1, which is characterized in that the softening agent is Gemini cations
Softening agent.
3. antibacterial deodourizing crease-shedding finishing agent as claimed in claim 1 or 2, which is characterized in that the antiseptic is chitin.
4. application of the claim 1-3 any one of them antibacterial deodourizing crease-shedding finishing agents in cotton/silk blended fabric.
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