CN108384413A - Environment-friendly type coating with fungus and mildew resistance and air purification function - Google Patents

Environment-friendly type coating with fungus and mildew resistance and air purification function Download PDF

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CN108384413A
CN108384413A CN201810152288.2A CN201810152288A CN108384413A CN 108384413 A CN108384413 A CN 108384413A CN 201810152288 A CN201810152288 A CN 201810152288A CN 108384413 A CN108384413 A CN 108384413A
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friendly type
powder
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CN108384413B (en
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王美琴
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Jiangsu shunlicheng new building materials Co., Ltd
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Chongqing En Guang Technology Co Ltd
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • C09D7/44Combinations of two or more thickening agents
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract

The present invention provides a kind of environment-friendly type coating with fungus and mildew resistance and air purification function, and the raw material of the coating includes following component by weight:55 60 parts of alkyd resin, 17 20 parts of polyacrylate dispersion, 10 12 parts of nano-attapulgite, 12 15 parts of nano-kaolinite, 8 10 parts of diatomite, 46 parts of lithium metasilicate, 58 parts of polyamide, 0.5 0.8 parts of mineral oil antifoam agent, 0.8 1.2 parts of nano-titanium oxide, 8 10 parts of net gas biocidal powder, 0.5 0.8 parts of organobentonite, 0.1 0.2 parts of ammonium polyacrylate dipersant, 0.1 0.2 parts of carboxymethyl cellulose, 46 parts of coconut oil, 45 55 parts of deionized water;The net gas biocidal powder by dry wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, lemon grass (Cymbopogon citratus) with mass ratio be 3:1:1:2:Composition is mixed after 1 crushing.

Description

Environment-friendly type coating with fungus and mildew resistance and air purification function
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of environment-friendly type with fungus and mildew resistance and air purification function Coating.
Background technology
Currently, the pollution of room air is caused to be mainly derived from 5 aspects:First, human body respiration, flue gas;Second is that finishing material Formaldehyde, ammonia, benzene, toluene in material etc.;Third, microorganism, virus, bacterium;Fourth, kitchen fume;Fifth, air conditioner comprehensive disease.These Pollutant enters inside of human body with breathing, and long-term accumulation seriously endangers the health of people.
And with progress of the epoch, by consumer it is long-term education and guiding, the environmentally friendly house ornamentation of consumer, healthy family The consciousness in residence is increasingly enhanced, and potentially rapid growth will occurs to the market demand of environmental protection coating material, currently, various environmental protection coating materials It emerges one after another, manufacturer attracts the eye of consumer in color, material and safety, and price is mostly more expensive.In addition to Expensive, existing environmental protection coating material often there is also some technical defects, such as energy of attachment force difference, is easy to fall off, resistance to Time property and stability are poor, are susceptible to mildew or are aoxidized, poor water resistance, are easy that Signs of Mould occurs because there was dampness in the air, special It is not southern plum rain season, air is moister, it is easier to the phenomenon that interior wall mildew occur, inconvenience is brought to consumer. In addition, in existing major part coating products, all contains the harmful substances such as certain formaldehyde, volatile organic matter, usually make Prolonged ventilation ability normal use is needed with rear, and the hazardous substances such as formaldehyde contained in some coating are also easy to Volatilization, environmental-protecting performance is excessively poor, is chronically under the environment and is easy to bring the body of people lasting harm.
Therefore, it is necessary to develop go out a kind of quality-high and inexpensive, nontoxic, environmentally friendly environment-friendly type coating with antimycotic antiseptic effect.
Invention content
In view of this, the present invention provides a kind of the environment friendly coated with fungus and mildew resistance and air purification function of asepsis environment-protecting Material, the coating also have excellent adhesive ability, weather resistance, stability and good water resistance.
The present invention provides a kind of environment-friendly type coating with fungus and mildew resistance and air purification function, and the raw material of the coating is pressed Parts by weight include following component:55-60 parts of alkyd resin, 17-20 parts of polyacrylate dispersion, 10-12 parts of nano-attapulgite, 12-15 parts of nano-kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium metasilicate, 5-8 parts of polyamide, mineral oil antifoam agent 0.5- 0.8 part, 0.8-1.2 parts of nano-titanium oxide, 8-10 parts of net gas biocidal powder, 0.5-0.8 parts of organobentonite, ammonium polyacrylate salt 0.1-0.2 parts of dispersant, 0.1-0.2 parts of carboxymethyl cellulose, 4-6 parts of coconut oil, 45-55 parts of deionized water;
The net gas biocidal powder is with mass ratio by wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, the lemon grass (Cymbopogon citratus) dried 3:1:1:2:Composition is mixed after 1 crushing;
Further, the raw material of the coating includes following component by weight:57 parts of alkyd resin, polyacrylate dispersion 19 parts, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium metasilicate, 6 parts of polyamide, mineral oil 0.6 part of antifoaming agent, 1.0 parts of nano-titanium oxide, 9 parts of herbal powder, 0.6 part of organobentonite, ammonium polyacrylate dipersant 0.1 part, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil, 50 parts of deionized water;
Further, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir at least 30min, be then added thereto ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, Mixed powder obtained in coconut oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, obtain tool There is the environment-friendly type coating of fungus and mildew resistance and air purification function.
Beneficial effects of the present invention:
The present invention is by mixing nontoxic each raw material component according to specific dosage and specific preparation method It closes, has prepared the environment-friendly type coating with fungus and mildew resistance and air purification function, wherein each raw material component organically forms one A entirety can mutually act synergistically, and complementary and synergistic effect be realized, preferably to play respective superiority Energy.
First, net hopping mad bacterium is made according to a specific ratio using wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti and lemon grass (Cymbopogon citratus) Powder, and powder is mixed with other raw materials, it can not only assign coating natural faint scent taste, with fresh air Effect, additionally it is possible to other component (such as nano-attapulgite, nano-titanium oxide, nanometer kaolinites with bactericidal effect with coating Stone, coconut oil etc.) synergy is carried out, to improve the biocidal efficacies of coating.Secondly, polyacrylate dispersion, the alkyd of use Resin and alkyd resin can realize good compatible, nano-attapulgite, nano-kaolinite, diatomite, lithium metasilicate, nanometer The raw materials such as titanium oxide, net gas biocidal powder, organobentonite can realize good dispersion wherein, and then can be preferably Play the mutual synergistic effect between raw material components, greatly improve the adhesive strength of coating, ageing-resistant performance, weather resistance, Chemical stability and water resistance etc. can not only avoid coating from falling off in use, Signs of Mould, also can It avoids being aoxidized because of sunshine or environmental change because of coating.In addition, the nano-titanium oxide used in the present invention can also play it The harmful organic substances such as formaldehyde, the acetaldehyde of the indoor generation of removal are decomposed under ultraviolet light as photochemical catalyst, with concave convex rod Soil, diatomite, lithium metasilicate, organobentonite and kaolinite mutually act synergistically, and realize that physical absorption combines chemical reaction to remove The harmful substances such as indoor formaldehyde, greenhouse gases play the effect of purification air.Organobentonite mixing carboxymethyl cellulose, After nano-attapulgite, three achievees the effect that optimize thickening effect and filming performance collectively as complex thickener.The present invention Middle to use mineral oil antifoam agent, defoaming capacity is strong, is easy to the mixing of other dispensings, side reaction will not be caused in film forming procedure;It adopts With ammonium polyacrylate dipersant, each raw material component can not only be made to be realized in coating evenly dispersed, additionally it is possible to improve coating Water resistance.The present invention has played the excellent properties of each raw material component, realizes the complementation of each raw material component and synergistic work With it is excellent finally to prepare adhesive strength, ageing-resistant performance, weather resistance, chemical stability and water resistance, and with killing The environment-friendly type coating of bacterium anti-mold effect, air purification effect.
Specific implementation mode
The present embodiment provides a kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the raw materials of the coating Include following component by weight:55-60 parts of alkyd resin, 17-20 parts of polyacrylate dispersion, nano-attapulgite 10-12 Part, 12-15 parts of nano-kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium metasilicate, 5-8 parts of polyamide, mineral oil antifoam agent 0.5-0.8 parts, 0.8-1.2 parts of nano-titanium oxide, 8-10 parts of net gas biocidal powder, 0.5-0.8 parts of organobentonite, polyacrylic acid 0.1-0.2 parts of ammonium salt dispersant, 0.1-0.2 parts of carboxymethyl cellulose, 4-6 parts of coconut oil, 45-55 parts of deionized water;
The net gas biocidal powder is with mass ratio by wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, the lemon grass (Cymbopogon citratus) dried 3:1:1:2:Composition is mixed after 1 crushing;
Preferably, the raw material of the coating includes following component by weight:57 parts of alkyd resin, polyacrylate dispersion 19 parts, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium metasilicate, 6 parts of polyamide, mineral oil 0.6 part of antifoaming agent, 1.0 parts of nano-titanium oxide, 9 parts of herbal powder, 0.6 part of organobentonite, ammonium polyacrylate dipersant 0.1 part, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil, 50 parts of deionized water;
The present embodiment is by carrying out nontoxic each raw material component according to specific dosage and specific preparation method Mixing, has prepared the environment-friendly type coating with fungus and mildew resistance and air purification function, and wherein each raw material component is organically formed One entirety, can mutually act synergistically, and complementary and synergistic effect be realized, preferably to play respective superiority Energy.First, net gas biocidal powder is made using wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti and lemon grass (Cymbopogon citratus) according to a specific ratio, And mix powder with other raw materials, it can not only assign coating natural faint scent taste, have the effect of fresh air, It can also be with other component (such as nano-attapulgite, nano-titanium oxide, nano-kaolinite, the coconut palms with bactericidal effect of coating Seed oil etc.) synergy is carried out, to improve the biocidal efficacies of coating.Secondly, the polyacrylate dispersion of use, alkyd resin and Alkyd resin, can realize well it is compatible, nano-attapulgite, nano-kaolinite, diatomite, lithium metasilicate, nano-titanium oxide, The raw materials such as net gas biocidal powder, organobentonite can realize good dispersion wherein, and then can preferably play original Expect the mutual synergistic effect between component, greatly the adhesive strength, ageing-resistant performance of raising coating, weather resistance, chemistry are steady It is qualitative can and water resistance etc., coating can not only be avoided to fall off in use, Signs of Mould, can also avoid because Coating is aoxidized because of sunshine or environmental change.In addition, the nano-titanium oxide used in the present embodiment can also play its conduct The effect of photochemical catalyst decomposes the harmful organic substances such as formaldehyde, the acetaldehyde of the indoor generation of removal, with bumps under ultraviolet light Stick soil, diatomite, lithium metasilicate, organobentonite and kaolinite mutually act synergistically, and realize that physical absorption is gone in conjunction with chemical reaction Except harmful substances such as indoor formaldehyde, greenhouse gases, the effect of purification air is played.Organobentonite mixing carboxymethyl cellulose After element, nano-attapulgite, complex thickener, the common effect for realizing optimization thickening effect and filming performance are formed.This implementation Mineral oil antifoam agent is used in example, defoaming capacity is strong, is easy to the mixing of other dispensings, side reaction will not be caused in film forming procedure; Using ammonium polyacrylate dipersant, each raw material component can not only be made to be realized in coating evenly dispersed, additionally it is possible to improve and apply The water resistance of material.The present embodiment has played the excellent properties of each raw material component, and the complementation and collaboration for realizing each raw material component increase Effect acts on, and it is excellent finally to prepare adhesive strength, ageing-resistant performance, weather resistance, chemical stability and water resistance, and has Have bactericidal mould proof effect, air purification effect environment-friendly type coating.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir at least 30min, be then added thereto ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, Mixed powder obtained in coconut oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, obtain tool There is the environment-friendly type coating of fungus and mildew resistance and air purification function;Preferably disperse conducive to each raw material, realize preferably it is compatible, reach Preferably cooperative synergism effect.
It is specific embodiment below:
Embodiment one
A kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the original of the coating are provided in the present embodiment Material includes following component by weight:55 parts of alkyd resin, 20 parts of polyacrylate dispersion, nano-attapulgite 10 part, nanometer 15 parts of kaolinite, 8 parts of diatomite, 6 parts of lithium metasilicate, 5 parts of polyamide, 0.8 part of mineral oil antifoam agent, nano-titanium oxide 0.8 Part, 10 parts of net gas biocidal powder, 0.5 part of organobentonite, 0.2 part of ammonium polyacrylate dipersant, carboxymethyl cellulose 0.1 Part, 6 parts of coconut oil, 45 parts of deionized water;The net gas biocidal powder is by wormwood, cape jasmine, lemon eucalyptus leaf, the apple eucalyptus dried Leaf, lemon grass (Cymbopogon citratus) are with mass ratio for 3:1:1:2:Composition is mixed after 1 crushing.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir 30min, and ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
Embodiment two
A kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the original of the coating are provided in the present embodiment Material includes following component by weight:60 parts of alkyd resin, 20 parts of polyacrylate dispersion, nano-attapulgite 12 part, nanometer 15 parts of kaolinite, 10 parts of diatomite, 6 parts of lithium metasilicate, 8 parts of polyamide, 0.8 part of mineral oil antifoam agent, nano-titanium oxide 1.2 Part, 10 parts of net gas biocidal powder, 0.8 part of organobentonite, 0.2 part of ammonium polyacrylate dipersant, carboxymethyl cellulose 0.2 Part, 6 parts of coconut oil, 55 parts of deionized water;The net gas biocidal powder is by wormwood, cape jasmine, lemon eucalyptus leaf, the apple eucalyptus dried Leaf, lemon grass (Cymbopogon citratus) are with mass ratio for 3:1:1:2:Composition is mixed after 1 crushing.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir 30min, and ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
Embodiment three
A kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the original of the coating are provided in the present embodiment Material includes following component by weight:60 parts of alkyd resin, 17 parts of polyacrylate dispersion, nano-attapulgite 12 part, nanometer 12 parts of kaolinite, 10 parts of diatomite, 4 parts of lithium metasilicate, 8 parts of polyamide, 0.5 part of mineral oil antifoam agent, nano-titanium oxide 1.2 Part, 8 parts of net gas biocidal powder, 0.8 part of organobentonite, 0.1 part of ammonium polyacrylate dipersant, 0.2 part of carboxymethyl cellulose, 4 parts of coconut oil, 55 parts of deionized water;The net gas biocidal powder by dry wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, lemon Lemon grass is with mass ratio for 3:1:1:2:Composition is mixed after 1 crushing.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir 30min, and ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
Example IV
The present embodiment provides a kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the raw materials of the coating Include following component by weight:57 parts of alkyd resin, 19 parts of polyacrylate dispersion, 11 part, nanometer height of nano-attapulgite 13 parts of ridge stone, 9 parts of diatomite, 5 parts of lithium metasilicate, 6 parts of polyamide, 0.6 part of mineral oil antifoam agent, 1.0 parts of nano-titanium oxide, 9 parts of herbal powder, 0.6 part of organobentonite, 0.1 part of ammonium polyacrylate dipersant, 0.2 part of carboxymethyl cellulose, coconut Oily 5 parts, 50 parts of deionized water;The net gas biocidal powder is by wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, the lemon grass (Cymbopogon citratus) dried With mass ratio for 3:1:1:2:Composition is mixed after 1 crushing.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir 30min, and ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
Embodiment five
A kind of environment-friendly type coating with fungus and mildew resistance and air purification function, the original of the coating are provided in the present embodiment Material includes following component by weight:55 parts of alkyd resin, 17 parts of polyacrylate dispersion, nano-attapulgite 10 part, nanometer 12 parts of kaolinite, 8 parts of diatomite, 4 parts of lithium metasilicate, 5 parts of polyamide, 0.5 part of mineral oil antifoam agent, nano-titanium oxide 0.8 Part, 8 parts of net gas biocidal powder, 0.5 part of organobentonite, 0.1 part of ammonium polyacrylate dipersant, 0.1 part of carboxymethyl cellulose, 4 parts of coconut oil, 45 parts of deionized water;The net gas biocidal powder by dry wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, lemon Lemon grass is with mass ratio for 3:1:1:2:Composition is mixed after 1 crushing.
In the present embodiment, the preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nanometer kaolinite Stone, nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and in the stirring of 300r/min speed Degree is lower to stir 30min, and ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
Raw material components in above-described embodiment can be bought by market.
Performance test:
1, by the environment-friendly type coating obtained with fungus and mildew resistance and air purification function point of one~embodiment of embodiment five It is not applied on a face wall, the dosage for controlling coating is that the area that five kinds of coating are applied to metope is identical, and observation coating was using Phenomenon in journey, and record, it the results are shown in Table 1:
Table 1
As shown in Table 1, environment-friendly type coating made from one~embodiment of embodiment five has excellent adhesion property, bonding strong Degree is high, and performance is excellent, also has the effect of fresh air.
2, using the water resistance of the environment-friendly type coating of one~embodiment of existing test method testing example five, impact Intensity, adhesive force grade, drying time, it the results are shown in Table 2:
Table 2
As shown in Table 2, environment-friendly type coating made from one~embodiment of embodiment five has excellent adhesion property and impact Intensity has good water resistance, solidification quick.
3, sterilization test:According to the antibacterial of one-embodiment of method testing example, five product in GB/T2591-2003 The calculation formula of rate, antibiotic rate is:Q=(X1-X2)/X1 × 100%, wherein:X1 is that blank control sample is averaged bacterial count recovered, X2 is that coating sample is averaged bacterial count recovered;Selection Escherichia coli, black-koji mould are tested, and the results are shown in Table 3:
Table 3
As shown in Table 3, the application has excellent antimycotic antiseptic performance.
Finally illustrate, the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although with reference to compared with Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the right of invention.

Claims (3)

1. a kind of environment-friendly type coating with fungus and mildew resistance and air purification function, it is characterised in that:The raw material of the coating is pressed Parts by weight include following component:55-60 parts of alkyd resin, 17-20 parts of polyacrylate dispersion, 10-12 parts of nano-attapulgite, 12-15 parts of nano-kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium metasilicate, 5-8 parts of polyamide, mineral oil antifoam agent 0.5- 0.8 part, 0.8-1.2 parts of nano-titanium oxide, 8-10 parts of net gas biocidal powder, 0.5-0.8 parts of organobentonite, ammonium polyacrylate salt 0.1-0.2 parts of dispersant, 0.1-0.2 parts of carboxymethyl cellulose, 4-6 parts of coconut oil, 45-55 parts of deionized water;
The net gas biocidal powder by dry wormwood, cape jasmine, lemon eucalyptus leaf, apple folium eucalypti, lemon grass (Cymbopogon citratus) with mass ratio be 3:1: 1:2:Composition is mixed after 1 crushing.
2. the environment-friendly type coating according to claim 1 with fungus and mildew resistance and air purification function, it is characterised in that:Institute The raw material for stating coating includes following component by weight:57 parts of alkyd resin, 19 parts of polyacrylate dispersion, nano-attapulgite 11 parts, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium metasilicate, 6 parts of polyamide, mineral oil antifoam agent 0.6 part, nanometer 1.0 parts of titanium oxide, 9 parts of herbal powder, 0.6 part of organobentonite, 0.1 part of ammonium polyacrylate dipersant, carboxymethyl cellulose 0.2 part of element, 5 parts of coconut oil, 50 parts of deionized water.
3. the environment-friendly type coating according to claim 1 with fungus and mildew resistance and air purification function, it is characterised in that:
The preparation method of the environment-friendly type coating includes the following steps:
A, diatomite, lithium metasilicate and organobentonite are first ground into fine powder, then with nano-attapulgite, nano-kaolinite, Nano-titanium oxide and net gas biocidal powder are uniformly mixed, and mixed powder is made;
B, alkyd resin, polyacrylate dispersion and polyamide is taken to be mixed, and under the mixing speed of 300r/min At least 30min is stirred, ammonium polyacrylate dipersant, mineral oil antifoam agent, carboxymethyl cellulose, coconut are then added thereto Mixed powder obtained in oil, deionized water and step a, and 8h is stirred under the mixing speed of 1000r/min, it obtains to have and kill The environment-friendly type coating of the mould proof simultaneous air purification function of bacterium.
CN201810152288.2A 2018-02-14 2018-02-14 Environment-friendly coating with sterilization, mould prevention and air purification functions Active CN108384413B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560205A (en) * 2020-07-08 2020-08-21 百草春天大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101186772A (en) * 2007-12-04 2008-05-28 华南农业大学 Helminthic emulsion paint and preparation method thereof
CN104513577A (en) * 2013-09-27 2015-04-15 天津单渡科技开发有限公司 Environmental-protection interior wall latex paint
CN107083141A (en) * 2017-06-17 2017-08-22 合肥市晨雷思建筑材料科技有限公司 A kind of indoor sterilization dust removing coating and preparation method
CN107325712A (en) * 2017-07-13 2017-11-07 安庆市星空化工涂料有限责任公司 A kind of fungicidal paint
CN107652895A (en) * 2017-10-23 2018-02-02 周瑛 Environment protection interior wall finish paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101186772A (en) * 2007-12-04 2008-05-28 华南农业大学 Helminthic emulsion paint and preparation method thereof
CN104513577A (en) * 2013-09-27 2015-04-15 天津单渡科技开发有限公司 Environmental-protection interior wall latex paint
CN107083141A (en) * 2017-06-17 2017-08-22 合肥市晨雷思建筑材料科技有限公司 A kind of indoor sterilization dust removing coating and preparation method
CN107325712A (en) * 2017-07-13 2017-11-07 安庆市星空化工涂料有限责任公司 A kind of fungicidal paint
CN107652895A (en) * 2017-10-23 2018-02-02 周瑛 Environment protection interior wall finish paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111560205A (en) * 2020-07-08 2020-08-21 百草春天大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof
CN111560205B (en) * 2020-07-08 2021-11-09 百草边大生物科技(青岛)有限公司 Artemisia argyi antioxidant water-based paint and preparation method thereof

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