CN108383472A - Nano silver system functionality ceramic frying pan with complex metal lager - Google Patents

Nano silver system functionality ceramic frying pan with complex metal lager Download PDF

Info

Publication number
CN108383472A
CN108383472A CN201810234327.3A CN201810234327A CN108383472A CN 108383472 A CN108383472 A CN 108383472A CN 201810234327 A CN201810234327 A CN 201810234327A CN 108383472 A CN108383472 A CN 108383472A
Authority
CN
China
Prior art keywords
nano
nano silver
system functionality
functionality ceramic
frying pan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810234327.3A
Other languages
Chinese (zh)
Inventor
成钢
成进学
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Snakes Treating Institute
Original Assignee
Nantong Snakes Treating Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Snakes Treating Institute filed Critical Nantong Snakes Treating Institute
Priority to CN201810234327.3A priority Critical patent/CN108383472A/en
Publication of CN108383472A publication Critical patent/CN108383472A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60—Agents for protection against chemical, physical or biological attack
    • C04B2103/67—Biocides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

It is to belong to nano silver system functionality ceramic frying pan with complex metal lager to prepare production technical field without sintering the invention discloses a kind of nano silver system functionality ceramic frying pan with complex metal lager.By nano silver medical stone dissolution element water purification drug abuse, the strong body of nanometer silver zeolite type antibacterial filter poison, nano silver glauconite glass silica gel antibiotic and sterilizing watch box, carry the malicious health care of silver-colored zinc hydroxyapatite ion-exchange antimicrobial drug abuse filter, nano silver vermiculite oxide type sterilizing disease-preventing, nano silver mullite far infrared body-building, nano silver tourmaline discharge element negative ion far-infrared enhancing immune nano silver system functionality ceramic frying pan with complex metal lager composition.There is institute's cooking " five viscera settling " centering god to control palpitation with fear, and hard bone relieving palpitation improving eyesight improves myocardial function, enhance myocardial nutrition and cell metabolism, antibiotic and sterilizing, water purification, net poison, takes drugs, filter poison, element negative ion far-infrared is discharged, nervous function is adjusted, promotes blood circulation, enhancing is immune, anti-cancer, lengthens one's life at anticancer, makes one energetic, the nano silver system functionality ceramic frying pan with complex metal lager of good health and a long life.

Description

Nano silver system functionality ceramic frying pan with complex metal lager
Technical field：
The invention discloses a kind of nano silver system functionality ceramic frying pan with complex metal lager, be belong to nano silver system functionality ceramic frying pan with complex metal lager without Production technical field is prepared in sintering.
Background technology：
Nano powder after the crushing such as a kind of natural antibacterial agent shell, clay, medical stone, zeolite, tourmaline, with selenium germanium silver nanoparticle It is flexible made of water glass solution, portland cement, suitable weak acid, vinegar, ethyl alcohol co-formulation after powder mixing Ceramic pan.Such ceramic pan does not follow the string because anhydrous, not sweating, and has excellent water resistance.
Before the use of silverware can trace back to more than 2,000 years, and it is prevailing in Tang, and very early, ancients find that silverware has macrobiosis Lengthen one's life and distinguish the effect of poison,《Compendium of Materia Medica》Claim silver that there is the effect of " five viscera settling, centering god control palpitation with fear, hard bone relieving palpitation improving eyesight ", Modern science has declared publicly wherein secret silver can be soluble in water in the form of an ion, thereon receives its colloid once encountering bacterium and adsorbing It holds back, solidifies, until death.
Medical stone is a kind of natural minerals with healthcare function.It is known as " east god's stone " in China in the main place of production.Early in The Ming Dynasty of China doctor's Li Shizhen (1518-1593 A.D.) is written《Compendium of Materia Medica》It is just expressly recited in one book.It is found according to modern scientific research, Observed under electron microscope, one micro mist of medical stone is equally porous as sponge, have physiological activity have again suction-operated and from Sub- exchange interaction, and contain the indispensable mineral element of human body.The transmitting far infrared beneficial to human body, tourmaline is a kind of day Right anion generator, it is spontaneous to be constantly be generated negative aeroion.
Tourmaline, Strange ice stone, negative aeroion are a kind of substances very useful to health.When people pass through breathing When negative aeroion is sent into alveolar, nervous system can be stimulated to generate good effect, through blood circulation institute it is electrically charged be sent to it is complete In each histocyte of body, myocardial function can be improved, enhance myocardial nutrition and cell metabolism, improve immunocompetence, promote health.People Nervous function can be adjusted by sucking certain density negative aeroion, be promoted blood circulation, and make one energetic, and health is long Longevity.Such as suck considerable amount of negative aeroion, moreover it is possible to drive away the illness such as asthma, hypertension, neurasthenia, pulmonary emphysema, coronary heart disease.
Shell, shrimp, crab, spiral shell, oyster, insect shell be that unique positively charged natural green that storage is most on the earth is anti- Microbial inoculum and tunicin, thus it is natural to have the absorption scavenging effect of strength with the various poisonous and harmful bacterial components of positive charge Antibacterial cleanser.
Invention content：
The purpose of the present invention is to provide a kind of nano silver system functionality ceramic frying pan with complex metal lager.
The technology of the present invention solve scheme be：
A kind of nano silver system functionality ceramic frying pan with complex metal lager, it is characterized in that：% is formed by following quality proportioning
Nanometer shell medical stone dissolution multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager 8-14；
The malicious body rich selenium germanium functionality ceramic frying pan with complex metal lager 9-15 by force of nano zeolite type antibacterial filter；
Nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager 10-16；
Carry zinc hydroxyapatite ion-exchange antimicrobial drug abuse filter malicious nano silver system functionality ceramic pot 11-17；
Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot 12-18；
Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot 13-19；
Nano-tourmaline discharges element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system functionality ceramic Pot 1-37；
Wherein（1）The nanometer shell medical stone dissolves out multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager, by following masses Proportioning composition %
Nanometer selenium 0.5-1.5；Sea shell micropowder 2-6；
Nano silver 0.2-0.6；Medical stone nano powder 3-9；
TiO20.1—0.3； SiO20.1—0.3；
Al2O30.1—0.3；Negative ion far-infrared powder 2-6；
ZrO20.1—0.3；Water glass solution 10-30；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
Production method：
Above-mentioned material is mixed well, is die-filling, make it harden both the malicious drug abuse water purification purification air launch of antibiotic and sterilizing filter it is remote Infrared anion nanometer silver system functionality ceramic pot.
（2）The strong body rich selenium germanium silver functionality ceramic frying pan with complex metal lager of nano zeolite type antibacterial filter poison, by following quality proportioning Form %
Organic Selenium 0.5-1.5；CONCHA MERETRICID SEU CYCLINAE micro mist 1-3；
AgNO22—6； CuSO41—3；
Zeolite nano powder 3-9； ZnCl21—3；
Sodium aluminate 1-3；Sodium metasilicate 1-3；
Kaolin 3-9；Water glass solution 25-75；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
The zeolite is a kind of with sodium aluminosilicate（Calcium）The holey of crystal structure is natural or artificial synthesized mineral material, often Type A zeolite as carrier can by sodium aluminate, sodium silicate solution at 90-100 DEG C hydrothermal synthesis or by kaolin families Mineral are transformed through calcining, alkali soluble, crystallization, 3-5 μm of aperture.Natural parastilbite mineral crystal structure is in pencil, puts Shape and drusy is penetrated, Contents of Main Components is about SiO258%、Al2O314%, CaO9% and minimal amount of Fe, Mn etc. have uniform Two-dimensional channel structure, 2.7-6.2 μm of aperture.The preparation of zeolite type antiseptic is that AgNO is added in aqueous zeolite suspension solution3 Or CuSO4、ZnCl2Aqueous solution, make antibacterial metal ions with zeolite occur ion exchange, by zeolite crystal structure sodium, Calcium is replaced into antibacterial metal ions, through filtering, washing, drying, is sintered.Wherein metal ion exchanged rate and solution concentration, PH value, temperature, ionic species, exchange times and zeolite type, granularity are related, consider product cost and operating condition, general to select It is room temperature to 80 DEG C to select exchange temperature, AgNO3Solution concentration 0.2mol/L, zeolite solid-liquid suspension is than 1：（7—10）, AgNO3With The amount ratio of zeolite material is advisable 0.1-0.2.
（3）The nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager, by following Quality proportioning forms %
Se-rich lucid ganoderma nano powder 0.5-1.5；Chitin nano powder 1-3；
Nano silver 0.5-1.5；Chlorite nano powder 2-6；
AgNO30.2—0.6； Ag2S2O30.2—0.6；
SiOCl40.2—0.6； ZnCl20.2—0.6；
B2O30.2—0.6；Silicate glass raw material 3-9；
Water glass solution 25-75；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Montmorillonite micro mist 2-6；Portland cement adds to 100%；
Preparation method：
Glass silica gel anti-biotic material is addition Ag, Zn or Cu ion when calcining silicate glass mixing raw materials, by controlling glass B in glass melt2O3Ratio, make glass that there is certain solubility, with the dissolving of glass, metal antibacterial ion quilt when use Gradually release, it is antiviral to play antibiotic and sterilizing.Also photocatalyst-type anti-biotic agent group can be coated in normal silicate glass surface Point, antibacterial components are mounted in the silicate sturcture of glass surface through calcining, active oxidation antibacterial group is discharged when light irradiates Point, play sterilization, antibacterial, antiviral.Silica gel type antiseptic is by SiOCl4In alkaline solution after hydrolyzable, in acid Gelation in property solution, adds AgNO3、Ag2S2O3Or ZnCl2Solution, colloid is through adsorbing, being dried to the component containing antibacterial metal Amorphous silica gel powder.Die-filling hardening to be dried is uniformly mixed with nano silver, glauconite, water glass solution, portland cement again After become needed for our and attached flexible nano silver system functionality ceramic pot.
（4）The load zinc hydroxyapatite ion-exchange antimicrobial, which is taken drugs, filters malicious nano silver system functionality ceramic pot, by following Quality proportioning forms %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
AgNO31—3； ZnCl21—3；
Basic zirconium phosphate 1-3；Hydroxyapatite 3-9；
Potassium titanate 1-3；Calcium silicates 1-3；
ZnO 2—6； Ca（OH）21—3；
Water glass solution 25-75；Oyster shell micro mist 1-3；
Clay grade mica powder 2-6；Portland cement adds to 100%；
Preparation method：
It is that the water system suspension of oyster shell micro mist, basic zirconium phosphate, hydroxyapatite, potassium titanate and calcium silicates etc. is situated between in acidity first In matter and nanometer selenium, organic germanium, AgNO3、ZnCl2Solution mixes, and controls certain mixing speed, and 4-are reacted at 40-50 DEG C 5h is attached to antibacterial metal ions in carrier crystal structure using the mutual exchanging action or molecular separating force of ion, after by Filter, dry and high-temperature calcination obtain finished product.If a kind of load silver-colored zinc hydroxyapatite preparation method is to add 25% phosphate aqueous solution 750ml For heat to 50 DEG C, stirring is lower to add ZnO 194.7g, then adds Ca（OH）2 35.4g reacts 4h, and solution is cooled to room temperature, and then moves into 2L Ball mill adds 25.2 AgNO3, silver 6h is carried, 4h is ground, by slurry filtration, washing, in 250 DEG C of dryings, dry powder is through air-flow crushing To 1 μm or so, product contains Ag3.0%, drying nano powder.Then by water glass solution and the common mixing of portland cement, mold is set In make its hardening needed for us and flexible nano silver system functionality ceramic frying pan with complex metal lager, be the nano silver of not cracky It is functionality ceramic frying pan with complex metal lager.
（5）Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot, by following quality proportioning group At %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Vermiculite nano powder 3-9；
Alcohol titanium salt nano powder 1-3；Titanium dioxide TiO20.3—0.9；
Alcohol titanium salt nano powder 1-3； TiCl40.5—1.5；
Ti（SO4）20.2—0.6； TiOSO40.2—0.6；
Water glass solution 10-30；Shrimp and crab shells micro mist 1-3；
Titanium dioxide three-iron nano powder Fe2O30.3—0.9；Portland cement adds to 100%；
Preparation method：
In oxide type antiseptic of the present invention, TiO2Activity is high, thermal stability is good, the antibacterial duration is long, price is low with it, A kind of photocatalyst-type anti-biotic agent harmless to the mankind.TiO2After light irradiates, original bound state electron hole pair becomes exciting State electronics, hole are spread to grain surface, and electronics, the quantity in hole to surface are more, then photocatalysis efficiency is high, and reactivity is big, Good anti-bacterial effect.Therefore, particle is smaller, and it is smaller that electronics, hole meet probability in particle, reaches that surface time is faster, and light is urged It is higher to change efficiency.The nano-TiO of integrated application effect most preferably 100nm or so at present2, nano-TiO2Gas phase can be used in preparation Method and liquid phase method, the raw materials used oil TiCl of vapor phase method4With alcohol titanium salt, there is TiCl using technique4Direct oxidation method, the cracking of alcohol titanium salt Method, gas phase hydrolysis method and gas phase hydrogen flame method, product has the characteristics that granularity is good, dispersed strong, active high, but there is yield Defect low, of high cost limits its application.It is mesh that liquid phase method, which is divided into peptisation, sol-gel processing and chemical coprecipitation, The most economical preparation method of nano-titanium dioxide used in preceding antiseptic, have raw material sources are wide, cost is relatively low, equipment is simple, The characteristics of convenient for mass producing, but to resolve superfine Ti O2During the filtering of slurry, drying and calcination easily caused by grain Agglomeration traits between son, the hard aggregation problem for especially making the dispersibility of product be deteriorated.Such as by TiCl4It is formulated into a certain concentration, is added Enter alkaline solution and carries out neutralizing hydrolysis, the TiO of gained2Up to nano-TiO after hydrate is washed, drying and calcination are handled2Production Product.Then it is die-filling nano silver, vermiculite, waterglass, portland cement to be uniformly mixed die-filling mixing, purpose accelerates setting rate, Suitable weak acid or ethyl alcohol is added, rear as this product to be hardened, which is not easy to break by a fall, breaks flexible nano silver system functionality ceramic Pot.
（6）Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot, is matched by following masses Than forming %
Se-rich lucid ganoderma nano powder 0.5-1.5；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Nano silver 0.5-1.5；Mullite nano powder 3-9；
Chromium oxide 0.2-0.6；Magnesia 0.2-0.6；
Carbide TiC 0.2-0.6；Nitride TiN 0.2-0.6；
Silicide TiSi20.2—0.6；Puff TiB20.2—0.6；
Portland cement 25-75；Clay 7-21；
Chitosan nano rice flour 0.5-1.5；Water adds to 100%；
Preparation method：
After above-mentioned material is kneaded, sets in mold cup, add vinegar or ethyl alcohol appropriate, to accelerate its hardening, various argentiferous are made The ceramic cooker of stone element or other any type of argentiferous stone element potteries after placing 12 hours, then are supported at normal temperatures Shield 3-5 days, you can nano silver stone element is made without sintering, nano silver system functionality ceramic frying pan with complex metal lager free from environmental pollution.This pot Its intensity is equally matched compared with the pottery being sintered at 1100-1200 DEG C.
（7）Nano-tourmaline release element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system Functionality ceramic pot forms % by following quality proportioning
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Tourmaline nano powder 2-6；
Titanium dioxide TiO20.2—0.6；Silica SiO20.2—0.6；
Alundum (Al2O3) Al2O30.2—0.6；ZnOw ZnOw 0.2-0.6；
Portland cement 25-75；Clay 10-30；
Spiral shell insect sea shell micropowder 1-3；Vermiculite nano powder 1-3；
Iron oxide FeO 1-3；Water adds to 100%；
Preparation method：
The various embodiments described above each component Mineral cellulosic material medical stone, zeolite, glauconite, apatite, vermiculite, mullite, electricity Gas stone, the solution cooling through calcining, alkali soluble, crystallization set room temperature and then move into ZL ball mills, and 25.2g AgNO are added3Carry silver 6h, grind 4h, by slurry filtration, washing, in 250 DEG C of dryings, dry powder through air-flow crushing to 0.5-2 μ g or so grain size, then with Each material is kneaded, die-filling, to accelerate its hardening plus suitable weak acid such as vinegar or ethyl alcohol, is placed 24 hours, then support at normal temperatures The ceramic ware cup for not polluting its intensity of air environment without sintering and being sintered at a temperature of 1100-1200 DEG C is made for 3-5 days in shield Compared to equally matched, and non-breakable break.
Clay is a kind of silicate compound with layer structure containing aluminium, iron, magnesium elements, and some clay substances also contain There are certain alkali and alkaline earth metal ions.Clay substance includes kaolin families substance, montmorillonite, vermiculite, clay grade mica, Erie Stone, glauconite, expands chlorite, the clay substance in relation to vermiculite and with transitional layer chain structure at chlorite The types such as the allophane of palygorskite, sepiolite and non crystalline structure.Due to the crystalline texture feature of clay substance, different is glutinous Ca in soil material crystallization2+、Mg2+、H+、NH4+、Na+Plasma has different degrees of ion exchangeable, wherein kaolin ion Exchange capacity, up to 100-150meq/100g.
Bentonite in clay antiseptic, because it is with very strong adsorption capacity and ion-exchange capacity, and as inorganic The ideal carrier of antiseptic.Bentonite is typical book clay mineral, and the cation easily of interlayer is exchanged, and is had prodigious Ion exchange capacity.Especially sodium bentonite, because of Na+With Ag+All there are good give-and-take conditions in electricity price and radius, therefore It can be Ag+Its interlayer is introduced into as antiseptic to be applied in product.But due to the Ag of its interlayer+In conjunction with weaker, it is easy to dissociate Come, to cause product discoloration, anti-microbial property decline, persistence is bad the shortcomings of.Usually utilize Ag+Organic complex substitute Ag+It can be largely overcoming this deficiency, also, even if organic matter decomposes under high temperature, as the precipitation of fine particle silver Have anti-microbial property, the antimycotic performance of inorganic antiseptic further can be improved using the organic reagent with anti-microbial property.Sea Afrodite, the layer chain structure of palygorskite and unique zeolite pore structure, make it have very strong absorption property and cation exchanges Performance.
Process engineering research institute of the Chinese Academy of Sciences develops nano lamellar silver series inorganic antibiosis by study on the carrier of phyllosilicate Agent has broad spectrum antibacterial, all has ideal inhibition to gram-negative bacteria, fungi and mould etc..Prevent to cure through China Anti-bacterial fibre prepared by this nanometer of silver-series antibacterial agent detects in subject institute, resists to Escherichia coli and staphylococcus aureus Bacterium rate can reach 99.9%, and the antiseptic is safe, and nontoxic non-stimulated, antibacterial is lasting.China University of Geosciences and Tsing-Hua University are big Etc. utilizes the cation exchange property of mineral vermiculite, by Cu2+It is implanted into vermiculite, obtained copper content is up to 5.5% inorganic antibacterial Agent, test result show that this antiseptic has both two kinds of antibacterium, fungi effects, and it is of low cost, stability is good.
Silver can kill the microorganisms such as bacterium, virus, fungi；But it is harmless to human normal cell.As one kind from soil The natural antibacterial agent of earth, silver-colored effect is very extensive, deserves to be called the second immunization barrier except human body innate immune system；Silver Ion pair treatment gastritis, malaria, parasitic infection, psoriasis, eye, ear and mouth infection, yeast infection have very well Effect, can take orally or external application.
The appearance of silver is the miracle of modern medicine, and a kind of antibiotic can kill 6 kinds of pathogenic organisms bacterium, and silver can kill 650 Kind, and can effectively control obstinate antibacterial bacterial strain；Minimal amount of silver can eliminate a large amount of pathogenic organisms；Under lab, still Do not find that any microorganism can not be killed in 6min by silver.
Nano silver system functionality ceramic frying pan with complex metal lager, using " nanometer " high energy wwater activated material, by far infrared radiation and Constantly dissolution element anion function activates water quality, while Strong oxdiative is also because the anion in nano material also has very Original work are used, and the activity of the cell membrane or cellular plasm organized enzyme in bacterium can be destroyed, thus it is antiviral to reach antibiotic and sterilizing Effect, and have the toxic elements such as heavy metal element lead, mercury, cadmium, arsenic in absorption antagonism water, take drugs, filter poison, poison short of money, water purification, work Water quality its mouthfeel after change is also accordingly adjusted, and eliminates peculiar smell, taste is more sweet, pure.
Nano silver system functionality ceramic frying pan with complex metal lager of the present invention, not only there is nano silver, AgNO3、TiO2、SiO2、Al2O3、ZrO2、 Ag2S2O3、SiOCl4、B2O3、ZnCl2、ZnO、Ca（OH）2、TiCl4、Ti（SO4）2、TiOSO4, also have anti-cancer, the selenium germanium member of anticancer The multiple elements composition composition such as element and far infrared radiation object oxide, carbide, nitride, silicide, while these elements are again It is various remedies, this nano silver of main component in medical stone, chlorite, zeolite, apatite, vermiculite, mullite, tourmaline It is the shared function and effect for increasing each element ion of cooperation that functionality ceramic frying pan with complex metal lager is multielement, the food of institute's boiling Elementary composition contained by object is high, is effectively facilitated human elementary balanced health and lengthens one's life cancer-preventing health.
With reference to embodiment, the present invention is further described
Specific implementation method：
Embodiment 1：A kind of nano silver system functionality ceramic frying pan with complex metal lager, it is characterized in that：% is formed by following quality proportioning
Nanometer shell medical stone dissolution multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager 8-14；
The malicious body rich selenium germanium silver functionality ceramic frying pan with complex metal lager 9-15 by force of nano zeolite type antibacterial filter；
Nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager 10-16；
Carry zinc hydroxyapatite ion-exchange antimicrobial drug abuse filter malicious nano silver system functionality ceramic pot 11-17；
Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot 12-18；
Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot 13-19；
Nano-tourmaline discharges element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system functionality ceramic Pot 1-37；
Wherein（1）The nanometer shell medical stone dissolves out multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager, by following masses Proportioning composition %
Nanometer selenium 0.5-1.5；Sea shell micropowder 2-6；
Nano silver 0.2-0.6；Medical stone nano powder 3-9；
TiO20.1—0.3； SiO20.1—0.3；
Al2O30.1—0.3；Negative ion far-infrared powder 2-6；
ZrO20.1—0.3；Water glass solution 10-30；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
（2）The strong body rich selenium germanium silver functionality ceramic frying pan with complex metal lager of nano zeolite type antibacterial filter poison, % is formed by following quality proportioning
Organic Selenium 0.5-1.5；CONCHA MERETRICID SEU CYCLINAE micro mist 1-3；
AgNO22—6； CuSO41—3；
Zeolite nano powder 3-9； ZnCl21—3；
Sodium aluminate 1-3；Sodium metasilicate 1-3；
Kaolin 3-9；Water glass solution 25-75；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
（3）The nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager, by following masses Proportioning composition %
Se-rich lucid ganoderma nano powder 0.5-1.5；Chitin nano powder 1-3；
Nano silver 0.5-1.5；Chlorite nano powder 2-6；
AgNO30.2—0.6； Ag2S2O30.2—0.6；
SiOCl40.2—0.6； ZnCl20.2—0.6；
B2O30.2—0.6；Silicate glass raw material 3-9；
Water glass solution 25-75；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Montmorillonite micro mist 2-6；Portland cement adds to 100%；
（4）The load zinc hydroxyapatite ion-exchange antimicrobial, which is taken drugs, filters malicious nano silver system functionality ceramic pot, by following masses Proportioning composition %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
AgNO31—3； ZnCl21—3；
Basic zirconium phosphate 1-3；Hydroxyapatite 3-9；
Potassium titanate 1-3；Calcium silicates 1-3；
ZnO 2—6； Ca（OH）21—3；
Water glass solution 25-75；Oyster shell micro mist 1-3；
Clay grade mica powder 2-6；Portland cement adds to 100%；
（5）Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot forms % by following quality proportioning
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Vermiculite nano powder 3-9；
Alcohol titanium salt nano powder 1-3；Titanium dioxide TiO20.3—0.9；
Alcohol titanium salt nano powder 1-3； TiCl40.5—1.5；
Ti（SO4）20.2—0.6； TiOSO40.2—0.6；
Water glass solution 10-30；Shrimp and crab shells micro mist 1-3；
Titanium dioxide three-iron nano powder Fe2O30.3—0.9；Portland cement adds to 100%；
（6）Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot, by following quality proportioning group At %
Se-rich lucid ganoderma nano powder 0.5-1.5；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Nano silver 0.5-1.5；Mullite nano powder 3-9；
Chromium oxide 0.2-0.6；Magnesia 0.2-0.6；
Carbide TiC 0.2-0.6；Nitride TiN 0.2-0.6；
Silicide TiSi20.2—0.6；Puff TiB20.2—0.6；
Portland cement 25-75；Clay 7-21；
Chitosan nano rice flour 0.5-1.5；Water adds to 100%；
（7）Nano-tourmaline release element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system function Property ceramic pan, by following quality proportioning form %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Tourmaline nano powder 2-6；
Titanium dioxide TiO20.2—0.6；Silica SiO20.2—0.6；
Alundum (Al2O3) Al2O30.2—0.6；ZnOw ZnOw 0.2-0.6；
Portland cement 25-75；Clay 10-30；
Spiral shell insect sea shell micropowder 1-3；Vermiculite nano powder 1-3；
Iron oxide FeO 1-3；Water adds to 100%.

Claims (1)

1. a kind of nano silver system functionality ceramic frying pan with complex metal lager, it is characterized in that：% is formed by following quality proportioning
Nanometer shell medical stone dissolution multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager 8-14；
The malicious body rich selenium germanium functionality ceramic frying pan with complex metal lager 9-15 by force of nano zeolite type antibacterial filter；
Nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager 10-16；
Carry zinc hydroxyapatite ion-exchange antimicrobial drug abuse filter malicious nano silver system functionality ceramic pot 11-17；
Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot 12-18；
Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot 13-19；
Nano-tourmaline discharges element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system functionality ceramic Pot 1-37；
Wherein（1）The nanometer shell medical stone dissolves out multiple element water purification drug abuse functionality ceramic frying pan with complex metal lager, by following masses Proportioning composition %
Nanometer selenium 0.5-1.5；Sea shell micropowder 2-6；
Nano silver 0.2-0.6；Medical stone nano powder 3-9；
TiO20.1—0.3； SiO20.1—0.3；
Al2O30.1—0.3；Negative ion far-infrared powder 2-6；
ZrO20.1—0.3；Water glass solution 10-30；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
（2）The strong silver-colored functionality ceramic frying pan with complex metal lager of body rich selenium germanium silver of nano zeolite type antibacterial filter poison, by following quality proportioning group At %
Organic Selenium 0.5-1.5；CONCHA MERETRICID SEU CYCLINAE micro mist 1-3；
AgNO22—6； CuSO41—3；
Zeolite nano powder 3-9； ZnCl21—3；
Sodium aluminate 1-3；Sodium metasilicate 1-3；
Kaolin 3-9；Water glass solution 25-75；
Organic germanium Ge-132 0.5-1.5；Portland cement adds to 100%；
（3）The nanometer chlorite glass silica gel antibiotic and sterilizing strong element of volume silver system functionality ceramic frying pan with complex metal lager, by following masses Proportioning composition %
Se-rich lucid ganoderma nano powder 0.5-1.5；Chitin nano powder 1-3；
Nano silver 0.5-1.5；Chlorite nano powder 2-6；
AgNO30.2—0.6； Ag2S2O30.2—0.6；
SiOCl40.2—0.6； ZnCl20.2—0.6；
B2O30.2—0.6；Silicate glass raw material 3-9；
Water glass solution 25-75；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Montmorillonite micro mist 2-6；Portland cement adds to 100%；
（4）The load zinc hydroxyapatite ion-exchange antimicrobial, which is taken drugs, filters malicious nano silver system functionality ceramic pot, by following masses Proportioning composition %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
AgNO31—3； ZnCl21—3；
Basic zirconium phosphate 1-3；Hydroxyapatite 3-9；
Potassium titanate 1-3；Calcium silicates 1-3；
ZnO 2—6； Ca（OH）21—3；
Water glass solution 25-75；Oyster shell micro mist 1-3；
Clay grade mica powder 2-6；Portland cement adds to 100%；
（5）Nanometer vermiculite oxide type sterilizing disease-preventing nano silver system functionality ceramic pot forms % by following quality proportioning
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Vermiculite nano powder 3-9；
Alcohol titanium salt nano powder 1-3；Titanium dioxide TiO20.3—0.9；
Alcohol titanium salt nano powder 1-3； TiCl40.5—1.5；
Ti（SO4）20.2—0.6； TiOSO40.2—0.6；
Water glass solution 10-30；Shrimp and crab shells micro mist 1-3；
Titanium dioxide three-iron nano powder Fe2O30.3—0.9；Portland cement adds to 100%；
（6）Nano mullite far infrared body-building anti-cancer element nano silver system functionality ceramic pot, by following quality proportioning group At %
Se-rich lucid ganoderma nano powder 0.5-1.5；Germanium-enriched glossy ganoderma nano powder 0.5-1.5；
Nano silver 0.5-1.5；Mullite nano powder 3-9；
Chromium oxide 0.2-0.6；Magnesia 0.2-0.6；
Carbide TiC 0.2-0.6；Nitride TiN 0.2-0.6；
Silicide TiSi20.2—0.6；Puff TiB20.2—0.6；
Portland cement 25-75；Clay 7-21；
Chitosan nano rice flour 0.5-1.5；Water adds to 100%；
（7）Nano-tourmaline release element negative ion far-infrared selenium germanium electric discharge magnetic wave enhancing immune elements nano silver system function Property ceramic pan, by following quality proportioning form %
Nanometer selenium 0.5-1.5；Organic germanium Ge-132 0.5-1.5；
Nano silver 0.5-1.5；Tourmaline nano powder 2-6；
Titanium dioxide TiO20.2—0.6；Silica SiO20.2—0.6；
Alundum (Al2O3) Al2O30.2—0.6；ZnOw ZnOw 0.2-0.6；
Portland cement 25-75；Clay 10-30；
Spiral shell insect sea shell micropowder 1-3；Vermiculite nano powder 1-3；
Iron oxide FeO 1-3；Water adds to 100%.
CN201810234327.3A 2018-03-21 2018-03-21 Nano silver system functionality ceramic frying pan with complex metal lager Withdrawn CN108383472A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810234327.3A CN108383472A (en) 2018-03-21 2018-03-21 Nano silver system functionality ceramic frying pan with complex metal lager

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810234327.3A CN108383472A (en) 2018-03-21 2018-03-21 Nano silver system functionality ceramic frying pan with complex metal lager

Publications (1)

Publication Number Publication Date
CN108383472A true CN108383472A (en) 2018-08-10

Family

ID=63068296

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810234327.3A Withdrawn CN108383472A (en) 2018-03-21 2018-03-21 Nano silver system functionality ceramic frying pan with complex metal lager

Country Status (1)

Country Link
CN (1) CN108383472A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114561800A (en) * 2022-04-29 2022-05-31 中国人民解放军总医院第一医学中心 Antibacterial heat-preservation chinlon and first-aid heat-preservation blanket comprising same
CN116813306A (en) * 2023-07-07 2023-09-29 江西拓本科技有限公司 Preparation method of enamel-free health-preserving black sand marmite

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922666A (en) * 2014-03-22 2014-07-16 南通蛇类治疗研究所 Silver selenium and germanium-enriched sintering-free pottery with sterilizing and poison filtering functions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922666A (en) * 2014-03-22 2014-07-16 南通蛇类治疗研究所 Silver selenium and germanium-enriched sintering-free pottery with sterilizing and poison filtering functions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114561800A (en) * 2022-04-29 2022-05-31 中国人民解放军总医院第一医学中心 Antibacterial heat-preservation chinlon and first-aid heat-preservation blanket comprising same
CN114561800B (en) * 2022-04-29 2022-07-15 中国人民解放军总医院第一医学中心 Antibacterial heat-preservation chinlon and emergency heat-preservation blanket comprising same
CN116813306A (en) * 2023-07-07 2023-09-29 江西拓本科技有限公司 Preparation method of enamel-free health-preserving black sand marmite
CN116813306B (en) * 2023-07-07 2024-04-16 江西拓本科技有限公司 Preparation method of enamel-free health-preserving black sand marmite

Similar Documents

Publication Publication Date Title
CN104072084B (en) Nano ore powder multiple-effect flexible ceramic vessel
KR100643047B1 (en) Method of Producting of The Biovital-water using material Radiating Far Infared and Mineral
CN109399932A (en) A kind of ceramic glaze and ceramics
CN106747278A (en) Cup and preparation method thereof
CN1742583A (en) Composite nano anti-biotic material and preparation method
El Nahrawy et al. Modern template design and biological evaluation of cephradine-loaded magnesium calcium silicate nanocomposites as an inhibitor for nosocomial bacteria in biomedical applications
CN101347124A (en) Method for preparing silver-carrying ion and copper ion kaolin anti-bacteria agent
CN103768643B (en) A kind of silver ion alginate sustained-release antibacterial gel and preparation method thereof
CN103922666A (en) Silver selenium and germanium-enriched sintering-free pottery with sterilizing and poison filtering functions
CN106927854A (en) A kind of tourmaline ceramic ball for purifying water and preparation method thereof
CN108383472A (en) Nano silver system functionality ceramic frying pan with complex metal lager
CN105272377A (en) Preparation method of antibacterial ceramic
Al Jahdaly et al. Tuning the compositional configuration of hydroxyapatite modified with vanadium ions including thermal stability and antibacterial properties
CN1164276C (en) Method of in vitro culturing medicine ox gallstone with natural ox gall
CN101785860B (en) Tegafur/layered duplex metal hydroxide nanometer hybrid and preparation method thereof
CN105712698A (en) Technology for producing environment-friendly ceramic glazed bricks through industrial waste glass and wastes
CN104724922B (en) A kind of bioglass particles material and its preparation technology
CN103301151A (en) Silver-iodide-doped bioactive glass as well as preparation method and application of silver-iodide-doped bioactive glass
KR101246849B1 (en) Minerals aqueous solution and its manufacturing method
KR20060108282A (en) Method of producting of the facial cream preparing biovital-water using material radiating far 0infared and mineral
CN108516787A (en) Rich selenium germanium cancer-preventing health far-infrared ceramic pot
CN106278212A (en) Egg thick soup tank
CN104709994A (en) Health cup made of nano ore elements and silver
KR101102429B1 (en) Sericite exchanged metal ion having anti-bacteria and preparing methods for thereof
Kar An overview of recent advances in application of some inorganic materials-biological and technological perspectives

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180810

WW01 Invention patent application withdrawn after publication