CN108381378A - A kind of atomization ultrasound polishing method based on GaAs wafers - Google Patents

A kind of atomization ultrasound polishing method based on GaAs wafers Download PDF

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Publication number
CN108381378A
CN108381378A CN201810099930.5A CN201810099930A CN108381378A CN 108381378 A CN108381378 A CN 108381378A CN 201810099930 A CN201810099930 A CN 201810099930A CN 108381378 A CN108381378 A CN 108381378A
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CN
China
Prior art keywords
polishing
polishing method
gaas wafers
ultrasonic
atomization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810099930.5A
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Chinese (zh)
Inventor
赵中阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Parker Trade Co Ltd
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Beijing Parker Trade Co Ltd
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Filing date
Publication date
Application filed by Beijing Parker Trade Co Ltd filed Critical Beijing Parker Trade Co Ltd
Priority to CN201810099930.5A priority Critical patent/CN108381378A/en
Publication of CN108381378A publication Critical patent/CN108381378A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/04Lapping machines or devices; Accessories designed for working plane surfaces
    • B24B37/07Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool
    • B24B37/10Lapping machines or devices; Accessories designed for working plane surfaces characterised by the movement of the work or lapping tool for single side lapping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B1/00Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B57/00Devices for feeding, applying, grading or recovering grinding, polishing or lapping agents
    • B24B57/02Devices for feeding, applying, grading or recovering grinding, polishing or lapping agents for feeding of fluid, sprayed, pulverised, or liquefied grinding, polishing or lapping agents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/304Mechanical treatment, e.g. grinding, polishing, cutting

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)

Abstract

The present invention provides a kind of atomization ultrasound polishing method based on GaAs wafers, by using specific polishing fluid, specific atomization ultrasound voltage, specific polishing pad rotating speed and polish pressure, ultrasonic atomizatio polishing is carried out to GaAs wafers, with using traditional polishing fluid to obtain wafer surface defects less, stress is lower, and surface quality is more preferably.

Description

A kind of atomization ultrasound polishing method based on GaAs wafers
Technical field
The present invention relates to semiconductor device fabrication fields, are polished more particularly, to a kind of atomization ultrasound based on GaAs wafers Technique.
Background technology
With the continuous development of current era semi-conductor industry, GaAs monocrystal materials have become semiconductor devices sum aggregate It is also being continuously improved at basic function material particularly important in circuit, while to the surface quality requirements of GaAs wafers.Chemistry Mechanical polishing (CMP) is current one of the mainstream technology for realizing the planarizing of GaAs crystal column surfaces, but there is throwings in tradition CMP The drawbacks such as light liquid largely wastes, material removal is inconsistent, abrasive grain is unevenly distributed.For drawback present in above-mentioned tradition CMP, originally Application proposes ultrasonic atomization and applies liquid polishing method, has been greatly saved the consumption of polishing fluid and has further improved GaAs crystalline substances Round surface quality, and applicant gropes through a large number of experiments, finds under specific burnishing parameters, can obtain quality of finish Excellent GaAs wafers.
Invention content
For the above-mentioned problems in the prior art, the application provide it is a kind of for GaAs wafers have specific polishing The polishing method of parameter, to obtain, surface damage degree is low, the good GaAs wafers of surface roughness.
The technical solution of the application is as follows:
A kind of atomization ultrasound polishing method based on GaAs wafers, this approach includes the following steps:
Polishing fluid is poured into ultrasonic atomizer, the polishing fluid be include deionized water, Ludox, surfactant, The mixed solution of white carbon;
GaAs wafers are adhered to the lower surface of the carrying disk of ultrasonic atomizatio burnishing device, and are in close contact with polishing pad;
The voltage 50-55v of ultrasonic atomizer, turn of polishing pad is arranged in the top cover labyrinth for closing ultrasonic atomizatio burnishing device Speed is 55-60r/min, polish pressure 7-9psi;
By the nozzle alignment GaAs wafers lower surface of the ultrasonic atomizer, ultrasonic atomizer is opened, starts to polish.
Using supersonic wave cleaning machine to the wafer cleaning after polishing, and drying and processing is carried out in vacuum drying chamber.
Wherein by the deionized water of 80-100 mass parts, the silica gel of 50-70 mass parts, the surfactant of 2-3 mass parts, Uniform stirring after the white carbon mixing of 10-15 mass parts, makes surfactant fully dissolve, in ultrasonic disperse 20-30 minutes, obtains To the polishing fluid.
Wherein surfactant is alkyl phenol polyoxyethylene ether.
Wherein the grain size of white carbon is 15nm.
Wherein polishing pad rotating speed is 60r/min, polish pressure 8psi.
The beneficial effects of the present invention are:
By using atomization ultrasound polishing method, the consumption of polishing fluid is saved, and using specific polishing fluid, specific The burnishing parameters such as voltage, specific polishing pad rotating speed and specific polish pressure are atomized, the GaAs with excellent polishing surface is obtained Wafer.
Description of the drawings:
Attached drawing 1 is the ultrasonic atomizatio burnishing device that the embodiment of the present application uses.
Attached drawing 2 is the GaAs crystal column surface micro-structure diagrams obtained using the application ultrasonic atomizatio burnishing parameters.
Attached drawing 3 is the GaAs crystal column surface micro-structure diagrams obtained using traditional polishing fluid.
Wherein:1 --- carrying disk
2 --- polishing pad
3 --- workbench
4 --- rotary shaft
5 --- lower capsul
6 --- pedestal
7 --- top cover labyrinth
8 --- excusing from death atomizer
Specific implementation mode:
Atomization ultrasound polishing method based on GaAs wafers, this approach includes the following steps:
Polishing fluid is configured first, by the deionized water of 80-100 mass parts, the silica gel of 50-70 mass parts, 2-3 mass parts Surfactant, uniform stirring after the white carbon mixing of 10-15 mass parts, makes surfactant fully dissolve, in ultrasonic disperse 20-30 minutes.Wherein, surfactant is alkyl phenol polyoxyethylene ether, and the grain size of white carbon is 15nm.
Compared to traditional SiO2 polishing fluids, due to being added to the white carbon and use alkane that grain size is 15nm in the application For base phenol polyethenoxy ether as surfactant, the GaAs crystal column surface lesion depths after polishing are shallower, reduce wafer defect With the generation of stress.
Then, GaAs wafers are adhered to the lower surface of the carrying disk 1 of ultrasonic atomizatio burnishing device, and tight with polishing pad 2 Contiguity is touched.Top cover labyrinth 7 is closed, prevents air in subsequent atomization polishing process from entering polishing intracavitary.
The voltage swing of atomizer directly influences the grain size of fog-supplying amount and spray film, to the surface layer of workpiece in polishing process Quality plays a crucial role.The grain size of spray film becomes smaller as voltage increases simultaneously, is conducive to be uniformly distributed in throwing Optical interface and the risk for reducing agglomerate grain finally take away the damaging layer of crystal column surface under the effect of the mechanical grinding of abrasive grain. The voltage that the present embodiment chooses ultrasonic atomizer is 50-55v;
About polishing pad rotating speed, when polishing pad rotating speed is relatively low, the abrasive grain and polishing pad reaction in atomized liquid are insufficient, brilliant The damaging layer removal of circular surfaces is insufficient;Under high speed conditions, polishing fluid can be thrown away polishing interface by centrifugal force, cause silicon chip Cooling effect reduce, polishing interface temperature increase, cause inside wafer generate cycle internal stress, ultimately cause internal tiny crack Germinating.Originally it is that embodiment goes polishing pad rotating speed for 60r/min.
About polish pressure, when pressure is relatively low, the surface damage depth of silicon chip is bigger, when pressure is too big, It was found that surface damage depth starts to show increase tendency, and there is different degrees of cut.The present embodiment is using 8psi's Polish pressure.
The nozzle 8 of the ultrasonic atomizer is directed at GaAs wafers lower surface, ultrasonic atomizer is opened, starts to polish.
Using supersonic wave cleaning machine to the wafer cleaning after polishing, and drying and processing is carried out in vacuum drying chamber, obtain The good GaAs wafers of surface quality.
By the GaAs of the GaAs wafers (referring to attached drawing 2) polished using above-mentioned ultrasonic atomizatio and traditional polishing fluid polishing Wafer (referring to attached drawing 3) observes comparison under the microscope, it can be found that brilliant using the GaAs that the application ultrasonic atomizatio parameter obtains Round surface quality is more much better than the GaAs surface quality that traditional polishing fluid polishes.

Claims (5)

1. a kind of atomization ultrasound polishing method based on GaAs wafers, this approach includes the following steps:
(1) polishing fluid is poured into ultrasonic atomizer, the polishing fluid be include deionized water, it is Ludox, surfactant, white The mixed solution of carbon black;
(2) GaAs wafers are adhered to the lower surface of the carrying disk of ultrasonic atomizatio burnishing device, and are in close contact with polishing pad;
(3) top cover labyrinth for closing ultrasonic atomizatio burnishing device, is arranged the voltage 50-55v of ultrasonic atomizer, the rotating speed of polishing pad For 55-60r/min, polish pressure 7-9psi;
(4) by the nozzle alignment GaAs wafers lower surface of the ultrasonic atomizer, ultrasonic atomizer is opened, starts to polish;
(5) it utilizes supersonic wave cleaning machine to the wafer cleaning after polishing, and carries out drying and processing in vacuum drying chamber.
2. atomization ultrasound polishing method according to claim 1, by the deionized water of 80-100 mass parts, 50-70 mass The silica gel of part, the surfactant of 2-3 mass parts, uniform stirring after the white carbon mixing of 10-15 mass parts make surfactant Fully dissolving obtained the polishing fluid in ultrasonic disperse 20-30 minutes.
3. atomization ultrasound polishing method according to claim 2, wherein surfactant are alkyl phenol polyoxyethylene ether.
4. atomization ultrasound polishing method according to claim 3, the wherein grain size of white carbon are 15nm.
5. atomization ultrasound polishing method according to claim 2, wherein polishing pad rotating speed are 60r/min, polish pressure is 8psi。
CN201810099930.5A 2018-02-01 2018-02-01 A kind of atomization ultrasound polishing method based on GaAs wafers Pending CN108381378A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810099930.5A CN108381378A (en) 2018-02-01 2018-02-01 A kind of atomization ultrasound polishing method based on GaAs wafers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN108381378A true CN108381378A (en) 2018-08-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110039405A (en) * 2019-03-20 2019-07-23 广东工业大学 A kind of pressurised atomised spray equipment, burnishing device and polishing method
CN117773697A (en) * 2024-02-23 2024-03-29 山东旭辉玻璃科技有限公司 Cutting corner polishing equipment for agricultural machinery glass

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003243343A (en) * 2002-02-22 2003-08-29 Sumitomo Electric Ind Ltd POLISHING METHOD AND DEVICE FOR GaAs WAFER
JP2005046947A (en) * 2003-07-28 2005-02-24 Nippei Toyama Corp Mechanochemical polishing method and mechanochemical polishing device
CN101468448A (en) * 2007-12-28 2009-07-01 安集微电子(上海)有限公司 Chemical mechanical polishing technological process
CN102009385A (en) * 2010-11-02 2011-04-13 北京通美晶体技术有限公司 Chemical mechanical polishing method for semiconductor wafer
CN102174295A (en) * 2011-03-25 2011-09-07 江南大学 Alkaline silicon dioxide polishing solution suitable for fine atomization CMP
CN102668043A (en) * 2009-10-30 2012-09-12 康宁股份有限公司 Semiconductor wafer re-use using chemical mechanical polishing
CN102672551A (en) * 2012-05-22 2012-09-19 江南大学 Ultrasonic atomization type polishing machine
JP2014117776A (en) * 2012-12-17 2014-06-30 Ebara Corp Polishing method
CN104736296A (en) * 2012-08-24 2015-06-24 埃科莱布美国股份有限公司 Methods of polishing sapphire surfaces
CN205668203U (en) * 2016-07-12 2016-11-02 吉姆西半导体科技(无锡)有限公司 A kind of chemical mechanical polishing apparatus

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003243343A (en) * 2002-02-22 2003-08-29 Sumitomo Electric Ind Ltd POLISHING METHOD AND DEVICE FOR GaAs WAFER
JP2005046947A (en) * 2003-07-28 2005-02-24 Nippei Toyama Corp Mechanochemical polishing method and mechanochemical polishing device
CN101468448A (en) * 2007-12-28 2009-07-01 安集微电子(上海)有限公司 Chemical mechanical polishing technological process
CN102668043A (en) * 2009-10-30 2012-09-12 康宁股份有限公司 Semiconductor wafer re-use using chemical mechanical polishing
CN102009385A (en) * 2010-11-02 2011-04-13 北京通美晶体技术有限公司 Chemical mechanical polishing method for semiconductor wafer
CN102174295A (en) * 2011-03-25 2011-09-07 江南大学 Alkaline silicon dioxide polishing solution suitable for fine atomization CMP
CN102672551A (en) * 2012-05-22 2012-09-19 江南大学 Ultrasonic atomization type polishing machine
CN104736296A (en) * 2012-08-24 2015-06-24 埃科莱布美国股份有限公司 Methods of polishing sapphire surfaces
JP2014117776A (en) * 2012-12-17 2014-06-30 Ebara Corp Polishing method
CN205668203U (en) * 2016-07-12 2016-11-02 吉姆西半导体科技(无锡)有限公司 A kind of chemical mechanical polishing apparatus

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110039405A (en) * 2019-03-20 2019-07-23 广东工业大学 A kind of pressurised atomised spray equipment, burnishing device and polishing method
CN110039405B (en) * 2019-03-20 2024-01-05 广东工业大学 Pressurized atomizing spray device, polishing device and polishing method
CN117773697A (en) * 2024-02-23 2024-03-29 山东旭辉玻璃科技有限公司 Cutting corner polishing equipment for agricultural machinery glass
CN117773697B (en) * 2024-02-23 2024-05-14 山东旭辉玻璃科技有限公司 Cutting corner polishing equipment for agricultural machinery glass

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Application publication date: 20180810