CN108373679A - Volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof - Google Patents
Volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof Download PDFInfo
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- CN108373679A CN108373679A CN201610995623.6A CN201610995623A CN108373679A CN 108373679 A CN108373679 A CN 108373679A CN 201610995623 A CN201610995623 A CN 201610995623A CN 108373679 A CN108373679 A CN 108373679A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
It is compound except methanal paint that the present invention provides a kind of volcanic rock bamboo charcoal comprising the raw material of following parts by weight：Styrene-acrylic emulsion 60~80, quartz sand 10~14, Pigment white 8~14, powdered whiting 10~14, kaolin 5~10, nano-titanium colloidal sol 1~2, melmac 1~1.5, nano carbon sol 0.5~1, sepiolite powder 0.8~1.2, volcanic rock 2~2.5, nanometer ca silicate fibre 0.6~1, lignin 0.1~0.4, nanometer zirconium silicate 0.2~0.5, bamboo charcoal 1.1~1.5, long oil alkyd 0.4~1, antifoaming agent 0.5~1.2, polyamide wax 0.5~0.9, propandiol butyl ether 22~30, water 28~36.The present invention also provides a kind of compound preparation methods except methanal paint of volcanic rock bamboo charcoal.The volcanic rock bamboo charcoal is compound, and except methanal paint PARA FORMALDEHYDE PRILLS(91,95) adsorption rate is fast, Adsorption effect is good, and depollution of environment rate is high, environmentally protective.
Description
Technical field
The invention belongs to paint fields, and in particular to a kind of volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof.
Background technology
It promulgates within 2010《ISO14020 international standard matched coating technical standards》To specification and promote water paint strong
Kang Fazhan will play very positive effect.Therefore the occupation rate of market for increasing water paint is extremely urgent, by aqueous painting
Expect the strategic products be included in scientific and technical innovation, given priority to, is industry and the responsibilities and obligations of enterprise.Modern science and technology and medical technology
It has been proved that organic solvent endangers environment and human health there is great.The World Health Organization is by room air
Pollution is included in " ten big mankind's Health Killers " list, especially as the formaldehyde of organic solvent.
Formaldehyde is a kind of volatile organic compound, colourless, have special odor, slightly overweights air, soluble easily in water.Formaldehyde is to people
Body health has a major impact, and has strong impulse effect to eyes, respiratory tract, human body mucous membrane and skin；Acute poisoning can cause
It sheds tears, runny nose, the symptoms such as cough, causes various respiratory tract disease；Chronic inhalation of low concentration can lead to unrelenting headache, inability, mistake
Sleep etc.；Chronic skin contact can lead to dermatitis, and bad shadow is generated to the respiratory system, digestive system and central nervous system of human body
It rings, causes lung and liver immunologic dysfunction.Formaldehyde harm to the human body is so serious, produce can effectively degradation of formaldehyde building materials production
Product cause the attention of building trade.
Therefore, formaldehyde can be removed and environmental-friendly water soluble paint by working out, it has also become paint field is important at present
Research direction.
Invention content
In view of this, the present invention is compound except methanal paint and preparation method thereof it is necessory to provide a kind of volcanic rock bamboo charcoal,
To solve the above problems.
It is compound except methanal paint that the present invention provides a kind of volcanic rock bamboo charcoal comprising the raw material of following parts by weight：Phenylpropyl alcohol breast
Liquid 60~80, quartz sand 10~14, Pigment white 8~14, powdered whiting 10~14, kaolin 5~10, nano-titanium colloidal sol 1~
2, melmac 1~1.5, nano carbon sol 0.5~1, sepiolite powder 0.8~1.2, volcanic rock 2~2.5, nanometer silicic acid
Calcium fiber 0.6~1, lignin 0.1~0.4, nanometer zirconium silicate 0.2~0.5, bamboo charcoal 1.1~1.5, long oil alkyd 0.4
~1, antifoaming agent 0.5~1.2, polyamide wax 0.5~0.9, propandiol butyl ether 22~30, water 28~36.Wherein, the nano-sized carbon
Soluble solids in colloidal sol is that mass percentage is 10%~15%.
Based on above-mentioned, the volcanic rock bamboo charcoal is compound except methanal paint includes the raw material of following parts by weight：Styrene-acrylic emulsion 65
~75, quartz sand 11~13, Pigment white 10~12, powdered whiting 11~13, kaolin 7~9, nano-titanium colloidal sol 1.3~
1.7, melmac 1.1~1.3, nano carbon sol 0.7~0.9, sepiolite powder 0.9~1.1, volcanic rock 2.2~2.4,
Nanometer ca silicate fibre 0.7~0.9, lignin 0.2~0.3, nanometer zirconium silicate 0.3~0.4, bamboo charcoal 1.2~1.4, long oil
Alkyd resin 0.6~0.9, antifoaming agent 0.7~1, polyamide wax 0.6~0.8, propandiol butyl ether 24~28, water 30~34.
Based on above-mentioned, the antifoaming agent is polyethers antifoaming agent, emulsification dimethicone or dimethyl silicone polymer.
It is described except formaldehyde environmental protection coating material further includes the raw material of following parts by weight based on above-mentioned：Manganese naphthenate 0.2~0.6.
The present invention also provides a kind of compound preparation methods except methanal paint of above-mentioned volcanic rock bamboo charcoal comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
0.5~1 h is calcined in stove at 240 DEG C~255 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 20~30 min under the mixing speed of 2500~3000 r/min, then adds remaining raw material, stirring 30
~40 min.Wherein, described " remaining raw material " refers in raw material in addition to volcanic rock, quartz sand, melmac, again
It is matter calcium carbonate, kaolin, nanometer ca silicate fibre, nanometer zirconium silicate, nano-titanium colloidal sol, sepiolite powder, nano carbon sol, wooden
Other raw materials except element and bamboo charcoal.
In the compound raw material except methanal paint of volcanic rock bamboo charcoal provided by the invention, the nano-titanium colloidal sol has
Stronger photocatalytic, bigger specific surface area, stronger chemical bonding adsorptivity, electrically charged hydroxyl, high surface
The advantages that active, so it can remove formaldehyde, purification air, antibacterial and mouldproof, deodorization, extremely strong anti-pollution, automatic cleaning action.This
Outside, the nano-titanium colloidal sol also has the effects that increase coating intensity, adhesion strength, wearability, thus it have it is relatively good at
Film property, and it is smooth to form a film, and improves coating scrubbing resistant performance.
Sepiolite powder has cheap, large specific surface area, the strength of materials are high, stability is good, are not readily susceptible to corrosion etc.
Advantage, and the nano titanium dioxide photocatalyst in nano-titanium colloidal sol can also be made as much as possible by lighting activation, to send out
Wave maximum photocatalytic effect；In addition, sepiolite powder has excellent pore passage structure, determine that it is having good surface lotus
Have the physical chemistry functions such as good absorption, filtering, function vector and ion exchange while electrical effect and Hole bottom cavity blast.Sea
Afrodite powder is to nano-TiO2There are preferable absorption and peptizaiton, can generate under natural light and be carried out with harmful substances such as formaldehyde
The OH of violent chemical reaction, and they are completely decomposed into the harmless objects such as hydrone, reduce air pollution.
10~100 nm of carbon granules diameter in the nano carbon sol, be in spherical dispersion, have great specific surface area and
High specific surface energy, surface Selective adsorption, excellent electric conductivity；It is imitated with quantum size effect and macroscopic quantum tunnel
It answers；With excellent environmental stability, still there are the singularitys such as high-strength, high-ductility under the high temperature conditions；Hydrophily is extremely strong, in water
Dispersibility it is fabulous, store do not reunite for 3 years at normal temperatures and pressures.
There are microcellular structures for volcanic rock and bamboo charcoal etc., have higher porosity and high-specific surface area, PARA FORMALDEHYDE PRILLS(91,95), volatility
The pernicious gases such as solvent have good Physical Absorption to act on.
Therefore, compared with prior art, the present invention is using nano carbon sol, sepiolite powder, powdered whiting, nanometer silicic acid
Calcium fiber, nanometer zirconium silicate, lignin, bamboo charcoal and volcanic rock etc. coordinate nano-titanium colloidal sol, enhance the strong of TiO 2 sol
The performance of degree, bactericidal properties, adsorbance, corrosion resistance and heat resistance etc., enhances adsorption capacity and adsorption rate, to tiny
Field trash has good adsorption effect, expands adsorption range；Sepiolite powder and nano-titanium colloidal sol arrange in pairs or groups again bamboo charcoal use, also
It can be chemically reacted with harmful substances such as formaldehyde, to achieve the purpose that remove formaldehyde；So the fire provided by the invention
Mountain rock bamboo charcoal is compound, and except methanal paint PARA FORMALDEHYDE PRILLS(91,95) adsorption rate is fast, Adsorption effect is good, and depollution of environment rate is high, environmentally protective,
The compound methanal paint that removes of volcanic rock bamboo charcoal prepared by the present invention has good removal effect, especially PARA FORMALDEHYDE PRILLS(91,95) to various pollutants
Removal effect it is high, preparation method is simple, and operability is strong, at low cost, is conducive to promote and apply.In addition, manganese naphthenate adds
Enter, can promote it is described except formaldehyde environmental protection coating material in use, coating quickly urges dry film forming.
Specific implementation mode
Below by specific implementation mode, technical scheme of the present invention will be described in further detail.
Embodiment 1
It is compound except methanal paint that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Styrene-acrylic emulsion
60, quartz sand 14, Pigment white 8, powdered whiting 14, kaolin 10, nano-titanium colloidal sol 1, melmac 1, nano-sized carbon are molten
Glue 1, sepiolite powder 0.8, volcanic rock 2, nanometer ca silicate fibre 0.6, lignin 0.1, nanometer zirconium silicate 0.2, bamboo charcoal 1.5, length
Oil content alkyd resin 0.4, antifoaming agent 0.5, polyamide wax 0.5, propandiol butyl ether 22, water 36.
The present embodiment also provides a kind of above-mentioned volcanic rock bamboo charcoal the compound preparation method except methanal paint comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
0.5 h is calcined in stove at 240 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 30 min under the mixing speed of 2500 r/min, then adds styrene-acrylic emulsion, Pigment white, long oil alkyd
Resin, polyethers antifoaming agent, polyamide wax, propandiol butyl ether and water stir 30 min.
Embodiment 2
It is compound except methanal paint includes the raw material of following parts by weight that the present embodiment provides a kind of volcanic rock bamboo charcoals：Styrene-acrylic emulsion 65,
Quartz sand 13, Pigment white 10, powdered whiting 13, kaolin 9, nano-titanium colloidal sol 1.3, melmac 1.1, nano-sized carbon are molten
Glue 0.9, sepiolite powder 0.9, volcanic rock 2.2, nanometer ca silicate fibre 0.7, lignin 0.2, nanometer zirconium silicate 0.3, bamboo charcoal
1.4, long oil alkyd 0.6, emulsification dimethicone 0.7, polyamide wax 0.6, manganese naphthenate 0.2, propandiol butyl ether 24,
Water 34.
The present embodiment provides a kind of compound preparation methods except methanal paint of above-mentioned volcanic rock bamboo charcoal comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
0.5 h is calcined in stove at 245 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 20 min under the mixing speed of 2700 r/min, then adds styrene-acrylic emulsion, Pigment white, long oil alkyd
Resin, emulsification dimethicone, polyamide wax, manganese naphthenate, propandiol butyl ether and water, stir 30 min.
Embodiment 3
It is compound except methanal paint includes the raw material of following parts by weight that the present embodiment provides a kind of volcanic rock bamboo charcoals：Styrene-acrylic emulsion 70,
Quartz sand 12, Pigment white 11, powdered whiting 12, kaolin 8, nano-titanium colloidal sol 1.5, melmac 1.3, nano-sized carbon are molten
Glue 0.8, sepiolite powder 1, volcanic rock 2.3, nanometer ca silicate fibre 0.8, lignin 0.3, nanometer zirconium silicate 0.4, bamboo charcoal 1.3,
Long oil alkyd 0.7, emulsification dimethicone 0.9, polyamide wax 0.7, manganese naphthenate 0.3, propandiol butyl ether 26, water
32。
The present embodiment provides a kind of compound preparation methods except methanal paint of above-mentioned volcanic rock bamboo charcoal comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
1 h is calcined in stove at 250 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 25 min under the mixing speed of 2800 r/min, then adds styrene-acrylic emulsion, Pigment white, long oil alkyd
Resin, emulsification dimethicone, polyamide wax, manganese naphthenate, propandiol butyl ether and water, stir 35 min.
Embodiment 4
It is compound except methanal paint that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Styrene-acrylic emulsion
75, quartz sand 11, Pigment white 12, powdered whiting 11, kaolin 7, nano-titanium colloidal sol 1.7, melmac 1.3, nanometer
Carbon sol 0.7, sepiolite powder 1.1, volcanic rock 2.4, nanometer ca silicate fibre 0.9, lignin 0.3, nanometer zirconium silicate 0.4, bamboo
Charcoal 1.2, long oil alkyd 0.9, dimethyl silicone polymer 1, polyamide wax 0.8, manganese naphthenate 0.4, propandiol butyl ether 28,
Water 30.
The present embodiment provides a kind of compound preparation methods except methanal paint of above-mentioned volcanic rock bamboo charcoal comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
0.5 h is calcined in stove at 255 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 20 min under the mixing speed of 3000 r/min, then adds styrene-acrylic emulsion, Pigment white, long oil alkyd
Resin, dimethyl silicone polymer, polyamide wax, manganese naphthenate, propandiol butyl ether and water stir 35 min.
Embodiment 5
It is compound except methanal paint that the present embodiment provides a kind of volcanic rock bamboo charcoals comprising the raw material of following parts by weight：Styrene-acrylic emulsion
80, quartz sand 10, Pigment white 14, powdered whiting 10, kaolin 5, nano-titanium colloidal sol 2, melmac 1.5, nano-sized carbon
Colloidal sol 0.5, sepiolite powder 1.2, volcanic rock 2.5, nanometer ca silicate fibre 1, lignin 0.4, nanometer zirconium silicate 0.5, bamboo charcoal
1.1, long oil alkyd 1, dimethyl silicone polymer 1.2, polyamide wax 0.9, manganese naphthenate 0.5, propandiol butyl ether 30, water
28。
The present embodiment provides a kind of compound preparation methods except methanal paint of above-mentioned volcanic rock bamboo charcoal comprising following step
Suddenly：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
1 h is calcined in stove at 255 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 20 min under the mixing speed of 3000 r/min, then adds styrene-acrylic emulsion, Pigment white, long oil alkyd
Resin, dimethyl silicone polymer, polyamide wax, manganese naphthenate, propandiol butyl ether and water stir 40 min.
Performance test
The volcanic rock bamboo charcoal provided above-described embodiment 1~5 is compound except methanal paint is according to the test event progressive in the following table 1
It can test, test result is as follows shown in table 1：
The volcanic rock bamboo charcoal that 1 each embodiment of table provides is compound except methanal paint performance test table
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| State in a reservoir | It is in uniform state without lump, after stirring | It is in uniform state without lump, after stirring | It is in uniform state without lump, after stirring | It is in uniform state without lump, after stirring | It is in uniform state without lump, after stirring |
| Application property | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice | It is accessible to brush twice |
| Appearance of film | Normally | Normally | Normally | Normally | Normally |
| Drying time | 120 min | 100 min | 95 min | 90 min | 90 min |
| PH value | 7.6 | 7.7 | 7.5 | 7.6 | 7.6 |
| Fineness≤ | 55 μm | 53 μm | 50 μm | 52 μm | 55 μm |
| Viscosity (25 DEG C ± 1 °) | 102 KU | 101 KU | 99 KU | 100 KU | 101 KU |
| Proportion | 1.32 g/cm3 | 1.31 g/cm3 | 1.30 g/cm3 | 1.32 g/cm3 | 1.33 g/cm3 |
| Gloss (60 °) | 4 | 4 | 3 | 3 | 5 |
| Contrast ratio (white/light colored) >= | 0.948 | 0.950 | 0.952 | 0.953 | 0.954 |
Purifying property test result
Using《JCT1074-2008 function of purifying indoor air coating material purifying properties》In test method to embodiment 1~
The 5 compound purifying properties except methanal paint of volcanic rock bamboo charcoal provided are tested.The results are shown in Table 2 for average test：
2 purifying property average test result of table
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Purifying formaldehyde rate | 96.5% | 97.3% | 98.1% | 98.2% | 97.9% |
| Toluene purifying rate | 85.1% | 86.2% | 87.5% | 88.0% | 79.4% |
Finally it should be noted that：The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof；Although ginseng
According to preferred embodiment, invention is explained in detail, those of ordinary skills in the art should understand that：It still can be with
It modifies to the specific implementation mode of the present invention or equivalent replacement is carried out to some technical characteristics；Without departing from skill of the present invention
The spirit of art scheme should all cover within the scope of the technical scheme claimed by the invention.
Claims (5)
1. a kind of volcanic rock bamboo charcoal is compound to remove methanal paint, which is characterized in that it includes the raw material of following parts by weight：Styrene-acrylic emulsion
60~80, quartz sand 10~14, Pigment white 8~14, powdered whiting 10~14, kaolin 5~10, nano-titanium colloidal sol 1~2,
Melmac 1~1.5, nano carbon sol 0.5~1, sepiolite powder 0.8~1.2, volcanic rock 2~2.5, nanometer calcium silicates
Fiber 0.6~1, lignin 0.1~0.4, nanometer zirconium silicate 0.2~0.5, bamboo charcoal 1.1~1.5, long oil alkyd 0.4~
1, antifoaming agent 0.5~1.2, polyamide wax 0.5~0.9, propandiol butyl ether 22~30, water 28~36.
2. volcanic rock bamboo charcoal according to claim 1 is compound to remove methanal paint, which is characterized in that it includes following parts by weight
Raw material：Styrene-acrylic emulsion 65~75, quartz sand 11~13, Pigment white 10~12, powdered whiting 11~13, kaolin 7~9,
Nano-titanium colloidal sol 1.3~1.7, melmac 1.1~1.3, nano carbon sol 0.7~0.9, sepiolite powder 0.9~1.1,
Volcanic rock 2.2~2.4, nanometer ca silicate fibre 0.7~0.9, lignin 0.2~0.3, nanometer zirconium silicate 0.3~0.4, bamboo charcoal
1.2~1.4, long oil alkyd 0.6~0.9, antifoaming agent 0.7~1, polyamide wax 0.6~0.8, propandiol butyl ether 24~
28, water 30~34.
3. volcanic rock bamboo charcoal according to claim 1 or 2 is compound to remove methanal paint, which is characterized in that it further includes following
The raw material of parts by weight：Manganese naphthenate 0.2~0.5.
4. volcanic rock bamboo charcoal according to claim 3 is compound to remove methanal paint, which is characterized in that the antifoaming agent is polyethers
Class antifoaming agent, emulsification dimethicone or dimethyl silicone polymer.
5. a kind of compound preparation method except methanal paint of Claims 1 to 4 any one of them volcanic rock bamboo charcoal comprising with
Lower step：
Volcanic rock is impregnated in concentrated sulfuric acid be washed with deionized after 12 h to neutrality dry after be ground into fine powder, then with stone
Sand, melmac, powdered whiting, kaolin, nanometer ca silicate fibre and nanometer zirconium silicate are uniformly mixed, in Muffle
0.5~1 h is calcined in stove at 240 DEG C~255 DEG C, is taken out after cooling, obtains volcanic rock mixture；
The volcanic rock mixture and nano-titanium colloidal sol, sepiolite powder, nano carbon sol, lignin and bamboo charcoal are blended in one
It rises, and to disperse 20~30 min under the mixing speed of 2500~3000 r/min, then adds remaining raw material, stirring 30
~40 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995623.6A CN108373679A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995623.6A CN108373679A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108373679A true CN108373679A (en) | 2018-08-07 |
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| CN201610995623.6A Withdrawn CN108373679A (en) | 2016-11-12 | 2016-11-12 | Volcanic rock bamboo charcoal is compound except methanal paint and preparation method thereof |
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Application publication date: 20180807 |