CN108344768A - A kind of device and method measuring gas-liquid component thermal coefficient - Google Patents

A kind of device and method measuring gas-liquid component thermal coefficient Download PDF

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Publication number
CN108344768A
CN108344768A CN201810233414.7A CN201810233414A CN108344768A CN 108344768 A CN108344768 A CN 108344768A CN 201810233414 A CN201810233414 A CN 201810233414A CN 108344768 A CN108344768 A CN 108344768A
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test bodies
valve
pipeline
gas
liquid
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CN108344768B (en
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李彦军
江巍雪
杜垲
郭艳萍
徐晓昂
黄耀华
汤宏玉
李舒宏
陈向阳
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Jiangsu Supervision and Inspection Institute for Product Quality
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/20Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Investigating Or Analyzing Materials Using Thermal Means (AREA)

Abstract

The invention discloses a kind of device and methods measuring gas-liquid component thermal coefficient, it can be achieved that temperature, pressure(Or concentration)Under controllable operating mode, while measuring the thermal coefficient of air-liquid binary states.The measuring device, including test bodies, gas phase heat conduction coefficient tester, condenser coil, liquid phase heat conduction coefficient tester, the first shut-off valve, data collecting instrument, water tank, solution pump, the second shut-off valve, heat exchanger, liquidus temperature sensor, temperature controller, heating coil, gas phase temperature sensor, constant pressure valve, pressure sensor;Condenser coil is fixedly connected in test bodies inner cavity, and the water outlet of condenser coil is connected by the first water inlet end of the first pipeline and water tank;The water outlet of water tank is connected by the water inlet end of the second pipeline and heat exchanger;The water outlet of heat exchanger and the water inlet end of condenser coil connect;Heating coil is fixedly connected in test bodies inner cavity, and temperature controller is connect with heating coil.

Description

A kind of device and method measuring gas-liquid component thermal coefficient
Technical field
The invention belongs to gas-liquid component performance measurement fields, it particularly relates to a kind of measurement gas-liquid component thermal coefficient Device and method.
Technical background
Thermal coefficient is most basic one of the thermophysical property of substance.Have widely in industries such as the energy, chemical industry, refrigeration Using.Thermal-hydraulic is especially in thermal apparatus(Such as evaporator, condenser, generator, rectifier)In often in air-liquid Coexisting state.At this point, temperature, pressure, volume in heat transmission equipment(Or temperature, pressure, concentration)In stable state or unstable state.Such as What can accurately measure the thermal coefficient of gas-liquid two-phase medium under transient state or stable state, be to carry out the premise of Calculation of Heat Transfer, and become Ensure one of the key factor rationally designed in heat transmission equipment.
Currently, heat conduction coefficient tester in the market, can only generally meet the test condition under room temperature operating mode.Especially when Tested liquid is volatile liquid or mixed solution(Such as ammonia spirit, lithium bromide, water lithium chloride solution or nano-fluid) When, pressure and concentration change with the change of temperature, and the variation of temperature and concentration can make thermal coefficient change.It is existing Some heat conduction coefficient tester devices can not meet the thermal coefficient under the conditions of the steady state condition of temperature, pressure or concentration necessary simultaneously It measures.
Invention content
Technical problem:Present invention solves the technical problem that being in view of the shortcomings of the prior art, proposing a kind of measurement gas-liquid group The device and method of part thermal coefficient is, it can be achieved that temperature, pressure(Or concentration)Under controllable operating mode, while measuring leading for gas-liquid binary states Hot coefficient.
Technology contents:In order to solve the above technical problems, technical solution used in the embodiment of the present invention is:
On the one hand, the embodiment of the present invention provides a kind of device measuring gas-liquid component thermal coefficient, including test bodies, gas phase are led Hot coefficient tester, condenser coil, liquid phase heat conduction coefficient tester, the first shut-off valve, data collecting instrument, water tank, solution pump, Two shut-off valves, heat exchanger, liquidus temperature sensor, temperature controller, heating coil, gas phase temperature sensor, constant pressure valve, pressure sensing Device;Gas phase heat conduction coefficient tester and liquid phase heat conduction coefficient tester are respectively arranged in test bodies;In use, gas phase heat conduction Coefficient tester is located above the liquid level in test bodies, and liquid phase heat conduction coefficient tester is located under the liquid level in test bodies Side;Condenser coil is fixedly connected in test bodies inner cavity, the water outlet of condenser coil pass through the first pipeline and water tank first Water inlet end connects, and the first shut-off valve is connected in the first pipeline;The water inlet that the water outlet of water tank passes through the second pipeline and heat exchanger End connection, solution pump and the second shut-off valve are connected in the second pipeline;The water outlet of heat exchanger and the water inlet of condenser coil End connection;Heating coil is fixedly connected in test bodies inner cavity, and temperature controller is connect with heating coil;Liquidus temperature sensor and Gas phase temperature sensor is respectively fixedly connected in test bodies;Constant pressure valve is connected to by third pipeline with test bodies;Pressure Sensor is fixedly connected on the top of test bodies;Pressure sensor, liquidus temperature sensor, gas phase temperature sensor, constant pressure Valve, gas phase heat conduction coefficient tester, the data output end of liquid phase heat conduction coefficient tester are defeated with the data of data collecting instrument respectively Enter end connection.
As preference, the device of the measurement gas-liquid component thermal coefficient, further includes visor, the visor and test Ontology is fixedly connected.
As preference, the visor is at least three, wherein first visor is opposite with condenser coil, and second regards Mirror is opposite with the liquid level in test bodies;Third visor is located at the top of test bodies.
As preference, the device of the measurement gas-liquid component thermal coefficient, further includes headlamp, the light extraction of headlamp Face is opposite with third visor.
As preference, the device of the measurement gas-liquid component thermal coefficient further includes the 4th pipeline and by-passing valve, and One end of four pipelines and the second piping connection, the other end of the 4th pipeline and the second water inlet end of water tank connect, by-passing valve connection In the 4th pipeline.
As preference, the test bodies, water tank, the first pipeline, the second pipeline, third pipeline, the 4th pipeline are all provided with There is outer wall insulating layer.
As preference, the device of the measurement gas-liquid component thermal coefficient, further includes safety valve, and the safety valve, which is fixed, to be connected It is connected at the top of test bodies, and is connected to test bodies.
On the other hand, the embodiment of the present invention also provides a kind of method measuring gas-liquid component thermal coefficient, including:
The first step:Measuring device keeps sealing state, and vacuumize process is carried out to test bodies 1;
Second step:Solution to be measured is filled into test bodies, the liquid level of solution to be measured submerges heating coil;
Third walks:Open the chilled(cooling) water return (CWR) in heat exchanger;Open the first shut-off valve, by-passing valve and the second shut-off valve, condensed water It is circulated in condenser coil, water tank and heat exchanger;Temperature controller is opened, heating coil is heated;
4th step:The power of temperature controller is adjusted, and adjusts condensate flow so that temperature, the pressure of solution to be measured reach balance State;Gas phase, the liquid phase Determination of conductive coefficients value of solution to be measured are obtained by data collecting instrument;
5th step:The 4th step is returned, the power and condensate flow of temperature controller are changed, obtains solution to be measured in different temperatures and pressure Gas phase, liquid phase Determination of conductive coefficients value under power terminate until measuring.
Advantageous effect:Compared with prior art, the embodiment of the present invention has the advantages that:The survey of the embodiment of the present invention Examination device and method can realize unitary solution, binary solution, complex solution and mixed solution(Such as nano-fluid)Needed for reaching The measurement of assigned temperature, pressure and gaseous state and liquid heat conductive coefficient under concentration steady state condition.Meanwhile the measurement dress of the present embodiment Set the test request for solving volatile liquid thermal coefficient in wide temperature, pressure limit.In the prior art, it is open type Measuring device, temperature regulating range is limited, and is unable to constant pressure.The measuring device of the present embodiment is enclosed construction.Device Inside have both heating and condense two links, it can be achieved that in larger warm area, wider pressure limit temperature and pressure adjusting.
Description of the drawings
Fig. 1 is the structural schematic diagram of the device of the embodiment of the present invention.
Have in figure:Test bodies 1, gas phase heat conduction coefficient tester 2, condenser coil 3, liquid phase heat conduction coefficient tester 4, One shut-off valve 5, data collecting instrument 6, water tank 7, solution pump 8, by-passing valve 9, the second shut-off valve 10, heat exchanger 11, liquidus temperature pass Sensor 12, temperature controller 13, heating coil 14, visor 15, gas phase temperature sensor 16, constant pressure valve 17, safety valve 18, headlamp 19, pressure sensor 20.
Specific implementation mode
It elaborates below to the embodiment of the present invention, the present embodiment is carried out lower based on the technical solution of the present invention Implement, provides detailed embodiment and specific operating process, but protection scope of the present invention is not limited to the embodiment of subordinate.
As shown in Figure 1, a kind of device of test gas-liquid component thermal coefficient of the embodiment of the present invention, including test bodies 1, Gas phase heat conduction coefficient tester 2, condenser coil 3, liquid phase heat conduction coefficient tester 4, the first shut-off valve 5, data collecting instrument 6, water Case 7, solution pump 8, the second shut-off valve 10, heat exchanger 11, liquidus temperature sensor 12, temperature controller 13, heating coil 14, gas phase temperature Spend sensor 16, constant pressure valve 17 and pressure sensor 20.Gas phase heat conduction coefficient tester 2 and liquid phase heat conduction coefficient tester 4 are divided It is not installed in test bodies 1;In use, gas phase heat conduction coefficient tester 2 is located above the liquid level in test bodies 1, liquid phase Heat conduction coefficient tester 4 is located at below the liquid level in test bodies 1.Condenser coil 3 is fixedly connected in 1 inner cavity of test bodies, The water outlet of condenser coil 3 is connect by the first pipeline with the first water inlet end of water tank 7, and the first shut-off valve 5 is connected to the first pipe Lu Zhong.The water outlet of water tank 7 is connect by the second pipeline with the water inlet end of heat exchanger 11, and solution pump 8 and the second shut-off valve 10 divide It is not connected in the second pipeline.The water outlet of heat exchanger 11 is connect with the water inlet end of condenser coil 3.Heating coil 14 is fixedly connected In 1 inner cavity of test bodies, temperature controller 13 is connect with heating coil 14.Liquidus temperature sensor 12 and gas phase temperature sensor 16 It is respectively fixedly connected in test bodies 1.Constant pressure valve 17 is connected to by third pipeline with test bodies 1;Pressure sensor 20 is solid Surely it is connected to the top of test bodies 1.Pressure sensor 20, liquidus temperature sensor 12, gas phase temperature sensor 16, constant pressure valve 17, gas phase heat conduction coefficient tester 2, the data output end data with data collecting instrument 6 respectively of liquid phase heat conduction coefficient tester 4 Input terminal connects.
In the device of the test gas-liquid component thermal coefficient of above-described embodiment, solution to be measured is contained in test bodies 1.It waits for It can be unitary solution to survey solution(Such as water, ethyl alcohol, refrigerant, oils), binary solution(Such as ammonium hydroxide, lithium bromide water solution, chlorination Lithium aqueous solution, Binary Refrigerant Mixtures etc.), complex solution(Diversity refrigerant or solution etc.), mixed solution(As addition is received The solution of rice or finely ground particles)Deng.Solution to be measured can be azeotropic solution or non-azeotropic solution.
It is in gaseous state that part solution to be measured volatilizees in test bodies 1, is still located in test bodies 1.Gas phase thermal coefficient is surveyed Examination instrument 2 is used to measure the thermal coefficient of gas.Liquid phase heat conduction coefficient tester 4 is used to measure the thermal coefficient of liquid.
Condenser coil 3, water tank 7, heat exchanger 11 constitute condensing unit.Condensing unit carries out temperature to gas in test bodies 1 Degree is adjusted.Specifically, for unitary solution, when temperature is constant, pressure also reaches balance, adjusts temperature at this time and also adjusts Pressure is saved;When solution is binary or is polynary, temperature, pressure and concentration three are entity, that is, are determined in three parameters When two parameters reach stable state, third parameter also determines.
Temperature controller 13 and heating coil 14 constitute heating device.Heating device carries out the solution in test bodies 1 Heating.Heating device heats solution, changes the temperature of solution, also changes the concentration of solution.
The flow of condensed water in condensing unit is adjusted by the first shut-off valve 5 and the second shut-off valve 10.Constant pressure valve 17 is used for Adjust gas pressure in test bodies 1 so that pressure can be constant at pressure needed for test in test bodies 1.
The heating power that above-described embodiment passes through condensate flow and heating device in adjusting condensing unit so that test Gas-liquid component in ontology 1 is under different temperature and pressure operating modes, realizes the thermal conductivity measurement to gas-liquid binary states.The reality The device of example is applied, the thermal coefficient of the gas-liquid binary states under the temperature and pressure operating mode in larger section can be measured.The present apparatus uses In enclosure space, have both two links of heating and condensation, can reach larger warm area, in wider pressure limit temperature and pressure tune Section.
Data collecting instrument 6 acquires the number in pressure sensor 20, liquidus temperature sensor 12, gas phase temperature sensor 16 According to when the pressure and temperature in test bodies 1, which reaches, measures required operating mode, data collecting instrument 6 acquires gas phase thermal coefficient and surveys The data in instrument 2, liquid phase heat conduction coefficient tester 4 are tried, gas phase thermal coefficient and liquid phase thermal coefficient are obtained.
Data collecting instrument 6 acquires the data in pressure sensor 20, liquidus temperature sensor 12, gas phase temperature sensor 16 Afterwards, when the pressure and temperature in test bodies 1, which cannot reach, measures required operating mode, pass through and adjust 14 heating amount of heating coil (Adjust temperature controller 13), condensed water circuit water flow(Adjust 9 aperture of by-passing valve)And 17 aperture of constant pressure valve so that survey The pressure and temperature tried in ontology 1 meets operating mode needed for measurement.Gas phase heat conduction coefficient tester is acquired by data collecting instrument 6 again 2, the data in liquid phase heat conduction coefficient tester 4 obtain gas phase thermal coefficient and liquid phase thermal coefficient.
As preference, the device of the test gas-liquid component thermal coefficient further includes visor 15, visor 15 and test Ontology 1 is fixedly connected.More preferred, the visor 15 is at least three, wherein first visor 15 and 3 phase of condenser coil Right, second visor 15 is opposite with the liquid level in test bodies 1;Third visor 15 is located at the top of test bodies 1.Pass through Three visors can be to provide illumination in test bodies 1.Pass through the condensation of first 15 Observable condenser coil of visor, 3 outer side gas Situation.Pass through the heating evaporation situation of second 15 Observable heating coil of visor, 14 outer liquid.
As preference, the device of the test gas-liquid component thermal coefficient, further includes headlamp 19, headlamp 19 goes out Smooth surface is opposite with third visor 15.The light-emitting surface of headlamp 19 is opposite with third visor 15 so that headlamp 19 projected Light can be irradiated to the solution in test bodies 1, convenient for survey crew by first visor 15 and second visor 15 more Add clear observation.
As preference, the device of the test gas-liquid component thermal coefficient further includes the 4th pipeline and by-passing valve 9, One end of 4th pipeline and the second piping connection, the other end of the 4th pipeline are connect with the second water inlet end of water tank 7, by-passing valve 9 It is connected in the 4th pipeline.
9 groups of condenser coil 3, the first shut-off valve 5, the second shut-off valve 10, water tank 7, solution pump 8, heat exchanger 11 and by-passing valve At condensation water loop.Condensation heat is brought by the cooling water in chilled(cooling) water return (CWR) in heat exchanger 11 and is released to air to cooling tower heat dissipation In.
As preference, the test bodies 1, water tank 7, the first pipeline, the second pipeline, third pipeline, the 4th pipeline are equal Equipped with outer wall insulating layer.The purpose that insulating layer is arranged is kept the temperature for entire measuring device, to prevent heat loss, is surveyed convenient for remaining required Trial work condition(Temperature, pressure)It is constant so that heat conducting coefficient measuring is more accurate.
As preference, the device of the test gas-liquid component thermal coefficient, further includes safety valve 18, and safety valve 18 is fixed It is connected to 1 top of test bodies, and is connected to test bodies 1.The purpose that safety valve 18 is arranged is that measurement dress can be previously set It sets and can bear maximum pressure(Allow maximum pressure).When pressure allows maximum pressure beyond system in test bodies 1, peace Full valve 18 i.e. rapid open releases stress, to prevent the emergent situation such as occur exploding.
The embodiment of the present invention also provides a kind of method of test gas-liquid component thermal coefficient, including:
The first step:Measuring device keeps sealing state, and vacuumize process is carried out to test bodies 1;
Second step:Solution to be measured is filled into test bodies 1, the liquid level of solution to be measured submerges heating coil 14;
Third walks:Open the chilled(cooling) water return (CWR) in heat exchanger 11;The first shut-off valve 5, by-passing valve 9 and the second shut-off valve 10 are opened, Condensed water circulates in condenser coil 3, water tank 7 and heat exchanger 11;Temperature controller 13 is opened, heating coil 14 is heated Processing;
4th step:The power of temperature controller 13 is adjusted, and adjusts condensate flow so that temperature, the pressure of solution to be measured reach flat Weighing apparatus state;Gas phase, the liquid phase Determination of conductive coefficients value of solution to be measured are obtained by data collecting instrument 6;
5th step:Return to the 4th step, change the power and condensate flow of temperature controller 13, obtain solution to be measured in different temperatures and Gas phase, liquid phase Determination of conductive coefficients value under pressure terminate until measuring.
In the method for above-described embodiment, as preference, the 4th step specifically includes:Heating coil is adjusted by temperature controller 13 14 heating amounts;By adjusting 9 aperture of by-passing valve, regulation and control condensed water circuit water flow;17 aperture of constant pressure valve is controlled, so that waiting for Temperature, the pressure for surveying solution reach equilibrium state, meet operating mode needed for measuring.
The measuring device of above-described embodiment can measure the thermal coefficient of the gas phase and liquid phase of solution to be measured, may be used also simultaneously Under different equilibrium state operating modes, to test the thermal coefficient of gaseous constituent and liquid component.
In the measuring device of above-described embodiment, temperature, pressure and the concentration of fluid to be measured can be constant, and adjustable.Its Method is specifically:Heating coil 14 heats the solution to be measured in test bodies 1 so that solution evaporation to be measured or the gas that boils (Or low boiling component);Starting solution pump 8, condensed water is recycled to condenser coil 3 from water tank 7 via solution pump 8, heat exchanger 11, Take away the heat for the gas that 1 headroom space of test bodies evaporates so that portion gas cools down cold in 3 outer surface of condenser coil Solidifying, condensation heat cooled water system in heat exchanger 11 is taken away to cooling tower.Temperature and pressure in test bodies 1 is by temperature controller 13 and condenser coil 3 in water flow control, be finally reached gas-liquid binary states test needed for temperature and pressure.In test bodies 1 Temperature and pressure can be by adjusting 14 heating amount of heating coil(Adjust temperature controller 13), condensed water circuit water flow(Adjust Save 9 aperture of by-passing valve)And 17 aperture of constant pressure valve, it is finally reached the temperature and pressure needed for the test of air-liquid binary states.If two Member or complex solution, the control of temperature, pressure can determine required concentration determination requirement.
The basic principles, main features and advantages of the invention have been shown and described above.Those skilled in the art should Understand, the present invention do not limited by above-mentioned specific embodiment, the description in above-mentioned specific embodiment and specification be intended merely into One step illustrates the principle of the present invention, without departing from the spirit and scope of the present invention, the present invention also have various change and It improves, these changes and improvements all fall within the protetion scope of the claimed invention.The scope of protection of present invention is wanted by right Ask book and its equivalent thereof.

Claims (8)

1. a kind of device measuring gas-liquid component thermal coefficient, which is characterized in that the device includes test bodies(1), gas phase leads Hot coefficient tester(2), condenser coil(3), liquid phase heat conduction coefficient tester(4), the first shut-off valve(5), data collecting instrument (6), water tank(7), solution pump(8), the second shut-off valve(10), heat exchanger(11), liquidus temperature sensor(12), temperature controller (13), heating coil(14), gas phase temperature sensor(16), constant pressure valve(17), pressure sensor(20);
Gas phase heat conduction coefficient tester(2)With liquid phase heat conduction coefficient tester(4)It is respectively arranged in test bodies(1)On;It uses When, gas phase heat conduction coefficient tester(2)Positioned at test bodies(1)In liquid level above, liquid phase heat conduction coefficient tester(4)It is located at Test bodies(1)In liquid level below;
Condenser coil(3)It is fixedly connected on test bodies(1)In inner cavity, condenser coil(3)Water outlet by the first pipeline with Water tank(7)The first water inlet end connection, the first shut-off valve(5)It is connected in the first pipeline;Water tank(7)Water outlet pass through second Pipeline and heat exchanger(11)Water inlet end connection, solution pump(8)With the second shut-off valve(10)It is connected in the second pipeline;It changes Hot device(11)Water outlet and condenser coil(3)Water inlet end connection;
Heating coil(14)It is fixedly connected on test bodies(1)In inner cavity, temperature controller(13)With heating coil(14)Connection;
Liquidus temperature sensor(12)With gas phase temperature sensor(16)It is respectively fixedly connected in test bodies(1)On;Constant pressure valve (17)Pass through third pipeline and test bodies(1)Connection;Pressure sensor(20)It is fixedly connected on test bodies(1)Top;
Pressure sensor(20), liquidus temperature sensor(12), gas phase temperature sensor(16), constant pressure valve(17), gas phase heat conduction Coefficient tester(2), liquid phase heat conduction coefficient tester(4)Data output end respectively with data collecting instrument(6)Data input End connection.
2. the device described in accordance with the claim 1 for measuring gas-liquid component thermal coefficient, which is characterized in that further include visor (15), the visor(15)With test bodies(1)It is fixedly connected.
3. measuring the device of gas-liquid component thermal coefficient according to claim 2, which is characterized in that the visor(15)Extremely It is three less, wherein first visor(15)With condenser coil(3)Relatively, second visor(15)With test bodies(1)Interior Liquid level is opposite;Third visor(15)Positioned at test bodies(1)Top.
4. the device described in accordance with the claim 3 for measuring gas-liquid component thermal coefficient, which is characterized in that further include headlamp (19), headlamp(19)Light-emitting surface and third visor(15)Relatively.
5. the device described in accordance with the claim 1 for measuring gas-liquid component thermal coefficient, which is characterized in that further include the 4th pipeline And by-passing valve(9), one end and the second piping connection of the 4th pipeline, the other end and water tank of the 4th pipeline(7)Second water inlet End connection, by-passing valve(9)It is connected in the 4th pipeline.
6. measuring the device of gas-liquid component thermal coefficient according to claim 5, which is characterized in that the test bodies (1), water tank(7), the first pipeline, the second pipeline, third pipeline, the 4th pipeline be equipped with outer wall insulating layer.
7. the device described in accordance with the claim 1 for measuring gas-liquid component thermal coefficient, which is characterized in that further include safety valve (18), the safety valve(18)It is fixedly connected on test bodies(1)Top, and and test bodies(1)Connection.
8. a kind of method measuring gas-liquid component thermal coefficient, which is characterized in that the method includes:
The first step:Measuring device keeps sealing state, and vacuumize process is carried out to test bodies 1;
Second step:To test bodies(1)Middle filling solution to be measured, the liquid level of solution to be measured submerge heating coil(14);
Third walks:Open heat exchanger(11)In chilled(cooling) water return (CWR);Open the first shut-off valve(5), by-passing valve(9)With the second cut-off Valve(10), condensed water is in condenser coil(3), water tank(7)And heat exchanger(11)In circulate;Open temperature controller(13), pair plus Hot coil(14)Heated;
4th step:Adjust temperature controller(13)Power, and adjust condensate flow so that temperature, the pressure of solution to be measured reach Equilibrium state;Pass through data collecting instrument(6)Obtain gas phase, the liquid phase Determination of conductive coefficients value of solution to be measured;
5th step:The 4th step is returned, temperature controller is changed(13)Power and condensate flow, obtain solution to be measured in different temperatures With gas phase, the liquid phase Determination of conductive coefficients value under pressure, terminate until measuring.
CN201810233414.7A 2018-03-21 2018-03-21 Device and method for measuring heat conductivity coefficient of gas-liquid component Active CN108344768B (en)

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