CN108329680A - A kind of anticracking reinforcing agent for new-energy automobile cable - Google Patents
A kind of anticracking reinforcing agent for new-energy automobile cable Download PDFInfo
- Publication number
- CN108329680A CN108329680A CN201810157143.1A CN201810157143A CN108329680A CN 108329680 A CN108329680 A CN 108329680A CN 201810157143 A CN201810157143 A CN 201810157143A CN 108329680 A CN108329680 A CN 108329680A
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- energy automobile
- reinforcing agent
- automobile cable
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/302—Polyurethanes or polythiourethanes; Polyurea or polythiourea
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：20 30 parts of polyaminoester emulsion, 8 15 parts of N dimethylamino succinamic acid, 10 15 parts of ethylene glycol, 5 10 parts of maleic anhydride inoculated polypropylene, 48 parts of modified ceramic fiber, 7 15 parts of isopropanol, 8 12 parts of rosin, 24 parts of polyacrylate emulsion, 5 10 parts of C5 hydrogenated petroleum resins, 13 parts of silicone oil, 46 parts of age resister.The present invention is using polyaminoester emulsion, N dimethylamino succinamic acid, ethylene glycol as primary raw material, and be added to maleic anhydride inoculated polypropylene, modified ceramic fiber, isopropanol, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins, silicone oil, age resister as modifying agent, the reinforcing agent that the present invention makes enhanced after being added in cable manufacturing process toughness, ductility, rotproofness, glossy property, with excellent anti-freezing anti-cracking effect.
Description
Technical field
The present invention relates to technical field of new energy, and in particular to a kind of anticracking for new-energy automobile cable enhances
Agent.
Background technology
New-energy automobile refers to all other energy automobile in addition to gasoline, diesel engine.Including fuel cell car,
Hybrid vehicle, hydrogen-powered vehicles and solar telephone etc..It has relatively low exhaust emission.According to incompletely statistics, entirely
Existing more than 4,000,000 liquefied petroleum gas automobiles in the world, more than 100 ten thousand gas-fueled vehicles.It is on sale new in Chinese market at present
Energy automobile is mostly hybrid vehicle and pure electric automobile.It is public according to People's Republic of China's national development and the reform committee
Accuse definition, new-energy automobile refer to using unconventional vehicle fuel as a source of power (or using conventional vehicle fuel, adopt
With new vehicle-mounted power plant), the technical principle of the dynamic Control and the advanced technology in terms of driving of comprehensive vehicle, formation is first
Into, the automobile with new technology, new construction.
Since the cable jacket of new-energy automobile is exposed to inside automobile bodies, used in moist, high and low temperature environment,
When being influenced by electric field, thermal field, mechanical stress, chemical attack and other environmental conditions, aging can occur for the shell of cable,
The aging of cable jacket can cause the damage of cable, be very easy to cause danger.
Invention content
Technical problem to be solved by the present invention lies in provide a kind of anticracking reinforcing agent for new-energy automobile cable.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：Polyurethane breast
20-30 parts of liquid, 8-15 parts of TMSDMA N dimethylamine base succinamic acid, 10-15 parts of ethylene glycol, 5-10 parts of maleic anhydride inoculated polypropylene,
4-8 parts of modified ceramic fiber, 7-15 parts of isopropanol, 8-12 parts of rosin, 2-4 parts of polyacrylate emulsion, C5 hydrogenated petroleum resins 5-
10 parts, 1-3 parts of silicone oil, 4-6 parts of age resister.
The component of the above-mentioned anticracking reinforcing agent for new-energy automobile cable, preferably following parts by weight is made：Polyurethane
25 parts of lotion, 13 parts of TMSDMA N dimethylamine base succinamic acid, 12 parts of ethylene glycol, 8 parts of maleic anhydride inoculated polypropylene, modified ceramic are fine
6 parts of dimension, 11 parts of isopropanol, 10 parts of rosin, 3 parts of polyacrylate emulsion, 7 parts of C5 hydrogenated petroleum resins, 2 parts of silicone oil, age resister 5
Part.
The age resister is made of the component of following parts by weight：4-8 parts of asbestos, 1-2 parts of chitooligosaccharide-, ethoxy are fine
Tie up 0.5-0.8 parts of element, 2-3 parts of ferrous sulfate, 1-3 parts of chitin, 3-5 parts of Vitamin C palmitate.
The component of the preferably following parts by weight of the age resister is made：6 parts of asbestos, 2 parts of chitooligosaccharide-, hydroxy ethyl fiber
0.6 part of element, 2.5 parts of ferrous sulfate, 2 parts of chitin, 4 parts of Vitamin C palmitate.
The modified ceramic fiber is modified through alkyd resin by ceramic fibre, and method of modifying is：To ceramic fibre
Rosin and hexamethylolmelamine pregnancy ether are added in dimension, microwave treater microwave treatment 5min is utilized after being sufficiently mixed, then
Alkyd resin, nano silicon dioxide and crospovidone is added, is uniformly mixed and continues microwave treatment 5min, and be transferred to 5-10 DEG C of ring
Sealing and standing 30min in border, again microwave treatment 5min, then cooled to room temperature, 5-10 DEG C of water water of gained mixture
It washes twice, is finally sent into freeze drier, fiber is made to get modified ceramic fibre through the broken machine of superfluorescent fiber in dry obtained solid
Dimension.
The ceramic fibre, rosin, hexamethylolmelamine pregnancy ether, alkyd resin, nano silicon dioxide and crosslinking
The quality amount ratio of povidone is 10-15:0.5-1:0.3-0.5:3-5:1-3:0.5-1.
The operating condition of the microwave treater is microwave frequency 2250MHz, output power 800W.
The preparation method of the above-mentioned anticracking reinforcing agent for new-energy automobile cable is as follows：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, into
Row is stirred to react, and mixing time is 20-30 minutes；
B, by TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrotreated petroleum trees
Fat, silicone oil are added in reaction kettle, and temperature setting is reacted in 120-150 degree, and the reaction time is 30-40 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 800-1000r/
Min, temperature setting 80-90, mixing time are 20-30 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 1200-1400r/min,
Temperature setting is 40-60, and mixing time is 30-40 minutes；
E, the mixture for handling step d well carries out five segmentation grindings to get to finished product.
It is described five times segmentation grinding speed be respectively：40-50/rpm, 60-80/rpm, 90-100/rpm, 100-120/
rpm。
The beneficial effects of the invention are as follows：The present invention is based on polyaminoester emulsion, TMSDMA N dimethylamine base succinamic acid, ethylene glycol
Raw material is wanted, and is added to maleic anhydride inoculated polypropylene, modified ceramic fiber, isopropanol, rosin, polyacrylate emulsion, C5 and adds
As modifying agent, reinforcing agent that the present invention makes increases after being added in cable manufacturing process for hydrogen Petropols, silicone oil, age resister
Strong toughness, ductility, rotproofness, glossy property, with excellent anti-freezing anti-cracking effect.
Specific implementation mode：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：Polyurethane breast
20 parts of liquid, 8 parts of TMSDMA N dimethylamine base succinamic acid, 10 parts of ethylene glycol, 5 parts of maleic anhydride inoculated polypropylene, modified ceramic fiber 4
Part, 7 parts of isopropanol, 8 parts of rosin, 2 parts of polyacrylate emulsion, 5 parts of C5 hydrogenated petroleum resins, 1 part of silicone oil, 4 parts of age resister.
The age resister is made of the component of following parts by weight：4 parts of asbestos, 1 part of chitooligosaccharide-, hydroxyethyl cellulose
0.5 part, 2 parts of ferrous sulfate, 1 part of chitin, 3 parts of Vitamin C palmitate.
The preparation method of the above-mentioned anticracking reinforcing agent for new-energy automobile cable is as follows：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, into
Row is stirred to react, and mixing time is 20 minutes；
B, TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins,
Silicone oil is added in reaction kettle, and temperature setting is reacted at 120 degree, and the reaction time is 30 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 800r/min, temperature
Degree is set as 80, and mixing time is 20 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 1200r/min, temperature is set
40 are set to, mixing time is 30 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：40/
Rpm, 60/rpm, 90/rpm, 100/rpm are to get to finished product.
Embodiment 2
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：Polyurethane breast
30 parts of liquid, 15 parts of TMSDMA N dimethylamine base succinamic acid, 15 parts of ethylene glycol, 10 parts of maleic anhydride inoculated polypropylene, modified ceramic are fine
8 parts of dimension, 15 parts of isopropanol, 12 parts of rosin, 4 parts of polyacrylate emulsion, 10 parts of C5 hydrogenated petroleum resins, 3 parts of silicone oil, age resister
6 parts.
The age resister is made of the component of following parts by weight：8 parts of asbestos, 2 parts of chitooligosaccharide-, hydroxyethyl cellulose
0.8 part, 3 parts of ferrous sulfate, 3 parts of chitin, 3-5 parts of Vitamin C palmitate.
The preparation method of the above-mentioned anticracking reinforcing agent for new-energy automobile cable is as follows：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, into
Row is stirred to react, and mixing time is 30 minutes；
B, TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins,
Silicone oil is added in reaction kettle, and temperature setting is reacted at 150 degree, and the reaction time is 40 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 1000r/min, temperature
Degree is set as 90, and mixing time is 30 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 1400r/min, temperature is set
60 are set to, mixing time is 40 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：50/
Rpm, 80/rpm, 100/rpm, 120/rpm are to get to finished product.
Control group 1
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：Polyurethane breast
20 parts of liquid, 8 parts of TMSDMA N dimethylamine base succinamic acid, 10 parts of ethylene glycol, 5 parts of maleic anhydride inoculated polypropylene, modified ceramic fiber 4
Part, 7 parts of isopropanol, 8 parts of rosin, 2 parts of polyacrylate emulsion, 5 parts of C5 hydrogenated petroleum resins, 1 part of silicone oil, 4 parts of age resister.
The age resister is common age resister.
The preparation method of the above-mentioned anticracking reinforcing agent for new-energy automobile cable is as follows：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, into
Row is stirred to react, and mixing time is 20 minutes；
B, TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins,
Silicone oil is added in reaction kettle, and temperature setting is reacted at 120 degree, and the reaction time is 30 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 800r/min, temperature
Degree is set as 80, and mixing time is 20 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 1200r/min, temperature is set
40 are set to, mixing time is 30 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：40/
Rpm, 60/rpm, 90/rpm, 100/rpm are to get to finished product.
Embodiment 2
A kind of anticracking reinforcing agent for new-energy automobile cable is made of the component of following parts by weight：Polyurethane breast
30 parts of liquid, 15 parts of TMSDMA N dimethylamine base succinamic acid, 15 parts of ethylene glycol, 10 parts of maleic anhydride inoculated polypropylene, modified ceramic are fine
8 parts of dimension, 15 parts of isopropanol, 12 parts of rosin, 4 parts of polyacrylate emulsion, 10 parts of C5 hydrogenated petroleum resins, 3 parts of silicone oil, age resister
6 parts.
The age resister is made of the component of following parts by weight：8 parts of asbestos, 2 parts of chitooligosaccharide-, hydroxyethyl cellulose
0.8 part, 3 parts of ferrous sulfate, 3 parts of chitin, 3-5 parts of Vitamin C palmitate.
The preparation method of the above-mentioned anticracking reinforcing agent for new-energy automobile cable is as follows：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, into
Row is stirred to react, and mixing time is 30 minutes；
B, TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins,
Silicone oil is added in reaction kettle, and temperature setting is reacted at 100 degree, and the reaction time is 40 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 600r/min, temperature
Degree is set as 90, and mixing time is 30 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 800r/min, temperature is set
60 are set to, mixing time is 40 minutes；
E, the mixture for handling step d well is ground to get to finished product.
Table 1 is that cable making, manufactured cable performance test is added with control group in the present invention
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of anticracking reinforcing agent for new-energy automobile cable, which is characterized in that be made of the component of following parts by weight：
20-30 parts of polyaminoester emulsion, 8-15 parts of TMSDMA N dimethylamine base succinamic acid, 10-15 parts of ethylene glycol, maleic anhydride inoculated polypropylene
5-10 parts, 4-8 parts of modified ceramic fiber, 7-15 parts of isopropanol, 8-12 parts of rosin, 2-4 parts of polyacrylate emulsion, C5 hydrotreated petroleums
5-10 parts of resin, 1-3 parts of silicone oil, 4-6 parts of age resister.
2. the anticracking reinforcing agent according to claim 1 for new-energy automobile cable, which is characterized in that preferably following weight
The component of amount number is made：25 parts of polyaminoester emulsion, 13 parts of TMSDMA N dimethylamine base succinamic acid, 12 parts of ethylene glycol, maleic anhydride
8 parts of graft polypropylene, 6 parts of modified ceramic fiber, 11 parts of isopropanol, 10 parts of rosin, 3 parts of polyacrylate emulsion, C5 hydrotreated petroleums
7 parts of resin, 2 parts of silicone oil, 5 parts of age resister.
3. the anticracking reinforcing agent according to claim 1 for new-energy automobile cable, which is characterized in that described anti-aging
Agent is made of the component of following parts by weight：4-8 parts of asbestos, 1-2 parts of chitooligosaccharide-, 0.5-0.8 parts of hydroxyethyl cellulose, sulfuric acid
It is 2-3 parts ferrous, 1-3 parts of chitin, 3-5 parts of Vitamin C palmitate.
4. the anticracking reinforcing agent according to claim 2 for new-energy automobile cable, which is characterized in that described anti-aging
The component of the preferably following parts by weight of agent is made：6 parts of asbestos, 2 parts of chitooligosaccharide-, 0.6 part of hydroxyethyl cellulose, ferrous sulfate
2.5 parts, 2 parts of chitin, 4 parts of Vitamin C palmitate.
5. the anticracking reinforcing agent according to claim 1 or 2 for new-energy automobile cable, which is characterized in that above-mentioned use
It is as follows in the preparation method of the anticracking reinforcing agent of new-energy automobile cable：
A, polyaminoester emulsion, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, is stirred
Reaction is mixed, mixing time is 20-30 minutes；
B, by TMSDMA N dimethylamine base succinamic acid, modified ceramic fiber, rosin, polyacrylate emulsion, C5 hydrogenated petroleum resins, silicon
Oil is added in reaction kettle, and temperature setting is reacted in 120-150 degree, and the reaction time is 30-40 minutes；
C, the mixture of step a mixtures and b are added in blender and are stirred, mixing speed 800-1000r/min, temperature
Degree is set as 80-90, and mixing time is 20-30 minutes；
D, age resister is added in the blender of step c, continues to stir, mixing speed 1200-1400r/min, temperature
It is set as 40-60, mixing time is 30-40 minutes；
E, the mixture for handling step d well carries out five segmentation grindings to get to finished product；The speed of five segmentations grinding
Degree is respectively：40-50/rpm, 60-80/rpm, 90-100/rpm, 100-120/rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157143.1A CN108329680A (en) | 2018-02-24 | 2018-02-24 | A kind of anticracking reinforcing agent for new-energy automobile cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157143.1A CN108329680A (en) | 2018-02-24 | 2018-02-24 | A kind of anticracking reinforcing agent for new-energy automobile cable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108329680A true CN108329680A (en) | 2018-07-27 |
Family
ID=62929770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810157143.1A Pending CN108329680A (en) | 2018-02-24 | 2018-02-24 | A kind of anticracking reinforcing agent for new-energy automobile cable |
Country Status (1)
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| CN (1) | CN108329680A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086280B (en) * | 2009-12-04 | 2014-04-16 | 中国石油化工股份有限公司 | Preparation method of polypropylene nano composite material |
| CN107383822A (en) * | 2017-08-03 | 2017-11-24 | 安徽新智电力科技有限公司 | A kind of anti-freezing anti-cracking reinforcing agent for cable |
-
2018
- 2018-02-24 CN CN201810157143.1A patent/CN108329680A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086280B (en) * | 2009-12-04 | 2014-04-16 | 中国石油化工股份有限公司 | Preparation method of polypropylene nano composite material |
| CN107383822A (en) * | 2017-08-03 | 2017-11-24 | 安徽新智电力科技有限公司 | A kind of anti-freezing anti-cracking reinforcing agent for cable |
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Application publication date: 20180727 |