CN108317529A - One kind is for being catalyzed burning adsorption method and device - Google Patents

One kind is for being catalyzed burning adsorption method and device Download PDF

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Publication number
CN108317529A
CN108317529A CN201810337298.3A CN201810337298A CN108317529A CN 108317529 A CN108317529 A CN 108317529A CN 201810337298 A CN201810337298 A CN 201810337298A CN 108317529 A CN108317529 A CN 108317529A
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China
Prior art keywords
gas
shell
heat
heat exchanger
exchange device
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Pending
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CN201810337298.3A
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Chinese (zh)
Inventor
彭国飞
赵亮
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Jiangxi Collar Er Environmental Protection Equipment Co Ltd
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Jiangxi Collar Er Environmental Protection Equipment Co Ltd
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Priority to CN201810337298.3A priority Critical patent/CN108317529A/en
Publication of CN108317529A publication Critical patent/CN108317529A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/14Gaseous waste or fumes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Incineration Of Waste (AREA)

Abstract

One kind belonging to catalysis burning technical field of heat exchangers for being catalyzed burning adsorption method and device.Catalytic bed and heat exchanger are combined side by side or up and down, catalytic bed lower part sets heating zone (electrical heating or gas heating), there is buffering area in centre, catalytic domain is arranged at top, heat exchanger is internally provided with a certain number of heat exchanging pipes, heat exchanger tube is integral arrangement, there are two types of the imports of gas for distribution on heat exchanger shell, the outlet of two kinds of gas, there is an exhanst gas outlet in outer end on tube side, there is a gas collection area for being divided into two regions in tube side upper end, there is a gas collection area in tube side lower end, high-temperature flue gas walks tube side, so that high-temperature flue gas detour enters heat exchanging body, increase hot fluid flows through path.Pre-heating temperature elevation is carried out at the same time to exhaust gas and desorption gas using high-temperature gas after burning, catalytic bed, preheater and heat exchanger are integrated into one, achieve the purpose that reduce energy consumption.

Description

One kind is for being catalyzed burning adsorption method and device
Technical field
The present invention relates to one kind for being catalyzed burning adsorption method and device, belongs to catalysis burning and is led with heat exchanger technology Domain.
Background technology
Traditional catalytic combustion system often generally uses mixed flow case heat exchange mode with heat exchanger, there is heating slowly, heat exchange Efficiency is low, and heat exchange is incomplete, high energy consumption, and equipment use cost is high.The purpose of the present invention is overcoming drawbacks described above, one kind is provided Thermal energy exchange is abundant, and heat utilization rate is high, preheating time fast catalysis burning heat exchanger.
Invention content
For overcome the deficiencies in the prior art, the present invention provides a kind of for being catalyzed burning adsorption method and device.
One kind for being catalyzed burning adsorbent equipment, combine side by side or up and down by catalytic bed and heat exchanger;Under catalytic bed Portion sets heating zone (electrical heating or gas heating), and centre has buffering area, top to have catalytic domain;Heat exchanger is internally provided with a number of Heat exchanging pipe, heat exchanger tube is integral arrangement;There are two types of the import of gas, the outlets of two kinds of gas for distribution on heat exchanger shell; There is exhanst gas outlet in outer end on tube side.
Tube side upper end has the gas collection area for being divided into two regions, tube side lower end to have gas collection area, high-temperature flue gas to walk pipe Journey so that high-temperature flue gas detour enters heat exchanging body, and increase hot fluid flows through path.
The shell of heat exchanger is equipped with isolation board, and two kinds of cold fluids are separated;Heat exchanger is internally provided with several pieces of bafflings Plate increases the flow path of cold fluid.
The side of shell is catalysis bed apparatus, and the other side of shell is heat exchanger apparatus, and the side roof part connection of shell is anti- The side inner cavity lower section of seam broken, the side inner cavity top connection Catalytic Layer of shell, shell connects electric heating layer, and Catalytic Layer adds with electric There is buffer space between thermosphere, exhaust outlet is connected at the top of the other side of shell, entrance, shell are connected in the middle part of the other side of shell The other side above connection outlet, absorption heat-exchange device and lower absorption heat-exchange device in the other side inner cavity connection of shell, Heat-exchange device is adsorbed above lower absorption heat-exchange device, absorption heat-exchange device connects air inlet.
One kind containing following steps for being catalyzed burning adsorption method:Have to the high concentration VOC in activated carbon adsorption bed When machine exhaust gas is desorbed, need clean air, and heat the boiling point for making up to organic exhaust gas, to by organic exhaust gas from Desorption comes out in activated carbon, and the high-concentration organic waste gas of desorption out, which is then introduced catalytic combustor, burns.
Containing there are two types of gas process step, first gas process step is:Organic exhaust gas enters lower heat of adsorption by entrance Switch, organic exhaust gas are circulated in lower absorption heat-exchange device after upper layer and lower layer, enter shell by multiple baffle plates Below the electric heating layer of side inner cavity, organic exhaust gas is heated in electric heating layer, and the organic exhaust gas temperature after heating reaches 250 DEG C ~280 DEG C, the organic exhaust gas after heating is by Catalytic Layer, the activation energy needed for catalyst degradation burning by Catalytic Layer, together When release a large amount of thermal energy, temperature reaches 350 DEG C, and organic exhaust gas is made to occur flameless combustion, and oxygenolysis be carbon dioxide and The innocuous substances such as water, the gas containing carbon dioxide enter the other side inner cavity of shell, and the gas containing carbon dioxide is by upper Heat-exchange device and lower absorption heat-exchange device are adsorbed, then is filled from below by lower absorption heat-exchange device and upper absorption heat exchange It sets, is discharged from exhaust outlet;Second gas process step is:Gas from air inlet by upper absorption heat-exchange device after, from outlet Discharge, the gas temperature of discharge reach 50 DEG C or more.
It is an advantage of the present invention to provide a kind of integrated devices for catalytic combustion process, can solve prior art heat The low problem of exchange efficiency has effects that improve heat exchanger effectiveness have the function of that crushing is small and saves space-efficient.
Description of the drawings
When considered in conjunction with the accompanying drawings, by referring to following detailed description, can more completely more fully understand the present invention with And be easy to learn the advantage that many of which is adjoint, but attached drawing described herein is used to provide further understanding of the present invention, The part of the present invention is constituted, the illustrative embodiments of the present invention and their descriptions are used to explain the present invention, does not constitute to this hair Bright improper restriction, such as figure are wherein:
Fig. 1 is the structural diagram of the present invention.
Present invention will be further explained below with reference to the attached drawings and examples.
Specific implementation mode
Obviously, those skilled in the art belong to the guarantor of the present invention based on many modifications and variations that spirit of the invention is done Protect range.
Those skilled in the art of the present technique are appreciated that unless expressly stated, singulative " one " used herein, " one It is a ", " described " and "the" may also comprise plural form.It is to be further understood that wording " the packet used in this specification Include " refer to there are the feature, integer, step, operation, element and/or component, but it is not excluded that presence or addition one or Other multiple features, integer, step, operation, element, component and/or their group.It should be understood that when claiming element, component quilt When ' attach ' to another element, component, it can be directly connected to other elements either component or there may also be cental elements Part or component.Wording "and/or" used herein includes any cells of one or more associated list items and complete It combines in portion.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art Language and scientific terminology) there is meaning identical with the general understanding of the those of ordinary skill in fields of the present invention.
For ease of the understanding to the embodiment of the present invention, it will be further explained explanation below, and each embodiment is not Constitute the restriction to the embodiment of the present invention.
Embodiment 1:As shown in Figure 1, it is a kind of for being catalyzed burning adsorption method, contain following steps;It is inhaled to activated carbon When high concentration VOC organic exhaust gas in attached bed is desorbed, clean air is needed, and heat the boiling for making up to organic exhaust gas Point comes out to which organic exhaust gas to be desorbed from activated carbon, and the high-concentration organic waste gas of desorption out is then introduced catalysis combustion Room is burnt to burn.
The principle of catalysis burning is dropped by catalyst using the hydrocarbon property for waiting comhustible components contained by organic exhaust gas VOC Low burn burns required activation energy, makes organic exhaust gas that flameless combustion occur under the conditions of lower initiation temperature, and oxygenolysis is The innocuous substances such as carbon dioxide and water, while a large amount of thermal energy are released, to make full use of this partial heat energy, catalytic combustion device to set Heat exchanger has been set, air is desorbed to the activated carbon for needing to heat up in thermal energy exchange, auxiliary heating system is simultaneously closed off, reduces energy Consumption.
The gas of pending high-concentration waste gas enters shell 1 from entrance 3, and lower adsorbent equipment 10 is arranged at the inner cavity lower part of shell 1, Gas enters electric heating layer 8 by the circuitous channel of lower adsorbent equipment 10, and electric heating layer 8 heats the gas of entrance, temperature Degree reaches 250 DEG C~280 DEG C, and the gas of heating ascends into Catalytic Layer 9, and the gas of heating drops by catalyst in Catalytic Layer 9 Low burn burns required activation energy, makes organic exhaust gas that flameless combustion occur under the conditions of lower initiation temperature, and oxygenolysis is The innocuous substances such as carbon dioxide and water, while a large amount of thermal energy are released, temperature reaches 350 DEG C, into catalytic reaction zone, reaches Organic exhaust gas after initiation temperature reacts rapidly under the effect of the catalyst, and releases a large amount of heat, and exhaust gas temperature rises;
Gas after catalysis burning enters upper absorption heat-exchange device 7, and absorption heat-exchange device 7 inhales the thermal energy of gas It is attached, heat exchange is carried out with external diluent air, diluent air is preheated, the temperature of recovery section thermal energy, gas is reduced to 100 DEG C or so, for the gas after cooling by 4 discharge of outlet, the top of shell 1 is connected with exhaust outlet 4, venting of dust explosion mouth 5.
Embodiment 2:As shown in Figure 1, a kind of for being catalyzed burning adsorbent equipment, the side of shell 1 is catalysis bed apparatus, shell The other side of body 1 is heat exchanger apparatus, and a side roof part of shell 1 connects venting 5, connects and urge above the side inner cavity of shell 1 Change layer 9, connects electric heating layer 8 below the side inner cavity of shell 1, there is buffer space, shell between Catalytic Layer 9 and electric heating layer 8 Exhaust outlet 4 is connected at the top of the other side of body 1, and entrance 3 is connected in the middle part of the other side of shell 1, is connected out above the other side of shell 1 The other side inner cavity of mouth 2, shell 1 connects absorption heat-exchange device 7 and lower absorption heat-exchange device 10, adsorbs heat-exchange device 7 above lower absorption heat-exchange device 10, and absorption heat-exchange device 7 connects air inlet 6.
Upper absorption heat-exchange device 7 and lower 10 inside of absorption heat-exchange device connect a number of heat exchanging pipe, shell 1 Inner cavity have several pieces of baffle plates, increase the flow path of cold fluid.
There is an isolation board in the inner cavity of upper absorption heat-exchange device 7 and lower absorption heat-exchange device 10, and isolation board is by two kinds of cold flows Body is separated.
Embodiment 3:As shown in Figure 1, a kind of for being catalyzed burning adsorbent equipment, i.e. catalytic bed, preheater and heat exchanger is whole Unify the catalysis burning adsorbent equipment of body.Catalytic bed, catalytic bed lower part set heating zone (electrical heating or gas heating), and centre has slow Area is rushed, catalytic domain is arranged at top.Heat exchanger is internally provided with a certain number of heat exchanging pipes, and heat exchanger tube is integral arrangement.
There are two types of the import of gas, the outlets of two kinds of gas for distribution on heat exchanger shell.
There is exhanst gas outlet in outer end on tube side.
Tube side upper end has the gas collection area for being divided into two regions, tube side lower end to have high-temperature flue gas gas collection area, high temperature Flue gas walks tube side so that high-temperature flue gas detour enters heat exchanging body, increases the path that flows through of hot fluid, and there is recuperated gas in tube side upper end Pooling zone.The shell of heat exchanger is equipped with isolation board, and two kinds of cold fluids are separated.Heat exchanger is internally provided with several pieces of bafflings Plate increases the flow path of cold fluid, increases heat transfer effect.
Embodiment 4:As shown in Figure 1, it is a kind of for being catalyzed burning adsorption method, contain following steps:
Containing there are two types of gas process step, first gas process step is:Organic exhaust gas enters lower heat of adsorption by entrance 3 Switch 10, organic exhaust gas are circulated in lower absorption heat-exchange device 10 after upper layer and lower layer, enter shell by multiple baffle plates 8 lower section of electric heating layer of the side inner cavity of body 1, organic exhaust gas are heated in electric heating layer 8, and the organic exhaust gas temperature after heating arrives Up to 250 DEG C~280 DEG C, organic exhaust gas after heating is by Catalytic Layer 9, needed for the catalyst degradation burning by Catalytic Layer 9 Activation energy, while a large amount of thermal energy are released, temperature reaches 350 DEG C, makes organic exhaust gas that flameless combustion occur, and oxygenolysis is two The innocuous substances such as carbonoxide and water, the gas containing carbon dioxide enter the other side inner cavity of shell 1, the gas containing carbon dioxide Body passes through upper absorption heat-exchange device 7 and lower absorption heat-exchange device 10, then passes through lower 10 He of absorption heat-exchange device from below Upper absorption heat-exchange device 7 is discharged from exhaust outlet 4.
Second gas process step is:Gas from air inlet 6 by upper absorption heat-exchange device 7 after, from outlet 2 discharge, The gas temperature of discharge reaches 50 DEG C or more.
Hollow arrow is first gas flow line in Fig. 1, and filled arrows are second gas flow line.
There are several pieces of baffle plates in the inner cavity of shell 1, increases the flow path of cold fluid.
There is an isolation board in the inner cavity of upper absorption heat-exchange device 7 and lower absorption heat-exchange device 10, and isolation board is by two kinds of cold flows Body is separated.
As described above, being explained in detail to the embodiment of the present invention, as long as but essentially without this hair of disengaging Bright inventive point and effect can have many deformations, this will be readily apparent to persons skilled in the art.Therefore, this The variation of sample is also integrally incorporated within protection scope of the present invention.

Claims (6)

1. one kind is for being catalyzed burning adsorbent equipment, it is characterised in that catalytic bed and heat exchanger are combined side by side or up and down; Catalytic bed lower part sets heating zone (electrical heating or gas heating), and centre has buffering area, top to have catalytic domain;Heat exchanger is internally provided with A number of heat exchanging pipe, heat exchanger tube are integral arrangement;There are two types of the import of gas, two kinds of gases for distribution on heat exchanger shell Outlet;There is exhanst gas outlet in outer end on tube side.
2. according to claim 1 a kind of for being catalyzed burning adsorbent equipment, it is characterised in that tube side upper end is divided into two The gas collection area in a region, tube side lower end have gas collection area, high-temperature flue gas to walk tube side so that high-temperature flue gas detour, which enters, changes Hot body, increase hot fluid flows through path.
3. according to claim 1 a kind of for being catalyzed burning adsorbent equipment, it is characterised in that the shell of heat exchanger is equipped with Isolation board separates two kinds of cold fluids;Heat exchanger is internally provided with several pieces of baffle plates, increases the flow path of cold fluid.
4. according to claim 3 a kind of for being catalyzed burning adsorbent equipment, it is characterised in that the side of shell is catalysis The other side of bed apparatus, shell is heat exchanger apparatus, and a side roof part of shell connects venting, connects above the side inner cavity of shell Catalytic Layer is connect, electric heating layer is connected below the side inner cavity of shell, there is buffer space, shell between Catalytic Layer and electric heating layer The other side at the top of connect exhaust outlet, connect entrance in the middle part of the other side of shell, connection outlet above the other side of shell, shell The connection of other side inner cavity on absorption heat-exchange device and lower absorption heat-exchange device, absorption heat-exchange device hands in lower heat of adsorption Above changing device, absorption heat-exchange device connects air inlet.
5. one kind is for being catalyzed burning adsorption method, it is characterised in that contain following steps:To the height in activated carbon adsorption bed When concentration VOC organic exhaust gas is desorbed, clean air is needed, and heat the boiling point for making up to organic exhaust gas, thus will Organic exhaust gas is desorbed from activated carbon and comes out, and the high-concentration organic waste gas of desorption out, which is then introduced catalytic combustor, is fired It burns.
6. according to claim 5 a kind of for being catalyzed burning adsorption method, it is characterised in that containing there are two types of gas flows Step, first gas process step are:Organic exhaust gas enters lower absorption heat-exchange device by entrance, and organic exhaust gas is in lower absorption After the upper layer and lower layer that circulates in heat-exchange device, enters by multiple baffle plates below the electric heating layer of the side inner cavity of shell, have Machine exhaust gas is heated in electric heating layer, and the organic exhaust gas temperature after heating reaches 250 DEG C~280 DEG C, the organic exhaust gas after heating By Catalytic Layer, the activation energy needed for catalyst degradation burning by Catalytic Layer, while a large amount of thermal energy are released, temperature reaches 350 DEG C, make organic exhaust gas that flameless combustion occur, and oxygenolysis is the innocuous substances such as carbon dioxide and water, contains carbon dioxide Gas enter the other side inner cavity of shell, the gas containing carbon dioxide is by upper absorption heat-exchange device and the friendship of lower heat of adsorption Changing device, then be discharged from below from exhaust outlet by lower absorption heat-exchange device and upper absorption heat-exchange device;Second gas stream Journey step is:Gas from air inlet by upper absorption heat-exchange device after, be discharged from outlet, the gas temperature of discharge reaches 50 DEG C More than.
CN201810337298.3A 2018-04-16 2018-04-16 One kind is for being catalyzed burning adsorption method and device Pending CN108317529A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108592059A (en) * 2018-07-25 2018-09-28 上海兰宝环保科技有限公司 A kind of catalytic combustion device for organic waste gases
CN109579534A (en) * 2018-12-03 2019-04-05 宁波力芯科信息科技有限公司 A kind of flameless burning heater based on heat exchange
CN110617491A (en) * 2019-09-25 2019-12-27 万华化学集团股份有限公司 Tail gas catalytic incineration tower and tail gas treatment method using same
CN112728566A (en) * 2020-11-29 2021-04-30 中船海洋动力部件有限公司 High-efficiency energy-saving catalytic combustion integrated device

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108592059A (en) * 2018-07-25 2018-09-28 上海兰宝环保科技有限公司 A kind of catalytic combustion device for organic waste gases
CN109579534A (en) * 2018-12-03 2019-04-05 宁波力芯科信息科技有限公司 A kind of flameless burning heater based on heat exchange
CN110617491A (en) * 2019-09-25 2019-12-27 万华化学集团股份有限公司 Tail gas catalytic incineration tower and tail gas treatment method using same
CN110617491B (en) * 2019-09-25 2021-03-09 万华化学集团股份有限公司 Tail gas catalytic incineration tower and tail gas treatment method using same
CN112728566A (en) * 2020-11-29 2021-04-30 中船海洋动力部件有限公司 High-efficiency energy-saving catalytic combustion integrated device

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