CN108314980A - A kind of adhesive and its application method - Google Patents

A kind of adhesive and its application method Download PDF

Info

Publication number
CN108314980A
CN108314980A CN201810113802.1A CN201810113802A CN108314980A CN 108314980 A CN108314980 A CN 108314980A CN 201810113802 A CN201810113802 A CN 201810113802A CN 108314980 A CN108314980 A CN 108314980A
Authority
CN
China
Prior art keywords
parts
component
adhesive
combination
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810113802.1A
Other languages
Chinese (zh)
Inventor
罗孝明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGGUAN COHUI INDUSTRIAL MATERIALS Co Ltd
Original Assignee
DONGGUAN COHUI INDUSTRIAL MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGGUAN COHUI INDUSTRIAL MATERIALS Co Ltd filed Critical DONGGUAN COHUI INDUSTRIAL MATERIALS Co Ltd
Priority to CN201810113802.1A priority Critical patent/CN108314980A/en
Publication of CN108314980A publication Critical patent/CN108314980A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09J133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention provides a kind of adhesive and its application methods.The adhesive includes component A and B component, and according to the mass fraction, the component A includes：0.1 1 parts of 40 65 parts of polymethyl methacrylate, 25 35 parts of acrylate monomer, 38 parts of urethane acrylate, 15 parts of elastomeric toughening agent, 10 20 parts of filler, 13 parts of reducing agent and polymerization inhibitor；The B component includes：15 parts of 65 80 parts of epoxy resin, 20 25 parts of oxidant and filler；Mass ratio between the component A and the B component is 10:0.9‑1.2.Adhesive provided by the invention can be used for the splicing of artificial stone or quartz, have the characteristics that cementability is good, color inhibition；It is used using the closing packaging cooperation glue rifle of fixed mixing ratio, proportioning is more accurate, improves safety of adhesive during storage, transport and use, reduces environmental pollution.

Description

A kind of adhesive and its application method
Technical field
The invention belongs to technical field of adhesive, and in particular to a kind of adhesive and its application method.
Background technology
Acrylic artificial stone, polyester's stone and quartz are that the kitchen and bath such as kitchen countertop, dining table, tea table, windowsill, bathtub use Common material in product has many advantages, such as scratch-resistant, not easy to pollute, nonflammable, nontoxic.Above-mentioned material is in actual application In, in order to form specific moulding, it usually needs spliced using adhesive.
Conventional artificial's stone or quartzy stone table board splicing deposit toughness after hardening using unsaturated polyester resin adhesive The shortcomings that difference, poor flame retardant properties.CN 106753147A disclose a kind of special high resistant retardant unsaturated polyester resin of quartzite slate Adhesive using unsaturated polyester resin as major ingredient, while adding styrene, pentaerythritol triacrylate, methacrylic acid Different monooctyl ester is diluent, improve the impact flexibility of gained adhesive, and it is big to overcome simple unsaturated polyester resin brittleness Defect.CN 106753148A disclose a kind of special unsaturated polyester resin adhesive of quartzite slate, with unsaturated polyester (UP) tree Fat is major ingredient, while it is diluent to add acrylic acid -2- hydroxyl ethyl esters and pentaerythritol triacrylate, improves gained bonding The impact flexibility of agent.
But above-mentioned unsaturated polyester resin adhesive there are still adhesion strengths it is low, inflammable and explosive the shortcomings of, and contain Styrene is inflammable, is suspecious carcinogen matter, has irritation, it is therefore desirable to be further improved.Moreover, insatiable hunger currently on the market With polyester resin glue packaging using open bottled, cobalt naphthenate (drier is commonly called as Lan Shui) and peroxide are contained in glue Change methyl ethyl ketone (initiator is commonly called as plain boiled water), Lan Shui and plain boiled water are hazardous chemicals, inflammable and explosive, open bottled to store up Deposit, transport and use during there are larger security risks；Worker rule of thumb adds plain boiled water when in use, and extemporaneous preparation is easy Environment is polluted, and is matched there are larger randomness, product bonding quality cannot ensure.
Therefore, it is expected to obtain a kind of novel adhesive for artificial stone or quartz in this field and its mating make With method, the adhesive property of adhesive is on the one hand improved, existing unsaturated polyester resin adhesive scene tune is on the other hand solved The problem of with there is proportioning inaccuracy and pollution environment.
Invention content
In view of the deficiencies of the prior art, the present invention intends to provide a kind of adhesive and its application method.It should Adhesive uses adhesive composition based on acrylate monomer and acrylic resin, makees oxygen using amine reducing agent and peroxide Agent forms redox system, has the characteristics that cementability is good, color inhibition, can be used for the splicing of artificial stone or quartz；It adopts With the closing of fixed mixing ratio pack cooperation glue rifle use, proportioning it is more accurate, improve adhesive in storage, transport and used Safety in journey, reduces environmental pollution.
For this purpose, the present invention uses following technical scheme：
On the one hand, the present invention provides a kind of adhesive, including component A and B component, according to the mass fraction, the component A packet It includes：40-65 parts of polymethyl methacrylate, 25-35 parts of acrylate monomer, 3-8 parts of urethane acrylate, elastomeric toughening agent 0.1-1 parts of 1-5 parts, 10-20 parts of filler, 1-3 parts of reducing agent and polymerization inhibitor；
The B component includes：1-5 parts of 65-80 parts of epoxy resin, 20-25 parts of oxidant and filler；
Mass ratio between the component A and the B component is 10:0.9-1.2.
In the present invention, in the component A mass fraction of polymethyl methacrylate can be 40 parts, 41 parts, 42 parts, 43 Part, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 Part, 59 parts, 60 parts, 61 parts, 62 parts, 63 parts, 64 parts or 65 parts etc..
In the component A mass fraction of acrylate monomer can be 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts or 35 parts etc..
In the component A mass fraction of urethane acrylate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 Part, 6 parts, 6.5 parts, 7 parts, 7.5 parts or 8 parts etc..
In the component A mass fraction of elastomeric toughening agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 Part, 4.5 parts or 5 parts etc..
In the component A mass fraction of filler can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 18 Part, 19 parts or 20 parts etc..
In the component A mass fraction of reducing agent can be 1 part, 1.2 parts, 1.5 parts, 1.8 parts, 2 parts, 2.2 parts, 2.5 Part, 2.8 parts or 3 parts etc..
In the component A mass fraction of polymerization inhibitor can be 0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part or 1 part etc..
The mass fraction of the B component epoxy resin can be 65 parts, 66 parts, 67 parts, 68 parts, 69 parts, 70 parts, 71 Part, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78 parts, 79 parts or 80 parts etc..
In the B component mass fraction of oxidant can be 20 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 22.5 parts, 23 parts, 23.5 parts, 24 parts, 24.5 parts or 25 parts etc..
In the B component mass fraction of filler can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 Part or 5 parts etc..
As the preferred technical solution of the present invention, the acrylate monomer is selected from methyl methacrylate, metering system One kind in acid butyl ester, hydroxyethyl methacrylate, hydroxy propyl methacrylate or methacrylic acid or at least two combination； The combination is typical but non-limiting examples have：The combination of methyl methacrylate and butyl methacrylate, methacrylic acid The combination of methyl esters and hydroxyethyl methacrylate, the combination of methyl methacrylate and hydroxy propyl methacrylate, metering system The combination of sour methyl esters and methacrylic acid, the combination of butyl methacrylate and hydroxyethyl methacrylate, methacrylic acid fourth The combination of ester and methacrylic acid, the combination of hydroxyethyl methacrylate and hydroxy propyl methacrylate, hydroxyethyl methacrylate second The combination etc. of ester and methacrylic acid.
Preferably, the one kind of the elastomeric toughening agent in neoprene, nitrile rubber, butadiene-styrene rubber or polyether rubber Or at least two combination；The combination is typical but non-limiting examples have：The combination of neoprene and nitrile rubber, neoprene rubber The combination of glue and butadiene-styrene rubber, the combination of neoprene and polyether rubber, nitrile rubber and butadiene-styrene rubber combination, nitrile rubber The combination etc. of combination, butadiene-styrene rubber and polyether rubber with polyether rubber.
As the preferred technical solution of the present invention, the reducing agent is selected from N- methyl-N- ethoxys-para-totuidine, N, N- Dimethyl-p-toluidine or N, one kind in accelerine or at least two combination；The combination is typical but non-limiting Example has：Combination, the N of N- methyl-N- ethoxys-para-totuidine and N, N- dimethyl-p-toluidine, N- dimethyl-p-toluidines And N, the combination of accelerine, N, accelerine and N- methyl-N- ethoxys-combination of para-totuidine, N- methyl- N- ethoxys-para-totuidine and N, N- dimethyl-p-toluidine and N, the combination etc. of accelerine three.
Preferably, the polymerization inhibitor is selected from 1,4-benzoquinone, hydroquinone, p methoxy phenol or 2,6-di-tert-butyl p-cresol In one kind or at least two combination；The combination is typical but non-limiting examples have：The combination of 1,4-benzoquinone and hydroquinone, Combination, 1,4-benzoquinone and the DBPC 2,6 ditertiary butyl p cresol of 1,4-benzoquinone and p methoxy phenol, hydroquinone and p methoxy phenol Combination, the combination of hydroquinone and DBPC 2,6 ditertiary butyl p cresol, p methoxy phenol and DBPC 2,6 ditertiary butyl p cresol Combination etc..
As the preferred technical solution of the present invention, the oxidant is selected from dibenzoyl peroxide, benzoyl peroxide uncle One kind in butyl ester or methyl ethyl ketone peroxide or at least two combination；The combination is typical but non-limiting examples have：Peroxide Change the combination of dibenzoyl and the benzoyl peroxide tert-butyl ester, the combination of the benzoyl peroxide tert-butyl ester and methyl ethyl ketone peroxide, Combination, dibenzoyl peroxide and the benzoyl peroxide tert-butyl ester of methyl ethyl ketone peroxide and dibenzoyl peroxide and peroxidating The combination etc. of methyl ethyl ketone three.
Oxidant is used to constitute redox system with reducing agent, causes the polymerisation of adhesive, reaches bond effect. The present invention mixes oxidant with epoxy resin, solves the problems, such as that peroxide is inflammable and explosive, reduces the danger of oxidant Property；Specific proportioning makes B component have suitable viscosity, to adapt to be used cooperatively with glue rifle.
As the preferred technical solution of the present invention, the filler includes silica and/or aluminium hydroxide.
As the preferred technical solution of the present invention, the component A further includes 2-5 parts of auxiliary agents.
Preferably, the auxiliary agent includes one kind in coupling agent, ultra-violet absorber or light stabilizer or at least two Combination.
Preferably, the component A further includes color.
Color is added in component A, adhesive provided by the invention can be adjusted according to the color of the base material docked Color, the volume ratio between component A and B component is about 10 when in use:1, it, will not after mixing since B component content is less The color of adhesive entirety is impacted, it is ensured that adhesive is consistent with substrate color, visually reaches slitless connection Effect.
As the preferred technical solution of the present invention, the coupling agent be selected from propyl methacrylate base trimethoxy silane, ('beta '-methoxy ethyoxyl) silane of vinyl three or one kind in γ-aminopropyltrimethoxysilane or at least two combination； The combination is typical but non-limiting examples have：Three ('beta '-methoxy of propyl methacrylate base trimethoxy silane and vinyl Ethyoxyl) combination of silane, the combination of ('beta '-methoxy ethyoxyl) silane of vinyl three and γ-aminopropyltrimethoxysilane, The combination of γ-aminopropyltrimethoxysilane and combination, the methacrylic acid third of propyl methacrylate base trimethoxy silane Ester group trimethoxy silane and the group of ('beta '-methoxy ethyoxyl) silane of vinyl three and γ-aminopropyltrimethoxysilane three Close etc..
As the preferred technical solution of the present invention, the ultra-violet absorber is selected from 2'- (2'- hydroxyl -3'- tertiary butyls - 5'- aminomethyl phenyls) -5- chlorobenzotriazoles, 2-hydroxy-4-n-octoxybenzophenone or (2- hydroxy-4-methoxyphenyls) phenyl One kind in ketone or at least two combination；The combination is typical but non-limiting examples have：2'- (the tertiary fourths of 2'- hydroxyls -3'- Base -5'- aminomethyl phenyls) -5- chlorobenzotriazoles and 2-hydroxy-4-n-octoxybenzophenone combination, the just pungent oxygen of 2- hydroxyls -4- The combination, (2- hydroxy-4-methoxyphenyls) phenyl ketone and 2'- of base benzophenone and (2- hydroxy-4-methoxyphenyls) phenyl ketone The combination of (2'- hydroxyl -3'- tertiary butyl -5'- aminomethyl phenyls) -5- chlorobenzotriazoles, 2'- (2'- hydroxyl -3'- tertiary butyls -5'- Aminomethyl phenyl) -5- chlorobenzotriazoles and 2-hydroxy-4-n-octoxybenzophenone and (2- hydroxy-4-methoxyphenyls) phenyl ketone The combination etc. of three.
As the preferred technical solution of the present invention, the light stabilizer is hindered amine light stabilizer.
On the other hand, the present invention provides a kind of application method of above-mentioned adhesive, and the application method is as follows：
The component A and the B component are packaged in respectively in the container with two chambers according to the ratio, the container Exit has static mixing tube, is squeezed out the component A and the B component using glue rifle, and in the static mixing tube Mixing, is then coated on the discharge surface of plugging into of base material to be spliced, cures at 5-45 DEG C.
It should be noted that the volumetric ratio between the two chambers of the container is according to the quality between component A and B component Than determination, that is, when ensureing that two chambers are filled, the mass ratio between component A and B component is equal to default proportioning.When use glue rifle will When component A and B component squeeze out, the two can preset proportioning and be mixed in static mixing tube.Component is measured due to being not necessarily to scene It is allocated, therefore burden control is more accurate, and safety easy to operate, environmental pollution are small.
As the preferred technical solution of the present invention, the base material is artificial stone or quartz, preferably quartz.
Compared with prior art, the invention has the advantages that：
Adhesive provided by the invention has stronger adhesion strength for artificial stone or quartz (especially quartz) (35-37MPa), and color inhibition, it is pollution-free, it is non-toxic, it can be used for the splicing of artificial stone or quartz.Using the envelope of fixed mixing ratio Closure assembly is closed glue rifle and is used, and proportioning is more accurate, improves safety of adhesive during storage, transport and use, Reduce environmental pollution.
Specific implementation mode
The technical solution further illustrated the present invention below by specific embodiment.Those skilled in the art should be bright , the embodiment, which is only to aid in, understands the present invention, should not be regarded as a specific limitation of the invention.
Embodiment 1
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 40 Part, 35 parts of methyl methacrylate, 3 parts of urethane acrylate, 5 parts of neoprene, 20 parts of silica, N- methyl-N- hydroxyls 0.5 part of 2 parts of ethyl-para-totuidine and 1,4-benzoquinone；
B component includes：65 parts of epoxy resin, 25 parts of dibenzoyl peroxide and silica 1 part；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
Embodiment 2
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 45 Part, 32 parts of butyl methacrylate, 4 parts of urethane acrylate, 4 parts of nitrile rubber, 18 parts of aluminium hydroxide, N, N- dimethyl pair 0.1 part of 1 part of toluidines and hydroquinone；
B component includes：2 parts of 68 parts of epoxy resin, 24 parts of the benzoyl peroxide tert-butyl ester and aluminium hydroxide；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
Embodiment 3
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 50 Part, 30 parts of hydroxyethyl methacrylate, 5 parts of urethane acrylate, 3.5 parts of butadiene-styrene rubber, 2 parts of silica 1, N, N- diformazans 1 part of 3 parts of base aniline and p methoxy phenol；
B component includes：3 parts of 70 parts of epoxy resin, 23 parts of methyl ethyl ketone peroxide and silica；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
Embodiment 4
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 55 Part, 28 parts of hydroxy propyl methacrylate, 6 parts of urethane acrylate, 3 parts of polyether rubber, 15 parts of aluminium hydroxide, N- methyl-N- 1 part of ethoxy-para-totuidine, 0.3 part of DBPC 2,6 ditertiary butyl p cresol, 1 part of propyl methacrylate base trimethoxy silane, 1 part of 1 part of 2'- (2'- hydroxyl -3'- tertiary butyl -5'- aminomethyl phenyls) -5- chlorobenzotriazoles and hindered amine light stabilizer；
B component includes：4 parts of 73 parts of epoxy resin, 22 parts of the benzoyl peroxide tert-butyl ester and aluminium hydroxide；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
Embodiment 5
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 60 Part, 26 parts of methacrylic acid, 7 parts of urethane acrylate, 2 parts of neoprene, 3 parts of silica 1, N, N- dimethyl is to toluene 2.5 parts of amine, 0.8 part of 1,4-benzoquinone, 2 parts of vinyl three ('beta '-methoxy ethyoxyl) silane and 2- hydroxyl -4- n-octyloxy hexichol first 0.5 part of ketone；
B component includes：5 parts of 76 parts of epoxy resin, 21 parts of dibenzoyl peroxide and silica；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
Embodiment 6
A kind of adhesive, including component A and B component, according to the mass fraction, component A includes：Polymethyl methacrylate 65 Part, 25 parts of methyl methacrylate, 8 parts of urethane acrylate, 1 part of nitrile rubber, 10 parts of aluminium hydroxide, N, N- dimethyl benzenes 1.5 parts of amine, 0.5 part of hydroquinone, 1.5 parts of γ-aminopropyltrimethoxysilane and (2- hydroxy-4-methoxyphenyls) phenyl ketone 1.5 part；
B component includes：5 parts of 80 parts of epoxy resin, 20 parts of methyl ethyl ketone peroxide and aluminium hydroxide；
Volume ratio between component A and B component is 10:1, weight ratio 10:0.9-1.2.
The container with A, B two chambers is selected, by the component A of above-described embodiment 1-6 adhesive provided and B component point It is not packaged in A chambers and B chambers, the volumetric ratio between A chambers and B chambers is 10:1, using glue rifle by component A and B component It squeezes out, and is mixed in the static mixing tube of container exit, be then coated on the discharge surface of plugging into of two pieces of quartzite slates, glue It connects and stands solidification after fixing at 5-45 DEG C.The adhesion strength between quartzite slate is measured, as a result as shown in table 1 below.
Table 1
Embodiment 1 2 3 4 5 6
Adhesion strength (MPa) 35 35.5 36 35.8 36.5 36.8
Applicant states, the foregoing is merely the specific implementation mode of the present invention, but protection scope of the present invention not office It is limited to this, person of ordinary skill in the field is it will be clearly understood that any belong to those skilled in the art and taken off in the present invention In the technical scope of dew, the change or replacement that can be readily occurred in are all fallen within protection scope of the present invention and the open scope.

Claims (10)

1. a kind of adhesive, which is characterized in that the adhesive includes component A and B component, according to the mass fraction, the component A Including：40-65 parts of polymethyl methacrylate, 25-35 parts of acrylate monomer, 3-8 parts of urethane acrylate, elastic toughening 0.1-1 parts of 1-5 parts of agent, 10-20 parts of filler, 1-3 parts of reducing agent and polymerization inhibitor；
The B component includes：1-5 parts of 65-80 parts of epoxy resin, 20-25 parts of oxidant and filler；
Mass ratio between the component A and the B component is 10:0.9-1.2.
2. adhesive according to claim 1, which is characterized in that the acrylate monomer is selected from methyl methacrylate One kind in ester, butyl methacrylate, hydroxyethyl methacrylate, hydroxy propyl methacrylate or methacrylic acid or at least Two kinds of combination；
Preferably, one kind in neoprene, nitrile rubber, butadiene-styrene rubber or polyether rubber of the elastomeric toughening agent or extremely Few two kinds of combination.
3. adhesive according to claim 1 or 2, which is characterized in that the reducing agent is selected from N- methyl-N- ethoxys- Para-totuidine, N, N- dimethyl-p-toluidines or N, one kind in accelerine or at least two combination；
Preferably, the polymerization inhibitor is in 1,4-benzoquinone, hydroquinone, p methoxy phenol or 2,6-di-tert-butyl p-cresol It is a kind of or at least two combination.
4. according to claim 1-3 any one of them adhesive, which is characterized in that the oxidant is selected from diphenyl peroxide first Acyl, the benzoyl peroxide tert-butyl ester or one kind in methyl ethyl ketone peroxide or at least two combination；
Preferably, the filler includes silica and/or aluminium hydroxide.
5. according to claim 1-4 any one of them adhesive, which is characterized in that the component A further includes 2-5 parts of auxiliary agents；
Preferably, the auxiliary agent includes one kind in coupling agent, ultra-violet absorber or light stabilizer or at least two combination；
Preferably, the component A further includes color.
6. adhesive according to claim 5, which is characterized in that the coupling agent is selected from propyl methacrylate base front three Oxysilane, ('beta '-methoxy ethyoxyl) silane of vinyl three or one kind in γ-aminopropyltrimethoxysilane or at least two The combination of kind.
7. adhesive according to claim 5 or 6, which is characterized in that the ultra-violet absorber is selected from 2'- (2'- hydroxyls Base -3'- tertiary butyl -5'- aminomethyl phenyls) -5- chlorobenzotriazoles, 2-hydroxy-4-n-octoxybenzophenone or (2- hydroxyls -4- Anisyl) one kind in phenyl ketone or at least two combination.
8. according to claim 5-7 any one of them adhesive, which is characterized in that the light stabilizer is that hindered amines light is steady Determine agent.
9. according to the application method of claim 1-8 any one of them adhesive, which is characterized in that the application method is such as Under：
The component A and the B component are packaged in respectively in the container with two chambers according to the ratio, the outlet of the container Place has static mixing tube, is squeezed out the component A and the B component using glue rifle, and mixed in the static mixing tube, Then it is coated on the discharge surface of plugging into of base material to be spliced, is cured at 5-45 DEG C.
10. application method according to claim 9, which is characterized in that the base material be artificial stone or quartz, preferably Quartz.
CN201810113802.1A 2018-02-05 2018-02-05 A kind of adhesive and its application method Pending CN108314980A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810113802.1A CN108314980A (en) 2018-02-05 2018-02-05 A kind of adhesive and its application method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810113802.1A CN108314980A (en) 2018-02-05 2018-02-05 A kind of adhesive and its application method

Publications (1)

Publication Number Publication Date
CN108314980A true CN108314980A (en) 2018-07-24

Family

ID=62901907

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810113802.1A Pending CN108314980A (en) 2018-02-05 2018-02-05 A kind of adhesive and its application method

Country Status (1)

Country Link
CN (1) CN108314980A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971371A (en) * 2019-03-25 2019-07-05 上海科秀新材料科技有限公司 A kind of metacrylic acid ester structure glue and preparation method thereof
CN111394013A (en) * 2020-03-14 2020-07-10 拓迪化学(上海)有限公司 Bi-component structural adhesive capable of being subjected to nondestructive testing, preparation method and application thereof, and electronic product
CN112209654A (en) * 2020-10-15 2021-01-12 吉林大学 Composite repairing agent and preparation method and application thereof
US10988640B2 (en) * 2017-06-02 2021-04-27 Lg Chem, Ltd. Two-component adhesive composition
JP2021531389A (en) * 2018-07-25 2021-11-18 ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング Fast Curing Epoxy Acrylic Liquid Sim

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102115641A (en) * 2010-12-03 2011-07-06 烟台德邦科技有限公司 High-toughness acrylate structural adhesive and preparation method thereof
CN102898963A (en) * 2012-10-18 2013-01-30 上海康达化工新材料股份有限公司 Acrylate structure adhesive and preparation method thereof
CN103087639A (en) * 2011-10-31 2013-05-08 北京天山新材料技术股份有限公司 Waterproof dual-component acrylate adhesive and its preparation method
CN106634641A (en) * 2017-01-04 2017-05-10 烟台信友新材料股份有限公司 Double-component crylic acid adhesive and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102115641A (en) * 2010-12-03 2011-07-06 烟台德邦科技有限公司 High-toughness acrylate structural adhesive and preparation method thereof
CN103087639A (en) * 2011-10-31 2013-05-08 北京天山新材料技术股份有限公司 Waterproof dual-component acrylate adhesive and its preparation method
CN102898963A (en) * 2012-10-18 2013-01-30 上海康达化工新材料股份有限公司 Acrylate structure adhesive and preparation method thereof
CN106634641A (en) * 2017-01-04 2017-05-10 烟台信友新材料股份有限公司 Double-component crylic acid adhesive and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10988640B2 (en) * 2017-06-02 2021-04-27 Lg Chem, Ltd. Two-component adhesive composition
JP2021531389A (en) * 2018-07-25 2021-11-18 ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング Fast Curing Epoxy Acrylic Liquid Sim
JP7259006B2 (en) 2018-07-25 2023-04-17 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン Fast curing epoxy acrylic liquid shim
CN109971371A (en) * 2019-03-25 2019-07-05 上海科秀新材料科技有限公司 A kind of metacrylic acid ester structure glue and preparation method thereof
CN109971371B (en) * 2019-03-25 2021-07-06 上海科秀新材料科技有限公司 Methacrylate structural adhesive and preparation method thereof
CN111394013A (en) * 2020-03-14 2020-07-10 拓迪化学(上海)有限公司 Bi-component structural adhesive capable of being subjected to nondestructive testing, preparation method and application thereof, and electronic product
CN111394013B (en) * 2020-03-14 2022-01-07 拓迪化学(上海)有限公司 Bi-component structural adhesive capable of being subjected to nondestructive testing, preparation method and application thereof, and electronic product
CN112209654A (en) * 2020-10-15 2021-01-12 吉林大学 Composite repairing agent and preparation method and application thereof
CN112209654B (en) * 2020-10-15 2021-09-17 吉林大学 Composite repairing agent and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN108314980A (en) A kind of adhesive and its application method
CA2894159C (en) Coating compositions for food and beverage containers
CA2650897C (en) Microspheres as thickening agents for organic peroxides
CA2824859C (en) Low temperature curable adhesive compositions
MXPA02004370A (en) Two-part structural adhesive having long working time.
CN101555382A (en) Scratch-resistant UV-finishing coat
CN104087127A (en) Ultraviolet curing antique roller coating matt base coat and preparation method thereof
CN102965059A (en) Polymeric solid wood splicing glue
US20150020965A1 (en) Low Temperature Curable Adhesive Compositions
JP6985055B2 (en) Adhesive for building structures
JP5556118B2 (en) Curable (meth) acrylic resin composition, laminate intermediate film and laminate
CN108285508B (en) Medium-high viscosity emulsion type acrylate pressure-sensitive adhesive for protective film, and preparation method and application thereof
JP2014196409A (en) Active energy ray-curable aqueous resin composition, active energy ray-curable aqueous coating, article applied with the coating
CN107955466A (en) A kind of self-drying type packaging protecting peelable blue gel and preparation method thereof
KR102239799B1 (en) Adhesive composition for artificial marble
CA2828025A1 (en) Additive for increasing toughness of marble glue
WO2013069441A1 (en) Resin composition for pressure vessels, and pressure vessel
CN107384108A (en) A kind of thick coated type epoxy anti-corrosive primer
JP7332378B2 (en) Composition and repair method
JP6238230B2 (en) Two-component mixed adhesive
CN106752238A (en) A kind of alloy fiber atomized ash and preparation method thereof
CN108913067B (en) Continuous production process of environment-friendly adhesive
JP5319957B2 (en) Resin composition
CN110204647B (en) Tearable film thermoplastic acrylic resin and preparation method thereof
CN106566307A (en) Lightweight multifunctional putty and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180724

RJ01 Rejection of invention patent application after publication