CN108314431A - Composite ceramics prefabricated component and preparation method thereof - Google Patents

Composite ceramics prefabricated component and preparation method thereof Download PDF

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Publication number
CN108314431A
CN108314431A CN201810272248.1A CN201810272248A CN108314431A CN 108314431 A CN108314431 A CN 108314431A CN 201810272248 A CN201810272248 A CN 201810272248A CN 108314431 A CN108314431 A CN 108314431A
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parts
granularity
mullite
prefabricated component
composite ceramics
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CN108314431B (en
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王伟
赵振江
冯晓磊
徐建民
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Henan Ant New Materials Co Ltd
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Henan Ant New Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite

Abstract

A kind of composite ceramics prefabricated component, high-performance micro-crystalline ceramic glaze including heat resisting ceramic body and surface recombination, the heat resisting ceramic body is by bauxite chamotte I, bauxite chamotte II, mullite gives up brick, cordierite, vitreous silica, silicon powder, high alumina cement is made, high-performance micro-crystalline ceramic glaze is by petalite, lepidolite, potassium feldspar, soft kaolin, calcined kaolin, wollastonite, burn talcum, quartz, barium carbonate, zirconium oxide is made, compared with the existing technology, composite ceramics prefabricated component of the present invention has high-performance micro-crystalline ceramic glaze because of surface recombination, dirt is not hung during use, easy to clean, later maintenance cost can be greatly lowered, thermal coefficient is lower, with better heat insulation effect, compared to traditional material, 20 ~ 30 DEG C can be reduced using position alien invasion temperature.

Description

Composite ceramics prefabricated component and preparation method thereof
Technical field
The present invention relates to ceramic processing technique fields, and in particular to a kind of composite ceramics prefabricated component, especially one kind have Thermal conductivity is low, long-lived, wear-resisting and self-cleaning property ceramic preform.
Background technology
Currently, the positions such as traditional coke oven door and tedge are by small-sized clay or Jin Celadon stone laying fireproof bricks It forms, since there are many puzzle joint, is easy product coke, carbon distribution at puzzle joint in use, with being repeated for reaction, puzzle joint holds very much Easily it is extended, with the expansion of puzzle joint, the closed and heat-insulating property rapid decrease of fire door runs cigarette, runs dirt, oozes coke thereupon, Not only it had caused environmental pollution but also had wasted the energy.Moreover, the mechanical strength and thermal shock performance of traditional fire door material are poor, the longevity is used Life do not grow, later maintenance is frequent, and the tar and dust being attached on fire door are difficult to clean up, need continual input manpower, Material resources are safeguarded that later maintenance is costly.
Traditional tedge, lower part use clay or the small brick masonry of cordierite, top bridge tube to use cast iron pipe more more, and there are the longevity It orders short, closed and poor thermal insulation property, be easy the problems such as coking and carbon distribution, both be easy to cause gas leak, pollute environment, and exist Security risk, later maintenance is difficult, and maintenance cost is higher.
Traditional stoke hole mostly uses clinker tile, and heat insulation is very poor, and energy waste is serious, and is easy after a period of use viscous Coking oil is degrading the working environment of furnace roof, causes environmental pollution to cause closed not tight, run away with fire and sparkling etc..
Invention content
In view of the above technical problems, the present invention provides a kind of composite ceramics prefabricated component, has better heat-insulating property, wear-resisting Performance, long-lived performance and self-cleaning property.
Technical scheme of the present invention is specially:
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, described heat-resisting Ceramic body is made of the raw material of following parts by weight:I 8~21 parts of bauxite chamotte, II 19~29 parts of bauxite chamotte, not Come useless 18~28 parts of the brick of stone, 5~15 parts of cordierite, 10~20 parts of vitreous silica, 5~15 parts of silicon powder, high alumina cement 3~10 Part;
I granularity of the bauxite chamotte is 5~8mm, and II granularity of bauxite chamotte is 3~5mm;
The high-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10~30 parts of petalite, lepidolite 5~15 Part, 5~15 parts of potassium feldspar, 3~8 parts of soft kaolin, 5~10 parts of calcined kaolin, 1~10 part of wollastonite, burning talcum 6~18 Part, 7~20 parts of quartz, 1~6 part of barium carbonate, 1~8 part of zirconium oxide.
The bauxite chamotte is GL-88A bauxite chamottes, and the useless brick granularity of mullite is 1~3mm, cordierite grain Degree is 0~1mm, and vitreous silica granularity is 0.088mm, and high alumina cement is CA-70 high alumina cements.
The mullite gives up brick as mullite firebrick waste product, will use jaw crusher after mullite firebrick waste recovery It is crushed to 30~80mm, then with the particle that cone crushing to granularity is 0~8mm, magnetic separator uses classifying screen after removing iron Screening obtains the particle that granularity is 1~3mm.
The calcined kaolin contains Fe2O3, Al2O3, SiO2, burns talcum and contains Fe2O3, MgO and CaO.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix, according to the proportioning of heat resisting ceramic body, add raw materials into planetary stirring machine premix 5~ 8min;
Step 2:Wet mixing, be added in pre- mixed heat resisting ceramic body premix into step 1 7%~9% it is clean from Water, 3~5min of mixed grind;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance are demoulded after molding green body stands 5~7h in step 3, will be molding after demoulding Green body is placed on 48~72h of maintenance in 20~30 DEG C of fog room;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, naturally cool to room temperature after the completion of dry;
Step 6:Enamel frit makeing, according to the proportioning of high-performance micro-crystalline ceramic glaze, by the glaze prepared be put into grinding 18 in ball mill~ 24h;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion.
Compared with the existing technology, technique effect of the invention is,
1, composite ceramics prefabricated component has a high-performance micro-crystalline ceramic glaze because of surface recombination, does not hang dirt during use, easy to clean, after Phase maintenance cost can be greatly lowered.
2, composite ceramics prefabricated component thermal coefficient is lower, and there is better heat insulation effect to use portion compared to traditional material Position alien invasion temperature can reduce by 20 ~ 30 DEG C.
3, compared with prior art, difficulty of construction is lower, more efficient, and construction efficiency can be improved for composite ceramics prefabricated component.
4, the use of composite ceramics prefabricated component can reduce fire door thickness at coke oven door position, and it is empty to increase coke furnace carbonization chamber Between, by taking 6 meters of coke ovens of JN60 types in a hole 2*55 as an example, ten thousand tons of coke of 1.2-1.5/annual can be increased production.
5, composite ceramics prefabricated component can be improved 2 ~ 3 times compared to traditional material service life.
Specific implementation mode
GL-88A bauxite chamottes, cordierite in the present invention are purchased from Henan RongAn Heat Engineering New Material Co., Ltd., melt Fused silica is purchased from Lianyun Harbour Tao Sheng vitreous silicas Co., Ltd, and silicon powder is purchased from Zhengzhou City Shangjie District Samsung micro mist factory, CA-70 high Aluminum water mud Zhengzhou Dengfeng Smelting Materials Co., Ltd., petalite, lepidolite, potassium feldspar, soft kaolin, calcined kaolin, silicon ash Stone, burning talcum, quartz, barium carbonate, zirconium oxide are purchased from Jiangsu Province Ceramics Institute Co., Ltd.
Embodiment 1
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, heat-stable ceramic Green body is made of the raw material of following parts by weight:I 8~21 parts of GL-88A bauxite chamottes, granularity are 5~8mm, GL-88A high aluminas II 19~29 parts of bauxite clinker, granularity are 3~5mm, and mullite give up 18~28 parts of brick, and granularity is 1~3mm, cordierite 5~15 Part, granularity be 0~1mm, 10~20 parts, granularity 0.088mm of vitreous silica, 5~15 parts of silicon powder, CA-70 high alumina cements 3~ 10 parts.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10~30 parts of petalite, lepidolite 5~15 Part, 5~15 parts of potassium feldspar, 3~8 parts of soft kaolin, 5~10 parts of calcined kaolin, 1~10 part of wollastonite, burning talcum 6~18 Part, 7~20 parts of quartz, 1~6 part of barium carbonate, 1~8 part of zirconium oxide, calcined kaolin contains Fe2O3、Al2O3、SiO2, burn talcum Contain Fe2O3, MgO and CaO.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix, according to the proportioning of heat resisting ceramic body, add raw materials into planetary stirring machine premix 5~ 8min;
Step 2:Pre- mixed heat resisting ceramic body premix in step 1 is added in planetary stirring machine, adds by wet mixing Enter 7%~9% clean tap water, 3~5min of mixed grind waits for material after mixing, you can discharging carries out vibration pouring molding;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance are demoulded after molding green body stands 5~7h in step 3, will be molding after demoulding Green body is placed on 48~72h of maintenance in 20~30 DEG C of fog room;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, is risen according to drying curve in table 1 Temperature is dry, as shown in table 1, after being warming up to 60 DEG C in shuttle kiln, keeps the temperature 4h, within the temperature range of 60 DEG C -120 DEG C, with The rate of average 15 DEG C/h heats up, and 10h is kept the temperature after being warming up to 120 DEG C, within the temperature range of 120 DEG C -180 DEG C, with flat The rate of equal 10 DEG C/h heats up, and 10h is kept the temperature after being warming up to 180 DEG C, within the temperature range of 180 DEG C -250 DEG C, with average The rate of 14 DEG C/h heats up, and 5h is kept the temperature after being warming up to 250 DEG C, within the temperature range of 250 DEG C -300 DEG C, with average 25 DEG C/rate of h heats up, 2h is kept the temperature after reaching 300 DEG C, within the temperature range of 300 DEG C -450 DEG C, with average 30 DEG C/h's Rate heats up, and 3h is kept the temperature after being warming up to 450 DEG C, room temperature is naturally cooled to after the completion of dry;
Step 6:Enamel frit makeing, according to the proportioning of high-performance micro-crystalline ceramic glaze, by the glaze prepared be put into grinding 18 in ball mill~ 24h;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to shown in table 2 It is burnt at curve, after being warming up to 450 DEG C in shuttle kiln, keeps the temperature 4h, within the temperature range of 450 DEG C -600 DEG C, with flat The rate of equal 30 DEG C/h heats up, and 4h is kept the temperature after being warming up to 600 DEG C, within the temperature range of 600 DEG C -800 DEG C, with average 40 DEG C/rate of h heats up, keep the temperature 4h after being warming up to 800 DEG C, within the temperature range of 800 DEG C -1000 DEG C, with it is 40 DEG C average/ The rate of h heats up, and 1h is kept the temperature after being warming up to 1000 DEG C, within the temperature range of 1000 DEG C -1300 DEG C, with average 30 DEG C/h Rate heat up, 4h is kept the temperature after reaching 1300 DEG C, within the temperature range of 1300 DEG C -1380 DEG C, with average 20 DEG C/h's Rate heats up, and 2h is kept the temperature after being warming up to 1380 DEG C, room temperature is naturally cooled to after the completion of heating;
Step 9:Kiln discharge sorts, and is sorted to burned product, and reject defective work.
Table 1
Table 2
Embodiment 2
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, heat-stable ceramic Green body is made of the raw material of following parts by weight:I 15 parts of GL-88A bauxite chamottes, granularity 5mm, GL-88A alumine are ripe Expect II 25 parts, granularity 3mm, mullite gives up 25 parts, granularity 2mm of brick, 10 parts, granularity 1mm of cordierite, vitreous silica 10 Part, granularity 0.088mm, 10 parts of silicon powder, 5 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:27 parts of petalite, 10 parts of lepidolite, potassium is long 5 parts of stone, 5 parts of soft kaolin, 8 parts of calcined kaolin, 4 parts of wollastonite burn 12 parts of talcum, 15 parts of quartz, 4 parts of barium carbonate, oxygen Change 6 parts of zirconium, calcined kaolin contains Fe2O3、Al2O3、SiO2, burn talcum and contain Fe2O3, MgO and CaO.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix add raw materials into according to the proportioning of heat resisting ceramic body and premix 5min in planetary stirring machine;
Step 2:Pre- mixed heat resisting ceramic body premix in step 1 is added in planetary stirring machine, adds by wet mixing Enter 7% clean tap water, mixed grind 5min waits for material after mixing, you can discharging carries out vibration pouring molding;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance have poured the heat resisting ceramic body finished after molding green body stands 6h in step 3 With the intensity needed for demoulding, is demoulded, after demoulding, molding green body is placed in 25 DEG C of fog room and conserves 48h;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, room temperature is naturally cooled to after the completion of dry, drying curve is identical as the drying curve of table 1 in embodiment 1;
Step 6:The glaze prepared is put into ball mill according to the proportioning of high-performance micro-crystalline ceramic glaze and grinds 20h by enamel frit makeing;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion, and sintering curve is identical as the sintering curve of table 2 in embodiment 1;
Step 9:Kiln discharge sorts, and is sorted to burned product, and reject defective work.
Embodiment 3
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, heat-stable ceramic Green body is made of the raw material of following parts by weight:I 8 parts of GL-88A bauxite chamottes, granularity 6mm, GL-88A alumine are ripe Expect II 19 parts, granularity 4mm, mullite gives up 20 parts, granularity 3mm of brick, 12 parts, granularity 0.5mm of cordierite, vitreous silica 15 Part, granularity 0.088mm, 8 parts of silicon powder, 7 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:20 parts of petalite, 15 parts of lepidolite, potassium is long 9 parts of stone, 3 parts of soft kaolin, 5 parts of calcined kaolin, 7 parts of wollastonite burn 9 parts of talcum, 20 parts of quartz, 3 parts of barium carbonate, oxidation 4 parts of zirconium, calcined kaolin contains Fe2O3、Al2O3、SiO2, burn talcum and contain Fe2O3, MgO and CaO.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix add raw materials into according to the proportioning of heat resisting ceramic body and premix 8min in planetary stirring machine;
Step 2:Pre- mixed heat resisting ceramic body premix in step 1 is added in planetary stirring machine, adds by wet mixing Enter 9% clean tap water, mixed grind 4min waits for material after mixing, you can discharging carries out vibration pouring molding;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance have poured the heat resisting ceramic body finished after molding green body stands 7h in step 3 With the intensity needed for demoulding, is demoulded, after demoulding, molding green body is placed in 20 DEG C of fog room and conserves 60h;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, room temperature is naturally cooled to after the completion of dry, drying curve is identical as the drying curve of table 1 in embodiment 1;
Step 6:The glaze prepared is put into ball mill according to the proportioning of high-performance micro-crystalline ceramic glaze and grinds 20h by enamel frit makeing;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion, and sintering curve is identical as the sintering curve of table 2 in embodiment 1;
Step 9:Kiln discharge sorts, and is sorted to burned product, and reject defective work.
Embodiment 4
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, heat-stable ceramic Green body is made of the raw material of following parts by weight:I 21 parts of GL-88A bauxite chamottes, granularity 7mm, GL-88A alumine are ripe Expect II 29 parts, granularity 5mm, mullite gives up 18 parts, granularity 1mm of brick, 5 parts, granularity 0.8mm of cordierite, vitreous silica 20 Part, granularity 0.088mm, 15 parts of silicon powder, 3 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10 parts of petalite, 5 parts of lepidolite, potassium is long 15 parts of stone, 8 parts of soft kaolin, 10 parts of calcined kaolin, 1 part of wollastonite burn 6 parts of talcum, 7 parts of quartz, 1 part of barium carbonate, oxygen Change 8 parts of zirconium, calcined kaolin contains Fe2O3、Al2O3、SiO2, burn talcum and contain Fe2O3, MgO and CaO.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix add raw materials into according to the proportioning of heat resisting ceramic body and premix 6min in planetary stirring machine;
Step 2:Pre- mixed heat resisting ceramic body premix in step 1 is added in planetary stirring machine, adds by wet mixing Enter 8% clean tap water, mixed grind 3min waits for material after mixing, you can discharging carries out vibration pouring molding;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance have poured the heat resisting ceramic body finished after molding green body stands 5h in step 3 With the intensity needed for demoulding, is demoulded, after demoulding, molding green body is placed in 30 DEG C of fog room and conserves 72h;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, room temperature is naturally cooled to after the completion of dry, drying curve is identical as the drying curve of table 1 in embodiment 1;
Step 6:The glaze prepared is put into ball mill according to the proportioning of high-performance micro-crystalline ceramic glaze and grinds 20h by enamel frit makeing;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion, and sintering curve is identical as the sintering curve of table 2 in embodiment 1;
Step 9:Kiln discharge sorts, and is sorted to burned product, and reject defective work.
Embodiment 5
A kind of composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, heat-stable ceramic Green body is made of the raw material of following parts by weight:I 18 parts of GL-88A bauxite chamottes, granularity 6mm, GL-88A alumine are ripe Expect II 22 parts, granularity 4mm, mullite gives up 28 parts, granularity 2mm of brick, 15 parts, granularity 0.5mm of cordierite, vitreous silica 12 Part, granularity 0.088mm, 5 parts of silicon powder, 10 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:30 parts of petalite, 8 parts of lepidolite, potassium is long 12 parts of stone, 6 parts of soft kaolin, 5 parts of calcined kaolin, 10 parts of wollastonite burn 18 parts of talcum, 10 parts quartzy, 6 parts of barium carbonate, 1 part of zirconium oxide, calcined kaolin contains Fe2O3、Al2O3、SiO2, burn talcum and contain Fe2O3, MgO and CaO.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component, includes the following steps,
Step 1:Raw material premix add raw materials into according to the proportioning of heat resisting ceramic body and premix 7min in planetary stirring machine;
Step 2:Pre- mixed heat resisting ceramic body premix in step 1 is added in planetary stirring machine, adds by wet mixing Enter 9% clean tap water, mixed grind 5min waits for material after mixing, you can discharging carries out vibration pouring molding;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance have poured the heat resisting ceramic body finished after molding green body stands 6h in step 3 With the intensity needed for demoulding, is demoulded, after demoulding, molding green body is placed in 20 DEG C of fog room and conserves 54h;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, room temperature is naturally cooled to after the completion of dry, drying curve is identical as the drying curve of table 1 in embodiment 1;
Step 6:The glaze prepared is put into ball mill according to the proportioning of high-performance micro-crystalline ceramic glaze and grinds 20h by enamel frit makeing;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion, and sintering curve is identical as the sintering curve of table 2 in embodiment 1;
Step 9:Kiln discharge sorts, and is sorted to burned product, and reject defective work.
Embodiment 6
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 10 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 27 parts, granularity 3mm, mullite gives up 18 parts, granularity 2mm of brick, 9 parts, granularity 1mm of cordierite, 10 parts of vitreous silica, Granularity is 0.088mm, 10 parts of silicon powder, 8 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:25 parts of petalite, 15 parts of lepidolite, potassium is long 5 parts of stone, 8 parts of soft kaolin, 10 parts of calcined kaolin, 8 parts of wollastonite burn 18 parts of talcum, 10 parts of quartz, 2 parts of barium carbonate, oxygen Change 6 parts of zirconium.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component is in embodiment 2, and which is not described herein again.
Embodiment 7
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 12 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 20 parts, granularity 5mm, mullite gives up 22 parts, granularity 1mm of brick, 12 parts, granularity 0.5mm of cordierite, vitreous silica 20 Part, granularity 0.088mm, 5 parts of silicon powder, 10 parts of CA-70 high alumina cements.
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:30 parts of petalite, 8 parts of lepidolite, potassium is long 10 parts of stone, 6 parts of soft kaolin, 8 parts of calcined kaolin, 1 part of wollastonite burn 14 parts of talcum, 20 parts of quartz, 1 part of barium carbonate, oxygen Change 8 parts of zirconium.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component is in embodiment 3, and which is not described herein again.
Embodiment 8
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 15 parts of GL-88A bauxite chamottes, granularity 7mm, GL-88A alumine are ripe Expect II 28 parts, granularity 4mm, mullite gives up 28 parts, granularity 3mm of brick, 5 parts, granularity 0.8mm of cordierite, vitreous silica 15 Part, granularity 0.088mm, 13 parts of silicon powder, 3 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10 parts of petalite, 12 parts of lepidolite, potassium feldspar 8 Part, 3 parts of soft kaolin, 5 parts of calcined kaolin, 5 parts of wollastonite, 10 parts of talcum of burning, 15 parts of quartz, 4 parts of barium carbonate, zirconium oxide 1 part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
The preparation method of composite ceramics prefabricated component is in embodiment 4, and which is not described herein again.
Embodiment 9
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 20 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 24 parts, granularity 4mm, mullite gives up 26 parts, granularity 3mm of brick, 15 parts, granularity 0.6mm of cordierite, vitreous silica 18 Part, granularity 0.088mm, 15 parts of silicon powder, 6 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:18 parts of petalite, 5 parts of lepidolite, potassium feldspar 15 Part, 5 parts of soft kaolin, 5 parts of calcined kaolin, 10 parts of wollastonite, 6 parts of talcum of burning, 7 parts of quartz, 6 parts of barium carbonate, zirconium oxide 4 Part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 10
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 8 parts of GL-88A bauxite chamottes, granularity 5mm, GL-88A alumine are ripe Expect II 19 parts, granularity 3mm, mullite gives up 18 parts, granularity 1mm of brick, 5 parts, granularity 0.1mm of cordierite, vitreous silica 10 Part, granularity 0.088mm, 5 parts of silicon powder, 3 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10 parts of petalite, 5 parts of lepidolite, potassium feldspar 5 Part, 3 parts of soft kaolin, 5 parts of calcined kaolin, 1 part of wollastonite, 6 parts of talcum of burning, 7 parts of quartz, 1 part of barium carbonate, zirconium oxide 1 Part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 11
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 21 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 29 parts, granularity 5mm, mullite gives up 28 parts, granularity 3mm of brick, 15 parts, granularity 1mm of cordierite, vitreous silica 20 Part, granularity 0.088mm, 15 parts of silicon powder, 10 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:30 parts of petalite, 15 parts of lepidolite, potassium feldspar 15 Part, 8 parts of soft kaolin, 10 parts of calcined kaolin, 10 parts of wollastonite burns 18 parts of talcum, 20 parts quartzy, and 6 parts of barium carbonate aoxidizes 8 parts of zirconium.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 12
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 15 parts of GL-88A bauxite chamottes, granularity 6mm, GL-88A alumine are ripe Expect II 24 parts, granularity 4mm, mullite gives up 23 parts, granularity 2mm of brick, 10 parts, granularity 0.5mm of cordierite, vitreous silica 15 Part, granularity 0.088mm, 10 parts of silicon powder, 7 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:20 parts of petalite, 10 parts of lepidolite, potassium feldspar 10 Part, 5 parts of soft kaolin, 8 parts of calcined kaolin, 5 parts of wollastonite, 12 parts of talcum of burning, 14 parts of quartz, 3 parts of barium carbonate, zirconium oxide 4 parts.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 13
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 8 parts of GL-88A bauxite chamottes, granularity 5mm, GL-88A alumine are ripe Expect II 29 parts, granularity 5mm, mullite gives up 28 parts, granularity 2mm of brick, 10 parts, granularity 1mm of cordierite, vitreous silica 15 Part, granularity 0.088mm, 10 parts of silicon powder, 10 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:30 parts of petalite, 15 parts of lepidolite, potassium feldspar 10 Part, 5 parts of soft kaolin, 8 parts of calcined kaolin, 5 parts of wollastonite, 18 parts of talcum of burning, 14 parts of quartz, 6 parts of barium carbonate, zirconium oxide 4 parts.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 14
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 8 parts of GL-88A bauxite chamottes, granularity 5mm, GL-88A alumine are ripe Expect II 24 parts, granularity 4mm, mullite gives up 23 parts, granularity 3mm of brick, 15 parts, granularity 0.1mm of cordierite, vitreous silica 20 Part, granularity 0.088mm, 15 parts of silicon powder, 7 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:20 parts of petalite, 10 parts of lepidolite, potassium feldspar 15 Part, 8 parts of soft kaolin, 10 parts of calcined kaolin, 10 parts of wollastonite burns 12 parts of talcum, 20 parts quartzy, and 3 parts of barium carbonate aoxidizes 8 parts of zirconium.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 15
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 21 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 19 parts, granularity 3mm, mullite gives up 23 parts, granularity 1mm of brick, 10 parts, granularity 0.1mm of cordierite, vitreous silica 10 Part, granularity 0.088mm, 5 parts of silicon powder, 3 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10 parts of petalite, 5 parts of lepidolite, potassium feldspar 10 Part, 3 parts of soft kaolin, 5 parts of calcined kaolin, 5 parts of wollastonite, 6 parts of talcum of burning, 14 parts of quartz, 3 parts of barium carbonate, zirconium oxide 4 Part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 16
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 21 parts of GL-88A bauxite chamottes, granularity 8mm, GL-88A alumine are ripe Expect II 24 parts, granularity 4mm, mullite gives up 18 parts, granularity 2mm of brick, 5 parts, granularity 0.5mm of cordierite, vitreous silica 15 Part, granularity 0.088mm, 10 parts of silicon powder, 7 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:20 parts of petalite, 10 parts of lepidolite, potassium feldspar 5 Part, 5 parts of soft kaolin, 8 parts of calcined kaolin, 1 part of wollastonite, 12 parts of talcum of burning, 7 parts of quartz, 1 part of barium carbonate, zirconium oxide 1 Part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 17
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 15 parts of GL-88A bauxite chamottes, granularity 6mm, GL-88A alumine are ripe Expect II 19 parts, granularity 3mm, mullite gives up 18 parts, granularity 3mm of brick, 5 parts, granularity 1mm of cordierite, 10 parts of vitreous silica, Granularity is 0.088mm, 15 parts of silicon powder, 3 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:30 parts of petalite, 15 parts of lepidolite, potassium feldspar 5 Part, 8 parts of soft kaolin, 10 parts of calcined kaolin, 10 parts of wollastonite burns 6 parts of talcum, 20 parts quartzy, and 6 parts of barium carbonate aoxidizes 1 part of zirconium.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
Embodiment 18
Composite ceramics prefabricated component includes the high-performance micro-crystalline ceramic glaze of heat resisting ceramic body and surface recombination, the heat-stable ceramic Green body is made of the raw material of following parts by weight:I 15 parts of GL-88A bauxite chamottes, granularity 6mm, GL-88A alumine are ripe Expect II 29 parts, granularity 5mm, mullite gives up 28 parts, granularity 1mm of brick, 15 parts, granularity 0.5mm of cordierite, vitreous silica 20 Part, granularity 0.088mm, 5 parts of silicon powder, 10 parts of CA-70 high alumina cements;
High-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10 parts of petalite, 5 parts of lepidolite, potassium feldspar 15 Part, 3 parts of soft kaolin, 5 parts of calcined kaolin, 1 part of wollastonite, 18 parts of talcum of burning, 7 parts of quartz, 1 part of barium carbonate, zirconium oxide 8 Part.
Mullite gives up brick as mullite firebrick waste product, and jaw crushing crusher machine will be used after mullite firebrick waste recovery It is the particle of 0~8mm to 30~80mm, then with cone crushing to granularity, magnetic separator is screened after removing iron using classifying screen Obtain the particle that granularity is 1~3mm.
Composite ceramics prefabricated component is during the preparation method is the same as that of Example 1, and which is not described herein again.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those skilled in the art, Under the premise of not departing from general idea of the present invention, several changes and improvements can also be made, these should also be considered as the present invention's Protection domain.

Claims (5)

1. a kind of composite ceramics prefabricated component, it is characterised in that:It makes pottery including heat resisting ceramic body and the high-performance crystallite of surface recombination Enamel, the heat resisting ceramic body are made of the raw material of following parts by weight:I 8~21 parts of bauxite chamotte, bauxite chamotte II 19~29 parts, mullite gives up 18~28 parts of brick, 5~15 parts of cordierite, 10~20 parts of vitreous silica, 5~15 parts of silicon powder, high 3~10 parts of aluminum water mud;
I granularity of the bauxite chamotte is 5~8mm, and II granularity of bauxite chamotte is 3~5mm;
The high-performance micro-crystalline ceramic glaze is made of the raw material of following parts by weight:10~30 parts of petalite, lepidolite 5~15 Part, 5~15 parts of potassium feldspar, 3~8 parts of soft kaolin, 5~10 parts of calcined kaolin, 1~10 part of wollastonite, burning talcum 6~18 Part, 7~20 parts of quartz, 1~6 part of barium carbonate, 1~8 part of zirconium oxide.
2. composite ceramics prefabricated component as described in claim 1, it is characterised in that:The bauxite chamotte is GL-88A high aluminas Bauxite clinker, mullite give up brick granularity as 1~3mm, and cordierite granularity is 0~1mm, and vitreous silica granularity is 0.088mm, high alumina Cement is CA-70 high alumina cements.
3. composite ceramics prefabricated component as described in claim 1, it is characterised in that:The mullite gives up brick as mullite firebrick Waste product will be crushed to 30~80mm after mullite firebrick waste recovery with jaw crusher, then extremely with cone crushing Granularity is the particle of 0~8mm, and magnetic separator screens to obtain the particle that granularity is 1~3mm using classifying screen after removing iron.
4. composite ceramics prefabricated component as described in claim 1, it is characterised in that:The calcined kaolin contains Fe2O3、Al2O3、 SiO2, burn talcum and contain Fe2O3, MgO and CaO.
5. the preparation method of composite ceramics prefabricated component as described in claim 1, it is characterised in that:Include the following steps,
Step 1:Raw material premix, according to the proportioning of heat resisting ceramic body, add raw materials into planetary stirring machine premix 5~ 8min;
Step 2:Wet mixing, be added in pre- mixed heat resisting ceramic body premix into step 1 7%~9% it is clean from Water, 3~5min of mixed grind;
Step 3:The material being stirred in step 2 is inserted in mold and carries out vibration moulding by molding;
Step 4:Demoulding, maintenance are demoulded after molding green body stands 5~7h in step 3, will be molding after demoulding Green body is placed on 48~72h of maintenance in 20~30 DEG C of fog room;
Step 5:It is dry, the product finished will be conserved in step 4 and is put into shuttle kiln, and it is dry to carry out heating according to drying curve It is dry, naturally cool to room temperature after the completion of dry;
Step 6:Enamel frit makeing, according to the proportioning of high-performance micro-crystalline ceramic glaze, by the glaze prepared be put into grinding 18 in ball mill~ 24h;
Step 7:Glaze spraying uniformly sprays ceramic glaze ground in step 6 on heat resisting ceramic body after the drying;
Step 8:Loading of kiln is burnt into, and the ceramic body that glaze has been sprayed in step 7 is fitted into shuttle kiln, is burnt according to sintering curve At heating naturally cools to room temperature after the completion.
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