CN108300291A - A kind of exterior coating and preparation method thereof and painting technique - Google Patents
A kind of exterior coating and preparation method thereof and painting technique Download PDFInfo
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- CN108300291A CN108300291A CN201810109136.4A CN201810109136A CN108300291A CN 108300291 A CN108300291 A CN 108300291A CN 201810109136 A CN201810109136 A CN 201810109136A CN 108300291 A CN108300291 A CN 108300291A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to building coating fields, and in particular to a kind of exterior coating and preparation method thereof and painting technique.The exterior coating in parts by weight, including following components:20.0~25.0 parts of silicone resin emulsion;25.0~30.0 parts of acrylate polymer emulsion;20.0~25.0 parts of color stuffing;0.1~1.0 part of dispersant;0.1~1.0 part of thickener;3.0~5.0 parts of coalescents;4.0~8.0 parts of silane coupling agent;0.5~1.0 part of rilanit special;10.0~20.0 parts of water.By adding particular kind of auxiliary agent, it is especially added with silane coupling agent, rilanit special;The polluting proofing property energy and wash-resistant property of coating can be significantly improved.
Description
Technical field
The invention belongs to building coating fields, and in particular to a kind of exterior coating and preparation method thereof and painting technique.
Background technology
Currently, the exterior coating that China uses, mainly using acrylic emulsion as base-material, water-borne acrylic coatings have cost
Moderate, the advantages that weatherability is excellent, adjustability is good, and organic solvent-free discharges is to develop very rapid a kind of apply in recent years
Expect product.Although such coating has many advantages, such as, but still the problem that contaminated resistance is poor, after a period of use metope
It is easily adhered many dusts and dirt, and is difficult to clean, needs to repaint construction so that some skyscrapers and height at present
The apartment of shelves uses face brick or lithotome as decoration of exterior wall type building coating one after another, encourages popularization exterior wall to make with country
Disagreed with non-ceramic class ornament materials, the main reason is that because exterior coating stain resistance it is larger the problem of, seriously
Constrain the popularization and application of this environmentally friendly exterior coating.
Invention content
For the above-mentioned shortcoming of the prior art, the present invention provides a kind of exterior coating, particular kind of by adding
Auxiliary agent has been especially added with silane coupling agent, rilanit special;The polluting proofing property energy and wash-resistant property of coating can be significantly improved.
Exterior coating provided by the invention, in parts by weight, including following components:
20.0~30.0 parts of silicone resin emulsion;
20.0~35.0 parts of acrylate polymer emulsion;
20.0~30.0 parts of color stuffing;
0.1~2.0 part of dispersant;
0.1~3.0 part of thickener;
1.0~10.0 parts of coalescents;
4.0~10.0 parts of silane coupling agent;
0.1~1.0 part of rilanit special;
10.0~20.0 parts of water.
Preferably, the exterior coating in parts by weight, including following components:
20.0~25.0 parts of silicone resin emulsion;
25.0~30.0 parts of acrylate polymer emulsion;
20.0~25.0 parts of color stuffing;
0.1~1.0 part of dispersant;
0.1~1.0 part of thickener;
3.0~5.0 parts of coalescents;
4.0~8.0 parts of silane coupling agent;
0.5~1.0 part of rilanit special;
10.0~20.0 parts of water.
Preferably, the color stuffing is mica powder, calcium carbonate or barium sulfate.
Preferably, the dispersant is Quadrafos or polyacrylic acid sodium salt.
Preferably, the thickener is hydroxyethyl cellulose, bentonite or xanthans.
Preferably, the coalescents are No. 200 solvent naphthas or 12 ester alcohols.
The present invention also provides the preparation methods of the exterior coating, include the following steps:
(1) add water, thickener under the stirring of 200rpm~500rpm rotating speeds, stir 1~5min;
(2) it turns speed and arrives 600rpm~900rpm, dispersant is added, stir 1~3min;
(3) it turns speed and arrives 1100rpm~1400rpm, color stuffing is added, stir 10~30min;
(4) it turns speed and arrives 600rpm~900rpm, coalescents, silane coupling agent and rilanit special, stirring is added
3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 10~15min, after stirring evenly to obtain the final product
Finished product.
The present invention also provides the painting techniques of the exterior coating, include the following steps:
(a) metope matrix is cleared up, is hung 24 hours after the completion of cleaning;
(b) it is plastered using putty the metope cleared up, paint thickness is 0.9~1.1mm, is hung after the completion of painting
24 hours;
(c) it to the metope handled by step (b), is painted with priming paint, paint thickness is 0.9~1.1mm, has been painted
It is hung after 24 hours;
(d) to by step (c) handle metope, painted with above-mentioned exterior coating, paint thickness be 0.9~
1.1mm is hung 24 hours after the completion of painting.
In above-mentioned painting technique, priming paint type is the third alkali-resistant primer of silicon, has preferable adhesive force with metope.
Compared with prior art, the present invention having an advantageous effect in that:
1, filmogen be silicone resin emulsion and acrylate polymer emulsion, silicone resin emulsion have it is hydrophobic,
The characteristics such as ventilative and weather-proof;Contain acrylate copolymer simultaneously, the adhesive force with acrylic emulsion is high, gloss is uniform, film
The characteristics such as plentiful.
2, by adding particular kind of auxiliary agent, silane coupling agent, rilanit special have been especially added with;Painting can be significantly improved
The polluting proofing property energy and wash-resistant property of material.
3, the preparation method of exterior coating of the present invention, it is easy to operate, facilitate realization, and use side of the present invention
Product prepared by method, the uniformity and compatibility etc. are preferable, have stronger bin stability.
Specific implementation mode
The invention discloses a kind of exterior coating and preparation method thereof and painting technique, those skilled in the art can use for reference
Present disclosure is suitably modified technological parameter realization.In particular, it should be pointed out that all similar substitutions and modifications are to this field skill
It is it will be apparent that they are considered as being included in the present invention for art personnel.The present invention method and application by compared with
Good embodiment is described, related personnel obviously can not depart from the content of present invention, in spirit and scope to as described herein
Methods and applications are modified or suitably change and combine, to realize and apply the technology of the present invention.
Experimental method in following embodiments is unless otherwise instructed conventional method.The examination that following embodiments are related to
Agent, equipment or raw material are common commercially available product unless otherwise noted, can all be bought and be obtained by market.Specific case is carried out below
Example is implemented, but the present invention is not limited to these following cases.
Embodiment 1
1, exterior coating formula provided by the invention, in parts by weight, including following components:Silicone resin emulsion 25.0
Part;25.0 parts of acrylate polymer emulsion;Using mica powder as 20.0 parts of color stuffing;Using Quadrafos as 0.1 part of dispersant;
Using hydroxyethyl cellulose as 1.0 parts of thickener;Using 12 ester alcohols as 3.0 parts of coalescents;8.0 parts of silane coupling agent;Hydrogen
Change 1.0 parts of castor oil;10.0 parts of water.
2, exterior coating is prepared using above-mentioned formula, included the following steps:
(1) add water, thickener under the stirring of 200rpm rotating speeds, stir 5min;
(2) it turns speed and arrives 600rpm, dispersant is added, stir 3min;
(3) it turns speed and arrives 1100rpm, color stuffing is added, stir 30min;
(4) it turns speed and arrives 600rpm, coalescents, silane coupling agent and rilanit special is added, stir 3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 15min, up to product after stirring evenly
1。
Embodiment 2:
1, exterior coating formula provided by the invention, in parts by weight, including following components:Silicone resin emulsion 20.0
Part;30.0 parts of acrylate polymer emulsion;Using calcium carbonate as 25.0 parts of color stuffing;Using polyacrylic acid sodium salt as dispersant
1.0 part;Using bentonite as 0.1 part of thickener;Using No. 200 solvent naphthas as 5.0 parts of coalescents;4.0 parts of silane coupling agent;
0.5 part of rilanit special;Water:20.0 parts.
2, exterior coating is prepared using above-mentioned formula, included the following steps:
(1) add water, thickener under the stirring of 200rpm rotating speeds, stir 5min;
(2) it turns speed and arrives 600rpm, dispersant is added, stir 3min;
(3) it turns speed and arrives 1100rpm, color stuffing is added, stir 30min;
(4) it turns speed and arrives 600rpm, coalescents, silane coupling agent and rilanit special is added, stir 3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 15min, up to product after stirring evenly
2。
Embodiment 3
The painting of exterior wall is used for using the exterior coating that embodiment 1 is prepared, painting technique to include the following steps:
(a) metope matrix is cleared up, is hung 24 hours after the completion of cleaning;
(b) it is plastered using putty the metope cleared up, paint thickness is 0.9~1.1mm, is hung after the completion of painting
24 hours;
(c) it to the metope handled by step (b), is painted with priming paint, paint thickness is 0.9~1.1mm, has been painted
It is hung after 24 hours;
(d) it to the metope handled by step (c), is painted with product 1, paint thickness is 0.9~1.1mm, painting
It hangs after the completion 24 hours.
Comparative example 1
1, exterior coating formula provided by the invention, in parts by weight, including following components:
25.0 parts of silicone resin emulsion;25.0 parts of acrylate polymer emulsion;Using mica powder as 20.0 parts of color stuffing;
Using Quadrafos as 0.1 part of dispersant;Using hydroxyethyl cellulose as 1.0 parts of thickener;With 12 ester alcohol coalescents 3.0
Part;1.0 parts of rilanit special;10.0 parts of water.
2, exterior coating is prepared using above-mentioned formula, included the following steps:
(1) add water, thickener under the stirring of 200rpm rotating speeds, stir 5min;
(2) it turns speed and arrives 600rpm, dispersant is added, stir 3min;
(3) it turns speed and arrives 1100rpm, color stuffing is added, stir 30min;
(4) it turns speed and arrives 600rpm, coalescents, rilanit special is added, stir 3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 15min, up to comparison after stirring evenly
Product 1.
Comparative example 2
1, exterior coating formula provided by the invention, in parts by weight, including following components:Silicone resin emulsion 25.0
Part;25.0 parts of acrylate polymer emulsion;Using mica powder as 20.0 parts of color stuffing;Using hydrochlorate as 0.1 part of dispersant;With hydroxyl
Ethyl cellulose is as 1.0 parts of thickener;With 3.0 parts of 12 ester alcohol coalescents;8.0 parts of silane coupling agent;10.0 parts of water.
2, exterior coating is prepared using above-mentioned formula, included the following steps:
(1) add water, thickener under the stirring of 200rpm rotating speeds, stir 5min;
(2) it turns speed and arrives 600rpm, dispersant is added, stir 3min;
(3) it turns speed and arrives 1100rpm, color stuffing is added, stir 30min;
(4) it turns speed and arrives 600rpm, coalescents and silane coupling agent is added, stir 3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 15min, up to comparison after stirring evenly
Product 2.
The said goods 1, product 2 and contrast product 1 and contrast product 2 are detected by GB9755-2014, measured
Indices see the table below 1:
Table 1
As seen from Table 1, the polluting proofing property and abrasion resistance of product 1 and product 2 are produced significantly better than contrast product 1 and comparison
Product 2, thus illustrate, exterior coating of the present invention, since the silane coupling agent and rilanit special of special ratios is added;Significantly
Improve the contaminated resistance and abrasion resistance of product.
The above case study on implementation be to the present invention be specifically described for example, technical staff belonging to the present invention can be with
Various concrete cases are modified or supplemented.
Claims (8)
1. a kind of exterior coating, which is characterized in that in parts by weight, including following components:
20.0~30.0 parts of silicone resin emulsion;
20.0~35.0 parts of acrylate polymer emulsion;
20.0~30.0 parts of color stuffing;
0.1~2.0 part of dispersant;
0.1~3.0 part of thickener;
1.0~10.0 parts of coalescents;
4.0~10.0 parts of silane coupling agent;
0.1~1.0 part of rilanit special;
10.0~20.0 parts of water.
2. exterior coating according to claim 1, which is characterized in that in parts by weight, including following components:
20.0~25.0 parts of silicone resin emulsion;
25.0~30.0 parts of acrylate polymer emulsion;
20.0~25.0 parts of color stuffing;
0.1~1.0 part of dispersant;
0.1~1.0 part of thickener;
3.0~5.0 parts of coalescents;
4.0~8.0 parts of silane coupling agent;
0.5~1.0 part of rilanit special;
10.0~20.0 parts of water.
3. exterior coating according to claim 1 or 2, which is characterized in that the color stuffing is mica powder, calcium carbonate or sulphur
Sour barium.
4. exterior coating according to claim 1 or 2, which is characterized in that the dispersant is Quadrafos or polypropylene
Acid sodium-salt.
5. exterior coating according to claim 1 or 2, which is characterized in that the thickener is hydroxyethyl cellulose, swelling
Soil or xanthans.
6. exterior coating according to claim 1 or 2, which is characterized in that the coalescents be No. 200 solvent naphthas or
12 ester alcohols.
7. the preparation method of any one of the claim 1-6 exterior coatings, includes the following steps:
(1) add water, thickener under the stirring of 200rpm~500rpm rotating speeds, stir 1~5min;
(2) it turns speed and arrives 600rpm~900rpm, dispersant is added, stir 1~3min;
(3) it turns speed and arrives 1100rpm~1400rpm, color stuffing is added, stir 10~30min;
(4) it turns speed and arrives 600rpm~900rpm, coalescents, silane coupling agent and rilanit special is added, stir 3min;
(5) silicone resin emulsion and acrylate polymer emulsion is added, stirs 10~15min, is got product after stirring evenly.
8. the painting technique of any one of the claim 1-6 exterior coatings, includes the following steps:
(a) metope matrix is cleared up, is hung 24 hours after the completion of cleaning;
(b) it is plastered using putty the metope cleared up, paint thickness is 0.9~1.1mm, and it is small to hang 24 after the completion of painting
When;
(c) it to the metope handled by step (b), is painted with priming paint, paint thickness is 0.9~1.1mm, after the completion of painting
It hangs 24 hours;
(d) it to the metope handled by step (c), is painted with above-mentioned exterior coating, paint thickness is 0.9~1.1mm, powder
It is hung 24 hours after the completion of brush.
Priority Applications (1)
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CN201810109136.4A CN108300291B (en) | 2018-02-05 | 2018-02-05 | Exterior wall coating and preparation method and painting process thereof |
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CN201810109136.4A CN108300291B (en) | 2018-02-05 | 2018-02-05 | Exterior wall coating and preparation method and painting process thereof |
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CN108300291A true CN108300291A (en) | 2018-07-20 |
CN108300291B CN108300291B (en) | 2020-04-10 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110358380A (en) * | 2019-04-24 | 2019-10-22 | 深圳市朗奥洁净科技股份有限公司 | Water paint |
CN113956788A (en) * | 2021-10-22 | 2022-01-21 | 九江立帆科技有限公司 | Building wall coating and preparation method thereof |
CN116200065A (en) * | 2022-11-18 | 2023-06-02 | 南京海配新材料有限公司 | Anti-settling paste for high-solid-content zinc-rich paint and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110358380A (en) * | 2019-04-24 | 2019-10-22 | 深圳市朗奥洁净科技股份有限公司 | Water paint |
CN113956788A (en) * | 2021-10-22 | 2022-01-21 | 九江立帆科技有限公司 | Building wall coating and preparation method thereof |
CN116200065A (en) * | 2022-11-18 | 2023-06-02 | 南京海配新材料有限公司 | Anti-settling paste for high-solid-content zinc-rich paint and preparation method thereof |
CN116200065B (en) * | 2022-11-18 | 2024-02-20 | 南京海配新材料有限公司 | Anti-settling paste for high-solid-content zinc-rich paint and preparation method thereof |
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