CN108299820A - One kind is exempted to spray 6 composite material of nano-nylon - Google Patents
One kind is exempted to spray 6 composite material of nano-nylon Download PDFInfo
- Publication number
- CN108299820A CN108299820A CN201810145693.1A CN201810145693A CN108299820A CN 108299820 A CN108299820 A CN 108299820A CN 201810145693 A CN201810145693 A CN 201810145693A CN 108299820 A CN108299820 A CN 108299820A
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- parts
- nylon
- nano
- mass fraction
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
Abstract
The invention discloses one kind to exempt to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：70 94 parts of 6 material of nano-nylon, 4 10 parts of metal Masterbatch, 1 10 parts of antistatic agent, 1 10 parts of antiseptic；6 material of nano-nylon includes following raw material according to the mass fraction：81 87 parts of caprolactam, 36 parts of montmorillonite.The composite material of the present invention saves coating, reduces the workload in production process without being sprayed, and has many advantages, such as environmental-protection function, also with color and luster sense is good, intensity is high, wearability is strong, antistatic and antibacterial.
Description
Technical field
The present invention relates to nano-nylon material, especially one kind to exempt to spray 6 composite material and preparation method of nano-nylon.
Background technology
Nylon 6 is a kind of polyamide product, with excellent mechanical property, chemical property and mechanical performance, while its
Corrosion resistance and electrical insulation capability are good, and proportion is small, are easy to processing and forming, are widely used in automobile, electronic apparatus, machine
The fields such as tool instrument.But it also has the shortcomings that prominent, for example color and luster sense is poor when being used as appearance member, rigidity not enough,
Wearability is low, and can not play the role of antistatic and antibacterial；The material is adding man-hour requirement to be sprayed, and increases whole road
The workload of process, while also needing to use spray painting or paint, it causes serious pollution to the environment, and not environmentally.
Invention content
To solve the above-mentioned problems, the object of the present invention is to provide one kind to exempt to spray 6 composite material of nano-nylon, has ring
Guarantor acts on, and has many advantages, such as that color and luster sense is good, intensity is high, wearability is strong, antistatic and antibacterial.
In order to make up for the deficiencies of the prior art, the technical solution adopted by the present invention is：
One kind is exempted to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：6 material of nano-nylon
70-94 parts, 4-10 parts of metal Masterbatch, 1-10 parts of antistatic agent, 1-10 parts of antiseptic；6 material of nano-nylon includes pressing below
The raw material of mass fraction meter：81-87 parts of caprolactam, 3-6 parts of montmorillonite.
Further, metal Masterbatch includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, color
5 parts of master batch pigment.
Further, antistatic agent includes following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, point
5 parts of powder.
Further, antiseptic includes following raw material according to the mass fraction：90 parts of zine series inorganic germicide, dispersant 10
Part.
The beneficial effects of the invention are as follows：The present invention provides one kind to exempt to spray 6 composite material of nano-nylon, wherein oneself is added
81-87 parts of lactams and the raw material of 3-6 parts of montmorillonite so that the composite material of the present invention prepared carries spraying effect,
There is no need to be sprayed, additionally by metal Masterbatch, antistatic agent and the antiseptic for selecting suitable proportion, make the present invention's
Glossiness, bending and the tensile strength of composite material, bending modulus and antibiotic rate, there is certain carry compared with the existing technology
It rises, while the volume resistivity of composite material declines to a great extent；Therefore, composite material of the invention is saved without being sprayed
Coating reduces the workload in production process, has environmental-protection function, also with color and luster sense is good, intensity is high, wearability is strong, anti-
The advantages that electrostatic and antibacterial.
Specific implementation mode
Embodiment one
One kind is exempted to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：6 material of nano-nylon
70-94 parts, 4-10 parts of metal Masterbatch, 1-10 parts of antistatic agent, 1-10 parts of antiseptic；6 material of nano-nylon includes pressing below
The raw material of mass fraction meter：81-87 parts of caprolactam, 3-6 parts of montmorillonite.
Wherein, metal Masterbatch includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, color masterbatch
5 parts of pigment of grain.
Wherein, antistatic agent includes following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, dispersion
5 parts of agent.
Wherein, antiseptic includes following raw material according to the mass fraction：90 parts of zine series inorganic germicide, 10 parts of dispersant.
Specifically, according to applicant's many experiments gained, using 81-87 parts of caprolactam and the original of 3-6 parts of montmorillonite
Material so that the composite material of the present invention prepared carries spraying effect, and there is no need to be sprayed.
In the conventional technology, for example common polyamide material, tensile strength are about 74MPa, and bending strength is about
96MPa, bending modulus are about 2.2Gpa or so, and glossiness 80%, for antibiotic rate more than 98.7%, volume resistivity is about 1014
Ω·cm。
And the tensile strength for exempting to spray 6 composite material of nano-nylon of the present invention is not less than 85MPa, compared to PA, i.e. phase
Than at least improving 15% in common polyamide material, and bending strength is not less than 120MPa, compared to common polyamide material
At least improve 25%, therefore intensity higher；
Bending modulus is more than 3Gpa, at least improves 50% compared to common polyamide material, therefore wearability is more preferable；
Glossiness is 100%, and compared to common polyamide material lift 20%, therefore color and luster sense is more preferable；
Antibiotic rate is more than 99%, has better antibacterial effect；
Volume resistivity is 109Ω cm have dropped 5 orders of magnitude compared to common polyamide material, can play more preferable
Anti-static electrification.
Therefore, composite material of the invention saves coating, reduces the work in production process without being sprayed
Amount, has many advantages, such as environmental-protection function, also with color and luster sense is good, intensity is high, wearability is strong, antistatic and antibacterial.
Embodiment two
One kind is exempted to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：6 material of nano-nylon
87 parts, 4 parts of metal Masterbatch, 3 parts of antistatic agent, 3 parts of antiseptic；6 material of nano-nylon include it is following according to the mass fraction
Raw material：87 parts of caprolactam, 3 parts of montmorillonite.
Wherein, metal Masterbatch includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, color masterbatch
5 parts of pigment of grain.
Wherein, antistatic agent includes following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, dispersion
5 parts of agent.
Wherein, antiseptic includes following raw material according to the mass fraction：90 parts of zine series inorganic germicide, 10 parts of dispersant.
The tensile strength of the composite material is 85Mpa, compared to common polyamide material lift 15%；
Bending strength is 120Mpa, compared to common polyamide material lift 25%；
Bending modulus is 3.5Gpa, compared to common polyamide material lift 50%；
Glossiness is 100%, compared to common polyamide material lift 20%；
Antibiotic rate is more than 99%；
Volume resistivity is 109Ω cm have dropped 5 orders of magnitude compared to common polyamide material.
Embodiment three
One kind is exempted to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：6 material of nano-nylon
81 parts, 10 parts of metal Masterbatch, 3 parts of antistatic agent, 3 parts of antiseptic；6 material of nano-nylon include it is following according to the mass fraction
Raw material：81 parts of caprolactam, 3 parts of montmorillonite.
Wherein, metal Masterbatch includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, color masterbatch
5 parts of pigment of grain.
Wherein, antistatic agent includes following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, dispersion
5 parts of agent.
Wherein, antiseptic includes following raw material according to the mass fraction：90 parts of zine series inorganic germicide, 10 parts of dispersant.
Example IV
One kind is exempted to spray 6 composite material of nano-nylon, including following raw material according to the mass fraction：6 material of nano-nylon
84 parts, 4 parts of metal Masterbatch, 3 parts of antistatic agent, 3 parts of antiseptic；6 material of nano-nylon include it is following according to the mass fraction
Raw material：84 parts of caprolactam, 6 parts of montmorillonite.
Wherein, metal Masterbatch includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, color masterbatch
5 parts of pigment of grain.
Wherein, antistatic agent includes following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, dispersion
5 parts of agent.
Wherein, antiseptic includes following raw material according to the mass fraction：90 parts of zine series inorganic germicide, 10 parts of dispersant.
The tensile strength of the composite material is 100Mpa, compared to common polyamide material lift 30%；
Bending strength is 180Mpa, compared to common polyamide material lift 80%；
Bending modulus is 5.5Gpa, compared to common polyamide material lift 150%；
Glossiness is 100%, compared to common polyamide material lift 20%；
Antibiotic rate is more than 99%；Volume resistivity is 109Ω cm have dropped 5 numbers compared to common polyamide material
Magnitude.
Presently preferred embodiments of the present invention and basic principle is discussed in detail in the above content, but the invention is not limited in
The above embodiment, those skilled in the art should be recognized that also had under the premise of without prejudice to spirit of that invention it is various
Equivalent variations and replacement, these equivalent variations and replacement all fall within the protetion scope of the claimed invention.
Claims (4)
1. one kind is exempted to spray 6 composite material of nano-nylon, which is characterized in that including following raw material according to the mass fraction：Nanometer
70-94 parts of nylon 6 material, 4-10 parts of metal Masterbatch, 1-10 parts of antistatic agent, 1-10 parts of antiseptic；6 material of the nano-nylon
Material includes following raw material according to the mass fraction：81-87 parts of caprolactam, 3-6 parts of montmorillonite.
2. one kind according to claim 1 is exempted to spray 6 composite material of nano-nylon, which is characterized in that the metal color masterbatch
Grain includes following raw material according to the mass fraction：95 parts of metal toner or bloom pearl powder, 5 parts of Masterbatch pigment.
3. one kind according to claim 1 is exempted to spray 6 composite material of nano-nylon, which is characterized in that the antistatic agent
Including following raw material according to the mass fraction：95 parts of macromolecule permanent antistatic agent, 5 parts of dispersant.
4. one kind according to claim 1 is exempted to spray 6 composite material of nano-nylon, which is characterized in that the antiseptic packet
Include following raw material according to the mass fraction：90 parts of zine series inorganic germicide, 10 parts of dispersant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810145693.1A CN108299820A (en) | 2018-02-12 | 2018-02-12 | One kind is exempted to spray 6 composite material of nano-nylon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810145693.1A CN108299820A (en) | 2018-02-12 | 2018-02-12 | One kind is exempted to spray 6 composite material of nano-nylon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108299820A true CN108299820A (en) | 2018-07-20 |
Family
ID=62865457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810145693.1A Pending CN108299820A (en) | 2018-02-12 | 2018-02-12 | One kind is exempted to spray 6 composite material of nano-nylon |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108299820A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791083A (en) * | 2019-08-26 | 2020-02-14 | 上海华合复合材料有限公司 | High-antibacterial high-weather-resistance spraying-free polyamide composite material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030004248A1 (en) * | 1997-09-08 | 2003-01-02 | Kazuyuki Wakamura | Polyamide resin composition |
| CN103694692A (en) * | 2012-09-27 | 2014-04-02 | 尤尼吉可株式会社 | Polyamide resin composition and molded body molded with the same |
| CN106751756A (en) * | 2016-11-30 | 2017-05-31 | 上海中镭新材料科技有限公司 | It is a kind of to exempt from the polyamide of spraying with metal effect and preparation method thereof |
| CN106832262A (en) * | 2017-02-13 | 2017-06-13 | 上海跃贝塑化科技有限公司 | With nano combined nylon material for exempting to spray optical property high and preparation method thereof |
| CN107353635A (en) * | 2017-07-19 | 2017-11-17 | 广东圆融新材料有限公司 | A kind of nanometer polyamide composition with metallic luster and preparation method thereof |
-
2018
- 2018-02-12 CN CN201810145693.1A patent/CN108299820A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030004248A1 (en) * | 1997-09-08 | 2003-01-02 | Kazuyuki Wakamura | Polyamide resin composition |
| CN103694692A (en) * | 2012-09-27 | 2014-04-02 | 尤尼吉可株式会社 | Polyamide resin composition and molded body molded with the same |
| CN106751756A (en) * | 2016-11-30 | 2017-05-31 | 上海中镭新材料科技有限公司 | It is a kind of to exempt from the polyamide of spraying with metal effect and preparation method thereof |
| CN106832262A (en) * | 2017-02-13 | 2017-06-13 | 上海跃贝塑化科技有限公司 | With nano combined nylon material for exempting to spray optical property high and preparation method thereof |
| CN107353635A (en) * | 2017-07-19 | 2017-11-17 | 广东圆融新材料有限公司 | A kind of nanometer polyamide composition with metallic luster and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791083A (en) * | 2019-08-26 | 2020-02-14 | 上海华合复合材料有限公司 | High-antibacterial high-weather-resistance spraying-free polyamide composite material and preparation method thereof |
| CN110791083B (en) * | 2019-08-26 | 2022-06-14 | 华合新材料科技股份有限公司 | High-antibacterial high-weather-resistance spraying-free polyamide composite material and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180720 |