CN108299135A - A kind of smokelessly cold light firework medicament without ammonia odor - Google Patents
A kind of smokelessly cold light firework medicament without ammonia odor Download PDFInfo
- Publication number
- CN108299135A CN108299135A CN201810085647.7A CN201810085647A CN108299135A CN 108299135 A CN108299135 A CN 108299135A CN 201810085647 A CN201810085647 A CN 201810085647A CN 108299135 A CN108299135 A CN 108299135A
- Authority
- CN
- China
- Prior art keywords
- cold light
- ammonia odor
- smokelessly
- light firework
- medicament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/08—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide with a nitrated organic compound
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/006—Stabilisers (e.g. thermal stabilisers)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of smokelessly cold light firework medicaments without ammonia odor, belong to fireworks and firecrackers field.The technical problem to be solved in the present invention is to provide a kind of combustion fumes are few, in addition it is smokeless, and jet power is strong, and spark is full, the cold light firework medicament of no ammonia odor comprising the component of following mass parts：13~91 parts of nitrocelluloses, 0.2~7 part of ferrocene, 0.5~2.5 part of stabilization agent, 8~80 parts of titanium valves.The present invention is by adjusting nitrocellulose, stabilization agent, ferrocene and titanium valve ratio, make the non smoke of setting off of cold light firework medicament, spark jetting stability and it is full, temperature is low, irritating ammonia odor is not generated after burning, securely and reliably, it is had a wide range of applications in fireworks and firecrackers field.
Description
Technical field
The invention belongs to fireworks and firecrackers fields, and in particular to a kind of smokelessly cold light firework medicament without ammonia odor.
Background technology
Cold light firework, which is called, makees cool flame fire, and common fireworks burning point is easy to cause human body at 500 DEG C~800 DEG C, burning
Injury, and cool flame fire burning point is at 60 DEG C~80 DEG C, 30 DEG C~50 DEG C of external temperature, to no damage to human body.Cool flame fire is suitable for room
Inside and outside to set off, brightness is high when setting off, smog is small, pollution is few, can play the role of strong setting off rendering by contrast to live atmosphere.It is various
The cold light firework product of shape-designing is suitble to different places to set off, such as outdoor dragon dance performance and indoor stage performance.
The medicament of presently commercially available cold light firework generally uses the mixture of single original washing powder, titanium valve and oxidant.Single original washing powder is to adopt
Prepared by broken with retired military single-base gun propellant hygrometric state yellow powder fiber, cigarette and residue are few when burning.Oxidant
Generally use ammonium perchlorate, potassium hyperchlorate etc., the cold light firework containing ammonium perchlorate, potassium hyperchlorate will produce NH setting off4、HCl、
Cl2, they can cause pungent smell and a certain amount of smog, be a kind of cool flame fire of micro- cigarette.Chinese patent CN1059400A
A kind of smoke less fire cracker and manufacturing method are disclosed, cool flame fire scope is belonged to, drug ingedient range is (by weight)：Nitrocellulose 75
~90%, magnalium cerium alloy 4~15%, Titanium 5~15% and shellac 5~10%.Interior is seted off, not only smokelessly but also with fireworks
Effect.But by the medicament of this trial-production, loaded on being seted off after paper web, fireworks jet power is weaker, spark level is dull, smog
Still larger.
Invention content
Technical problem solved by the invention is to provide that a kind of burning is smokeless, and jet power is strong, and spark is full, no ammonia odor
Cold light firework medicament.
There is provided a kind of smokelessly cold light without ammonia odor for technological means used by the present invention solves above-mentioned technical problem
Fireworks medicament comprising the component of following mass parts：13~91 parts of nitrocelluloses, 0.2~7 part of ferrocene, 0.5~2.5 part
Stabilization agent, 8~80 parts of titanium valves.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the degree of nitration of the nitrocellulose is not
Less than 175mL/g.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the stabilization agent is diphenylamines, in No. I
Determine at least one of agent or No. II centralite.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the titanium valve be Titanium, yellow light titanium,
At least one of titanium sponge or titantium hydride.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the granularity of the titanium valve is 20~200
Mesh.
The present invention also provides the preparation method of the cold light firework medicament of smokeless no ammonia odor described above, this method packets
Include following steps：By each component be uniformly mixed to get.
In addition, the present invention also provides the cold light firework medicaments of smokeless no ammonia odor described above in fireworks and firecrackers
Using.
Beneficial effects of the present invention：
The present invention makes setting off for cold light firework medicament by adjusting nitrocellulose, stabilization agent, ferrocene and titanium valve ratio
Non smoke, spark jetting stability and it is full, temperature is low, irritating ammonia odor is not generated after burning；It is free of in medicament of the present invention
Potassium hyperchlorate or ammonium perchlorate, and enough jet powers can be generated using ferrocene is combustion-supporting, reach outstanding firework display effect, more
Securely and reliably；Cold light firework medicament of the present invention has a wide range of applications in fireworks and firecrackers field, is worthy to be popularized.
Specific implementation mode
Specifically, a kind of smokelessly cold light firework medicament without ammonia odor comprising the component of following mass parts：13~91 parts
Nitrocellulose, 0.2~7 part of ferrocene, 0.5~2.5 part of stabilization agent, 8~80 parts of titanium valves.
The present invention using the degree of nitration be not less than 175mL/g nitrocellulose, come ensure burning generate gas can will
Titanium valve particle sprays, and forms appreciation effect；It is a plurality of types of that Titanium, yellow light titanium, titanium sponge or titantium hydride etc. can be used in titanium valve
Titanium valve derives from a wealth of sources；It is sufficiently mixed for ease of each component, reaches excellent combustion efficiency, the granularity requirements of titanium valve in the present invention
For 20~200 mesh；Stabilization agent is at least one of diphenylamines, No. I centralite or No. II centralite.
The preparation method of the smokeless cold light firework medicament without ammonia odor of the present invention is simple, safe efficient, and each component is mixed
Uniformly to get.
The smokelessly cold light firework medicament without ammonia odor provided by the invention has extensive use in fireworks and firecrackers, such as by medicine
After agent plastotype, packaging, cake cool flame fire, hand-held cold light fireworks, wedding celebration cold light fireworks etc. are can be used as, firework display effect is good, uses peace
Entirely.
Below by embodiment, invention is further described in detail, but does not therefore limit the scope of the present invention
Among the embodiment described range.
Embodiment 1
The smokelessly cold light firework medicament without ammonia odor：Weigh 40 mass parts of nitrocellulose of degree of nitration 210mL/g, hexichol
Above-mentioned raw material are uniformly mixed i.e. by 1 mass parts of amine, 7 mass parts of ferrocene, 52 mass parts of spongy titanium powder of 40~60 mesh of granularity
.
Waterfall cool flame fire：30 millimeters of powder columns of diameter are made in above-mentioned medicament, stage property is seted off in loading, when setting off, bright fire
Flower is in cascade, is afforded a magnificent spectacle.
Embodiment 2
The smokelessly cold light firework medicament without ammonia odor：Weigh 70 mass parts of nitrocellulose of degree of nitration 180mL/g, hexichol
1 mass parts of amine, No. I 0.5 mass parts of centralite, 0.5 mass parts of ferrocene, 28 mass of hydride powder of 180~200 mesh of granularity
Part, above-mentioned raw material are uniformly mixed to obtain the final product.
Cake cool flame fire：10 millimeters of powder columns of diameter are made in above-mentioned medicament, stage property is seted off in loading, and when setting off, spark is upward
Injection, smokelessly, without the taste that is pungent, no residue is fallen, and top is divided into spark, and lower part flame is suitable for being inserted on cake and set off,
Increase celebration atmosphere.
Embodiment 3
The smokelessly cold light firework medicament without ammonia odor：Weigh 85 mass parts of nitrocellulose of degree of nitration 210mL/g, hexichol
2 mass parts of amine, 1 mass parts of ferrocene, 12 mass parts of metallic titanium powder of 100~120 mesh of granularity, above-mentioned raw material are uniformly mixed
To obtain the final product.
Wedding celebration cold light fireworks：22 millimeters of powder columns of diameter are made in above-mentioned medicament, loading sets off stage property, when setting off, sets off height
Degree is 2.5m~3m, can be placed on red carpet both sides, for smoke-free and tasteless without slag, flame is bright and colourful when setting off.
Embodiment 4
The smokelessly cold light firework medicament without ammonia odor：Weigh 90 mass parts of nitrocellulose of degree of nitration 190mL/g, hexichol
0.5 mass parts of amine, 0.5 mass parts of ferrocene, 9 mass parts of hydride powder of 180~200 mesh of granularity, above-mentioned raw material are mixed
Uniformly to obtain the final product.
Hand-held cold light fireworks：4 millimeters of powder columns of diameter are made in above-mentioned medicament, outer layer applies flame retardant paint, when setting off, powder column is inserted
Enter handheld component, without solid residue clean environment firendly after burning, spark temperature is low, plays suitable for children.
Embodiment 5~8
Embodiment 5 and embodiment 6 prepare the smokelessly cold light firework medicine without ammonia odor using method same as Example 1
Agent, the difference is that using powder column size made of the medicament；Embodiment 7 and embodiment 8 use side same as Example 3
Method prepares the smokelessly cold light firework medicament without ammonia odor, the difference is that using powder column size made of the medicament；Embodiment 5
Smokelessly the cold light firework finished medicament data without ammonia odor are shown in Table 1 to~8 gained.
1 embodiment of table, 5~8 powder column size
| Embodiment | 5 | 6 | 7 | 8 |
| Powder column size | Diameter：40mm | Diameter：22mm | Diameter：18mm | Diameter：10mm |
Stage property is seted off in the powder column being prepared by the cold light firework medicament of the smokeless no ammonia odor of embodiment 5 and 6, loading,
When setting off, bright spark is in cascade, is afforded a magnificent spectacle；By the cold light firework medicine of the smokeless no ammonia odor of embodiment 7 and 8
The powder column that agent is prepared, stage property is seted off in loading, and when setting off, it is 1.5m~3m to set off height, can be placed on red carpet both sides, sets off
When smoke-free and tasteless without slag, flame is bright and colourful.
By above-described embodiment it is found that the present invention smokelessly the cold light firework medicament without ammonia odor is seted off smokelessly, without pungent gas
Taste, spark jetting stability and full, temperature is low, securely and reliably, has extensive use in life.
Claims (7)
1. the smokelessly cold light firework medicament without ammonia odor, it is characterised in that：Include the component of following mass parts：13~91 parts of nitrifications
Cellulose, 0.2~7 part of ferrocene, 0.5~2.5 part of stabilization agent, 8~80 parts of titanium valves.
2. the smokelessly cold light firework medicament without ammonia odor according to claim 1, it is characterised in that：The nitrocellulose
The degree of nitration be not less than 175mL/g.
3. the smokelessly cold light firework medicament without ammonia odor according to claim 1, it is characterised in that：The stabilization agent is two
At least one of aniline, No. I centralite or No. II centralite.
4. the smokelessly cold light firework medicament without ammonia odor according to claim 1, it is characterised in that：The titanium valve is metal
At least one of titanium, yellow light titanium, titanium sponge or titantium hydride.
5. the smokeless cold light firework medicament without ammonia odor according to Claims 1 to 4 any one of them, it is characterised in that：It is described
The granularity of titanium valve is 20~200 mesh.
6. the preparation method of the smokeless cold light firework medicament without ammonia odor of Claims 1 to 5 any one of them, feature exist
In：By each component be uniformly mixed to get.
7. smokelessly application of the cold light firework medicament in fireworks and firecrackers without ammonia odor of Claims 1 to 5 any one of them.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810085647.7A CN108299135A (en) | 2018-01-29 | 2018-01-29 | A kind of smokelessly cold light firework medicament without ammonia odor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810085647.7A CN108299135A (en) | 2018-01-29 | 2018-01-29 | A kind of smokelessly cold light firework medicament without ammonia odor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108299135A true CN108299135A (en) | 2018-07-20 |
Family
ID=62867047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810085647.7A Pending CN108299135A (en) | 2018-01-29 | 2018-01-29 | A kind of smokelessly cold light firework medicament without ammonia odor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108299135A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108981486A (en) * | 2018-08-30 | 2018-12-11 | 浏阳象形精品烟花出口制造有限公司 | A kind of anaerobic agent cold light cake firework |
| CN110228997A (en) * | 2019-07-11 | 2019-09-13 | 武汉重远炉窑工程技术服务有限公司 | A kind of mullite ceramic welding material |
| CN110950726A (en) * | 2019-12-20 | 2020-04-03 | 江西吉润花炮新材料科技有限公司 | Smokeless and sulfur-free firework bomb lift-off agent and preparation method thereof |
| CN110963867A (en) * | 2019-12-03 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | Smokeless sulfur-free bright green indoor setting-off type cold firework explosive and preparation method thereof |
| CN110963868A (en) * | 2019-12-20 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | High-explosive-sound firecracker medicament |
| CN110981652A (en) * | 2019-12-03 | 2020-04-10 | 北京理工大学 | Smokeless and sulfur-free firework stabilizer and preparation method thereof |
| CN110981667A (en) * | 2019-12-03 | 2020-04-10 | 北京理工大学 | Smokeless sulfur-free carmine indoor setting-off type cold firework explosive and preparation method thereof |
| CN113461468A (en) * | 2021-06-11 | 2021-10-01 | 南京信息职业技术学院 | Environment-friendly cold firework and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059400A (en) * | 1991-05-03 | 1992-03-11 | 浏阳县沿溪鞭炮烟花公司花炮厂 | Smokeless fireworks and its making method |
| CN104276908A (en) * | 2013-07-10 | 2015-01-14 | 周健 | Safe environment-friendly novel pyrotechnic composition |
| CN107619364A (en) * | 2016-11-30 | 2018-01-23 | 湖北航天化学技术研究所 | A kind of red bright pearl material of few cigarette and its preparation method and application |
-
2018
- 2018-01-29 CN CN201810085647.7A patent/CN108299135A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059400A (en) * | 1991-05-03 | 1992-03-11 | 浏阳县沿溪鞭炮烟花公司花炮厂 | Smokeless fireworks and its making method |
| CN104276908A (en) * | 2013-07-10 | 2015-01-14 | 周健 | Safe environment-friendly novel pyrotechnic composition |
| CN107619364A (en) * | 2016-11-30 | 2018-01-23 | 湖北航天化学技术研究所 | A kind of red bright pearl material of few cigarette and its preparation method and application |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108981486A (en) * | 2018-08-30 | 2018-12-11 | 浏阳象形精品烟花出口制造有限公司 | A kind of anaerobic agent cold light cake firework |
| CN110228997A (en) * | 2019-07-11 | 2019-09-13 | 武汉重远炉窑工程技术服务有限公司 | A kind of mullite ceramic welding material |
| CN110228997B (en) * | 2019-07-11 | 2021-08-20 | 武汉重远炉窑工程技术服务有限公司 | Mullite ceramic welding material |
| CN110963867A (en) * | 2019-12-03 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | Smokeless sulfur-free bright green indoor setting-off type cold firework explosive and preparation method thereof |
| CN110981652A (en) * | 2019-12-03 | 2020-04-10 | 北京理工大学 | Smokeless and sulfur-free firework stabilizer and preparation method thereof |
| CN110981667A (en) * | 2019-12-03 | 2020-04-10 | 北京理工大学 | Smokeless sulfur-free carmine indoor setting-off type cold firework explosive and preparation method thereof |
| CN110981652B (en) * | 2019-12-03 | 2020-12-01 | 北京理工大学 | Smokeless and sulfur-free firework stabilizer and preparation method thereof |
| CN110950726A (en) * | 2019-12-20 | 2020-04-03 | 江西吉润花炮新材料科技有限公司 | Smokeless and sulfur-free firework bomb lift-off agent and preparation method thereof |
| CN110963868A (en) * | 2019-12-20 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | High-explosive-sound firecracker medicament |
| CN113461468A (en) * | 2021-06-11 | 2021-10-01 | 南京信息职业技术学院 | Environment-friendly cold firework and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108299135A (en) | A kind of smokelessly cold light firework medicament without ammonia odor | |
| CN108218644A (en) | A kind of smokeless dulcet cold light firework medicament | |
| CN103030483B (en) | Bright green cold firework composition and production method thereof | |
| JP4920018B2 (en) | Extinguishing agent for aerosol fire extinguisher and method for producing extinguishing agent for aerosol fire extinguisher | |
| CN101270014B (en) | Blast black powder for fireworks | |
| CN105533800B (en) | A kind of cigarette energetic material and low-temperature heat type cigarette | |
| CN101481286B (en) | Smokeless lead medicament composition of firework | |
| CN102050685A (en) | Micro smoke gun propellant for fireworks | |
| CN104973998A (en) | Firework gunpowder composition for firework sounding beads | |
| CN111689823A (en) | Micro-smoke lead formula and preparation process thereof | |
| CN103224434A (en) | Sulfur-free fountain-type firework drug | |
| CN100413817C (en) | Gunpowder for fireworks in ejecting flowers | |
| CN107235815A (en) | Non- reservoir pressure extinguishing device gas producing medicinal and preparation method | |
| CN102219623A (en) | Smokeless and quick lead medicament for fireworks and firecrackers | |
| CN106316726A (en) | Novel safe and environmentally-friendly firecracker lead agent | |
| CN111018640A (en) | Stabilizing treatment and preparation method of high-explosive-sound smokeless sulfur-free firecracker nitrate medicament | |
| CN106316728A (en) | Novel environment-friendly firecracker explosive | |
| CN103980074B (en) | Smokeless firework lead powder and firing line thereof | |
| CN111499483A (en) | Formula of micro-smoke nontoxic croton seed and preparation process thereof | |
| CN107149167A (en) | Low temperature thermal source containing energy and preparation method thereof during cigarette is used | |
| CN100393203C (en) | Easy lighted up mosquito-repellent incense | |
| CN107628918B (en) | Environment-friendly and low-toxicity bright pearl material of green of one kind and its preparation method and application | |
| CN110981668A (en) | Moisture-proof smokeless sulfur-free cold firework chemical and preparation method thereof | |
| SU1741817A1 (en) | Method of extinguishing fire | |
| CN103170083A (en) | Fire-extinguishing composition containing transition metal compound |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180720 |
|
| RJ01 | Rejection of invention patent application after publication |