CN108298913B - Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof - Google Patents

Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof Download PDF

Info

Publication number
CN108298913B
CN108298913B CN201810288172.1A CN201810288172A CN108298913B CN 108298913 B CN108298913 B CN 108298913B CN 201810288172 A CN201810288172 A CN 201810288172A CN 108298913 B CN108298913 B CN 108298913B
Authority
CN
China
Prior art keywords
pipe body
fiber
pipe
pile
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201810288172.1A
Other languages
Chinese (zh)
Other versions
CN108298913A (en
Inventor
姬永生
刘本琳
石博文
张莉
吴守荣
徐圣楠
张领雷
黄国栋
刘丽丽
李军
李果
刘志勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China University of Mining and Technology CUMT
Original Assignee
China University of Mining and Technology CUMT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China University of Mining and Technology CUMT filed Critical China University of Mining and Technology CUMT
Priority to CN201810288172.1A priority Critical patent/CN108298913B/en
Publication of CN108298913A publication Critical patent/CN108298913A/en
Application granted granted Critical
Publication of CN108298913B publication Critical patent/CN108298913B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D5/00Bulkheads, piles, or other structural elements specially adapted to foundation engineering
    • E02D5/22Piles
    • E02D5/58Prestressed concrete piles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Piles And Underground Anchors (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a prestressed pipe pile for an underground sulfate erosion environment and a preparation method thereof, belonging to the field of civil engineering material manufacture. The pipe body of the prestressed pipe pile is a double-layer pipe body, the outer layer of the pipe body is a fiber-reinforced geopolymer-based composite material protective layer, the inner layer of the pipe body is a reinforced concrete pipe layer, and hardened foam concrete is filled in the pipe body. The protective layer isolates the prestressed reinforced concrete pipe layer loaded inside from the external corrosion environment. And after pile sinking is carried out in a construction site, foam concrete is filled into the pipe diameter, so that the inner wall of the pipe body is prevented from being directly damaged by infiltration of underground water, and the service life of the pile body in an underground sulfate corrosion environment is prolonged. The invention has simple construction process, can realize industrialized high-efficiency production, has high pipe body forming quality and durability, and can meet the requirement on the durability of the pile body in various underground sulfate erosion environments.

Description

Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof
Technical Field
The invention relates to a prestressed pipe pile, in particular to a prestressed pipe pile suitable for an underground sulfate corrosion environment and a preparation method thereof.
Background
Pile foundations have been widely used in today's various projects because they can overcome the effects of adverse geological conditions and provide high bearing capacity. The tubular pile is used as an important pile foundation form, and due to the characteristics of low water cement ratio centrifugal forming, prestressed reinforcement cage inclusion, industrial control production and the like, the tubular pile has good pile body forming quality and high strength, and is convenient and rapid to construct and can meet the requirements of various engineering geological bearing capacities. With the rapid development of economic construction in China and the continuous promotion of urbanization and coastal large development, the demand of the tubular pile is huge, and by the incomplete statistics of relevant data, the annual production of the tubular pile in China is nearly 2.5 million meters and the production value reaches more than 300 million yuan RMB by the end of 2007; by the end of 2011, more than 500 tubular pile production enterprises exist in China, the annual output exceeds 3.5 hundred million meters, and the tubular pile production method becomes the country with the highest tubular pile production in the world.
China has wide territory, complex and various natural environments, complex and various service environments of pile foundations, and very common marine and offshore chloride ion corrosion environments and inland salt lakes and saline-alkali soil sulfate corrosion environments. The degree and mechanism of the corrosion damage of the concrete structure in different corrosion environments are different, the concrete structure deterioration in the marine and offshore chloride corrosion environments is mainly rust swelling cracking damage caused by steel bar corrosion, but the durability deterioration of the concrete structure in the salt lake and saline-alkali soil sulfate corrosion environments is mainly sulfate crystallization swelling cracking damage. The corrosive action of the corrosive ions under the environmental conditions can cause considerable damage to the pile body, the quality of the pile body is seriously affected, the bearing capacity and various performances of the pile body are endangered, the damage phenomenon is continuously aggravated along with the prolonging of time, serious potential safety hazards are brought, and the safety of the upper structure is seriously threatened.
Therefore, the industrial building anti-corrosion design code GB50046-2008 stipulates that SO is a problem that the prestressed reinforcement of the pipe pile is sensitive to corrosion and the pipe wall is thin4 2-And Cl < - > are strong corrosive media, the prestressed concrete pipe pile in a sulfate corrosion environment is not adopted, and the prestressed concrete pipe pile in a chloride corrosion environment is not easy to adopt. The standard limitation undoubtedly brings crisis to the development of the pipe pile industry, and the urgent requirement is also metPile shapes more meeting the industry requirements are designed to serve the development of the building industry.
Geopolymer materials are a new type of inorganic non-metallic materials which are newly developed in recent years, and are the most promising type of alkali-activated cementing materials. The material is a gelled material bonded by aluminosilicate gelling components, and is prepared by taking natural aluminosilicate minerals or industrial solid wastes as main raw materials, fully mixing the natural aluminosilicate minerals or industrial solid wastes with other mineral admixtures and alkali silicate solutions, and then curing, forming and hardening the mixture at normal temperature or under a steam curing condition. Compared with the traditional portland cement, the geopolymer material has the advantages of high strength (the compressive strength can reach 60-150 MPa), acid and alkali corrosion resistance (the material is soaked in a sulfate solution for a long time, the performance is stable, the corrosion is avoided), compact microstructure and extremely low permeability (the permeability coefficient is less than one percent of that of portland cement), and the like; is an environment-friendly green building material. If the outer wall of the geopolymer protective layer is added on the surface of the pipe pile, the sulfate corrosion resistance of the pipe pile can be greatly improved, and therefore the pipe pile is applied to a sulfate corrosion environment.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a prestressed pipe pile suitable for an underground sulfate corrosion environment and a preparation method thereof so as to meet the requirement on the durability of a pile body under the underground sulfate corrosion condition.
In order to achieve the purpose, the technical scheme of the invention is realized as follows:
the prestressed pipe pile suitable for underground sulfate erosion environment comprises a pipe body. The pipe body is a double-layer pipe body, the outer layer of the pipe body is a fiber-reinforced geopolymer-based composite material protective layer, and the inner layer is a reinforced concrete pipe layer; the interior of the pipe body is filled with hardened foam concrete.
The fiber-reinforced geopolymer-based composite material is composed of a powder material and organic fibers, wherein the fibers account for the powder material in percentage by mass: 3 to 8 percent.
The powder material comprises the following components in percentage by mass: 50-70% of granulated blast furnace slag micro powder; volcanic ash material 10-30%; 5-15% of Portland cement; sodium silicate excitant (measured by Na2O contained in it) 4-8%.
The organic fiber is polypropylene fiber, polyacrylonitrile fiber, ultra-high molecular weight polyethylene fiber, polyvinyl alcohol fiber, polyester fiber or polyformaldehyde fiber.
The granulated blast furnace slag micro powder is S95-grade granulated blast furnace slag micro powder, and is prepared by carrying out magnetic separation and iron removal on granulated blast furnace slag and grinding the granulated blast furnace slag to ensure that the specific surface area is more than or equal to 400 m2/kg, wherein the superfine granulated blast furnace slag micro powder with the particle size of less than 30 mu m accounts for more than 90 percent of the total mass;
the volcanic ash material is silica fume, kaolin or fly ash.
The sodium silicate excitant is sodium silicate which is prepared by adjusting sodium hydroxide to sodium silicate, has the modulus of 1.0-2.0 and the baume degree of 37-41 degrees.
The foam concrete is a novel light heat-insulating material containing a large number of closed air holes, which is formed by fully foaming a foaming agent in a mechanical mode through a foaming system of a foaming machine, uniformly mixing foam and cement slurry, then carrying out cast-in-place construction or mould forming through a pumping system of the foaming machine and carrying out natural maintenance.
The tubular pile is produced by a secondary centrifugal process, the outer wall of the sulfate erosion resistant protective layer is formed by centrifugation for the first time, the isolation and containment function is mainly played, and the reinforced concrete pipe body is formed by centrifugation for the second time, and the stress bearing function is mainly played. The outer wall of the anti-corrosion protective layer formed for the first time is used for isolating the internal bearing pipe body from the external corrosion environment, so that the damage of the structural integrity of the internal bearing pipe body in the corrosion environment and the decline of various performances are avoided. The water consumption is preferably slurry liquid-solid ratio =0.3-0.5
The invention relates to a preparation method of a prestressed pipe pile suitable for an underground sulfate corrosion environment, which comprises the following steps:
step 1, adding water to prepare fiber-reinforced polymer-based composite material slurry according to the liquid-solid mass ratio = 0.3-0.5.
Step 2. preparation of sulfate erosion resistant pipe body
Placing a reinforcement cage in a centrifuge die; then, injecting fiber-reinforced geopolymer-based composite material slurry, wrapping a fiber-reinforced geopolymer-based composite material protective layer on the outer surface of the centrifugal casting pipe body, curing with a mold for a set time, and performing primary molding; and then distributing the concrete mixture of the pipe body, tensioning the prestressed tendons according to the construction process of the existing prestressed pipe pile, performing centrifugal molding again, and performing autoclaved curing to obtain the sulfate erosion resistant pipe body.
Step 3. core filling protection
After pile sinking on the construction site, foam concrete is filled into the sulfate erosion resistant pipe body, and the pipe pile is obtained after the foam concrete is hardened. The foam concrete does not bear load, and mainly plays a filling role to prevent underground water containing aggressive media from permeating into the pipe through the pipe pile joint and directly generating erosion damage to the inner part of the pipe body.
The size of the sulfate erosion resistance of the tubular pile is closely related to the performance of the outer wall of the protective layer formed by centrifugation for the first time, and the concrete characteristics are as follows: with the increase of the erosion resistance of the outer wall (material) and the thickness of the outer wall, the higher the erosion resistance of the tubular pile. In actual engineering, materials and wall thickness can be reasonably adjusted and designed according to the specific corrosion degree of the underground sulfate environment.
The time interval of two centrifugation of rational control, after the protective layer outer wall of first centrifugal forming is congealed and reaches certain intensity for the beginning, just can continue the feed and carry out the centrifugal forming for the second time, concrete intensity numerical value should be in order to guarantee that the tubular pile outer wall is not damaged in the centrifugal forming process for the second time and carry out the reasonable arrangement design as the basis. Thereby satisfying and making primary molded's outer wall and post forming's body zonulae occludens on the basis of not producing the damage to the outer wall furthest.
The tubular pile has the following beneficial effects:
(1) high anti-corrosion ability of sulfate and durability.
The protective layer outer wall structure of the product is prepared by adopting a fiber reinforced geopolymer material with high sulfate corrosion resistance. Through the protective layer outer wall structure of first centrifugal molding for the reinforced concrete structure of inside bearing avoids the interference of outside aggressive factors. Meanwhile, foam concrete is poured into the pipe, so that the corrosion of the inner wall of the pipe pile caused by the invasion of underground water is prevented. The two components act together to ensure that the bearing capacity of the pile body is stable, all the performances do not decline, and the requirement on the durability of the pile body in an erosion environment is met. The sulfate erosion resistance of the underground concrete structure construction requirement can be met through preliminary tests.
(2) Can meet the underground environment with different sulfate erosion degrees.
According to the difference of the sulfate ion content of the underground environment, the requirements of the underground erosion environment with different degrees on the durability of the pile body can be met by reasonably designing the wall thickness of the outer wall of the protective layer formed by first centrifugal molding. I.e. the greater the concentration of aggressive media in the underground environment, the more aggressive the attack and the thicker the centrifugally formed outer wall should be.
(3) Reasonable structure combination form and high bearing capacity
The outer wall of the protective layer and the filled foam concrete which are centrifugally formed for the first time play a role in isolation and protection, and also play a role in lateral restraint on the prestressed reinforced concrete pipe body, so that the mechanical property of the pipe body can be better played when the pipe body bears pressure, and the mechanical bearing capacity of the pipe pile is obviously higher than that of an equivalent prestressed pipe pile through tests.
(4) High production efficiency, high quality and low cost
The invention is suitable for large-scale industrialized and mechanized production, and has the advantages of high production efficiency, high molding quality, convenient construction, good durability, durability and high economic value.
Detailed Description
The present invention will be described in further detail with reference to examples.
Embodiment 1 is applicable to the prestressing force tubular pile of underground sulfate erosion environment, and its body is the reinforced concrete body. And wrapping a fiber-reinforced polymer-based composite material protective layer on the outer surface of the pipe body, and filling hardened foam concrete into the pipe body.
The fiber-reinforced geopolymer-based composite material of the fiber-reinforced geopolymer-based composite material protective layer is composed of a powder material and organic fibers, wherein the fibers account for the powder material in percentage by mass: 5 percent.
The powder material comprises the following components in percentage by mass: 60% of granulated blast furnace slag micro powder; 20% of volcanic ash material; 10% of Portland cement; sodium silicate trigger (measured as Na2O contained therein) 8%.
The organic fiber is polypropylene fiber.
The granulated blast furnace slag micro powder is S95-grade granulated blast furnace slag micro powder, and is prepared by carrying out magnetic separation and iron removal on blast furnace granulated slag and grinding the slag to ensure that the specific surface area is more than or equal to 400 m2/kg, wherein the superfine granulated blast furnace slag micro powder with the particle size of less than 30 mu m accounts for more than 90% of the total mass.
The volcanic ash material is silica fume.
The sodium silicate excitant is sodium silicate regulated by sodium hydroxide, and has a modulus of 1.5 and a baume degree of 39 degrees.
The foam concrete is a novel light heat-insulating material containing a large number of closed air holes, which is formed by fully foaming a foaming agent in a mechanical mode through a foaming system of a foaming machine, uniformly mixing foam and cement slurry, then carrying out cast-in-place construction or mould forming through a pumping system of the foaming machine and carrying out natural maintenance.
The preparation process of the tubular pile of the embodiment is as follows:
step 1, adding water to prepare fiber-reinforced polymer-based composite material slurry according to the liquid-solid mass ratio = 0.3-0.5.
Step 2. preparation of sulfate erosion resistant pipe body
Placing a reinforcement cage in a centrifuge die; then, injecting fiber-reinforced geopolymer-based composite material slurry, wrapping a fiber-reinforced geopolymer-based composite material protective layer on the outer surface of the centrifugal casting pipe body, maintaining the centrifugal casting pipe body with a mould for a set time, and forming; and then distributing the concrete mixture of the pipe body, tensioning the prestressed tendons according to the construction process of the existing prestressed pipe pile, performing centrifugal molding again to obtain the sulfate erosion resistant pipe body, and maintaining and molding.
Step 3. core filling protection
After pile sinking on the construction site, foam concrete is filled into the sulfate erosion resistant pipe body, and the pipe pile is obtained after the foam concrete is hardened.
Example 2, essentially the same as example 1, except that: the fiber of the fiber-reinforced geopolymer-based composite material accounts for the mass percentage of the powder material as follows: 3 percent.
The powder material comprises the following components in percentage by mass: 50% of granulated blast furnace slag micro powder; 30% of volcanic ash material; 15% of Portland cement; sodium silicate trigger (measured as Na2O contained therein) 5%.
The organic fiber is polyacrylonitrile fiber, ultra-high molecular weight polyethylene fiber, polyvinyl alcohol fiber, polyester fiber or polyformaldehyde fiber.
The volcanic ash material is kaolin or fly ash.
The sodium silicate excitant is sodium silicate regulated by sodium hydroxide, the modulus of which is 1.0 and the baume degree of which is 37 degrees.
Example 3 is essentially the same as example 1, except that: the fiber-reinforced geopolymer-based composite material is composed of a powder material and organic fibers, wherein the fibers account for the powder material in percentage by mass: 8 percent.
The powder material comprises the following components in percentage by mass: 70% of granulated blast furnace slag micro powder; pozzolanic material 10%; 15% of Portland cement; sodium silicate trigger (measured as Na2O contained therein) 5%.
The sodium silicate excitant is sodium silicate regulated by sodium hydroxide, and has a modulus of 2.0 and a baume degree of 41 degrees.

Claims (1)

1. A prestressed pipe pile suitable for underground sulfate erosion environment comprises a pipe body; the method is characterized in that: the pipe body is a double-layer pipe body, the outer layer of the pipe body is a fiber-reinforced geopolymer-based composite material protective layer, and the inner layer is a reinforced concrete pipe layer; filling hardened foam concrete into the pipe body;
the fiber-reinforced geopolymer-based composite material is composed of a powder material and organic fibers, wherein the organic fibers account for the powder material in percentage by mass: 3 to 8 percent;
the organic fiber is polypropylene fiber, polyacrylonitrile fiber, ultra-high molecular weight polyethylene fiber, polyvinyl alcohol fiber, polyester fiber or polyformaldehyde fiber;
the powder material comprises the following components in percentage by mass: 50-70% of granulated blast furnace slag micro powder; volcanic ash material 10-30%; 5-15% of Portland cement; sodium silicate excitant, Na contained therein2Metering O, which is 4-8%;
the granulated blast furnace slag micro powder is S95-grade granulated blast furnace slag micro powder, and is obtained by carrying out magnetic separation and iron removal treatment on blast furnace granulated slag and grinding the blast furnace granulated slag to ensure that the specific surface area is more than or equal to 400 m2The powder is prepared by per kg, wherein the superfine granulated blast furnace slag micro powder with the grain size of less than 30 mu m accounts for more than 90 percent of the total mass;
the volcanic ash material is silica fume, kaolin or fly ash;
the sodium silicate excitant is sodium silicate which is prepared by adjusting sodium hydroxide to sodium silicate, has the modulus of 1.0-2.0 and the baume degree of 37-41 degrees;
the prestressed pipe pile suitable for the underground sulfate corrosion environment is prepared according to the following steps:
step 1, adding water to prepare fiber-reinforced geopolymer-based composite material slurry according to the liquid-solid mass ratio = 0.3-0.5;
step 2. preparation of tube body
Placing a reinforcement cage in a centrifuge die; then, injecting fiber-reinforced geopolymer-based composite material slurry, wrapping a fiber-reinforced geopolymer-based composite material protective layer on the outer surface of the centrifugal casting pipe body, curing with a mold for a set time, and performing primary molding; distributing the concrete mixture of the pipe body, tensioning the prestressed tendons according to the construction process of the existing prestressed pipe pile, performing centrifugal molding again, and performing autoclaved curing to obtain the pipe body;
step 3. core filling protection
After pile sinking on the construction site, foam concrete is filled into the pipe body, and the pipe body is hardened.
CN201810288172.1A 2018-04-03 2018-04-03 Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof Active CN108298913B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810288172.1A CN108298913B (en) 2018-04-03 2018-04-03 Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810288172.1A CN108298913B (en) 2018-04-03 2018-04-03 Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof

Publications (2)

Publication Number Publication Date
CN108298913A CN108298913A (en) 2018-07-20
CN108298913B true CN108298913B (en) 2021-02-12

Family

ID=62846956

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810288172.1A Active CN108298913B (en) 2018-04-03 2018-04-03 Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108298913B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109081640A (en) * 2018-09-13 2018-12-25 福建瑞森水泥制品发展有限公司 A kind of geo-polymer composite pole and preparation method thereof
EP3880628A4 (en) * 2018-11-16 2022-08-03 Canasia Australia Pty Ltd Geopolymer compositions
US10843969B2 (en) 2019-03-01 2020-11-24 King Fahd University Of Petroleum And Minerals Alkali activated natural pozzolan based concrete containing ground granulated blast furnace slag
CN110423060A (en) * 2019-07-04 2019-11-08 福建省大地管桩有限公司 The steam-cured tubular pole manufacturing process of double moldings

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06336766A (en) * 1993-05-28 1994-12-06 Shimizu Corp Construction of high strength rc column/beam member, and form therefor
CN101275425A (en) * 2008-04-28 2008-10-01 北京航空航天大学 High durability inorganic gel material surface layer sheet material and construction method thereof
CN101289304A (en) * 2008-05-20 2008-10-22 南昌大学 Strengthen material for concrete antiabrasion layer of ocean engineering and production method thereof
CN106698992A (en) * 2017-01-10 2017-05-24 广西壮族自治区水利科学研究院 Anti-crack corrosion-resistant concrete admixture as well as preparation and application of anti-crack corrosion-resistant concrete admixture
CN106917400A (en) * 2017-03-03 2017-07-04 苏州中材建设有限公司 A kind of antidetonation corrosion resistant pile for prestressed pipe and preparation method thereof
CN107188467A (en) * 2017-06-06 2017-09-22 浙江加州国际纳米技术研究院台州分院 A kind of maritime concrete protects land used polymer coating materials
CN107268609A (en) * 2017-06-06 2017-10-20 哈尔滨工业大学深圳研究生院 A kind of double-decker damping stake and its construction method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06336766A (en) * 1993-05-28 1994-12-06 Shimizu Corp Construction of high strength rc column/beam member, and form therefor
CN101275425A (en) * 2008-04-28 2008-10-01 北京航空航天大学 High durability inorganic gel material surface layer sheet material and construction method thereof
CN101289304A (en) * 2008-05-20 2008-10-22 南昌大学 Strengthen material for concrete antiabrasion layer of ocean engineering and production method thereof
CN106698992A (en) * 2017-01-10 2017-05-24 广西壮族自治区水利科学研究院 Anti-crack corrosion-resistant concrete admixture as well as preparation and application of anti-crack corrosion-resistant concrete admixture
CN106917400A (en) * 2017-03-03 2017-07-04 苏州中材建设有限公司 A kind of antidetonation corrosion resistant pile for prestressed pipe and preparation method thereof
CN107188467A (en) * 2017-06-06 2017-09-22 浙江加州国际纳米技术研究院台州分院 A kind of maritime concrete protects land used polymer coating materials
CN107268609A (en) * 2017-06-06 2017-10-20 哈尔滨工业大学深圳研究生院 A kind of double-decker damping stake and its construction method

Also Published As

Publication number Publication date
CN108298913A (en) 2018-07-20

Similar Documents

Publication Publication Date Title
CN108298913B (en) Prestressed pipe pile suitable for underground sulfate corrosion environment and preparation method thereof
CN102718456B (en) Pre-tensioning method prestress concrete anticorrosion pipe pile as well as manufacture method and application thereof
CN112960952B (en) High-crack-resistance light-weight high-strength self-compacting concrete and preparation method thereof
CN113307597B (en) Nano recycled concrete, processing technology and application
CN101549976B (en) Concrete mixing proportion for deposition tube tunneltron segment
CN108409243B (en) Constraint pipe cast-in-place pile for underground sulfate erosion environment and preparation method thereof
CN110922118A (en) All-light high-strength concrete for assembled components and preparation method thereof
CN111116110A (en) Bulk solid waste base geopolymer thermal insulation concrete and preparation method thereof
CN104230259B (en) Water conveyance steel tube sand-cement slurry inner lining material
CN113045266A (en) Self-repairing fiber reinforced ultra-high performance concrete pole and processing method thereof
CN111533513A (en) Ultrahigh-performance concrete, electric pole and preparation method thereof
Nguyen-Tuan et al. Experimental study on mechanical and hydraulic properties of porous geopolymer concrete
WO2022199171A1 (en) Anti-crack concrete for frozen well walls and preparation method therefor
CN110818339A (en) Preparation method of light high-impermeability concrete
CN113754384A (en) Strong acid corrosion resistant cement mortar and preparation method thereof
CN111574185A (en) Acid corrosion resistant concrete pipe pile and preparation method thereof
CN116217193B (en) Alkali-activated full-solid waste seawater sea sand coral concrete for island reefs and preparation process
CN110922129A (en) Self-fireproof ultrahigh-performance concrete for reinforcing underground structure and application thereof
CN101475357B (en) Preparation of impervious material for wall of leachate balance basin
CN110606707A (en) Preparation method of light energy-saving anti-seismic partition plate
CN207211522U (en) Assembled steel tube high-strength concrete column
CN213268585U (en) Confined concrete column based on sea sand seawater TRC prefabricated shell
CN108487241B (en) Preparation method of prestressed pipe pile for chloride corrosion environment
Wang et al. Influence of recycled concrete fines content on the dynamic mechanical properties of coal mine roadway support mortar
CN104478307B (en) High-strength special concrete filled steel tube

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant