CN108295490A - A kind of colored hubble-bubble liquid and preparation method thereof with long preservation period that fades - Google Patents
A kind of colored hubble-bubble liquid and preparation method thereof with long preservation period that fades Download PDFInfo
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- CN108295490A CN108295490A CN201810042790.8A CN201810042790A CN108295490A CN 108295490 A CN108295490 A CN 108295490A CN 201810042790 A CN201810042790 A CN 201810042790A CN 108295490 A CN108295490 A CN 108295490A
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- bubble
- colored
- fades
- hubble
- bubble liquid
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/28—Soap-bubble toys; Smoke toys
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a kind of colored hubble-bubble liquid with long preservation period that fades, raw material includes by weight：Surfactant 5 10%；Weak cation type high molecular polymer 0.5 1%；Phenolphthalein and its derivative 4 8%；Organic amine acid-base buffer agent 1 3%；Polymer colloid 0.05 0.2%；Water-retaining agent 3 8%；Water 69.8 86.45%.The bubble is made in the following manner：1, it adds polymer colloid and increases vacuolar membrane thickness；2, organic amine acid-base buffer agent is added, so that bubble liquid is kept alkalinity and is shown color, but also increase the solubility of pigment；3, the pigment of cationic high-molecular Polymer adsorption anionic is added, increases the content of pigment on vacuolar membrane.
Description
Technical field
It can fade colored hubble-bubble liquid and preparation method thereof the present invention relates to one kind, it is especially a kind of with long preservation period to take off
The colored hubble-bubble liquid of color.
Background technology
Current market sales of bubble liquid is mostly water white transparency, light irradiation under film interference and show various face
Color.Both at home and abroad have in bubble liquid add water colo(u)r colored bubble in terms of patent (CN200810197188.8,
US20060004110, US2012035311A1).But colored hubble-bubble liquid made of this method is stained on clothing not easy cleaning,
It is unable to get promotion and application.Chinese patent CN 201110034788 describe it is a kind of use household liquid detergent as foaming agent,
The production method of phenolphthalein and its derivative as the colored bubble that fades of coloring agent.Phenolphthalein and its derivative exist in the bubble liquid
It develops the color in alkaline solution.Carbon dioxide in bubble or residue exposure in air absorption air, makes acid-base value drop to
It is neutral and aobvious colourless.Colored hubble-bubble liquid made from this method is stained with clothing clear water and is easy washing, is stained with to several days of the objects such as floor
It also can self-discoloration.This method has the following defects, it is made to cannot achieve commercialization：One, use household liquid detergent as foaming
Agent, complicated component, the coloured bubble shelf-life obtained is short, apt to deteriorate；Two, sodium hydroxide is corrosive to skin, should not use
In toy.Chinese patent CN 106890459A introduce a kind of colorful bubble liquid that fades of rose scent (actually bubble
Cream), which uses ethyl perfluorobutyl ether and petroleum ether to be used as discoloration pigment as automatic foaming agent, phenolphthalein and its derivative,
Carboxymethyl cellulose and other thickeners make the colored foam liquid for the automatic foaming that can be faded as thickener.The invention is used
Sodium bicarbonate replaces sodium hydroxide as alkaline conditioner, non-corrosive.But due to the too low defect of pigment concentration, color is too
It is light close to colourless, conventional bubble toy can not be fabricated to, therefore can be only applied to foam bubble.Foam bubble bubble film compares
It is thick.The intensive overlapping of bubble.Color can receive in this way.
Seem very simple to bubble colouring, is one highly difficult in fact, especially it also wants energy colour killing.Because of bubble
The thickness of vacuolar membrane only has hundreds of nanometers.And be affected by gravity and be unevenly distributed, top is thin, and lower part is thick.Pigment concentration is inadequate
Words do not show color at all.Pigment concentration is too high, and bubble liquid can not complete colour killing, contamination clothing and furniture.In suitable pigment
Color can just be shown by being also required to increase the thickness of bubble film under concentration.
Invention content
It is an object of the invention to overcome the above problem of the existing technology, proposes that one kind is with long preservation period and fade
Colored hubble-bubble liquid.The present invention can be applied not only to foam bubbles and can be also used for common bubbles.
The present invention is realized using following technical scheme：
One kind can fade colored hubble-bubble liquid, and raw material includes by weight：
A kind of preparation method of the colored hubble-bubble liquid with long preservation period that fades, which is characterized in that add macromolecule glue
Body increases vacuolar membrane thickness；Organic amine acid-base buffer agent is added, its bubble liquid is made to show color in alkalinity and is kept for a period of time,
When its generation bubble or raffinate exposure in air when with absorbing carbon dioxide fast reaction and slowly decompose, be in neutrality
And it fades；The pigment of cationic high-molecular Polymer adsorption anionic is added, increases the content of pigment on vacuolar membrane.
A kind of preparation method of the colored hubble-bubble liquid with long preservation period that fades, includes the following steps：
1) in 80 DEG C of water in ratio be added polymer colloid, prepare macromolecule glue liquid solution.
2) in 6 parts of water in ratio 1 part of ethanol amine and 3 parts of sodium bicarbonates are added, prepare organic amino acid alkali buffer.
3) organic amine acid-base buffer agent and water-retaining agent are pre-mixed according to the above ratio, phenolphthalein and its derivative and height is added
Cooling defoaming is placed in speed stirring.
4) macromolecule glue liquid solution, water and surfactant, weak cation type height is added in above-mentioned mixed liquor in order
Molecularly Imprinted Polymer, stirring at low speed mix to get the colored hubble-bubble liquid with long preservation period that fades.
In the present invention, the surfactant includes anionic surfactant, nonionic surfactant and two
Property surfactant, can be the mixture of a kind of or a variety of surfactants.Wherein anionic surfactant packet
Include salt, higher aliphatic sulfuric acid ester, aliphatic sulfonic compound, alkyl aryl sulphonic acid compound and the alkylnaphthalene of higher fatty acids
Azochlorosulfonate acid compound, such as neopelex, lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol etc.；It is used non-
Ionic surface active agent is polyoxyethylene non-ionic surfactant, such as alkyl phenol polyoxyethylene ether, high-carbon fatty alcohol are poly-
Ethylene oxide ether, polyoxyethylene carboxylate, polyoxyethylene amine, polyoxyethylate amide, polypropylene glycol ethylene oxide adduct,
Polyoxyethylated ionic surfactant etc.；Amphoteric surfactant includes amino acid pattern, betaine type, imidazoline type
With amine oxide type amphoteric surfactant, such as dodecyl alanine, dodecyl hydroxypropyl sulfobetaines, both sexes
Imidazoline, octadecyl dihydroxy ethyl amine oxide etc..
The phenolphthalein and its derivative have shows particular color under alkaline environment, and is in colourless spy under neutral environment
Property.Such as phenolphthalein, o-cresolphthalein, alpha naphthol phthalein and thymolphthalein etc..
The weak cation type high molecular polymer has a variety of active groups, can, absorption shape affine with many substances
At hydrogen bond, negatively charged pigment is adsorbed, and compatible with anion surfactant.Such as cationic polyacrylamide, diformazan
Base diallyl ammonium chloride-acrylamide copolymer etc..
The organic amine acid-base buffer agent has keeps pH for alkalinity in bubble liquid, increases the solubility of alkaline pigment,
And to skin without aggressive, the specially mixture of ethanol amine and sodium bicarbonate.
The polymer colloid has the function of that increase system viscosity improves bubble stability, such as polyvinyl alcohol, poly- second
Glycol and gelatin etc..It can be the mixture of a kind of or a variety of polymer colloids.
There is the water-retaining agent stronger hygroscopicity, the volatilization for slowing down moisture on bubble film to improve bubble in air
In duration, such as propylene glycol, glycerine and sorbierite.It can be the mixture of a kind of or a variety of water-retaining agent.
Compared with prior art, the present invention the advantage is that：
1, it adds polymer colloid and increases vacuolar membrane thickness；2, organic amine acid-base buffer agent is added, bubble liquid had both been made to keep alkali
Property and aobvious color, and increase the solubility of pigment；3, the color of cationic high-molecular Polymer adsorption anionic is added
Element increases the content of pigment on vacuolar membrane.
Specific implementation mode
It is below specific embodiments of the present invention, but is not limited only to the embodiment.
Embodiment 1
0.05 part of polyvinyl alcohol is added in 30 parts of 80 DEG C of water first and is stirred, is uniformly dissolved that be configured to polyvinyl alcohol molten
Liquid.Again in 6 parts of water in ratio 1 part of ethanol amine and 3 parts of sodium bicarbonates are added, prepare organic amino acid alkali buffer.Then exist
1 part of organic amine acid-base buffer agent and 8 parts of propylene glycol are added in another container, are uniformly mixed, add 4 parts of phenolphthalein and high-speed stirring
It mixes, places cooling defoaming.Prepared poly-vinyl alcohol solution, 48.45 parts of water are finally added in above-mentioned mixed liquor in order
With 8 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.5 part of cationic polyacrylamide, stirring at low speed mixes to protect for a long time
The red bubble liquid that fades deposited.
Embodiment 2
0.1 part of gelatin is added in 60 parts of 80 DEG C of water first and is stirred, is uniformly dissolved and is configured to gelatin solution.Again at 6 parts
In water in ratio 1 part of ethanol amine and 3 parts of sodium bicarbonates are added, prepare organic amino acid alkali buffer.Then in another container
2 parts of organic amine acid-base buffer agents and 6 parts of glycerine are added, are uniformly mixed, add 6 parts of o-cresolphthaleins and high-speed stirred, place
Cooling defoaming.Prepared gelatin solution, 18.9 parts of water and 6 parts of nonyl phenols are finally added in above-mentioned mixed liquor in order
Polyoxyethylene ether (degree of polymerization 8), 1 part of dimethyl diallyl ammonium chloride-acrylamide copolymer, stirring at low speed mixing to get
The pink colour bubble liquid with long preservation period that fades.
Embodiment 3
0.2 part of polyethylene glycol is added in 50 parts of 80 DEG C of water first and is stirred, is uniformly dissolved and is configured to polyglycol solution.
Again in 6 parts of water in ratio 1 part of ethanol amine and 3 parts of sodium bicarbonates are added, prepare organic amino acid alkali buffer.Then another
3 parts of organic amine acid-base buffer agents and 3 parts of sorbierites are added in one container, are uniformly mixed, add 5 parts of alpha naphthol phthaleins and high speed
Cooling defoaming is placed in stirring.It is last be added in above-mentioned mixed liquor in order prepared polyglycol solution, 29.8 parts
Water, 5 parts of lauryl sodium sulfate, 3 parts of dodecyl hydroxypropyl sulfobetaines and 1 part of dimethyl diallyl ammonium chloride-the third
Acrylamide copolymer, stirring at low speed mix to get the green bubble liquid with long preservation period that fades.
Embodiment 4
0.1 part of polyvinyl alcohol and 0.1 part of gelatin are added in 50 parts of 80 DEG C of water and are stirred first, is uniformly dissolved and is configured to gather
Vinyl alcohol-gelatin mixed solution.Again in 6 parts of water in ratio 1 part of ethanol amine and 3 parts of sodium bicarbonates are added, prepare organic amine
Acid-base buffer agent.Then 3 parts of organic amine acid-base buffer agents, 2 parts of glycerine and 4 parts of propylene glycol, mixing are added in another container
Uniformly, 4 parts of thymolphthaleins and high-speed stirred are added, cooling defoaming is placed.Finally it is added in above-mentioned mixed liquor in order
Prepared polyvinyl alcohol-gelatine mixed solution, 28.3 parts of water, 3 parts of amphoteric imidazolines, 5 parts of neopelexes and
0.5 part of cationic polyacrylamide, stirring at low speed mix to get the blue bubble liquid with long preservation period that fades.
Embodiment 1,2 embodiment 3 of embodiment and embodiment 4 to be generated using the toy bubble gun bought in the market made respectively
Red, powder red, green and blue bubble.
Claims (8)
1. a kind of colored hubble-bubble liquid with long preservation period that fades, raw material include by weight：
2. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, it is characterised in that：It lives on the surface
Property agent include anionic surfactant, nonionic surfactant and amphoteric surfactant, can be a kind of, or more
The mixture of kind surfactant.
3. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, it is characterised in that：The phenolphthalein and
Its derivative has shows particular color under alkaline environment, and is in colourless characteristic under neutral environment.
4. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, it is characterised in that：It is described it is weak sun from
Subtype high molecular polymer has a variety of active groups, can, absorption affine with many substances form hydrogen bond, absorption is negatively charged
Pigment, and it is compatible with anion surfactant.
5. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, it is characterised in that：The organic amine
Acid-base buffer agent has keeps pH for alkalinity in bubble liquid, increases the solubility of alkaline pigment, and to skin without strong corrosion
Property, the specially mixture of ethanol amine and sodium bicarbonate.
6. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, which is characterized in that the macromolecule
Colloid has the function of that increase system viscosity improves bubble stability.
7. a kind of colored hubble-bubble liquid with long preservation period that fades as described in claim 1, it is characterised in that：The water-retaining agent
With stronger hygroscopicity, the volatilization for slowing down moisture on bubble film improves the bubble aerial duration.
8. a kind of preparation method of the colored hubble-bubble liquid with long preservation period that fades, which is characterized in that add polymer colloid
Increase vacuolar membrane thickness；Organic amine acid-base buffer agent is added, its bubble liquid is made to show color in alkalinity and is kept for a period of time, when it
Generation bubble or raffinate exposure in air when with absorbing carbon dioxide fast reaction and slowly decompose, be in neutrality and take off
Color；The pigment of cationic high-molecular Polymer adsorption anionic is added, increases the content of pigment on vacuolar membrane.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810042790.8A CN108295490A (en) | 2018-01-17 | 2018-01-17 | A kind of colored hubble-bubble liquid and preparation method thereof with long preservation period that fades |
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| CN201810042790.8A CN108295490A (en) | 2018-01-17 | 2018-01-17 | A kind of colored hubble-bubble liquid and preparation method thereof with long preservation period that fades |
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| CN108295490A true CN108295490A (en) | 2018-07-20 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110339582A (en) * | 2019-05-29 | 2019-10-18 | 湖北文理学院 | A kind of bubble-water and preparation method thereof of bubble rapid decrease |
| CN114042326A (en) * | 2021-12-17 | 2022-02-15 | 萍乡亨厚新材科技有限公司 | Bubble water and preparation method thereof |
| CN116099397A (en) * | 2023-01-16 | 2023-05-12 | 广东省粤东技师学院 | Bubble water and preparation method thereof |
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| JP2005028038A (en) * | 2003-07-11 | 2005-02-03 | Tomoda Shokai:Kk | Soap bubble solution |
| US20060004110A1 (en) * | 2004-06-17 | 2006-01-05 | Sabnis Ram W | Composition and method for producing colored bubbles |
| CN102172434A (en) * | 2011-01-27 | 2011-09-07 | 山西大学 | Colored hubble-bubble liquid |
| CN102371075A (en) * | 2010-08-24 | 2012-03-14 | 上海复云文化传播有限公司 | Monochromatic color bubble solution capable of fading |
| JP2013078561A (en) * | 2011-10-04 | 2013-05-02 | Duck Hwan Bae | Soap bubble generator |
| CN106890459A (en) * | 2015-12-17 | 2017-06-27 | 焦秀花 | A kind of what rose fragrant was fade colorful bubble liquid |
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| JPH10507456A (en) * | 1994-10-20 | 1998-07-21 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Composition for body care |
| JP2005028038A (en) * | 2003-07-11 | 2005-02-03 | Tomoda Shokai:Kk | Soap bubble solution |
| US20060004110A1 (en) * | 2004-06-17 | 2006-01-05 | Sabnis Ram W | Composition and method for producing colored bubbles |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110339582A (en) * | 2019-05-29 | 2019-10-18 | 湖北文理学院 | A kind of bubble-water and preparation method thereof of bubble rapid decrease |
| CN114042326A (en) * | 2021-12-17 | 2022-02-15 | 萍乡亨厚新材科技有限公司 | Bubble water and preparation method thereof |
| CN114042326B (en) * | 2021-12-17 | 2023-05-26 | 萍乡亨厚新材科技有限公司 | Bubble water and preparation method thereof |
| CN116099397A (en) * | 2023-01-16 | 2023-05-12 | 广东省粤东技师学院 | Bubble water and preparation method thereof |
| CN116099397B (en) * | 2023-01-16 | 2023-10-24 | 广东省粤东技师学院 | Bubble water and preparation method thereof |
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| CB02 | Change of applicant information |
Address after: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant after: Xiamen Cara wind Education Technology Co., Ltd. Address before: 361000 07, unit 13, Po Ye tower, 66 East Taiwan Road, Guanyin Mountain, Xiamen, Fujian. Applicant before: Xiamen Cara wind Entertainment Co., Ltd. |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180720 |
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| RJ01 | Rejection of invention patent application after publication |