CN108277052A - A kind of heavy oil, diesel oil in alcohol group compound emulsifying agent preparation method - Google Patents
A kind of heavy oil, diesel oil in alcohol group compound emulsifying agent preparation method Download PDFInfo
- Publication number
- CN108277052A CN108277052A CN201810337464.XA CN201810337464A CN108277052A CN 108277052 A CN108277052 A CN 108277052A CN 201810337464 A CN201810337464 A CN 201810337464A CN 108277052 A CN108277052 A CN 108277052A
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- Prior art keywords
- parts
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- oil
- organic solvent
- added
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- 239000000295 fuel oil Substances 0.000 title claims abstract description 35
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 34
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 alcohol group compound Chemical class 0.000 title claims description 11
- 239000000178 monomer Substances 0.000 claims abstract description 30
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011737 fluorine Substances 0.000 claims abstract description 21
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 21
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 17
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 17
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 17
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000008117 stearic acid Substances 0.000 claims abstract description 17
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 16
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims abstract description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 12
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 12
- 239000011734 sodium Substances 0.000 claims abstract description 12
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical class C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000003158 alcohol group Chemical group 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 239000003960 organic solvent Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 14
- 239000012456 homogeneous solution Substances 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 13
- 238000009413 insulation Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000004945 emulsification Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- CAQWNKXTMBFBGI-UHFFFAOYSA-N C.[Na] Chemical compound C.[Na] CAQWNKXTMBFBGI-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 229910003472 fullerene Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 208000021760 high fever Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010729 system oil Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
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- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
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- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid
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- C10L1/14—Organic compounds
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- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
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- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
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- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/228—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen double bond, e.g. guanidines, hydrazones, semicarbazones, imines; containing at least one carbon-to-nitrogen triple bond, e.g. nitriles
- C10L1/2283—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen double bond, e.g. guanidines, hydrazones, semicarbazones, imines; containing at least one carbon-to-nitrogen triple bond, e.g. nitriles containing one or more carbon to nitrogen double bonds, e.g. guanidine, hydrazone, semi-carbazone, azomethine
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
- C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
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Abstract
The present invention discloses a kind of preparation method for heavy oil, the compound emulsifying agent of diesel oil in alcohol group, including the mass ratio of component A and B component is 35:1, wherein wherein component A includes 30 60 parts of acrylic monomers, 1 10 parts of fluorine component, 13 parts of polyisocynate monomer, 0.1 2 parts of fatty alcohol polyoxyethylene ether, 5 10 parts of methyl benzotriazazole;B component includes 0.5 10 parts of sulfomethylated humic acid sodium, 5 20 parts of sorbester p17,1 30 parts of cobalt naphthenate, 5 10 parts of ethylenediamine, 15 25 parts of phthalic anhydride, 48 parts of stearic acid.The compound emulsifying agent of this technology production can be used for oil products system, be widely used, and make simply, cost is relatively low, and stability is good.
Description
Technical field
The present invention relates to a kind of systems of the high-efficiency environment friendly energy-conservation emulsifier in emulsifier more particularly to heavy oil, diesel oil in alcohol group
Preparation Method.
Background technology
The energy is the lifeline of national security, is asked wherein non-renewable petroleum resources are most important the energy safety of supply
One of topic.In order to effectively construct energy security, each state all attaches great importance to oil consumption and deposit, and various methods is taken actively to grind
Study carefully reduction or substitutes the consumption of petroleum resources.With science and technology and economic rapid development, the practical owning amount of automobile in China and by
This caused oil demand is always in rapid growth.Auto industry is one of the mainstay of the national economy industry in China, since
Since 2010, auto industry accounts for 5.5% or more of the proportion of GDP, and China's auto output has leapt to third place in the world, accounted for about
The 6%~8% of world car total output.According to statistics, China is in motor benzines in 2018 and diesel consumption total amount ratio 2014
It nearly doubles, reaches 300,000,000 tons or so, therefore petrol and diesel oil problem in short supply will be more serious.
Heavy oil and diesel oil in alcohol group are all a kind of important fuel, many in oil plant, chemical plant, steel mill and power plant etc.
Place generally all uses heavy oil as fuel, still, since heavy oil is oil deep processing surplus materials, no matter which kind of high fever is used
The combustion apparatus of effect, direct combusting heavy oil inevitably cause combustion reaction incomplete, form black smoke, coking and carbon deposit,
The problem of causing fuel largely to waste, while also bringing environmental pollution.It is abundant generally for burning is ensured, excessive sky need to be injected
Gas, and heat has been taken away in the discharge of these excess airs, causes thermal loss.
To generally burn after heavy oil emulsive to solve the above problems at present, but do not have also it is a kind of effectively can make emulsification after
Heavy oil active combustion, while can also environmental emission reduction emulsifier.
Invention content
For overcome the deficiencies in the prior art, a kind of performance of present invention offer is stable, can efficiently synthesize heavy oil, also has section
High-efficiency environment friendly energy-conservation emulsifier and preparation method thereof that can be in the heavy oil of environment protecting, diesel oil.In addition, the composite milk of the application
Agent can be also used for emulsification alcohol radical-diesel oil system, so that diesel oil in alcohol group is steadily in the state of alcohol oil-in always, effective
It is not layered in time limit.
The technical scheme is that:A kind of preparation method of heavy oil, diesel oil in alcohol group environment-friendly type compound emulsifying agent, including with
Lower step:
A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then mixed acrylate monomer, fluorochemical monomer equal
It is even, then be slowly dropped into organic solvent, feed time is controlled, charging, which finishes, continues insulation reaction 2-4h, and stopping reaction is simultaneously cooling
Fluorine-containing oligomer resin solution is obtained to room temperature;
B, it by fatty alcohol polyoxyethylene ether, polyisocynate monomer input fluorine-containing oligomer resin solution, fully stirs
After mixing 1~2h, methyl benzotriazazole, stirring is added, reaction 1h obtains component A mixed solution;
C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, ethylenediamine stirs evenly at 40-70 DEG C according to proportioning, is then added
Phthalic anhydride and stearic acid continue to stir 1h, form B component homogeneous solution;
D, the B component homogeneous solution of step c is added in the component A mixed solution that step b is obtained, keeps 40-60 DEG C of reaction
1-3h removes excessive organic solvent, obtains mixed emulsifier, preferably 50 DEG C of reaction condition, 2h;
Wherein,
Component A includes the component of following mass fraction:
About 30-60 parts of acrylic monomers,
1-10 parts of fluorine component,
1-3 parts of polyisocynate monomer,
0.1-2 parts of fatty alcohol polyoxyethylene ether,
5-10 parts of methyl benzotriazazole;
B component includes the component of following mass fraction:
0.5-10 parts of sulfomethylated humic acid sodium,
5-20 parts of sorbester p17,
1-30 parts of cobalt naphthenate,
5-10 parts of ethylenediamine,
15-25 parts of phthalic anhydride,
4-8 parts of stearic acid.
Preferably, the mass ratio of compound emulsifying agent of the present invention, component A and B component is 3-5:1, wherein A group agent
Component and its weight part ratio be:40-50 parts of acrylic monomers, 5-10 parts of fluorine component, 1-2 parts of polyisocynate monomer,
0.1-1 parts of fatty alcohol polyoxyethylene ether, 5-8 parts of methyl benzotriazazole;
The component and its weight part ratio of B group agent be:0.5-3 parts of sulfomethylated humic acid sodium, 8-10 parts of sorbester p17, cobalt naphthenate
10-20 parts, 8-10 parts of ethylenediamine, 15-20 parts of phthalic anhydride, 4-6 parts of stearic acid.
Wherein, it according to mass ratio is 1 that the acrylate monomer, which is styrene, methyl methacrylate or the two,:(2-
20)Composition;The fluorine component is Hexafluorobutyl mathacrylate.
The polyisocynate monomer is toluene di-isocyanate(TDI) and its polymer, 4,4- diphenylmethane diisocyanates
One kind in ester or its multiple combinations.
The organic solvent is propylene glycol or ethylene glycol.
In the present invention, because generating fluorine-containing propene acid oligomer using acrylate monomer in component A and fluorochemical monomer polymerization,
So that polymer shows certain physico-chemical properties of fluorochemical to a certain extent.Therefore, to have excellent hydrophobicity same
When, it is also equipped with certain oil repellency, can steadily emulsify containing alcohol-oil interface or heavy oil, diesel oil system, increases alcohols and bavin
The intersolubility of oil, application system is extensive, and effect stability;Because using the naphthenic compound in group agent B and suitably feeding intake
Proportioning, has the function of catalytic combustion-supporting, and to make the emulsifier of the present invention by after heavy oil emulsive, the discharge of heavy oil combustion subtracts significantly
It is few, SO2Discharge can reduce 90% or more, methyl benzotriazazole also has the work for preventing gasoline engine or diesel-engine equipment from corroding
With;The emulsifiers such as component B stearic acid, phthalic anhydride, make the present invention emulsifier have very strong emulsifying capacity, heavy oil emulsification when,
The ratio of heavy oil and water can reach 1:1, the heavy oil after emulsification is the molecular structure of water-in-oil type, and the heavy oil storage one after emulsification
Year or more be not in water-oil separating for a long time, performance is highly stable.
The emulsifier of the present invention can be applied not only to emulsification heavy oil, while can also be applied to diesel oil emulsification or contain alcohol
Base-diesel oil system, while compound system is taken into account, application is good, and the compound emulsifying agent of formation has stability good, is easy recycling,
The advantages of recycling.
The present invention emulsifier effectively heavy oil, diesel oil or fuel oil can be emulsified, make the heavy oil after emulsification, diesel oil or
It can more effectively burn, it, can fuel-economizing 35%-45%, reduction SO after heavy oil emulsifier using the present invention290% or more discharge, storage
It is not in water-oil separating to deposit 1 year or more, and performance is highly stable.The present invention is by a part of conventional heavy oils emulsifier component and newly
Type resin emulsifier forms composite emulsifying system, and heavy wool system can be emulsified, small for different oil product usage amounts,
Preparation method is simple, at low cost, recyclable, and the stability of oil emulsion is good, not stratified, is taking into account the same of many body system oil product raw material
When, good emulsifying effectiveness may be implemented.
Specific implementation mode
The present invention will be further described in detail with reference to the specific embodiments.
Embodiment 1
Heavy oil, alcohol radical-diesel oil high efficiency composition emulsifier preparation method, by component A and B component according to mass ratio 3:1 is having
It is prepared in solvent, wherein component A includes 30-60 parts of styrene and methyl methacrylate, methacrylic acid hexafluoro fourth
1-10 parts of ester, 4,4- 1-3 parts of methyl diphenylene diisocyanates, 0.1-2 parts of fatty alcohol polyoxyethylene ether, methyl benzotriazazole
5-10 parts;B component includes 0.5-10 parts of sulfomethylated humic acid sodium, 5-20 parts of sorbester p17,1-30 parts of cobalt naphthenate, ethylenediamine 5-
10 parts, 15-25 parts of phthalic anhydride, 4-8 parts of stearic acid.It prepares in accordance with the following methods:A, organic solvent is added in reaction kettle, is heated up
To 50-70 DEG C, then acrylate monomer, fluorochemical monomer are uniformly mixed, then is slowly dropped into organic solvent, when control feeds
Between, charging, which finishes, continues insulation reaction 2-4h, stops reacting and is cooled to room temperature to obtain fluorine-containing oligomer resin solution;
B, 1 will be sufficiently stirred in fatty alcohol polyoxyethylene ether, polyisocynate monomer input fluorine-containing oligomer resin solution~
After 2h, methyl benzotriazazole, stirring is added, reaction 1h obtains mixed solution;C, by methyl sodium humate, sapn, aphthenic acids
Cobalt, ethylenediamine are stirred evenly according to proportioning at 40-70 DEG C, and phthalic anhydride and stearic acid is then added, and continue to stir 1h, are formed uniformly molten
Liquid;D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, 40-60 DEG C of reaction 1-3h is kept, according to need
It wants, removes excessive organic solvent, obtain mixed emulsifier.
Embodiment 2
Heavy oil, alcohol radical-diesel oil high efficiency composition emulsifier preparation method, by component A and B component according to mass ratio 3:1 is having
It is prepared in solvent, wherein component A includes 30 parts of styrene, 1 part of Hexafluorobutyl mathacrylate, 4,4- diphenyl methanes
1 part of diisocyanate, 0.1 part of fatty alcohol polyoxyethylene ether, 5 parts of methyl benzotriazazole;B component includes sulfomethylated humic acid sodium
0.5 part, 5 parts of sorbester p17,1 part of cobalt naphthenate, 5 parts of ethylenediamine, 15 parts of phthalic anhydride, 4 parts of stearic acid.It prepares in accordance with the following methods:
A, organic solvent is added in reaction kettle, is warming up to 50 DEG C, be then uniformly mixed acrylate monomer, fluorochemical monomer, then delay
It is slow to instill in organic solvent, feed time is controlled, charging, which finishes, continues insulation reaction 2h, stops reacting and is cooled to room temperature to obtain
Fluorine-containing oligomer resin solution;B, fatty alcohol polyoxyethylene ether, polyisocynate monomer input fluorine-containing is low
In copolymer resin solution, after being sufficiently stirred 1h, methyl benzotriazazole, stirring is added, reaction 1h obtains mixed solution;C, Jiang Jia
Base sodium humate, sapn, cobalt naphthenate, ethylenediamine are stirred evenly according to proportioning at 40 DEG C, and phthalic anhydride and stearic acid is then added, after
Continuous stirring 1h, forms homogeneous solution;D, the homogeneous solution of step c is added in the mixed solution that step b is obtained, is kept for 40 DEG C
1h is reacted, as needed, excessive organic solvent is removed, obtains mixed emulsifier.
Embodiment 3
Heavy oil, alcohol radical-diesel oil high efficiency composition emulsifier preparation method, by component A and B component according to mass ratio 3:1 is having
It being prepared in solvent, wherein component A includes 40 parts of methyl methacrylate, 5 parts of Hexafluorobutyl mathacrylate, and 4,4- bis-
2 parts of methylenebis phenyl isocyanate, 1 part of fatty alcohol polyoxyethylene ether, 8 parts of methyl benzotriazazole;B component includes that sulphur methyl is rotten
Grow 5 parts of sour sodium, 10 parts of sorbester p17,10 parts of cobalt naphthenate, 6 parts of ethylenediamine, 20 parts of phthalic anhydride, 6 parts of stearic acid.In accordance with the following methods
It prepares:A, organic solvent is added in reaction kettle, is warming up to 60 DEG C, be then uniformly mixed acrylate monomer, fluorochemical monomer,
It is slowly dropped into organic solvent again, controls feed time, charging, which finishes, continues insulation reaction 3h, stops reacting and being cooled to room temperature
Obtain fluorine-containing oligomer resin solution;B, fatty alcohol polyoxyethylene ether, polyisocynate monomer are put into fluorine-containing propene
In acid oligomer resin solution, after being sufficiently stirred 1~2h, methyl benzotriazazole, stirring is added, reaction 1h obtains mixing molten
Liquid;C, by methyl sodium humate, sapn, cobalt naphthenate, ethylenediamine stirs evenly according to proportioning at 50 DEG C, be then added phthalic anhydride and
Stearic acid continues to stir 1h, forms homogeneous solution;D, the homogeneous solution of step c is added to the mixed solution that step b is obtained
In, keep 50 DEG C of reaction 2h to remove excessive organic solvent as needed, obtain mixed emulsifier.
Embodiment 4
Heavy oil, alcohol radical-diesel oil high efficiency composition emulsifier preparation method, by component A and B component according to mass ratio 3:1 is having
It is prepared in solvent, wherein component A includes 60 parts of styrene and methyl methacrylate, Hexafluorobutyl mathacrylate 10
Part, 4,4- 3 parts of methyl diphenylene diisocyanates, 2 parts of fatty alcohol polyoxyethylene ether, 10 parts of methyl benzotriazazole;B component packet
Include 10 parts of sulfomethylated humic acid sodium, 20 parts of sorbester p17,30 parts of cobalt naphthenate, 10 parts of ethylenediamine, 25 parts of phthalic anhydride, 8 parts of stearic acid.
It prepares in accordance with the following methods:A, organic solvent is added in reaction kettle, is warming up to 70 DEG C, then by acrylate monomer, fluorine-containing
Monomer is uniformly mixed, then is slowly dropped into organic solvent, and feed time is controlled, and charging, which finishes, continues insulation reaction 4h, stops anti-
It should and be cooled to room temperature to obtain fluorine-containing oligomer resin solution;B, by fatty alcohol polyoxyethylene ether, polyisocyanates list
Body is put into fluorine-containing oligomer resin solution, after being sufficiently stirred 2h, methyl benzotriazazole is added, 1h is reacted in stirring
Obtain mixed solution;C, by methyl sodium humate, sapn, cobalt naphthenate, ethylenediamine stirs evenly according to proportioning at 70 DEG C, then
Phthalic anhydride and stearic acid is added, continues to stir 1h, forms homogeneous solution;D, the homogeneous solution of step c is added to what step b was obtained
In mixed solution, 60 DEG C of reaction 3h is kept to remove excessive organic solvent as needed, obtain mixed emulsifier.
Embodiment 5
Heavy oil, alcohol radical-diesel oil high efficiency composition emulsifier preparation method, by component A and B component according to mass ratio 2:1 is having
It is prepared in solvent, wherein component A includes 50 parts of styrene and methyl methacrylate, Hexafluorobutyl mathacrylate 8
Part, 4,4- 2 parts of methyl diphenylene diisocyanates, 1 part of fatty alcohol polyoxyethylene ether, 6 parts of methyl benzotriazazole;B component packet
Include 8 parts of sulfomethylated humic acid sodium, 10 parts of sorbester p17,20 parts of cobalt naphthenate, 7 parts of ethylenediamine, 16 parts of phthalic anhydride, 6 parts of stearic acid.It presses
It is prepared according to following methods:A, organic solvent is added in reaction kettle, is warming up to 50-60 DEG C, then by acrylate monomer, fluorine-containing
Monomer is uniformly mixed, then is slowly dropped into organic solvent, and feed time is controlled, and charging, which finishes, continues insulation reaction 2-3h, stops
It reacts and is cooled to room temperature to obtain fluorine-containing oligomer resin solution;B, by fatty alcohol polyoxyethylene ether, polyisocyanates
Monomer is put into fluorine-containing oligomer resin solution, and after being sufficiently stirred 2h, methyl benzotriazazole is added, stirs, reaction
1h obtains mixed solution;C, by methyl sodium humate, sapn, cobalt naphthenate, ethylenediamine stirs according to proportioning at 40-50 DEG C equal
It is even, phthalic anhydride and stearic acid is then added, continues to stir 1h, forms homogeneous solution;D, the homogeneous solution of step c is added to step
In the mixed solution that b is obtained, 40-50 DEG C of reaction 1-3h is kept to remove excessive organic solvent as needed, obtain composite milk
Agent.
By oil product:Compound emulsifying agent:Solvent:Graphene or fullerene are according to 100-120:10-20:5-10:0.1-1 weight
Than obtaining oil emulsion after mixing, our experiments show that, it can stablize after oil emulsion is static not stratified;For heavy oil emulsive, by one
Year or more still there is not water-oil separating, and sulphur-containing substance discharge can be reduced with fuel-economizing 30%, for diesel oil in alcohol group, due to tool
There are the effect of part resin, diesel oil in alcohol group that can dissolve each other very well, less carbon emission, and also component A can be played with component B and be cooperateed with work
With the consumption of diesel oil or heavy oil can be substantially reduced, and can reduce petrochemical industry cost, while being applicable in multiple systems, pair simultaneously
System with diesel oil and/or diesel oil in alcohol group is with good emulsifying effectiveness.
Application examples 1
100kg heavy oil is taken, 60 DEG C is heated to and stirs evenly, adds 10 kg emulsifiers, 5g solvents, 0.1g fullerenes, through high speed
5-15min is stirred, appropriate 60 DEG C of water is added as needed, is used after standing 24 hours.
Application examples 2
120kg diesel oil in alcohol group is taken, 60 DEG C is heated to and stirs evenly, adds 10 kg emulsifiers, 10g solvents, 0.5g fullerenes,
Through high-speed stirred 5-15min, the water of 70 DEG C of addition, which is mixed evenly, as needed becomes high-efficiency environment friendly oil emulsion, stands
It is used after 24 hours.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those skilled in the art within the technical scope disclosed by the invention, can without the variation that creative work is expected or
It replaces, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims
Subject to fixed protection domain.
Claims (2)
1. a kind of preparation method for heavy oil, the compound emulsifying agent of diesel oil in alcohol group, which is characterized in that include the following steps:
A, organic solvent is added in reaction kettle, is warming up to 50-70 DEG C, then mix styrene, Hexafluorobutyl mathacrylate
It closes uniformly, then is slowly dropped into organic solvent, control feed time, charging, which finishes, continues insulation reaction 2-4h, stops reacting simultaneously
It is cooled to room temperature to obtain fluorine-containing oligomer resin solution;
B, it by fatty alcohol polyoxyethylene ether, polyisocynate monomer input fluorine-containing oligomer resin solution, fully stirs
After mixing 1~2h, methyl benzotriazazole, stirring is added, reaction 1h obtains component A mixed solution;
C, by sulfomethylated humic acid sodium, sapn, cobalt naphthenate, ethylenediamine about stirs evenly at 40-70 DEG C according to proportioning, then plus
Enter phthalic anhydride and stearic acid, continues to stir 1h, form B component homogeneous solution;
D, the B component homogeneous solution of step c is added in the component A mixed solution that step b is obtained, keeps 50 DEG C of reaction 2h,
Excessive organic solvent is removed, compound emulsifying agent is obtained;
Wherein,
Wherein component A is grouped as by the group of following mass fraction:
30 parts of styrene,
1 part of Hexafluorobutyl mathacrylate,
1 part of polyisocynate monomer,
0.1 part of fatty alcohol polyoxyethylene ether,
5 parts of methyl benzotriazazole;
B component is grouped as by the group of following mass fraction:
0.5 part of sulfomethylated humic acid sodium,
5 parts of sorbester p17,
1 part of cobalt naphthenate,
5 parts of ethylenediamine,
15 parts of phthalic anhydride,
4 parts of stearic acid;
The polyisocynate monomer is in toluene di-isocyanate(TDI) and its polymer, 4,4- methyl diphenylene diisocyanates
One kind or its multiple combinations, organic solvent be propylene glycol or ethylene glycol.
2. preparation method according to claim 1, which is characterized in that the mass ratio of component A and B component is 3-5:1.
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