CN108264868A - 一种新型双组份水性胶黏剂及其制备的复合纸 - Google Patents

一种新型双组份水性胶黏剂及其制备的复合纸 Download PDF

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CN108264868A
CN108264868A CN201710994207.9A CN201710994207A CN108264868A CN 108264868 A CN108264868 A CN 108264868A CN 201710994207 A CN201710994207 A CN 201710994207A CN 108264868 A CN108264868 A CN 108264868A
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洪逸宾
谢伏将
张彦杰
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Wuxi Edward Color Printing Packaging Co Ltd
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    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/31—Heat sealable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/24—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00—Animal or vegetable based
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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Abstract

本发明涉及一种粘合剂，尤其是一种新型双组份水性胶黏剂，包括乙烯‑醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯‑醋酸乙烯聚合物体系为主剂，异氰酸根聚合物为固化剂，主剂与固化剂配比为100:1~3。所述异氰酸根聚合物为二异氰酸酯、三异氰酸酯、甲苯二异氰酸酯、二苯基甲烷二异氰酸酯或异佛尔酮二异氰酸酯中的一种或两种以上。本发明提供的一种新型双组份水性胶黏剂复合牢度好、耐温性好、高温高湿环境下热封不起泡、价格低，用一种新型双组份水性胶黏剂制成的复合纸不易出现气泡、耐高温、含水率低，复合纸的制备方法简单、生产效率高。

Description

一种新型双组份水性胶黏剂及其制备的复合纸
技术领域
本发明涉及一种粘合剂，尤其是一种新型双组份水性胶黏剂及其制备的复合纸。
背景技术
现有的铝纸复合时所用单组份或双组份胶水，复合时容易出现气泡，出现复合不良的情况。大部分的铝纸在进行食品包装时需要高温封口，此时粘合剂若是不耐高温、含水率高、或者有复合不良区域等其他因素，就容易出现热封后起泡或者复合材料被气泡涨裂的情况，生产出的产品也不合格。
发明内容
为解决上述问题，本发明提供一种复合牢度好、耐温性好、高温高湿环境下热封不起泡、价格低的一种新型双组份水性胶黏剂，具体技术方案为：
一种新型双组份水性胶黏剂，包括乙烯-醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯-醋酸乙烯聚合物体系为主剂，异氰酸根聚合物为固化剂，主剂与固化剂配比为100:1~3。
优选的，所述异氰酸根聚合物为二异氰酸酯、三异氰酸酯、甲苯二异氰酸酯、二苯基甲烷二异氰酸酯或异佛尔酮二异氰酸酯中的一种或两种以上。
一种复合纸，包括依次紧贴的复合层、粘合层和纸张层；所述粘合层的粘合剂为一种新型双组份水性胶黏剂。
优选的，所述复合层为铝箔、聚烯烃、聚酯或尼龙中的一种。
进一步，所述粘合剂的涂布量为1.5~2.5g/m2。
一种复合纸的制备方法，包括以下步骤：
S1、将粘合剂涂布在纸张层或复合层上，然后复合纸张层和复合层得到复合纸；
S2、将复合纸在温度为65~85℃下进行熟化；
S3、熟化后的固化时间不小于1h。
优选的，步骤S1中所述的粘合剂的涂布量为1.5~2.5g/m2。
一种新型双组份水性胶黏剂涂布量在1.5~2.5g/m2之间，复合温度在65~85℃之间，可常温熟化。可作为纸张与铝箔、纸张与处理过的聚烯烃、聚酯、尼龙等材料的粘合剂。可以应用在糖果、巧克力、调味品、咖啡等的食品包装上。复合后1小时就能达到很好的复合强度，并且可以在复合完成后立即进行分切工作。
与现有技术相比本发明具有以下有益效果：
本发明提供的一种新型双组份水性胶黏剂复合牢度好、耐温性好、高温高湿环境下热封不起泡、价格低，用一种新型双组份水性胶黏剂制成的复合纸不易出现气泡、耐高温、含水率低，复合纸的制备方法简单、生产效率高。
说明书附图
图1是一种复合纸的结构示意图。
具体实施方式
现结合附图对本发明作进一步说明。
实施例一
一种新型双组份水性胶黏剂，包括乙烯-醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯-醋酸乙烯聚合物体系为主剂、异氰酸根聚合物为固化剂，主剂与固化剂配比为100:1。
异氰酸根聚合物包括二异氰酸酯、甲苯二异氰酸酯和二苯基甲烷二异氰酸酯。实施例二
一种新型双组份水性胶黏剂，包括乙烯-醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯-醋酸乙烯聚合物体系为主剂、异氰酸根聚合物为固化剂，主剂与固化剂配比为100:2。
异氰酸根聚合物包括三异氰酸酯、甲苯二异氰酸酯、和异佛尔酮二异氰酸酯。
实施例三
一种新型双组份水性胶黏剂，包括乙烯-醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯-醋酸乙烯聚合物体系为主剂、异氰酸根聚合物为固化剂，主剂与固化剂配比为100:3。
异氰酸根聚合物包括二异氰酸酯、三异氰酸酯、甲苯二异氰酸酯、二苯基甲烷二异氰酸酯和异佛尔酮二异氰酸酯。
实施例四
如图1所示，一种复合纸，包括依次紧贴的复合层、粘合层和纸张层；所述粘合层的粘合剂为一种新型双组份水性胶黏剂，复合层为铝箔。粘合剂的涂布量为1.5g/m2。
实施例五
如图1所示，一种复合纸，包括依次紧贴的复合层、粘合层和纸张层；所述粘合层的粘合剂为一种新型双组份水性胶黏剂，复合层为聚酯。粘合剂的涂布量为2.5g/m2。
实施例六
一种复合纸的制备方法，包括以下步骤：
S1、将粘合剂涂布在纸张层或复合层上，然后复合纸张层和复合层得到复合纸，粘合剂的涂布量为1.5g/m2；
S2、将复合纸在温度为65℃下进行熟化；
S3、熟化后的固化时间为1.2h。
实施例七
一种复合纸的制备方法，包括以下步骤：
S1、将粘合剂涂布在纸张层或复合层上，然后复合纸张层和复合层得到复合纸，粘合剂的涂布量为2.5g/m2；
S2、将复合纸在温度为85℃下进行熟化；
S3、熟化后的固化时间为1h。

Claims (7)

1.一种新型双组份水性胶黏剂，其特征在于，包括乙烯-醋酸乙烯共聚物和异氰酸根聚合物，所述乙烯-醋酸乙烯聚合物体系为主剂、异氰酸根聚合物为固化剂，主剂与固化剂配比为100:1~3。
2.根据权利要求1所述的一种新型双组份水性胶黏剂，其特征在于，所述异氰酸根聚合物为二异氰酸酯、三异氰酸酯、甲苯二异氰酸酯、二苯基甲烷二异氰酸酯或异佛尔酮二异氰酸酯中的一种或两种以上。
3.一种复合纸，其特征在于，包括依次紧贴的复合层、粘合层和纸张层；所述粘合层的粘合剂为权利要求1所述的一种新型双组份水性胶黏剂。
4.根据权利要求3所述的一种复合纸，其特征在于，所述复合层为铝箔、聚烯烃、聚酯或尼龙中的一种。
5.根据权利要求3所述的一种复合纸，其特征在于，所述粘合剂的涂布量为1.5~2.5g/m2。
6.根据权利要求3所述的一种复合纸的制备方法，其特征在于，包括以下步骤：
S1、将粘合剂涂布在纸张层或复合层上，然后复合纸张层和复合层得到复合纸；
S2、将复合纸在温度为65~85℃下进行熟化；
S3、熟化后的固化时间不小于1h。
7.根据权利要求6所述的一种复合纸的制备方法，其特征在于，
步骤S1中所述的粘合剂的涂布量为1.5~2.5g/m2。
CN201710994207.9A 2018-04-16 2018-04-16 一种新型双组份水性胶黏剂及其制备的复合纸 Pending CN108264868A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59152974A (ja) * 1983-02-21 1984-08-31 Dainippon Ink & Chem Inc 紙ばり化粧板
CN102433087A (zh) * 2011-08-29 2012-05-02 华南理工大学 一种耐高温纸塑复膜胶及其制备方法
CN105415453A (zh) * 2015-10-22 2016-03-23 德华兔宝宝装饰新材股份有限公司 一种水性异氰酸酯胶合重组装饰材的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59152974A (ja) * 1983-02-21 1984-08-31 Dainippon Ink & Chem Inc 紙ばり化粧板
CN102433087A (zh) * 2011-08-29 2012-05-02 华南理工大学 一种耐高温纸塑复膜胶及其制备方法
CN105415453A (zh) * 2015-10-22 2016-03-23 德华兔宝宝装饰新材股份有限公司 一种水性异氰酸酯胶合重组装饰材的制备方法

Non-Patent Citations (1)

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Title
朱新连等编著: "《塑料印刷技术及应用》", 31 January 2014, 北京：印刷工业出版社 *

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Application publication date: 20180710