CN108251126A - Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste and preparation method thereof - Google Patents

Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste and preparation method thereof Download PDF

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Publication number
CN108251126A
CN108251126A CN201810226918.6A CN201810226918A CN108251126A CN 108251126 A CN108251126 A CN 108251126A CN 201810226918 A CN201810226918 A CN 201810226918A CN 108251126 A CN108251126 A CN 108251126A
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radix glycyrrhizae
soil
parts
waste
soil conditioner
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王永利
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Ningxia Yijiayi Biological Technology Co Ltd
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Ningxia Yijiayi Biological Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The present invention relates to the compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste, each component is by mass parts:Radix Glycyrrhizae extracts waste:15 50 parts;Traditional Chinese medicine waste:15 30 parts;Fermented cow dung:50 100 parts;Desulfurated plaster:3 30 parts;Complex microbial inoculum:1 10 parts.Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste of the present invention and preparation method thereof, the problem of soil hardening and the soil salinization can effectively be improved, soil conditioner is of low cost, function and effect are apparent, and it is not only with obvious effects to improveing the physical behavior of soil, while culture fertility and the salt resistance ability aspect significant effect of raising crop to soil.By improving mineral nutrient in soil physical properties, activating soil to the adjusting of soil microenvironment during microorganism species nature growth and breeding, improving quantity of useful microbe and enzymatic activity, inhibition sex pheromone vigor in soil, enhance the disease resistance and resistance of plant, so as to achieve the purpose that crop yield is had a good harvest.

Description

Compound microbial soil conditioner and its preparation containing Radix Glycyrrhizae extraction waste Method
Technical field
The present invention relates to soil ecologies to repair field, relates in particular to a kind of containing the compound of Radix Glycyrrhizae extraction waste Microbe soil conditioner and preparation method thereof.
Background technology
Salinization soil is distributed widely in more than 100 a countries and regions of the whole world, and area reaches 1.0x109hm2, it is total to account for land 30% or so of area is distributed in different continents arid area.The salinized soil ratio of China is apparently higher than world average level, There are about salinization soil 1.7x107hm2, there is salination in nearly 1/3 Irrigated Area Soils.
The soil conditioner that China introduces and promotes and applies at present divides three categories:(1) inorganic soil conditioner, such as ardealite H in soil is mainly reduced in acid soil by calcium, sulphur+、Al3+Play opsonic action, it can effectively adsorb and discharge ammonium, Phosphorus and potassium reduce the loss of soil N P, K.(2) organic soil conditioner, such as with C12Fatty alcohol polyoxyethylene ether sulfate of ammoniac is The soil conditioner of main body is acted on, this high molecular polymer meets water and resolves into hydrophilic small molecular weight material, replaces iron in soil The cation such as aluminium calcium adjusts soil physico-chemical property variation.(3) microbial soil conditioner, using microorganism as the soil of effect main body Conditioner, by the way that the adjusting of growing environment is improved soil physical and chemical property, carried during microorganism species nature growth and breeding High soil water-retaining, fertilizer conservation performance, enhancing crop disease-resistant ability and raising crop yield, outstanding feature is at low cost, effect is good, It has no toxic side effect.
Microbial soil conditioner is new soil improved products developed in recent years, since it is improving soil object Beneficial microbe and enzymatic activity, inhibition in mineral nutrient, improvement plant nutrient level, raising soil in rationality matter, activating soil Sex pheromone enhances the disease resistance of plant and the protrusion function of resistance (drought resisting, salt tolerant, antiacid etc.) etc., exists rapidly It is used widely in farmland ecosystem.Therefore developing and using microorganism improves the conditioner of salinization soil with important Practical significance.Such as Chen Chang and et al. a kind of patent of invention " composite microbiological bacteriocin saline-alkali soil improver and preparation method thereof With application " soil conditioner prepared using microorganism and organic substrate compounding, patent provides a kind of complex microorganism rhzomorph salt Keep a full stand of seedings to alkali technology, using microorganism to the repair function of soil, improve soil environment, decompose the harmful substance in soil and corruption Substance is lost, adjusts the molecular structure of soil, eliminates soil hardening, chesson, soil micro-ecosystem balance is maintained, makes soil fertility It is sufficient.
Invention content
It is an object of the invention to extract waste combining with fermentation cow dung using the distinctive genunie medicinal materials Radix Glycyrrhizae in Ningxia and take off Compound microbial soil conditioner that sulphur gypsum is prepared and preparation method thereof.
In order to solve the above technical problems, the purpose of the present invention is be achieved through the following technical solutions:
Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste, the compound microbial soil conditioner In, each component is by mass parts:
Radix Glycyrrhizae extracts waste:15-50 parts;
Traditional Chinese medicine waste:15-30 parts;
Fermented cow dung:50-100 parts;
Desulfurated plaster:3-30 parts;
Complex microbial inoculum:1-10 parts.
The Radix Glycyrrhizae extraction waste generates after extracting glycyrrhizic acid and liquiritin using microwave auxiliary extraction technology for Radix Glycyrrhizae Waste mixture.
The glycyrrhizic acid and liquiritin in Radix Glycyrrhizae are extracted using the microwave―assisted extraction:Radix Glycyrrhizae is weighed, it is molten to add in extraction Agent (60%+15% acetonitrile of ethyl alcohol+water), Radix Glycyrrhizae:The weight ratio of Extraction solvent is 1: 15, is positioned in microwave abstracting machine, 80 1-3h is extracted at DEG C, filter liquor recycles Extraction solvent, obtains the refined liquid containing a large amount of glycyrrhizic acids and liquiritin, remaining Precipitate waste material is Radix Glycyrrhizae extraction waste.
The waste mixture that the traditional Chinese medicine waste generates in being processed for any one or more Chinese medicine.
The fermented cow dung is the cow dung after the fully decomposed fermentation of 70 DEG C of During High-Temperature Compostings.
The production method of fermented cow dung:
1st, fermentation dry cow dung:
Enough moisture will be added in dry cow dung so that moisture control is in 40-65%, addition cattle manure agent strain It with corn flour and the mixture of wheat bran, and adds in a small amount of urea and adjusts carbon-nitrogen ratio, after stirring evenly, heap high 1.5-2m in heaps is wide 2m, the unlimited raft of length, dry cow dung:The mixture of corn flour and wheat bran:Cattle manure agent strain is 1000: 500: 0.25, Upper cover sealed plastic cloth, control temperature is at 15-30 DEG C, and fermentation calefaction control is fermented below 65-70 DEG C, and fermentation time is 7-10 days.Fermentation maturity cow dung is in dark brown, and temperature starts to be down to room temperature, shows that fermentation is completed.
2nd, the fresh cow dung of fermentation:
The mixture that sawdust, stalk are added in fresh cow dung is absorbed into moisture, microorganism is promoted to ferment, then add ox Manure fermentation agent strain.Wherein, wet cow dung:The mixture of sawdust, stalk:Cattle manure agent strain is 3000: 1000: 0.25, is mixed It is even spare.By the cow dung got ready, in fungus scattering, Jian Dui, heap high 1.5-2m, wide 2m, length are unlimited.The moisture of fermented cow dung should Control is in 40-65%.Start-up temperature should be at 15-25 DEG C, and fermentation calefaction is controlled at 65-70 DEG C.Mix ventilation thoroughly so that cow dung is accumulated 7-10 days, the fresh cow dung material that ferments was in dark brown, and temperature starts to be down to room temperature, showed that fermentation maturity is completed.
The by-product generated after the sulfur dioxide that the desulfurated plaster is administered for the industrial and mining enterprises of natural air drying in flue gas.
The complex microbial inoculum is:The composite bacteria agent that bacillus and Halophiles are formed.
The bacillus is specially:Gel-shaped series bacillus, bacillus licheniformis and Paenibacillus polymyxa.
The complex microbial inoculum is by mass parts:4-10 parts of Halophiles, 2-5 parts of gel-shaped series bacillus, lichens 2-5 parts of bacillus, 2-5 parts of Paenibacillus polymyxa.
The Halophiles can effectively improve the problem of soil hardening and soil salinization, while to the fertilizing of soil And improve significant effect in terms of the salt resistance ability of crop.
The bacillus has the metabolism that moisture retention is strong, organic matter decomposition power is strong, antibacterial, harmful power of going out is strong and generation is abundant The advantages that product, can form the poly- Vetsin of the superfine natural material of intensity, as the protective film of soil, prevent nutrient And moisture loss, while proliferation, the amylase of high activity can be disengaged, the macromolecular substances that hardly possible is decomposed are resolved into can profit Small-molecule substance, and the substances such as a variety of organic acids, enzyme, physiological activity can be synthesized and other a variety of be easily utilized Nutrient.Bacillus can also inhibit the harmful microbes growth and breeding such as harmful bacteria, pathogen, while can decompose generation evil Organic substance, organic sulfur compound, organic nitrogen of odour etc., substantially improve soil environment.Bacillus licheniformis can adjust flora Imbalance reaches therapeutic purposes, and body can be promoted to generate antibacterial substance, kill pathogenic bacteria;Resistant activity material can be generated, and is had There is unique biology take oxygen mechanism, the growth and breeding of pathogenic bacteria can be inhibited.Bacillus polymyxa exists with spore form, resistance to Warm nature is good, stable quality, lasting medicine;It is preferable to be not only the soil-borne diseases such as prevention bacterial wilt, droop, root rot, soft rot Medicament, and have the function of significantly promote growth, improve yield, improving quality.
The preparation method comprises the steps of:
1) complex microbial inoculum is inoculated into seed liquid culture medium respectively, fermentation seed liquid is made;
2) fermentation seed liquid obtained in step 1) is inoculated in respectively in the solid-phase culture base containing traditional Chinese medicine waste, connect Kind amount 10-15%, in 25-30 DEG C of standing for fermentation in tray solid-state fermentation installation, is made complex microbial inoculum after mixing;
3) by microbial composite bacteria obtained in Radix Glycyrrhizae extraction waste, fermented cow dung, desulfurated plaster and step 2) Agent is uniformly mixed, and shading carries out fermentation process, 10-40 DEG C, fermentation time 10-15D is maintained the temperature in fermentation process, fermentation After the completion to get to containing Radix Glycyrrhizae extraction waste compound microbial soil conditioner.
The compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste is applied in salt-soda soil, ploughed depth For 20-40cm, improved salt-soda soil is the farmland for being capable of Planting Crops.
The formula of seed liquid culture medium:Each component is by weight:Glucose 2%, dusty yeast 0.2%, peptone 0.2%, 1000ml solution is prepared into, contains the 150g potato balls boiled, pH6.0-6.3.
The formula of solid-phase culture base:Each component is by weight:Traditional Chinese medicine waste 50%, sucrose 2-5%, corn starch 1- 3%th, dregs of beans 10-30%, calcium hydroxide 1-3%, by water by 1: the wood vinegar 30% of (60-300) dilution proportion.
The beneficial effects of the present invention are:
Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste of the present invention and preparation method thereof, Neng Gouyou It the problem of improvement soil hardening and the soil salinization of effect, has great significance to agroecological environment.It is carried containing Radix Glycyrrhizae Take the compound microbial soil conditioner of waste it is of low cost, using it is efficient, function and effect are apparent, and not only to improvement The physical behavior of soil is with obvious effects, while the fertilizing to soil and the salt resistance ability aspect significant effect of raising crop.Pass through Mineral in soil physical properties, activating soil is improved to the adjusting of growing environment during microorganism species nature growth and breeding Nutrient improves plant nutrient level, improves beneficial microbe and enzymatic activity in soil, inhibits sex pheromone, enhances plant Disease resistance and resistance.
Specific embodiment
The present invention is described in further detail below:The present embodiment under based on the technical solution of the present invention into Row is implemented, and gives detailed embodiment, but protection scope of the present invention is not limited to following embodiments.
Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste, each component are by mass parts:
Radix Glycyrrhizae extracts waste:15-50 parts;
Traditional Chinese medicine waste:15-30 parts;
Fermented cow dung:50-100 parts;
Desulfurated plaster:3-30 parts;
Complex microbial inoculum:1-10 parts.
The Radix Glycyrrhizae extraction waste generates after extracting glycyrrhizic acid and liquiritin using microwave auxiliary extraction technology for Radix Glycyrrhizae Waste mixture.
The waste mixture that the traditional Chinese medicine waste generates in being processed for any one or more Chinese medicine.
The fermented cow dung is the cow dung after the fully decomposed fermentation of 70 DEG C of During High-Temperature Compostings.
The by-product generated after the sulfur dioxide that the desulfurated plaster is administered for the industrial and mining enterprises of natural air drying in flue gas.
The complex microbial inoculum is:The composite bacteria agent that bacillus and Halophiles are formed.
The bacillus is specially:Gel-shaped series bacillus, bacillus licheniformis and Paenibacillus polymyxa.
The complex microbial inoculum is by mass parts:4-10 parts of Halophiles, 2-5 parts of gel-shaped series bacillus, lichens 2-5 parts of bacillus, 2-5 parts of Paenibacillus polymyxa.
The preparation method comprises the steps of:
1) complex microbial inoculum is inoculated into seed liquid culture medium respectively, fermentation seed liquid is made;
2) fermentation seed liquid obtained in step 1) is inoculated in respectively in the solid-phase culture base containing traditional Chinese medicine waste, connect Kind amount 10-15%, in 25-30 DEG C of standing for fermentation in tray solid-state fermentation installation, is made complex microbial inoculum after mixing;
3) by microbial composite bacteria obtained in Radix Glycyrrhizae extraction waste, fermented cow dung, desulfurated plaster and step 2) Agent is uniformly mixed, and carries out fermentation process, 10-40 DEG C, fermentation time 10-15D is maintained the temperature in fermentation process, fermentation is completed Afterwards to get to containing Radix Glycyrrhizae extraction waste compound microbial soil conditioner.
The compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste is applied in salt-soda soil, ploughed depth For 20-40cm, improved salt-soda soil is the farmland for being capable of Planting Crops.
Embodiment 1:
The preparation method comprises the steps of:
1) by the complex microbial inoculum:Halophiles 4kg, 2kg parts of gel-shaped series bacillus, bacillus licheniformis 2kg, Paenibacillus polymyxa 2kg are inoculated into seed liquid culture medium respectively, and fermentation seed liquid is made;
2) fermentation seed liquid obtained in step 1) is inoculated in the solid-phase culture base containing traditional Chinese medicine waste 18kg respectively In, in 25 DEG C of standing for fermentation in tray solid-state fermentation installation, complex microbial inoculum is made in inoculum concentration 10% after mixing;
It 3) will be obtained in Radix Glycyrrhizae extraction waste 45kg, fermented cow dung 100kg, desulfurated plaster 15kg and step 2) Complex microbial inoculum is uniformly mixed, and shading carries out fermentation process, maintains the temperature at 10-40 DEG C in fermentation process, fermentation time For 10-15D, after fermentation to get to the compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste.
Embodiment 2:
The preparation method comprises the steps of:
1) by the complex microbial inoculum:Halophiles 5kg, 3kg parts of gel-shaped series bacillus, bacillus licheniformis 2kg, Paenibacillus polymyxa 2kg are inoculated into seed liquid culture medium respectively, and fermentation seed liquid is made;
2) fermentation seed liquid obtained in step 1) is inoculated in the solid-phase culture base containing traditional Chinese medicine waste 60kg respectively In, in 25-30 DEG C of standing for fermentation in tray solid-state fermentation installation, microbial composite bacteria is made in inoculum concentration 10-15% after mixing Agent;
It 3) will be obtained in Radix Glycyrrhizae extraction waste 80kg, fermented cow dung 180kg, desulfurated plaster 30kg and step 2) Complex microbial inoculum is uniformly mixed, and shading carries out fermentation process, maintains the temperature at 20 DEG C in fermentation process, fermentation time is 13D, after fermentation to get to containing Radix Glycyrrhizae extraction waste compound microbial soil conditioner.
The foregoing is only a preferred embodiment of the present invention, these specific embodiments are all based on the present invention Different realization methods under general idea, and protection scope of the present invention is not limited thereto, it is any to be familiar with the art Technical staff in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in, should all cover the present invention Within protection domain.

Claims (10)

1. the compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste, it is characterised in that:
In the compound microbial soil conditioner, each component is by mass parts:
Radix Glycyrrhizae extracts waste:15-50 parts;
Traditional Chinese medicine waste:15-30 parts;
Fermented cow dung:50-100 parts;
Desulfurated plaster:3-30 parts;
Complex microbial inoculum:1-10 parts.
2. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The Radix Glycyrrhizae extraction waste is useless using being generated after microwave auxiliary extraction technology extraction glycyrrhizic acid and liquiritin for Radix Glycyrrhizae Gurry mixture.
3. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The waste mixture that the traditional Chinese medicine waste generates in being processed for any one or more Chinese medicine.
4. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The fermented cow dung is the cow dung after the fully decomposed fermentation of 70 DEG C of During High-Temperature Compostings.
5. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The by-product generated after the sulfur dioxide that the desulfurated plaster is administered for the industrial and mining enterprises of natural air drying in flue gas.
6. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The complex microbial inoculum is:The composite bacteria agent that bacillus and Halophiles are formed.
7. the compound microbial soil conditioner according to claim 6 containing Radix Glycyrrhizae extraction waste, feature exist In:
The bacillus is specially:Gel-shaped series bacillus, bacillus licheniformis and Paenibacillus polymyxa.
8. the compound microbial soil conditioner according to claim 7 containing Radix Glycyrrhizae extraction waste, feature exist In:
The complex microbial inoculum is by mass parts:4-10 parts of Halophiles, 2-5 parts of gel-shaped series bacillus, lichens gemma 2-5 parts of bacillus, 2-5 parts of Paenibacillus polymyxa.
9. the preparation side of the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste Method, it is characterised in that:
The preparation method comprises the steps of:
1) complex microbial inoculum is inoculated into seed liquid culture medium respectively, fermentation seed liquid is made;
2) fermentation seed liquid obtained in step 1) is inoculated in respectively in the solid-phase culture base containing traditional Chinese medicine waste, inoculum concentration In 25-30 DEG C of standing for fermentation in tray solid-state fermentation installation, complex microbial inoculum is made in 10-15% after mixing;
3) complex microbial inoculum obtained in Radix Glycyrrhizae extraction waste, fermented cow dung, desulfurated plaster and step 2) is mixed Uniform, progress fermentation process is closed, 10-40 DEG C, fermentation time 10-15D is maintained the temperature in fermentation process, after fermentation, Obtain the compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste.
10. the compound microbial soil conditioner according to claim 1 containing Radix Glycyrrhizae extraction waste, feature exist In:
The compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste is applied in salt-soda soil, and ploughed depth is 20-40cm, improved salt-soda soil are the farmland for being capable of Planting Crops.
CN201810226918.6A 2018-03-19 2018-03-19 Compound microbial soil conditioner containing Radix Glycyrrhizae extraction waste and preparation method thereof Pending CN108251126A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111484224A (en) * 2020-03-09 2020-08-04 杭州埃莫森环保科技有限公司 Method and system for manufacturing anti-hardening ecological nutrient soil by using sludge
CN111484232A (en) * 2020-03-09 2020-08-04 杭州埃莫森环保科技有限公司 Biological treatment method and biological treatment system for manufacturing anti-hardening ecological nutrient soil
CN113403086A (en) * 2021-07-09 2021-09-17 湖南省农业环境生态研究所 Soil conditioner and preparation method thereof
CN114736689A (en) * 2022-03-30 2022-07-12 中诚国联(河南)生物科技有限公司 Compound microbial agent for saline-alkali soil remediation and preparation method and application thereof
CN115611665A (en) * 2022-09-27 2023-01-17 沈阳化工研究院有限公司 Preparation method of organic fertilizer from Chinese medicinal material waste

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN103936471A (en) * 2014-05-15 2014-07-23 王耀 Organic fertilizer prepared from cattle and sheep manure and wheat bran and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103936471A (en) * 2014-05-15 2014-07-23 王耀 Organic fertilizer prepared from cattle and sheep manure and wheat bran and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111484224A (en) * 2020-03-09 2020-08-04 杭州埃莫森环保科技有限公司 Method and system for manufacturing anti-hardening ecological nutrient soil by using sludge
CN111484232A (en) * 2020-03-09 2020-08-04 杭州埃莫森环保科技有限公司 Biological treatment method and biological treatment system for manufacturing anti-hardening ecological nutrient soil
CN113403086A (en) * 2021-07-09 2021-09-17 湖南省农业环境生态研究所 Soil conditioner and preparation method thereof
CN114736689A (en) * 2022-03-30 2022-07-12 中诚国联(河南)生物科技有限公司 Compound microbial agent for saline-alkali soil remediation and preparation method and application thereof
CN115611665A (en) * 2022-09-27 2023-01-17 沈阳化工研究院有限公司 Preparation method of organic fertilizer from Chinese medicinal material waste

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Application publication date: 20180706