CN108250940A - High abrasion UV mould release coating applied to slippers transfer and preparation method thereof - Google Patents
High abrasion UV mould release coating applied to slippers transfer and preparation method thereof Download PDFInfo
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- CN108250940A CN108250940A CN201711486528.4A CN201711486528A CN108250940A CN 108250940 A CN108250940 A CN 108250940A CN 201711486528 A CN201711486528 A CN 201711486528A CN 108250940 A CN108250940 A CN 108250940A
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- slippers
- transfer
- mould release
- release coating
- high abrasion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof, and the coating includes each component of following weight percent：Initiator body 2 5%；Aided initiating 5 12%；Reactive diluent 20 40%；Urethane acrylate 20~40%；Alkoxylated acrylate 10~30%；Silane coupling agent 1~5%.UV mould release paint solidifications degree prepared by the present invention is high, and dissolubility is good, and absorbing wavelength is up to 390nm, and organic solvent-free discharges in solidification process and product obtained, and cured ultraviolet energy only needs 50mj/cm2, hardening time only needs 1 3s, be it is a kind of efficiently, the release coating of photocuring of energy-saving and environmental protection, can be widely applied to slippers transfer.
Description
Technical field
The present invention relates to back-coating technical fields, and in particular to a kind of high abrasion UV mould releases applied to slippers transfer
Coating and preparation method thereof.
Background technology
Different slippers materials are typically necessary certain pattern on its surface printing, the directly possibility in slippers surface printing
Property is very small, is centainly realized at present by following technique：Printable mould release is coated on the base materials such as OPP/CPP, in mould release
The upper various ink of printing, then ink last layer transfer glue is being printed, by certain temperature and pressure printed patterns after cutting
It is transferred on slippers, usual mould release can be stayed on slippers.
The use of mould release is typically at present acrylic materials, the type material can guarantee printing performance and release work(
Can, but can be to meet the high abrasion requirement of slippers surface.Generally by rear road spray again one layer of UV photocurings gloss oil can provide it is high resistance to
Grind performance.
Photocuring technology is gradually replacing as a kind of new and effective, environmentally friendly, economy, the green technology of wide adaptability
Traditional solvent-borne production technology.Ultraviolet-curing paint is a kind of environment-friendly and energy-efficient coating of exploitation the 1960s,
Because there is no or low VOC emission, save the energy (energy consumption is only 1/10 or so of solvent based coating), the fast (0.1- of curing rate
10s), production efficiency is high, be suitble to flow line production, the features such as solidification temperature is low and paid close attention to by researcher, at present about
The research of photocuring mould release is in the starting stage, and technical aspect is also there are a degree of deficiency, up for perfect.As in
State patent CN 104371543 discloses a kind of preparation method of photocuring mould release, consolidates although having filled up light to a certain extent
Change the blank of mould release, but the Diaryl iodonium salt initiators excessively unification wherein used, diaryl iodonium salt is only to wavelength
UV light near 250nm has strong absorption, and dissolubility is poor in reactive diluent, while salt compounded of iodine toxicity is larger, leads to UV
The capacity usage ratio of light source is very low.And photocuring mould release is difficult to meet printing performance and slippers material requirements substantially at present
Flexibility.
Invention content
For the defects in the prior art, the present invention provides a kind of high abrasion UV mould release material applied to slippers transfer
And preparation method thereof.First aspect present invention introduces a kind of free radical and the compound initiator system of hydrogen-abstraction, with the use of helping
Initiator solves the problems such as oxygen inhibition, slow curing that initiator unification is brought, while laser curing velocity is fast, and dissolubility is good,
Absorbing wavelength is up to 390nm；Second aspect adds a certain proportion of silane coupling agent in UV photocuring mould releases, to ensure
Printing functionality is realized on UV mould releases；The third aspect is diluted using two official's polyurethane acrylic resins and alkoxylated acrylate
Agent is ensureing flexibility that is deliquescent while can further improving UV mould releases.It is a kind of efficient, energy-saving and environmental protection light
Cure release coating.
The purpose of the present invention is what is be achieved through the following technical solutions：
The present invention provides a kind of high abrasion UV mould release coating applied to slippers transfer, including following weight percent
Each component：
The too high levels of each component are too low, can coating property be caused to decline.
Preferably, the initiator system is radical initiator and the compound system of hydrogen-abstraction initiator；Free radical draws
Send out agent and hydrogen-abstraction initiator weight ratio：1:5-10；
The radical initiator be selected from ɑ, ɑ '-dimethyl benzil ketals, 2- hydroxy-2-methyl -1- phenylacetones, 2,
4,6- tri-methyl benzophenones, 1- hydroxycyclohexyl phenyl ketones, 2,2- dimethoxy -2- phenyl acetophenones, benzoin propyl ether,
Benzoin ethyl ether, benzyl dimethyl ketal, 1- (4- cumenyls) 2- hydroxy-2-methyl propyl- 1- ketone, 2- hydroxy-2-methyls-
It is one or more in 1- phenyl propyl- 1- ketone, 2,4,6-trimethylbenzoyldiphenylphosphine oxide；As IRGACURE184,
1173rd, 651,819,907 etc..
The hydrogen-abstraction initiator is selected from 4,4 '-diaminobenzophenone, Michler's keton, benzophenone, methyl benzoyl
Formic acid esters thioxanthones, 2-isopropylthioxanthone, 2-chlorothioxanthone, 2- methyl-1s-(4- (methyl mercapto) phenyl) -2- morpholine propyl-s 1-
It is one or more in ketone.Such as the product of following model：BP, MK, DETX, CTX etc..
Preferably, the aided initiating is selected from tertiary amine-type benzoic ether, N, N- mesitylenic acids ethyl ester, N, N- dimethyl
Benzoic acid -2- ethylhexyls, benzoic acid dimethylaminoethyl or from the reactive amines tertiary amine of acryloxy (refer in particular to)
One or more.Such as the product of following model：CN371,7100,6422 etc..
Preferably, the reactive diluent is selected from 1,6- hexanediyl esters (HDDA), tripropylene glycol diacrylate
Ester (TPGDA), polyethyleneglycol diacrylate (PEGDA), trimethylolpropane trimethacrylate, trimethylol propane trimethyl
One kind in acrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol hexaacrylate or
It is several.
Preferably, the alkoxylated acrylate is one in ethoxyquin class acrylate, the third oxidation category acrylate
Kind or two kinds.Such as：TMP(EO)TA、TMP(EO)3TA、TMP(PO)TA、TMP(PO)3TA、TMP(EO)MEDA、NPG(PO)
2DA, PE (EO) 4TA etc..
Preferably, the polyurethane acrylic resin is two official's polyurethane acrylic resins.
Preferably, the silane coupling agent includes at least one of kh550, a171, si69.
The present invention also provides a kind of preparation method of the high abrasion UV mould release coating applied to slippers transfer, features
It is, includes the following steps：
A1, urethane acrylate, alkoxylated acrylate are added in reactive diluent, are evenly stirred until completely
Dissolving；
A2, initiator body, aided initiating and silane coupling agent are added in into mixture made from step A1, stirred evenly,
Then cool down, filter to get.
The prior art is compared, and the present invention has following advantageous effect：
(1) present invention, with the use of aided initiating, is solved initiator unification and brought using composite photoinitiator system
Oxygen inhibition, slow curing, UV light sources absorb the problems such as narrow, while curing degree is high, dissolubility is good, and absorbing wavelength is up to 390nm；
(2) a certain proportion of silane coupling agent is added in UV photocuring mould releases, to ensure to realize on UV mould releases
Printing functionality；
(3) present invention is being ensured using two official's polyurethane acrylic resins, alkoxylated acrylate and diluent compounding
Flexibility deliquescent while that UV mould releases can be further improved.
(4) present invention is using the UV mould release coating prepared, when being cured using photocuring technology, production process and production
Organic solvent-free discharges in product, and ultraviolet energy only needs 50mj/cm2, hardening time only needs 1-3s, is a kind of efficient, energy saving, ring
The release coating of photocuring of guarantor.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1
A kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof is present embodiments provided, it is described
The each component and weight of high abrasion UV mould release coating applied to slippers transfer are as shown in table 1.
The preparation method is specially：
(1) urethane acrylate, alkoxylated acrylate are added in reactive diluent, are evenly stirred until completely
Dissolving；
(2) it is equal that initiator body, aided initiating and silane coupling agent, high-speed stirred are added in into mixture made from step A1
It is even；
(3) cooling, viscosimetric and solid content, filter and package to obtain UV mould release coating.
(4) coating is coated on OPP/CPP films, coating weight 1.5g/m2, in UV energy 200mj/cm2Under the conditions of it is aerobic
Cure 1-3s, after curing, solidification effect is confirmed very well (curing degree reaches 90%) using infrared tester, flexibility test is adopted
Reach 2H with TMI tests off-type force 0.041, pencil hardness, yellow, red, the orange three sections of fastness of gravure ink printing are all fine, are transferred to
Flexibility (360 ° of bending is almost flawless) and wear-resisting property are detected on slippers (artificial wearing 40 days or more is almost without scratch).
Table 1
| Component | Weight (kg) |
| Two official's polyurethane acrylic resins | 35 |
| Ethoxyquin acrylate | 20 |
| HDDA and PEG (400) DA | 28 |
| 184 and benzophenone | 4 |
| CN371 | 10 |
| a171 | 3 |
Embodiment 2
A kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof is present embodiments provided, it is described
The each component and weight of high abrasion UV mould release coating applied to slippers transfer are as shown in table 2.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
93%) degree reaches, flexibility test tests off-type force 0.047 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all fine, are transferred on slippers and detect flexibility (360 ° of bending is almost flawless) and wear-resisting property (manually
Wearing 40 days or more is almost without scratch).
Table 2
| Component | Weight (kg) |
| Two official's polyurethane acrylic resins | 30 |
| Ethoxyquin acrylate and the third propylene oxide acid esters | 18 |
| HDDA and TPGDA | 31 |
| 1173 and benzophenone | 5 |
| N, N- mesitylenic acid -2- ethylhexyls | 12 |
| kh550 | 4 |
Embodiment 3
A kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof is present embodiments provided, it is described
The each component and weight of high abrasion UV mould release coating applied to slippers transfer are as shown in table 3.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
88%) degree reaches, flexibility test tests off-type force 0.036 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all fine, are transferred on slippers and detect flexibility (360 ° of bending is almost flawless) and wear-resisting property (manually
Wearing 40 days or more is almost without scratch).
Table 3
| Component | Weight (kg) |
| Two official's polyurethane acrylic resins | 27 |
| Third propylene oxide acid esters | 28 |
| HDDA | 35 |
| 819 and benzophenone | 2 |
| Benzoic acid dimethylaminoethyl | 7 |
| kh550 | 1 |
Embodiment 4
A kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof is present embodiments provided, it is described
The each component and weight of high abrasion UV mould release coating applied to slippers transfer are as shown in table 4.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
91%) degree reaches, flexibility test tests off-type force 0.041 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all fine, are transferred on slippers and detect flexibility (360 ° of bending is almost flawless) and wear-resisting property (manually
Wearing 40 days or more is almost without scratch).
Table 4
| Component | Weight (kg) |
| Two official's polyurethane acrylic resins | 40 |
| Ethoxyquin acrylate | 10 |
| HDDA and TPGDA | 30 |
| 1173 and BP | 5 |
| Benzoic acid dimethylaminoethyl | 10 |
| kh550 | 5 |
Embodiment 5
A kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof is present embodiments provided, it is described
The each component and weight of high abrasion UV mould release coating applied to slippers transfer are as shown in table 5.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
90%) degree reaches, flexibility test tests off-type force 0.036 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all fine, are transferred on slippers and detect flexibility (360 ° of bending is almost flawless) and wear-resisting property (manually
Wearing 40 days or more is almost without scratch).
Table 5
| Component | Weight (kg) |
| Two official's polyurethane acrylic resins | 40 |
| Third propylene oxide acid esters | 20 |
| HDDA | 20 |
| 819 and BP | 5 |
| 7100 | 12 |
| si69 | 3 |
Comparative example 1
This comparative example provides a kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof, described
The component and weight of high abrasion UV mould release coating applied to slippers transfer are substantially the same manner as Example 1, and difference only exists
In：The urethane acrylate used in this comparative example is three official's urethane acrylate.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
90%) degree reaches, flexibility test tests off-type force 0.044 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all fine, are transferred on slippers and detect flexibility (360 ° of bending has apparent a few road slight cracks) and wear-resisting property
(artificial wearing 40 days or more is almost without scratch).Comparative example 1, other performance indicators are attained by requirement, but are transferred to and drag
There are apparent a few road slight cracks in 360 ° of flexibility test bending on footwear, is significantly deteriorated using three official's urethane acrylate flexibilities,
Customer requirement is not achieved.
Comparative example 2
This comparative example provides a kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof, described
The component and weight of high abrasion UV mould release coating applied to slippers transfer are substantially the same manner as Example 1, and difference only exists
In：The initiator system used in this comparative example is 184.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect be deteriorated (curing
Degree only reaches 62%, some are viscous on surface), flexibility test reaches 4B using TMI tests off-type force 0.041, pencil hardness, recessed
Yellow, red, the orange three sections of fastness of stamp-pad ink ink print are all not bad, be transferred on slippers detect flexibility (bending 360 ° almost flawless) and
Wear-resisting property (artificial wearing has apparent scratch in 1 day).Comparative example 1, using independent free radical initiator system 184,
Since oxygen inhibition causes curing degree there was only 62%, UV release surfaces, some are viscous under similarity condition, and case hardness only has 4B, transfer
It is wear-resisting there is also apparent problem on to slippers, customer requirement is far not achieved.
Comparative example 3
This comparative example provides a kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof, described
The component and weight of high abrasion UV mould release coating applied to slippers transfer are substantially the same manner as Example 1, and difference only exists
In：The initiator body used in this comparative example is BP.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect be deteriorated (curing
Degree only reaches 60%, some are viscous on surface), flexibility test reaches 4B using TMI tests off-type force 0.041, pencil hardness, recessed
Yellow, red, the orange three sections of fastness of stamp-pad ink ink print are all not bad, be transferred on slippers detect flexibility (bending 360 ° almost flawless) and
Wear-resisting property (artificial wearing has apparent scratch in 1 day).Comparative example 1, using independent hydrogen-abstraction initiator, in similarity condition
Under since oxygen inhibition causes curing degree there was only 60%, UV release surfaces, some are viscous, case hardness only has 4B, is transferred on slippers
It is wear-resisting there is also apparent problem, customer requirement is far not achieved.
Comparative example 4
This comparative example provides a kind of high abrasion UV mould release coating applied to slippers transfer and preparation method thereof, described
The component and weight of high abrasion UV mould release coating applied to slippers transfer are substantially the same manner as Example 1, and difference only exists
In：Silane coupling agent is not added in this comparative example.
The preparation method is same as Example 1.The coating is coated on OPP/CPP films, coating weight 1.5g/m2,
UV energy 200mj/cm2Under the conditions of aerobic curing 1-3s, after curing, using infrared tester confirm solidification effect very well (curing
93%) degree reaches, flexibility test tests off-type force 0.041 using TMI, pencil hardness reaches 2H, gravure ink printing Huang,
Red, orange three sections of fastness are all poor (drawing of 3M adhesive tapes takes off all to fall), are transferred on slippers and detect flexibility (360 ° of bending is almost flawless)
With wear-resisting property (artificial wearing 40 days or more is almost without scratch).Comparative example 1, does not add silane coupling agent, other performances
Index is attained by requirement, but customer requirement is not achieved completely without fastness with gravure ink.
There are many concrete application approach of the present invention, and the above is only the preferred embodiment of the present invention.More than it should be pointed out that
Embodiment is merely to illustrate the present invention, and the protection domain being not intended to restrict the invention.For the common skill of the art
For art personnel, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as this hair
Bright protection domain.
Claims (8)
1. a kind of high abrasion UV mould release coating applied to slippers transfer, which is characterized in that including following weight percent
Each component：
2. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that described to draw
It is photoinitiator to send out agent body, is chosen in particular from ɑ, ɑ '-dimethyl benzil ketals, 2- hydroxy-2-methyl -1- phenylacetones, 2,4,
6- tri-methyl benzophenones, 1- hydroxycyclohexyl phenyl ketones, 2,2- dimethoxy -2- phenyl acetophenones,；4,4 '-diamino
Benzophenone, Michler's keton, benzophenone, benzoin propyl ether, benzoin ethyl ether, benzyl dimethyl ketal, 1- (4- isopropylbenzenes
Base) 2- hydroxy-2-methyl propyl- 1- ketone, 2- hydroxy-2-methyl -1- phenyl propyl- 1- ketone, methylbenzoyl formate thioxanthones,
2-isopropylthioxanthone, 2-chlorothioxanthone, 2- methyl-1s-(4- (methyl mercapto) phenyl) -2- morpholines propyl- 1- ketone and 2,4,6- front threes
It is one or more in base benzoyl diphenyl phosphine oxide.
3. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that described to help
Initiator is selected from tertiary amine-type benzoic ether, N, N- mesitylenic acids ethyl ester, N, N- mesitylenic acid -2- ethylhexyls, benzene
One or more of formic acid dimethylaminoethyl or tertiary amine with acryloxy.
4. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that the work
Property diluent be selected from 1,6- hexanediyl esters, tripropylene glycol diacrylate, polyethyleneglycol diacrylate, three hydroxyl first
Base propane triacrylate, trimethylol-propane trimethacrylate, pentaerythritol triacrylate, pentaerythrite tetrapropylene
One or more of acid esters, dipentaerythritol hexaacrylate.
5. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that the alkane
Oxygroup acrylate is ethoxyquin class acrylate, one or two kinds of in the third oxidation category acrylate.
6. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that described poly-
Urethane acrylate resin is two official's polyurethane acrylic resins.
7. the high abrasion UV mould release coating according to claim 1 applied to slippers transfer, which is characterized in that the silicon
Alkane coupling agent includes at least one of kh550, a171, si69.
8. a kind of preparation for being applied to the high abrasion UV mould release coating that slippers transfer according to claim 1-7 any one of them
Method, which is characterized in that include the following steps：
A1, urethane acrylate, alkoxylated acrylate are added in reactive diluent, are evenly stirred until completely molten
Solution；
A2, initiator body, aided initiating and silane coupling agent are added in into mixture made from step A1, stirred evenly, then
Cooling, filter to get.
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| CN201711486528.4A CN108250940B (en) | 2017-12-29 | 2017-12-29 | High-wear-resistance UV release agent coating applied to slipper transfer printing and preparation method thereof |
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Cited By (1)
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| CN110370831A (en) * | 2019-07-10 | 2019-10-25 | 深圳市杰瑞表面技术有限公司 | A method of nanometer film layer is transferred on glass |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110370831A (en) * | 2019-07-10 | 2019-10-25 | 深圳市杰瑞表面技术有限公司 | A method of nanometer film layer is transferred on glass |
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