CN108250661A - A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof - Google Patents
A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof Download PDFInfo
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- CN108250661A CN108250661A CN201810000470.6A CN201810000470A CN108250661A CN 108250661 A CN108250661 A CN 108250661A CN 201810000470 A CN201810000470 A CN 201810000470A CN 108250661 A CN108250661 A CN 108250661A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses heat-resisting weather-proof modified materials of a kind of ABS and preparation method thereof, belong to new material technology field.Its main constituents and quality proportioning are：80 85 parts of ABS resin, 45 parts of R105 titanium dioxides, ethylene bis stearamide EBS are 0.7 0.9 parts, 1 1.05 parts of PE waxes, ultraviolet absorber UV P are 0.3 0.35 parts, and polyamide 1010 is 0.3 0.4 parts, 770 0.25 0.3 parts of light stabilizer, 168 be 0.2 0.25 parts, 8 10 parts of MS NB heat-resistant agents.The advantage of the invention is that：The heat-resisting weather-proof modified materials of ABS are made of plurality of raw materials according to specific proportioning, are remarkably improved its heat-resisting weatherability, easy to utilize.
Description
Technical field
The present invention relates to new material technology field, specially a kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof.
Background technology
ABS coating is that a kind of multi-phase fluid of complexity consolidates dispersion, and coating resin allows for dissolving and formed in a solvent
Liquid with excellent fluidity simultaneously disperses to form stable lotion in liquid medium, relative to PVC is more environmentally-friendly, intensity
Height, price is low, is increasingly favored by market, but its heat-resisting and weatherability is not strong, and at summer and winter, bonding plane easily goes out
Now loosely face and cause quality problems, limit ABS sheet materials, edge band, film are promoted the use of, therefore be badly in need of improving existing ABS
Heat-resisting weatherability.
Invention content
The purpose of the present invention is to provide heat-resisting weather-proof modified materials of a kind of ABS and preparation method thereof, are mainly used in solution
State problem.
The present invention solves technical problem and adopts the following technical scheme that：
A kind of heat-resisting weather-proof modified materials of ABS are provided, main constituents and quality proportioning are：80-85 parts of ABS resin, R105
4-5 parts of titanium dioxide, ethylene bis stearamide EBS are 0.7-0.9 parts, and 1-1.05 parts of PE waxes, ultraviolet absorber UV-P is 0.3-
0.35 part, polyamide 1010 is 0.3-0.4 parts, 770 0.25-0.3 parts of light stabilizer, and 168 be 0.2-0.25 parts, and MS-NB is resistance to
8-10 parts of thermit powder.
A kind of preparation method of the heat-resisting weather-proof modified materials of ABS, mainly includes the following steps：
（1）Dispensing：By raw material ABS resin, ethylene bis stearamide EBS, PE wax, polyamide 1010,168, MS-NB is heat-resisting
Agent carries out dispensing according to above-mentioned quality proportioning；
（2）Batch mixing:By step（1）300min, whipping temp 65-70 are stirred in homogenizer with the raw material got ready
℃；
（3）Cooling：By step（2）Mixed batch mixing adds in ultraviolet absorber UV-P, light stabilizer 770 and R105 titanium dioxides and obtains
To modified materials A；
（4）Drying：Modified materials A is being continued into stirring no less than one hour, and room temperature cools down, and obtains modified materials B；
（5）Injection molding:The injection molding on injection molding machine by modified materials B；
Preferably, heat-resisting its whiteness of weather-proof modified materials of the ABS reaches more than 94 L values, A values reach+0.1, B values can reach-
0.6。
Preferably, after its form burn-in test of the heat-resisting weather-proof modified materials of the ABS is tested 96 hours, Δ E values are within 4.
Preferably, heat-resisting its softening point of weather-proof modified materials of the ABS is not less than 180 DEG C, and heat distortion temperature is not less than 98 DEG C,
Martin Heat Resistant Temperature is not less than 88 DEG C.
Compared with prior art, advantage is the present invention：The heat-resisting weather-proof modified materials of ABS are by plurality of raw materials according to spy
Fixed proportioning is made, and is remarkably improved its heat-resisting weatherability, easy to utilize.
Specific embodiment
The present invention is specifically described below by specific embodiment.
A kind of heat-resisting weather-proof modified materials of ABS, main constituents and quality proportioning are：80-85 parts of ABS resin, R105
4-5 parts of titanium dioxide, ethylene bis stearamide EBS are 0.7-0.9 parts, and 1-1.05 parts of PE waxes, ultraviolet absorber UV-P is 0.3-
0.35 part, polyamide 1010 is 0.3-0.4 parts, 770 0.25-0.3 parts of light stabilizer, and 168 be 0.2-0.25 parts, and MS-NB is resistance to
8-10 parts of thermit powder.
A kind of preparation method of the heat-resisting weather-proof modified materials of ABS, mainly includes the following steps：
（1）Dispensing：By raw material ABS resin, ethylene bis stearamide EBS, PE wax, polyamide 1010,168, MS-NB is heat-resisting
Agent carries out dispensing according to above-mentioned quality proportioning；
（2）Batch mixing:By step（1）300min, whipping temp 65-70 are stirred in homogenizer with the raw material got ready
℃；
（3）Cooling：By step（2）Mixed batch mixing adds in ultraviolet absorber UV-P, light stabilizer 770 and R105 titanium dioxides and obtains
To modified materials A；
（4）Drying：Modified materials A is being continued into stirring no less than one hour, and room temperature cools down, and obtains modified materials B；
（5）Injection molding:The injection molding on injection molding machine by modified materials B；
In order to advanced optimize technical solution, described heat-resisting its whiteness of weather-proof modified materials of ABS reaches more than 94 L values, and A values reach+
0.1, B value can reach -0.6.
In order to advanced optimize technical solution, its form burn-in test of the heat-resisting weather-proof modified materials of ABS is tested 96 hours
Afterwards, Δ E values are within 4.
In order to advanced optimize technical solution, described heat-resisting its softening point of weather-proof modified materials of ABS is not less than 180 DEG C, thermal change
Shape temperature is not less than 98 DEG C, and Martin Heat Resistant Temperature is not less than 88 DEG C.
Embodiment 1
A kind of heat-resisting weather-proof modified materials of ABS, main constituents and quality proportioning are：80 parts of ABS resin, R105 titanium dioxides 5
Part, ethylene bis stearamide EBS is 0.7 part, 1.05 parts of PE waxes, and ultraviolet absorber UV-P is 0.35 part, polyamide 1010 0.4
Part, 770 0.25 part of light stabilizer, 168 be 0.2 part, 10 parts of MS-NB heat-resistant agents.
Embodiment 2
A kind of heat-resisting weather-proof modified materials of ABS, main constituents and quality proportioning are：85 parts of ABS resin, R105 titanium dioxides 4
Part, ethylene bis stearamide EBS is 0.9 part, 1 part of PE waxes, and ultraviolet absorber UV-P is 0.3 part, and polyamide 1010 is 0.3 part,
770 0.25 part of light stabilizer, 168 be 0.25 part, 9 parts of MS-NB heat-resistant agents.
The preparation method of the heat-resisting weather-proof modified materials of the ABS of embodiment 1 and embodiment 2, carries out as steps described below：
A kind of preparation method of the heat-resisting weather-proof modified materials of ABS, mainly includes the following steps：
（1）Dispensing：By raw material ABS resin, ethylene bis stearamide EBS, PE wax, polyamide 1010,168, MS-NB is heat-resisting
Agent carries out dispensing according to above-mentioned quality proportioning；
（2）Batch mixing:By step（1）300min, whipping temp 65-70 are stirred in homogenizer with the raw material got ready
℃；
（3）Cooling：By step（2）Mixed batch mixing adds in ultraviolet absorber UV-P, light stabilizer 770 and R105 titanium dioxides and obtains
To modified materials A；
（4）Drying：Modified materials A is being continued into stirring no less than one hour, and room temperature cools down, and obtains modified materials B；
（5）Injection molding:The injection molding on injection molding machine by modified materials B；
Basic principle, main feature and the advantages of the present invention of the present invention has been shown and described above.The technical staff of the industry
It should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe the present invention
Principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these variation and
Improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent
Object defines.
Claims (5)
1. a kind of heat-resisting weather-proof modified materials of ABS, which is characterized in that its main constituents and quality proportioning are：ABS resin 80-
85 parts, 4-5 parts of R105 titanium dioxides, ethylene bis stearamide EBS is 0.7-0.9 parts, 1-1.05 parts of PE waxes, ultraviolet absorber UV-
P is 0.3-0.35 parts, and polyamide 1010 is 0.3-0.4 parts, 770 0.25-0.3 parts of light stabilizer, and 168 be 0.2-0.25 parts,
8-10 parts of MS-NB heat-resistant agents.
2. a kind of preparation method of the heat-resisting weather-proof modified materials of ABS, mainly includes the following steps：
Dispensing：By raw material ABS resin, ethylene bis stearamide EBS, PE wax, polyamide 1010,168, MS-NB heat-resistant agents press
Dispensing is carried out according to above-mentioned quality proportioning；
Batch mixing:By step（1）300min is stirred in homogenizer with the raw material got ready, whipping temp is 65-70 DEG C；
Cooling：By step（2）Mixed batch mixing adds in ultraviolet absorber UV-P, light stabilizer 770 and R105 titanium dioxides and obtains
Modified materials A；
Drying：Modified materials A is being continued into stirring no less than one hour, and room temperature cools down, and obtains modified materials B；
Injection molding:The injection molding on injection molding machine by modified materials B.
A kind of 3. heat-resisting weather-proof modified materials of ABS according to claim 1, which is characterized in that the heat-resisting weather-proof modified materials of ABS
Its whiteness reaches more than 94 L values, and A values, which reach+0.1, B values, can reach -0.6.
4. heat-resisting weather-proof modified materials of a kind of ABS and preparation method thereof according to claim 1, which is characterized in that the ABS is resistance to
After weather-proof its form burn-in test of modified materials of heat is tested 96 hours, Δ E values are within 4.
A kind of 5. heat-resisting weather-proof modified materials of ABS according to claim 1, which is characterized in that the heat-resisting weather-proof modified materials of ABS
Its softening point is not less than 180 DEG C, and heat distortion temperature is not less than 98 DEG C, and Martin Heat Resistant Temperature is not less than 88 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810000470.6A CN108250661A (en) | 2018-01-02 | 2018-01-02 | A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof |
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| CN201810000470.6A CN108250661A (en) | 2018-01-02 | 2018-01-02 | A kind of heat-resisting weather-proof modified materials of ABS and preparation method thereof |
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| CN108250661A true CN108250661A (en) | 2018-07-06 |
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Citations (10)
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|---|---|---|---|---|
| CN101121805A (en) * | 2006-08-09 | 2008-02-13 | 上海金发科技发展有限公司 | Noumenon method ABS modified material for automobile and preparation method thereof |
| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
| CN102367321A (en) * | 2011-08-31 | 2012-03-07 | 上海锦湖日丽塑料有限公司 | Heatproof ABS (acrylonitrile-butadiene-styrene) resin with improved long-term weather resistance and preparation method thereof |
| CN102532794A (en) * | 2012-01-16 | 2012-07-04 | 重庆巨翁塑料制造有限公司 | Matt ABS (acrylonitrile butadiene styrene) board and preparation method thereof |
| CN105038096A (en) * | 2015-09-02 | 2015-11-11 | 连云港海水化工有限公司 | White high-brightness weather-proof material containing ABS resin and preparation method of white high-brightness weather-proof material |
| CN106280205A (en) * | 2015-05-27 | 2017-01-04 | 上海华谊聚合物有限公司 | A kind of heat-proof ABS compositions and preparation method thereof |
| CN106280210A (en) * | 2016-08-05 | 2017-01-04 | 苏州玖圣塑料科技有限公司 | A kind of Heat resistance ABS material and preparation method thereof |
| CN107043516A (en) * | 2016-12-26 | 2017-08-15 | 上海金山锦湖日丽塑料有限公司 | Dark heat-proof ABS resin composition with improvement weatherability |
| CN107298827A (en) * | 2017-06-29 | 2017-10-27 | 上海金山锦湖日丽塑料有限公司 | Low gloss heat-resisting ABS resin and preparation method thereof |
| CN107474467A (en) * | 2017-07-10 | 2017-12-15 | 上海长伟锦磁工程塑料有限公司 | A kind of ultralow gloss Heat resistance ABS material |
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2018
- 2018-01-02 CN CN201810000470.6A patent/CN108250661A/en active Pending
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| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
| CN102367321A (en) * | 2011-08-31 | 2012-03-07 | 上海锦湖日丽塑料有限公司 | Heatproof ABS (acrylonitrile-butadiene-styrene) resin with improved long-term weather resistance and preparation method thereof |
| CN102532794A (en) * | 2012-01-16 | 2012-07-04 | 重庆巨翁塑料制造有限公司 | Matt ABS (acrylonitrile butadiene styrene) board and preparation method thereof |
| CN106280205A (en) * | 2015-05-27 | 2017-01-04 | 上海华谊聚合物有限公司 | A kind of heat-proof ABS compositions and preparation method thereof |
| CN105038096A (en) * | 2015-09-02 | 2015-11-11 | 连云港海水化工有限公司 | White high-brightness weather-proof material containing ABS resin and preparation method of white high-brightness weather-proof material |
| CN106280210A (en) * | 2016-08-05 | 2017-01-04 | 苏州玖圣塑料科技有限公司 | A kind of Heat resistance ABS material and preparation method thereof |
| CN107043516A (en) * | 2016-12-26 | 2017-08-15 | 上海金山锦湖日丽塑料有限公司 | Dark heat-proof ABS resin composition with improvement weatherability |
| CN107298827A (en) * | 2017-06-29 | 2017-10-27 | 上海金山锦湖日丽塑料有限公司 | Low gloss heat-resisting ABS resin and preparation method thereof |
| CN107474467A (en) * | 2017-07-10 | 2017-12-15 | 上海长伟锦磁工程塑料有限公司 | A kind of ultralow gloss Heat resistance ABS material |
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Application publication date: 20180706 |