CN108239447A - A kind of production method and equipment of PVDF fluorocarbon powder paints - Google Patents

A kind of production method and equipment of PVDF fluorocarbon powder paints Download PDF

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Publication number
CN108239447A
CN108239447A CN201611222861.XA CN201611222861A CN108239447A CN 108239447 A CN108239447 A CN 108239447A CN 201611222861 A CN201611222861 A CN 201611222861A CN 108239447 A CN108239447 A CN 108239447A
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CN
China
Prior art keywords
pvdf
fluorocarbon powder
powder paints
pressure roller
crushing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611222861.XA
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Chinese (zh)
Inventor
纪志勇
李�昊
陶月明
王俊
张涛
钱光凝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu KFCC New Materials Co Ltd
Original Assignee
Jiangsu KFCC New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu KFCC New Materials Co Ltd filed Critical Jiangsu KFCC New Materials Co Ltd
Priority to CN201611222861.XA priority Critical patent/CN108239447A/en
Publication of CN108239447A publication Critical patent/CN108239447A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/031Powdery paints characterised by particle size or shape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • C09D5/035Coloring agents, e.g. pigments

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The present invention relates to a kind of production methods and equipment of PVDF fluorocarbon powder paints, and this method is mainly for the method and apparatus of PVDF fluorocarbon powder paint crushing process.This method include by the heating melting extrusion of the raw materials such as PVDF resins, acrylic resin and color stuffing and pressure roller it is in blocks after crush, crushing while, is cooled down and then is dried, and is packed.Production method of the present invention effectively shortens the time for crushing pressure roller piece, effectively by size controlling between 20 30 microns;In addition, the airflow drying after crushing, the PVDF fluorocarbon powder paints particle after crushing, which is effectively ensured, to lump because of condensed water, it is ensured that the high-performance of fluorocarbon coating paint film.The production equipment of the present invention by the way that the equipment for being crushed to drying is connected, realizes the uninterrupted production of automation, production efficiency is high.

Description

A kind of production method and equipment of PVDF fluorocarbon powder paints
Technical field
The present invention relates to the production method and special equipment of a kind of fluorocarbon coating, more particularly to a kind of PVDF fluorocarbon coatings life Produce method and apparatus.
Background technology
Powdery paints is the form entirely different with general coating, it is with existing for the state of attritive powder.Due to not Using solvent, so referred to as powdery paints.The main feature of powdery paints has:With harmless, high efficiency, save resource and environmental protection Feature.
Powdery paints has the advantages that energy conservation and environmental protection, three-waste free pollution, and wherein fluorocarbon powder paint is excellent resistance to old with its The property changed especially weatherability and the surface that construction material, household electrical appliance and electronic device are widely used as the features such as chemical-resistant Coating, market potential are very big.
Existing powdery paints belongs to heat curable powder coating mostly, and resin and color stuffing is can be mixed by production process Melt extruded is crushed into powder again in flakes afterwards.But the materials such as PVDF resins, acrylic resin and color stuffing in PVDF fluorocarbon coatings Melt extruded such as reapplies the existing equipment once crushed later in flakes, since PVDF resins are that thermoplastics type holds in crushing process Be also easy to produce high temperature, leading to be prone at high temperature plasticizing causes molecular weight to become larger, and be easy to be ground into after its plasticizing grain size compared with Big particle influences the performance that coating uses rear paint film.In addition, using the method that liquid nitrogen cooling is used in crushing process, meeting PVDF powder fluorocarbon powder paints after crushing is caused to contain a large amount of condensed water and make its caking, are unfavorable for later stage PVDF fluorine carbon dust Coating application and seriously affect its paint film property.
Invention content
The purpose of the present invention is:Above-mentioned deficiency in the prior art is solved, a kind of production of PVDF fluorocarbon powder paints is provided Method and apparatus, this method is mainly for the method and apparatus of PVDF fluorocarbon powder paint crushing process.This method includes will The heating melting extrusion such as PVDF resins, acrylic resin and color stuffing and pressure roller it is in blocks after crush, crushing while, carries out The heating melting extrusion of the raw materials such as PVDF resins, acrylic resin and color stuffing and pressure roller are carried out powder by cooling, drying afterwards in flakes It is broken, it is carried out at the same time cooling;It crushes cooling and carries out airflow drying later, packaging obtains PVDF fluorocarbon powder paints.By PVDF trees The heating melting extrusion of the raw materials such as fat, acrylic resin and color stuffing and pressure roller it is in blocks after successively crush and be carried out at the same time cooling, Effectively shorten the time for crushing pressure roller piece, effectively by size controlling between 20-30 microns;In addition, gas is used after crushing Stream drying, the PVDF fluorocarbon powder paints particle after crushing, which is effectively ensured, to lump because of condensed water, it is ensured that fluorine carbon applies Expect the high-performance of paint film.The production equipment of the present invention by the way that the equipment for being crushed to drying is connected, is realized between automating not Medium well is produced, and production efficiency is high.
The production method of above-mentioned PVDF fluorocarbon powder paints, cooling medium is liquid in the pressure roller crushing process in blocks Nitrogen.
The production method of above-mentioned PVDF fluorocarbon powder paints, the cooling medium consumption are 1000-10000mL/min, More preferable 5000-8000mL/min.
The production method of above-mentioned PVDF fluorocarbon powder paints, the temperature of the air-flow after the crushing is 85-150 DEG C, More preferable 100~125 DEG C.
Realize that the production equipment of production method that the pressure roller of PVDF fluorocarbon powder paints of the present invention crushes in flakes has Three independent production equipments, the i.e. production of pressure roller reducing mechanism in blocks, liquid nitrogen cooling device and Pneumatic drying device are set It is standby.Wherein the discharge port of pressure roller reducing mechanism in blocks and Pneumatic drying device is passed through certainly by the discharge port of roller reducing mechanism in blocks Body weight enters in air current drying device.Three sets of independent equipment realize the uninterrupted production of automation, and production efficiency is high.
The production equipment of the production method of PVDF fluorocarbon powder paints of the present invention specifically includes pressure roller powder in blocks Crushing device, liquid nitrogen cooling device and Pneumatic drying device;The pressure roller reducing mechanism in blocks include reducing mechanism discharge port, Material-receiving device;The Pneumatic drying device includes dry gas flow control and temperature controller, discharge port.Pressure roller reducing mechanism in blocks Lower end, liquid nitrogen cooling device, reducing mechanism discharge port connection material-receiving device, splicing dress are connected with before reducing mechanism discharge port The discharging bottom plate put is connect with Pneumatic drying device;The Pneumatic drying device be equipped with dry gas flow and temperature controller and Discharge port.
The production equipment of above-mentioned PVDF fluorocarbon powder paints, the preferably material-receiving device discharging bottom plate and horizontal plane are into 45 Spend angle, the fluid bed splicing isolation board of Pneumatic drying device and horizontal plane are into 30 degree of angles.
The present invention has positive effect:The production method of PVDF fluorocarbon powder paints of the present invention, by PVDF resins, propylene The raw materials such as acid resin and color stuffing heating melting extrusion crushes after simultaneously pressure roller is in blocks, is carried out at the same time cooling, effectively shortening will The time that pressure roller piece crushes, effectively by size controlling between 20-30 microns;Airflow drying after crushing, is effectively ensured powder PVDF fluorocarbon powder paints particle after broken will not lump because of condensed water, it is ensured that the high-performance of fluorocarbon coating paint film.This The production equipment of invention by the way that the equipment for being crushed to drying is connected, realizes the uninterrupted production of automation, production efficiency It is high.
Description of the drawings
In order that the present invention can be more clearly and readily understood, it is right below according to specific embodiment and with reference to attached drawing The present invention is described in further detail, wherein
Fig. 1 is the structural diagram of the present invention.
Wherein, 1 pressure roller reducing mechanism in blocks, 2 liquid nitrogen cooling devices, 3 reducing mechanism discharge ports, 4 material-receiving devices, 5 dry gas Flow and temperature controller, 6 Pneumatic drying devices, 7 discharge ports, 8 discharging bottom plates, 9 fluid bed splicing isolation boards.
Specific embodiment
(embodiment 1) is shown in Fig. 1
The present embodiment PVDF fluorocarbon powder paint production equipments, including feeding device, resin melting device, extrusion device, Press pressure roller reducing mechanism 1 in blocks, liquid nitrogen cooling device 2 and Pneumatic drying device 6.Wherein pressure roller reducing mechanism 1 in blocks has Reducing mechanism discharge port 3, material-receiving device 4;Pneumatic drying device 6 has dry gas flow control and temperature controller 5, discharge port 7. Installation position of each device of the production line of aforementioned crushing and drying in workshop, is the common arrangement side of art of powder coatings Formula.Pressure roller reducing mechanism 1 in blocks includes liquid nitrogen cooling device 2 and Pneumatic drying device 6;Reducing mechanism discharge port 3, splicing Device 4;Pneumatic drying device 6 includes dry gas flow control and temperature controller 5, discharge port 7.Pressure roller reducing mechanism 1 in blocks Liquid nitrogen cooling device 2 is connected with before lower end, reducing mechanism discharge port 3, reducing mechanism discharge port 3 connects material-receiving device 4, splicing The discharging bottom plate 8 of device 4 connect the discharging bottom plate 8 of material-receiving device 4 and horizontal plane with Pneumatic drying device 6 into 45 degree of angles, air-flow 6 fluid bed splicing isolation board 9 of drying device and horizontal plane are into 30 degree of angles.In this way, the powder own wt of PVDF powdery paints into Enter in air current drying device.
PVDF fluorocarbon powder paints are produced using above equipment, 100kg companies are produced rolling piece PVDF powder first applies Expect predecessor, launch into pressure roller reducing mechanism 1 in blocks and while start liquid nitrogen cooling device 2, flow control 1000- 10000mL/min, it is 100-120 DEG C to open pneumatic conveying dryer 6 and set each area's temperature, then can prepare of the present invention PVDF fluorocarbon powder paints.
Particular embodiments described above has carried out the purpose of the present invention, technical solution and advantageous effect further in detail It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention Within the scope of shield.

Claims (7)

1. a kind of production method of PVDF fluorocarbon powder paints, this method is included PVDF resins, acrylic resin and color stuffing It waits raw materials heating melting, extrusion and pressure roller in flakes and then crushes, cooling, pack, it is characterised in that:By PVDF resins, acrylic acid The raw materials such as resin and color stuffing heating melting, squeeze out and pressure roller it is in blocks after crush, crushing while, is cooled down;It crushes cold But airflow drying is carried out after, then packaging obtains PVDF fluorocarbon powder paints.
2. the production method of PVDF fluorocarbon powder paints according to claim 1, it is characterised in that:The pressure roller powder in blocks Cooling medium is liquid nitrogen during broken.
3. the production method of PVDF fluorocarbon powder paints according to claim 1, it is characterised in that:The cooling medium stream It measures as 1000-10000mL/min.
4. the production method of PVDF fluorocarbon powder paints according to claim 1, it is characterised in that:After the crushing Airflow drying mode is fluidized-bed structure.
5. the production method of PVDF fluorocarbon powder paints according to claim 1, it is characterised in that:After the crushing The temperature for drying air-flow is 85-150 DEG C.
6. a kind of production equipment for the production method for realizing the PVDF fluorocarbon powder paints as described in Claims 1 to 5 is any, packet Include feeding device, resin melting device, extrusion device, pressure roller reducing mechanism in blocks, it is characterised in that:Pressure roller reducing mechanism in blocks (1) lower end, reducing mechanism discharge port (3) are connected with liquid nitrogen cooling device (2) before, and reducing mechanism discharge port (3) connection connects Expect device (4), the discharging bottom plate (8) of material-receiving device (4) is connect with Pneumatic drying device (6);Pneumatic drying device (6) peace Equipped with dry gas flow and temperature controller (5) and discharge port (7).
7. the production equipment of PVDF fluorocarbon powder paints according to claim 6, it is characterised in that:The material-receiving device (4) discharging bottom plate (8) and horizontal plane are into 45 degree of angles;The fluid bed splicing isolation board (9) and horizontal plane of Pneumatic drying device (6) Into 30 degree of angles.
CN201611222861.XA 2016-12-27 2016-12-27 A kind of production method and equipment of PVDF fluorocarbon powder paints Pending CN108239447A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611222861.XA CN108239447A (en) 2016-12-27 2016-12-27 A kind of production method and equipment of PVDF fluorocarbon powder paints

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611222861.XA CN108239447A (en) 2016-12-27 2016-12-27 A kind of production method and equipment of PVDF fluorocarbon powder paints

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CN108239447A true CN108239447A (en) 2018-07-03

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114085574A (en) * 2021-11-22 2022-02-25 擎天材料科技有限公司 Powder coating and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140283A (en) * 2011-04-14 2011-08-03 常州市双辉化工有限公司 Preparation method for super-weatherability powder coating
CN204434533U (en) * 2014-12-31 2015-07-01 江苏考普乐新材料有限公司 The production unit of PVDF fluorocarbon coating
WO2016002724A1 (en) * 2014-07-01 2016-01-07 旭硝子株式会社 Composition for powder paint, powder paint, and painted article
CN205112310U (en) * 2015-10-30 2016-03-30 科威嘉粉末涂料(天津)股份有限公司 Powder coating serialization production system
CN105802365A (en) * 2014-12-31 2016-07-27 江苏考普乐新材料有限公司 Production method and equipment for PVDF fluorocarbon coating
CN205528564U (en) * 2016-01-21 2016-08-31 江苏考普乐新材料有限公司 PVDF fluorine carbon powder coating's production facility
CN206494886U (en) * 2016-12-27 2017-09-15 江苏考普乐新材料有限公司 A kind of production equipment of PVDF fluorocarbon powder paints

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140283A (en) * 2011-04-14 2011-08-03 常州市双辉化工有限公司 Preparation method for super-weatherability powder coating
WO2016002724A1 (en) * 2014-07-01 2016-01-07 旭硝子株式会社 Composition for powder paint, powder paint, and painted article
CN204434533U (en) * 2014-12-31 2015-07-01 江苏考普乐新材料有限公司 The production unit of PVDF fluorocarbon coating
CN105802365A (en) * 2014-12-31 2016-07-27 江苏考普乐新材料有限公司 Production method and equipment for PVDF fluorocarbon coating
CN205112310U (en) * 2015-10-30 2016-03-30 科威嘉粉末涂料(天津)股份有限公司 Powder coating serialization production system
CN205528564U (en) * 2016-01-21 2016-08-31 江苏考普乐新材料有限公司 PVDF fluorine carbon powder coating's production facility
CN206494886U (en) * 2016-12-27 2017-09-15 江苏考普乐新材料有限公司 A kind of production equipment of PVDF fluorocarbon powder paints

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黄之祥等: "氟碳粉末涂料的发展趋势", 《中国涂料》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114085574A (en) * 2021-11-22 2022-02-25 擎天材料科技有限公司 Powder coating and preparation method and application thereof

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Application publication date: 20180703