CN108231945A - Graphene/hexagonal boron nitride/graphene ultraviolet light detector and preparation method - Google Patents

Graphene/hexagonal boron nitride/graphene ultraviolet light detector and preparation method Download PDF

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Publication number
CN108231945A
CN108231945A CN201810004657.3A CN201810004657A CN108231945A CN 108231945 A CN108231945 A CN 108231945A CN 201810004657 A CN201810004657 A CN 201810004657A CN 108231945 A CN108231945 A CN 108231945A
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Prior art keywords
graphene
hexagonal boron
boron nitride
layer
ultraviolet light
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刘恒
张兴旺
尹志岗
孟军华
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Institute of Semiconductors of CAS
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Institute of Semiconductors of CAS
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Priority to CN201810004657.3A priority Critical patent/CN108231945A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by at least one potential-jump barrier or surface barrier, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • H01L31/102Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier or surface barrier
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

A kind of graphene/hexagonal boron nitride/graphene ultraviolet light detector, including:One substrate;One insulating layer makes on substrate, plays the role of insulation;One first graphene layer, makes intermediate position on the insulating layer, which is strip;One hexagonal boron is produced on the side on the first graphene layer, and covering part insulating layer;One second graphene layer, is produced on hexagonal boron, and covering part insulating layer;One first electrode, make on the insulating layer, and with the end thereof contacts of the first graphene layer;One second electrode, make on the insulating layer, and with the end thereof contacts of the second graphene layer.The invention can ensure that device has high response speed and responsiveness, while using longitudinal device architecture, improve the integrated level of device.

Description

Graphene/hexagonal boron nitride/graphene ultraviolet light detector and preparation method
Technical field
The invention belongs to two-dimensional material applied technical fields, are related to a kind of graphene/hexagonal boron nitride/graphene ultraviolet light Detector and preparation method.
Background technology
With the discovery of graphene, two-dimensional material is more and more paid close attention to by people, become present material field most by One of hot spot of concern.Compared with body material, two-dimensional material has high specific surface area and excellent electricity, optical characteristics, Have broad application prospects in fields such as high-speed electronic components, light emitting diode, optical detector, solar cells.Six sides nitrogenize Boron, the isolog of graphene have many advantages, such as high band edge absorption coefficient, loose band gap (5.9eV), high thermal conductivity, It is considered as a kind of excellent deep ultraviolet light detection material.Recently, Sajjad et al. is reported based on hexagonal boron nitride nanosheet Photoconduction type deep ultraviolet detector, show excellent spectrum-selectivity characteristic.However, it is visited with certain high-performance deep ultraviolet light It surveys device to compare, the response speed of the hexagonal boron nitride ultraviolet light detector is slower, and responsiveness is relatively low, is also difficult to meet practical application Needs.Deficiency of the hexagonal boron nitride deep ultraviolet light detector in performance can be attributed to hexagonal boron nitride weak carrier point From with transport capability.Research shows that structure heterojunction structure can realize the quick separating of photo-generated carrier in two-dimensional material.Graphite Alkene is as a kind of material for possessing high carrier mobility, it is considered to be a kind of excellent carrier-transporting material.In addition, stone Black alkene is isolog with hexagonal boron nitride, and lattice mismatch is only 1.8%, is conducive to graphene/hexagonal boron nitride/graphene three The structure of Mingzhi's structure makes up the deficiency of hexagonal boron nitride performance, promotes the performance of boron nitride ultraviolet light detector.
Invention content
The object of the present invention is to provide a kind of graphene/hexagonal boron nitride/graphene ultraviolet light detector and preparation sides Method can ensure that device has high response speed and responsiveness, while using longitudinal device architecture, improves the integrated of device Degree.
To achieve the above objectives, the present invention provides a kind of graphene/hexagonal boron nitride/graphene ultraviolet light detector, packet It includes:
One substrate;
One insulating layer makes on substrate, plays the role of insulation;
One first graphene layer, makes intermediate position on the insulating layer, which is strip;
One hexagonal boron is produced on the side on the first graphene layer, and covering part insulating layer;
One second graphene layer, is produced on hexagonal boron, and covering part insulating layer;
One first electrode, make on the insulating layer, and with the end thereof contacts of the first graphene layer;
One second electrode, is produced on the insulating layer, and with the end thereof contacts of the second graphene layer.
2. graphene/hexagonal boron nitride according to claim 1/graphene ultraviolet light detector, wherein the lining The material at bottom is the monocrystalline silicon of heavy doping.
3. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein described The material of insulating layer is silica.
4. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein described First, second graphene layer is individual layer or a small number of multilayers, and the thickness of the hexagonal boron is 1-20 nanometers.
5. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein described The material of first electrode and second electrode is Ti, Cr, Au or Ag, and thickness is 100-200 nanometers.
The present invention also provides a kind of preparation method of graphene/hexagonal boron nitride/graphene ultraviolet light detector, including with Lower step:
Step 1:The graphene of individual layer and a small number of multilayers is prepared on transition metal using chemical vapour deposition technique;
Step 2:Multilayer hexagonal boron nitride film is prepared on another transition metal using Assisted by Ion Beam sputtering method;
Step 3:One layer of rosin of spin coating on graphene removes transition metal layer by wet etching, only retains graphene And rosin;
Step 4:Then transfer graphene on the insulating layer on substrate, and the pine of graphene surface is washed with acetone It is fragrant;
Step 5:Using to step 3 to the similar method of step 4, hexagonal boron nitride and the are shifted on the first graphene Two graphenes, the structure graphene-structured of the first graphene/hexagonal boron nitride/second;
Step 6:One end deposition of first electrode on the first graphene;
Step 7:One end deposition second electrode on the second graphene.
It can be seen from the above technical proposal that a kind of graphene/hexagonal boron nitride/graphene ultraviolet light proposed by the present invention Detector and preparation method have the advantages that:
Graphene has high carrier mobility and high light transmission rate, graphene is combined with hexagonal boron nitride, structure Graphene/hexagonal boron nitride/graphene is built, carrier fill level in graphene is adjusted by applied voltage, it can not only be real The quick separating of existing photo-generate electron-hole pair can also greatly improve the transport efficiency of carrier.As shown in figure 3, in grid voltage Under effect, the carrier filling situation of graphene will change, so as to form energy in graphene/hexagonal boron nitride/graphene Band gradient.Under illumination condition, electron hole pair is generated in hexagonal boron nitride, carrier shifts under the action of electric field, Realize the separation of carrier.Therefore, graphene/hexagonal boron nitride/graphene heterojunction structure is expected to make up hexagonal boron nitride ultraviolet The deficiency of detector, it is whole to promote device performance.
Description of the drawings
For the technology contents further illustrated the present invention, with reference to embodiments and attached drawing is described in detail as after, wherein:
Fig. 1 is the structure diagram of graphene/hexagonal boron nitride/graphene ultraviolet light detector;
Fig. 2 is flow chart of the method for the present invention;
Fig. 3 is graphene/hexagonal boron nitride/graphene heterostructure band schematic diagram after applying grid voltage to the structure of Fig. 1.
Specific embodiment
Refering to Figure 1, the present invention provides a kind of ultraviolet light detector of graphene/hexagonal boron nitride/graphene, packet It includes:
One substrate 10, the material of the substrate 10 are the monocrystalline silicon of heavy doping, as the gate electrode of optical detector, realization pair The adjusting of graphene, hexagonal boron nitride carrier fill level;
One insulating layer 20 makes over the substrate 10, plays the role of insulation, the material of the insulating layer 20 is titanium dioxide Silicon;
One first graphene layer 30 is produced on the intermediate position on insulating layer 20, which is strip, First graphene layer 30 is individual layer or a small number of multilayers, and main function is to form heterojunction structure with hexagonal boron nitride, so as to real The quick separating of photo-generated carrier in existing hexagonal boron nitride;
One hexagonal boron 40 is produced on the side on the first graphene layer 30, and covering part insulating layer 20, institute The thickness for stating hexagonal boron 40 is 1-20 nanometers, and hexagonal boron nitride is wide bandgap semiconductor, there is very strong light absorpting ability, Photo-generate electron-hole pair is generated after absorbing ultraviolet light, the detection to ultraviolet light is realized in conductive capability enhancing;
One second graphene layer 50, is produced on hexagonal boron 40, and covering part insulating layer 20, and described second Graphene layer 50 is individual layer or a small number of multilayers, and on the one hand the second layer graphene can form heterojunction structure with hexagonal boron nitride, real The transfer of existing carrier, is on the other hand also used as transparent electrode, and the absorption to ultraviolet light is reduced while conduction;
One first electrode 60, is produced on insulating layer 20, and with the end thereof contacts of the first graphene layer 30, described first The material of electrode 60 is Ti, Cr, Au or Ag, and thickness is 100-200 nanometers;
One second electrode 70, is produced on insulating layer 20, and with the end thereof contacts of the second graphene layer 50, described The material of two electrodes 70 is Ti, Cr, Au or Ag, and thickness is 100-200 nanometers.
It please refers to Fig. 2 and combination is as shown in fig.1, a kind of graphene/hexagonal boron nitride/graphene of present invention offer is heterogeneous Ultraviolet detector preparation method, include the following steps:
Step 1:The graphene of individual layer and a small number of multilayers is prepared in transition metal using chemical vapour deposition technique, was grown By adjusting the thickness of graphene and domain size prepared by growth temperature and growth time adjusting in journey;
Step 2:Multilayer hexagonal boron nitride film is prepared on another transition metal using Assisted by Ion Beam sputtering method, is grown In the process by adjusting the thickness of hexagonal boron nitride and domain size prepared by growth temperature and growth time adjusting;
Step 3:One layer of rosin of spin coating on graphene removes transition metal layer by wet etching, only retains graphene And rosin, graphene and rosin is cleaned multiple times using deionized water, removes remaining corrosive liquid;
Step 4:Then transfer graphene on the insulating layer 20 on substrate 10, and graphene surface is washed with acetone Rosin, the material of the substrate 10 is the monocrystalline silicon of heavy doping, and the material of the insulating layer 20 is silica;
Step 5:Using to step 3 to the similar method of step 4, shifted on the first graphene 30 hexagonal boron nitride 40 with And second graphene 50,30/ 40/ second graphene of hexagonal boron nitride of the first graphene of structure, 50 structure ensure in transfer process There are hexagonal boron nitride interval, first, second graphene among first graphene layer and the second graphene layer overlapping region Layer 30,50 is individual layer or a small number of multilayers, and the thickness of the hexagonal boron 40 is 1-20 nanometers;
Step 6:One end deposition of first electrode 60 on the first graphene 30, the material of the first electrode 60 is Ti, Cr, Au or Ag, thickness are 100-200 nanometers;
Step 7:One end deposition second electrode 70 on the second graphene 50, the material of the second electrode 70 is Ti, Cr, Au or Ag, thickness are 100-200 nanometers.
Particular embodiments described above has carried out the purpose of the present invention, technical solution and advantageous effect further in detail It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention Within the scope of shield.

Claims (10)

1. a kind of graphene/hexagonal boron nitride/graphene ultraviolet light detector, including:
One substrate;
One insulating layer makes on substrate, plays the role of insulation;
One first graphene layer, makes intermediate position on the insulating layer, which is strip;
One hexagonal boron is produced on the side on the first graphene layer, and covering part insulating layer;
One second graphene layer, is produced on hexagonal boron, and covering part insulating layer;
One first electrode, make on the insulating layer, and with the end thereof contacts of the first graphene layer;
One second electrode, is produced on the insulating layer, and with the end thereof contacts of the second graphene layer.
2. graphene/hexagonal boron nitride according to claim 1/graphene ultraviolet light detector, wherein the substrate Material is the monocrystalline silicon of heavy doping.
3. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein the insulation The material of layer is silica.
4. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein described first, Second graphene layer is individual layer or a small number of multilayers, and the thickness of the hexagonal boron is 1-20 nanometers.
5. the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 1, wherein described first Electrode and the material of second electrode are Ti, Cr, Au or Ag, and thickness is 100-200 nanometers.
6. a kind of preparation method of graphene/hexagonal boron nitride/graphene ultraviolet light detector, includes the following steps:
Step 1:The graphene of individual layer and a small number of multilayers is prepared on transition metal using chemical vapour deposition technique;
Step 2:Multilayer hexagonal boron nitride film is prepared on another transition metal using Assisted by Ion Beam sputtering method;
Step 3:One layer of rosin of spin coating on graphene removes transition metal layer by wet etching, only retains graphene and pine It is fragrant;
Step 4:Then transfer graphene on the insulating layer on substrate, and the rosin of graphene surface is washed with acetone;
Step 5:Using to step 3 to the similar method of step 4, hexagonal boron nitride and the second stone are shifted on the first graphene Black alkene, the structure graphene-structured of the first graphene/hexagonal boron nitride/second;
Step 6:One end deposition of first electrode on the first graphene;
Step 7:One end deposition second electrode on the second graphene.
7. the preparation method of the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 6, Described in substrate material be heavy doping monocrystalline silicon.
8. the preparation method of graphene/hexagonal boron nitride according to claim 6/graphene ultraviolet light detector, wherein The material of the insulating layer is silica.
9. the preparation method of the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 6, Described in first, second graphene layer be individual layer or a small number of multilayer, the thickness of the hexagonal boron is 1-20 nanometers.
10. the preparation method of the ultraviolet light detector of graphene/hexagonal boron nitride/graphene according to claim 6, Described in the material of first electrode and second electrode be Ti, Cr, Au or Ag, thickness be 100-200 nanometers.
CN201810004657.3A 2018-01-03 2018-01-03 Graphene/hexagonal boron nitride/graphene ultraviolet light detector and preparation method Pending CN108231945A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN111244222A (en) * 2020-01-20 2020-06-05 中国科学院半导体研究所 Hexagonal boron nitride ultraviolet light detector and preparation method thereof
CN111710750A (en) * 2020-06-24 2020-09-25 吉林大学 Deep ultraviolet photoelectric detector based on hexagonal boron nitride thick film and preparation method
WO2020243118A1 (en) * 2019-05-24 2020-12-03 Seven Z's Trust Solar energy processing unit
CN114551626A (en) * 2022-02-22 2022-05-27 吉林大学 Deep ultraviolet photoelectric detector and preparation method and application thereof

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CN106505115A (en) * 2016-10-17 2017-03-15 浙江大学 Quantum dot light doped graphene/boron nitride/gallium nitride ultraviolet detector and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020243118A1 (en) * 2019-05-24 2020-12-03 Seven Z's Trust Solar energy processing unit
CN112714961A (en) * 2019-05-24 2021-04-27 塞文Z`S崔斯特公司 Solar energy processing unit
CN111244222A (en) * 2020-01-20 2020-06-05 中国科学院半导体研究所 Hexagonal boron nitride ultraviolet light detector and preparation method thereof
CN111710750A (en) * 2020-06-24 2020-09-25 吉林大学 Deep ultraviolet photoelectric detector based on hexagonal boron nitride thick film and preparation method
CN111710750B (en) * 2020-06-24 2022-12-13 吉林大学 Deep ultraviolet photoelectric detector based on hexagonal boron nitride thick film and preparation method
CN114551626A (en) * 2022-02-22 2022-05-27 吉林大学 Deep ultraviolet photoelectric detector and preparation method and application thereof
CN114551626B (en) * 2022-02-22 2024-01-26 吉林大学 Deep ultraviolet photoelectric detector and preparation method and application thereof

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Application publication date: 20180629