CN108219758A - The anhydrous noncongeable oil of superconduction and its application - Google Patents
The anhydrous noncongeable oil of superconduction and its application Download PDFInfo
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- CN108219758A CN108219758A CN201810083643.5A CN201810083643A CN108219758A CN 108219758 A CN108219758 A CN 108219758A CN 201810083643 A CN201810083643 A CN 201810083643A CN 108219758 A CN108219758 A CN 108219758A
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- superconduction
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
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Abstract
The invention discloses a kind of anhydrous noncongeable oil of superconduction, each substance including following mass percentage：86~88% 1,2 propylene glycol；0.22~0.24% sodium molybdate；0.45~3.65% dibutyl hydroxy toluene；0.35~0.45% benzotriazole；3.0~3.3% sebacic acid；2.2~2.5% potassium hydroxide；The phosphoric acid of 1.8~2.3%85Wt.%；1.6~1.8% sodium benzoates；0.2~0.28% hydrolysis of polymaleic anhydride；0.008~0.012% Denatonium Benzoate；Surplus is adjuvant；The anhydrous noncongeable oil boiling point of the superconduction is higher than 210 DEG C, freezing point is less than 60 DEG C, the close neutrality of pH, without any violated raw material, it is harmless, meet the environmental protection standard of the current international practice, the anhydrous noncongeable oil of the superconduction can use under various natural environmental conditions, and thoroughly solve the problems, such as that oil and gasoline engine boils due to overheat.
Description
Technical field
The present invention relates to anti-icing fluid technical field, more particularly, to a kind of anhydrous noncongeable oil of superconduction and its application.
Background technology
Antifreeze is winter protection against cold and freezing conditions measure, is mainly used for automobile, crops, family etc., antifreezing measures are added to automobile
Non-congealable oil, anti-icing fluid；All anti-icing fluid on the market now, is mainly dissolved with water by ethylene glycol (chemical name) and formed.Water
Although with good heat conductivity, this is common sense, and since the freezing point of water is 0 DEG C, boiling point is 100 DEG C, therefore water is opened at 0 DEG C
Begin to freeze, it can freezing cylinder body；It comes to life, therefore lead to engine overheat when 100 DEG C, until causing to paralyse.It is true
It is that Engine Cylinder Wall begins to generate vapor, bubble when engine temperature reaches 85 DEG C.Existing ethylene glycol antifreeze
Its freezing point is -30 DEG C or so, although it solves the problems, such as antifreeze, other defects, such as its low boiling point, ice to a certain extent
The problem of point is not low enough is not resolved；And product of the ethylene glycol in human body is hydroxyl, acetic acid and oxalic acid, easily makes human body
Interior acid-base imbalance generates destruction to kidney.Ethylene glycol in use can be also evaporated to water vapour in air, and when replacement is sprinkled upon
It on ground, is polluted to environment and air, compromises the physical and mental health of people；In addition under electrolyte effect electrification occurs for water
Corrosion and generation incrustation scale, evaporation, cavitation erosion, gradually corrode cylinder body, water tank and rubber parts, just as " ant cave ", cause to vehicle
Damage shortens the service life of automobile.These harm attract great attention already in the more flourishing country of economy, as Switzerland exists
Promulgate after " Switzerland's poisonous substance method " that Switzerland forbids in supermarket, part shops public offering ethylene glycol type coolant within 1972；
In addition the heat transfer of existing coolant and heat-energy transducer force difference, it is impossible to meet actual demand.
Since the use environment of automobile is round-the-clock for the whole world, the coolant of engine should can be at subzero 50~60 DEG C it is cruel
Ensure not freeze, and can keep not boiling in the heat environment in tropical desert in cold, be provided simultaneously with cold-proof and heat-resisting, existing skill
The heat transfer of coolant existing for art and heat-energy transducer force difference, it is impossible to meet the application demand of automobile under various circumstances.
Invention content
According to an aspect of the present invention, provide a kind of superconduction anhydrous noncongeable oil first, to solve above-mentioned technical problem
It is at least one.
The anhydrous noncongeable oil of superconduction, each substance including following mass percentage：
The above-mentioned anhydrous noncongeable oil of superconduction may also be referred to as superconducting fluid either superconduction noncongeable oil or superconduction water-free cooling,
The change of its title can't influence the superconductive liquid system obtained by the material mixing of above-mentioned specific proportioning.
In the above-mentioned anhydrous noncongeable oil of superconduction of the present invention, main body is 1,2-PD, itself is exactly a kind of Jie of heat transfer
Matter, and metabolite of the 1,2-PD in human body is Lactic acid and Pyruvic acid, the two substances are body eubolism
Product, and it is harmless to human body and animal；By the way that 1,2-PD and other substances are compounded, and by a large amount of screenings, adopt
Above-mentioned substance is subjected to mixing with certain content ratio and obtains a superconductive liquid system.
The superconductive liquid system start-up temperature being mixed to form of above-mentioned substance of the present invention is low, it is only necessary to which 35 DEG C can start to pass
Temperature, and typically contain the coolant of water either strong transmit of water just must be over or reach 100 DEG C in anti-icing fluid, water heating
It is very slow, transmit slower, the startup heating of general hot-water heating has to pass through one to two hour and can be only achieved room temperature, however institute of the present invention
Superconductive liquid system to be protected only needs a few minutes can be radiators heat so that automotive interior can be realized quickly
Heat transfer and heat dissipation, so as to improve the performance of automobile.
In addition, particularly dibutyl hydroxy toluene causes the superconductive liquid system to compare tradition with the addition of Denatonium Benzoate
Coolant and anti-icing fluid, boiling point improve to 210 DEG C, freezing point down to -60 DEG C, then can by higher boiling point and lower freezing point
Ensure that it does not freeze in -60~-50 DEG C of bitter cold, and can keep not boiling in the heat environment in tropical desert, i.e., simultaneously
Has splendid cold-proof and heat-resisting effect.
Moreover, the close neutrality of the superconductive liquid system pH value, and any violated raw material is free of, and it is harmless, meet state
The environmental protection standard that border is passed through, the anhydrous noncongeable oil of the superconduction can thoroughly use (either snowy region under various natural environmental conditions
Plateau or tropical desert will not freeze and boil), and thoroughly solve what oil and gasoline engine boiled due to overheat
Problem.
In the above-mentioned superconductive liquid system injection metal shell of the present invention, after heated, absorb heat, can be generated in shell interior
Pressure, is in a disguised form conducted heat under certain pressure intensity.I.e. according to explosive evaporation, heat absorption and heat storage and the mechanism progress for condensing exothermic chemical gesture
Heat transfer；, when carrying out heat transfer for 165 DEG C~210 DEG C, constant bad during conduction, operating mode is good, securely and reliably for it.
In some embodiments, the adjuvant in the anhydrous noncongeable oil of above-mentioned superconduction in antifoaming agent, dyestuff at least one
Kind.
Above-mentioned antifoaming agent can be to avoid the anhydrous noncongeable oil of superconduction within the scope of very wide temperature and under various mal-conditions
Defoam suds；Dyestuff is painted to the anhydrous noncongeable oil of superconduction, can be used for significantly judging whether automobile has the phenomenon of leakage.
The antifoaming agent and dyestuff that can be used in the antifoaming agent of the present invention and dye selection anti-icing fluid.
In some embodiments, the mass percentage of above-mentioned antifoaming agent is 0.0005~0.001%；The quality of dyestuff
Percentage composition is 0.005~0.0055%.
It using the anhydrous noncongeable oil of above-mentioned superconduction, can cause the oil consumption of motor vehicle to significantly reduce, reduce engine noise, because
This, the present invention also provides application of the anhydrous noncongeable oil of above-mentioned superconduction in terms of motor vehicle fuel consumption is reduced.
The above-mentioned anhydrous noncongeable oil of superconduction of the present invention has further the advantage that：
(1) have superpower heat conductivity, liquid viscosity variation with temperature and change, so as to balanced engine
Internal temperature keeps engine in the temperature range being more suitable for so that fuel combustion is more complete.
(2) heat for having the circumferential metal of high long-acting control " combustion chamber fire point " excessively high, discharges the consumption of engine completely
Power, so that automobile engine plays perfect performance.
(3) engine zero is corroded, low-pressure, primary filling can cause 800,000 kilometers of running car.
Specific embodiment
With reference to embodiment, the present invention is described in further detail.
Embodiment 1
The anhydrous noncongeable oil 1 of superconduction, each substance including following mass percentage：87.954% 1,2-PD；
0.24% sodium molybdate；2.34% dibutyl hydroxy toluene；0.45% benzotriazole；3.0% sebacic acid；2.2% potassium hydroxide；
The phosphoric acid of 2.0% 85Wt.%；1.6% sodium benzoate；0.2% hydrolysis of polymaleic anhydride；0.01% Denatonium Benzoate；
0.001% antifoaming agent；0.005% dyestuff.
Embodiment 2
The anhydrous noncongeable oil 2 of superconduction, each substance including following mass percentage：86% 1,2-PD；0.23%
Sodium molybdate；3.2715% dibutyl hydroxy toluene；0.3% benzotriazole；3.3% sebacic acid；2.5% potassium hydroxide；2.3%
85Wt.% phosphoric acid；1.8% sodium benzoate；0.28% hydrolysis of polymaleic anhydride；0.012% Denatonium Benzoate；0.001%
Antifoaming agent；0.0055% dyestuff.
Embodiment 3
The anhydrous noncongeable oil 3 of superconduction, each substance including following mass percentage：88% 1,2-PD；0.22%
Sodium molybdate；2.0131% dibutyl hydroxy toluene；0.4% benzotriazole；3.2% sebacic acid；2.4% potassium hydroxide；1.8%
85Wt.% phosphoric acid；1.7% sodium benzoate；0.25% hydrolysis of polymaleic anhydride；0.011% Denatonium Benzoate；0.0005%
Antifoaming agent；0.0054% dyestuff.
The anhydrous noncongeable oil 1 of superconduction that embodiment 1 is prepared to embodiment 3 carries out performance to the anhydrous noncongeable oil 3 of superconduction
It characterizes (test condition all same), as a result such as table 1.
Table 1
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, not
Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to the protection model of the present invention
It encloses.
Claims (4)
1. the anhydrous noncongeable oil of superconduction, which is characterized in that each substance including following mass percentage：
2. the anhydrous noncongeable oil of superconduction according to claim 1, which is characterized in that the adjuvant is in antifoaming agent, dyestuff
At least one.
3. the anhydrous noncongeable oil of superconduction according to claim 2, which is characterized in that the mass percentage of the antifoaming agent is
0.0005~0.001%；The mass percentage of dyestuff is 0.005~0.0055%.
4. application of the anhydrous noncongeable oil of any one of claims 1 to 3 superconduction in terms of motor vehicle fuel consumption is reduced.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083643.5A CN108219758B (en) | 2018-01-29 | 2018-01-29 | Superconductive anhydrous antifreeze oil and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083643.5A CN108219758B (en) | 2018-01-29 | 2018-01-29 | Superconductive anhydrous antifreeze oil and application thereof |
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| Publication Number | Publication Date |
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| CN108219758A true CN108219758A (en) | 2018-06-29 |
| CN108219758B CN108219758B (en) | 2020-08-28 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319134A (en) * | 2007-06-06 | 2008-12-10 | 黄永红 | Long-acting liquid coolant not containing ethylene glycol |
| CN102260486A (en) * | 2011-06-23 | 2011-11-30 | 江苏张家港迪克汽车化学品有限公司 | 1,2-propylene glycol antifreezing liquid coolant |
| CN102559152A (en) * | 2012-01-10 | 2012-07-11 | 广州市标榜汽车用品实业有限公司 | All-organic waterless engine coolant |
| CN104673253A (en) * | 2013-12-03 | 2015-06-03 | 青岛惠城石化科技有限公司 | Research on components of novel automotive anti-freeze fluid |
| CN105524598A (en) * | 2016-02-02 | 2016-04-27 | 武威龙华微工贸有限公司 | Anhydrous coolant and preparation method thereof |
| CN106566483A (en) * | 2016-11-15 | 2017-04-19 | 安徽超际环保科技有限公司 | Waterless liquid coolant for engine under extreme conditions and preparation method thereof |
-
2018
- 2018-01-29 CN CN201810083643.5A patent/CN108219758B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319134A (en) * | 2007-06-06 | 2008-12-10 | 黄永红 | Long-acting liquid coolant not containing ethylene glycol |
| CN102260486A (en) * | 2011-06-23 | 2011-11-30 | 江苏张家港迪克汽车化学品有限公司 | 1,2-propylene glycol antifreezing liquid coolant |
| CN102559152A (en) * | 2012-01-10 | 2012-07-11 | 广州市标榜汽车用品实业有限公司 | All-organic waterless engine coolant |
| CN104673253A (en) * | 2013-12-03 | 2015-06-03 | 青岛惠城石化科技有限公司 | Research on components of novel automotive anti-freeze fluid |
| CN105524598A (en) * | 2016-02-02 | 2016-04-27 | 武威龙华微工贸有限公司 | Anhydrous coolant and preparation method thereof |
| CN106566483A (en) * | 2016-11-15 | 2017-04-19 | 安徽超际环保科技有限公司 | Waterless liquid coolant for engine under extreme conditions and preparation method thereof |
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