CN108217950A - The device and method that FNA reinforcement sludges ferment and realize sewerage short-cut denitrification dephosphorization - Google Patents

The device and method that FNA reinforcement sludges ferment and realize sewerage short-cut denitrification dephosphorization Download PDF

Info

Publication number
CN108217950A
CN108217950A CN201810203310.1A CN201810203310A CN108217950A CN 108217950 A CN108217950 A CN 108217950A CN 201810203310 A CN201810203310 A CN 201810203310A CN 108217950 A CN108217950 A CN 108217950A
Authority
CN
China
Prior art keywords
sludge
reactor
fna
valve
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810203310.1A
Other languages
Chinese (zh)
Other versions
CN108217950B (en
Inventor
彭永臻
王增花
王博
宫小斐
乔昕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing University of Technology
Original Assignee
Beijing University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Technology filed Critical Beijing University of Technology
Priority to CN201810203310.1A priority Critical patent/CN108217950B/en
Publication of CN108217950A publication Critical patent/CN108217950A/en
Application granted granted Critical
Publication of CN108217950B publication Critical patent/CN108217950B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Microbiology (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

FNA reinforcement sludges ferment and the apparatus and method of realization sewerage short-cut denitrification dephosphorization, belong to sewage sludge process field.The device includes:Raw water box, sbr reactor device, intermediate water tank, UASB reactors, Treatment of Sludge reactor, sludge fermentation tank.Free nitrous acid (FNA) is inhibited nitrite oxidizing bacteria to realize short distance nitration with both hydrolysis acidifications being promoted to be combined as sludge fermentation pre-treatment step by this method, short distance nitration reactor spoil disposal is returned through FNA processing rear portions, and another part enters sludge fermentation tank.Sbr reactor device elder generation anoxic denitrification removal extra nitrous of upper period, anaerobic phosphorus release again, the concurrent first portion short distance nitration of aerobic phosphorus absorption, water outlet enters UASB together with sludge fermentation liquid, with nitrous by anaerobic ammonia oxidizing bacteria autotrophic denitrification, remaining nitrous removes part ammonia nitrogen with organic matter denitrification in the Nitrate-N Use sludge fermentation liquid generated.The present invention promotes internal carbon source to develop and realize municipal sewage denitrogenation dephosphorizing, and mud decrement using FNA, reduces sewage disposal energy consumption.

Description

The device and method that FNA reinforcement sludges ferment and realize sewerage short-cut denitrification dephosphorization
Technical field
The present invention relates to the apparatus and method of a kind of fermentation of FNA reinforcement sludges and realization sewerage short-cut denitrification dephosphorization, belong to Technical field of biological sewage treatment.The innovation inhibits free nitrous acid (FNA) nitrite oxidizing bacteria realization short Journey nitrification is removed with both hydrolysis acidifications being promoted to be combined as sludge fermentation pre-treatment step in realization short distance nitration biological denitrificaion Reinforcement sludge internal carbon source is developed while phosphorus, and the processing disposition for urban domestic sewage sludge provides a new approaches.
Background technology
Municipal sewage plant of China mostly realizes nitrogen in sewage using traditional nitration denitrification biological denitrification process at present Qualified discharge.Ammonia oxidation bacteria (AOB) is using oxygen as electron acceptor in traditional biological denitrification process, by NH4 +It is oxidized to NO2 -, with Nitrite oxidizing bacteria (NOB) is using oxygen as electron acceptor afterwards, by NO2 -It is oxidized to NO3 -, last denitrifying bacterium made with organic matter For electron donor, by NO3 -It is reduced to N2, it is finally reached the purpose for removing nitrogen from sewage.The discovery of anaerobic ammonia oxidizing bacteria makes dirt Water autotrophic denitrification is possibly realized, and anaerobic ammonia oxidizing bacteria utilizes NO2 -NH is aoxidized as electron acceptor4 +Generate N2, the process is with inorganic Carbon does not need to organic matter as carbon source, so as to achieve the purpose that denitrification of autotrophic organism as carbon source.And Anammox biology skill The key that art is applied to municipal sewage denitrogenation processing is exactly substrate NO2 -Stablize obtain.
Short distance nitration technology is ammonia oxidizing bacteria by NH4 +It is oxidized to NO2 -, substrate NO can be provided for Anammox2 -.Mesh The preceding stable Technical comparing for realizing municipal sewage short distance nitration is few, therefore stablizes and realize that municipal sewage short distance nitration is limitation city The bottleneck of anerobic sowage ammoxidation autotrophic denitrification.Recent studies have found that inhibition of the nitrous acid (FNA) to NOB that dissociate under anoxia condition Effect is more than the inhibition to AOB, is advantageously implemented short distance nitration.
Biological denitrification process based on activated sludge process is widely used to field of municipal sewage treatment, but a large amount of in sewage Organic substance be transferred in sludge sludge yield caused to increase, aggravate the investment of sewage treatment plant and operation burden.In addition, city The characteristics of city's sewage low-carbon nitrogen ratio, leads to that outer carbon source must be added in its biological denitrification process, this results in the fortune of sewage treatment plant Row expense greatly increases.Therefore, realize excess sludge minimizing and recycling and exploitation sludge internal carbon source, it has also become city The difficult point and emphasis of sewage disposal.Sludge fermentation can realize that organic matter transformation is volatile fatty acid (VFAs) in sludge, and Afterwards as the available advantage carbon source of microorganism in biological denitrification process.However, sludge decomposition is typically considered excess sludge Rate-limiting step in fermentation process.Sludge fermentation is generally by pyrolysis, physics (ultrasound), electricity and chemical sludge pre-treatment techniques Cause microbial cell broken wall.But above-mentioned technology is big (high temperature or high pressure) there are energy consumption, need a large amount of chemical substances (chlorine, it is smelly Oxygen and basicity etc.) and pollution environment the problems such as.Therefore, a kind of sludge pre-treatment techniques are found to improve biodegradability particularly It is important.Pertinent literature pre-processes excess sludge using FNA, promotes sludge due to the microorganism in excess sludge is inactivated Disintegrate, improve excess sludge fermentation character.
Invention content
To solve the above-mentioned problems, the purpose of the present invention is inhibit nitrite oxidizing bacteria real free nitrous acid (FNA) Existing short distance nitration takes off with both hydrolysis acidifications being promoted to be combined as sludge fermentation pre-treatment step in realization short distance nitration biology Reinforcement sludge internal carbon source is developed while nitrogen dephosphorization.Short distance nitration reactor spoil disposal is returned through FNA processing rear portions, another portion Divide and enter sludge fermentation tank.Sbr reactor device elder generation anoxic denitrification removal extra nitrous of upper period, then anaerobic phosphorus release, aerobic phosphorus absorption Concurrent first portion short distance nitration is discharged same sludge fermentation liquid and enters UASB reactors together, and part ammonia nitrogen passes through anaerobism with nitrous Organic matter denitrification removes in ammonia oxidation bacteria autotrophic denitrification, remaining nitrous and the Nitrate-N Use sludge fermentation liquid generated, so as to Realize the advanced nitrogen dephosphorization of sanitary sewage.
To achieve the above object, the present invention provides a kind of FNA reinforcement sludges fermentation and realizes sewerage short-cut denitrification dephosphorization Device, including:Raw water box (1), sbr reactor device (2), intermediate water tank (3), UASB reactors (4), Treatment of Sludge reactor (5), Sludge fermentation tank (6);Raw water box (1) is supplied water by raw water intake pump (1.1) to sbr reactor device (2), and sbr reactor device (2) is equipped with First temperature control device (2.1), the first agitating device (2.2), the first pH analyzers (2.6), DO analyzers (2.7), by being equipped with Gas flowmeter (2.3), air valve (2.4), air compressor (2.5), aeration head (2.9) aerator be oxygenated, lead to It crosses drain valve (2.8) water outlet and enters intermediate water tank (3), be discharged to excess sludge by mud valve I (2.10), sludge pump (2.11) Treatment of Sludge reactor (5);Intermediate water tank (3) is anti-by nitrification liquid intake pump (3.1) and nitrification liquid inlet valve (3.2) and UASB Device (4) is answered to be connected;UASB reactors (4) are provided with gas collecting apparatus (4.1), outlet pipe (4.2), three phase separator (4.3), add Tropical device (4.4), water-distributing device (4.5), internal circulation pump (4.6), interior circulating valve (4.7);Treatment of Sludge reactor (5) is set There are chemical feed pipe (5.1), the second agitating device (5.2), pass through mud valve II (5.3) and mud valve III (5.4) and sludge fermentation tank (6) it is connected, by returned sludge valve (5.5) and return sludge pump (5.6) by processed sludge reflux to sbr reactor device (2);Sludge fermentation tank (6) is provided with the second temperature control device (6.1), third agitating device (6.2), the 2nd pH analyzers (6.3), By the way that fermented sludge is pumped into UASB reactors (4) into dredge pump (6.4) and Mud-intake valve (6.5).
Present invention simultaneously provides a kind of FNA reinforcement sludges fermentation and realize sewerage short-cut denitrification dephosphorization method, including with Lower step:
Device start-up operation is as follows:
The startup of sbr reactor device:It is anti-that SBR is injected using the complete nitrification sludge of actual cities sewage treatment plant as seed sludge Device (2) is answered, control sludge concentration is 2500-4000mg/L, and hydraulic detention time 6-8h, draining ratio is 40%~60%, control Dissolved oxygen processed is 0.8~1.5mg/L, is 15~20d by discharging excess sludge to control sludge age, excess sludge enters at sludge Manage reactor (5), the inhibition of nitrite oxidizing bacteria is much larger than using free nitrous acid (FNA) to the inhibition of ammonia oxidation bacteria come Realize short distance nitration, when being discharged nitrite accumulation rate more than 95% and persistently maintaining 15 days or more, SBR short distance nitrations are able to It realizes.According to pH change curves, stop aeration before ammonia nitrogen has reacted completely, realize part short distance nitration, make water outlet nitrous/ Between 1.3~1.5, part short distance nitration is stablized to be realized ammonia nitrogen concentration ratio.
The startup of sludge fermentation tank:Sludge fermentation tank (6) is semi batch reacor, and seed sludge is municipal sewage plant Sludge from final clarifier, for sludge retention time SRT at 10~20 days, control pH was pre- through FNA in 9~10, Treatment of Sludge reactor (5) The excess sludge of processing is discharged into sludge fermentation tank (6), according to SRT by fermented sludge by into dredge pump (6.4) and Mud-intake valve (6.5) It is pumped into UASB reactors (4).
The startup of UASB reactors:Seed sludge is mixed for municipal sewage anaerobic ammonia oxidation reactor sludge with sludge from final clarifier Close object, volume ratio 5:1~10:1, to ensure the superiority of anaerobic ammonia oxidizing bacteria.Hydraulic detention time 3-5h, sludge stop Time 10-20d is stayed, water inlet is using NH4 +-N/NO2 -- N concentration ratios are 1:1.3 artificial distribution, a concentration of 20mg/L of starting TN are simultaneously Nitrogen load is incrementally increased until 60mg/L with the gradient of 20mg/L, the time point for increasing nitrogen load every time is that autotrophic denitrification rate is more than 95% and persistently maintain 15 days or more, finally complete to Anammox acclimation;Water inlet is using NH4 +-N/NO2 -- N concentration Than being 1:1.3 and TN is the artificial distribution of 60mg/L, while adds sodium acetate and make a concentration of 100- of SCOD as denitrifying carbon source 150mg/L, when TN removal rates higher than 90% and persistently maintain 15 days or more when, Anammox and it is denitrifying couple successfully reality It is existing;SCOD concentration is made to be continuously maintained at 100-150mg/L using sludge fermentation mixture substituted acetic acid sodium as denitrifying carbon source, When TN removal rates are higher than 90% and persistently maintain 15 days or more, realize that Anammox is coupled with denitrifying.
Operation is as follows during runing adjustment:
Sanitary sewage enters sbr reactor device (2) together with the excess sludge handled through FNA, and sbr reactor device (2) first carries out 1~1.5h of anoxia stirring restarts air compressor (2.10), adjusts air valve (2.9) and gas flow meter (2.8) and is exposed Gas, control dissolved oxygen are 0.8~1.5mg/L, and sbr reactor device (2) carries out part short distance nitration reaction, and part mineralized nitrogen is Asia Nitrate nitrogen determines aeration time according to real-time control pH change curves, makes water outlet ammonia nitrogen in 8~12mg/L, nitrous 10~ 15mg/L.The water outlet of sbr reactor device enters intermediate water tank (3), arranges excess sludge to Treatment of Sludge reactor (5), by dirt Mud treatment reactor (5) adds sodium nitrite, makes its interior nitrite concentration for 300~1000mg/L, and by add acid or Alkali controls pH as 5.5~6.0, the Treatment of Sludge time for 12~for 24 hours.The sludge 30~40% handled flows back into sbr reactor Device (2), 60~70% enter sludge fermentation tank (6).Sludge fermentation mixture is together with nitrified effluent from UASB reactors (4) bottom Portion is pumped into, and UASB temperature of reactor is controlled at 28~32 DEG C, 3~5h of hydraulic detention time, is discharged after processing and is passed through outlet pipe row Go out.
The technical principle of the present invention is as follows:
Free nitrous acid (FNA) is inhibited nitrite oxidizing bacteria to realize short distance nitration and as dirt by novelty of the invention Mud fermentation pre-treatment step promotes both hydrolysis acidifications to be combined, and strengthens while short distance nitration biological carbon and phosphorous removal is realized dirty Mud internal carbon source is developed.Short distance nitration reactor spoil disposal is returned through FNA processing rear portions, and another part enters sludge fermentation tank. Sbr reactor device elder generation anoxic denitrification removal extra nitrous of upper period, then anaerobic phosphorus release, the concurrent first portion short distance nitre of aerobic phosphorus absorption Change, be discharged same sludge fermentation liquid and enter UASB reactors together, part ammonia nitrogen and nitrous by anaerobic ammonia oxidizing bacteria autotrophic denitrification, Organic matter denitrification removes in remaining nitrous and the Nitrate-N Use sludge fermentation liquid generated, so as to fulfill the depth of sanitary sewage Denitrogenation dephosphorizing.
Compared with prior art, the present invention has the following advantages:
Excess sludge is subjected to free nitrous acid (FNA) processing, not only realizes short distance nitration, but also as sludge fermentation Pre-treatment step promotes sludge cracking to strengthen internal carbon source exploitation.
The present invention can realize the advanced nitrogen dephosphorization of sanitary sewage, Anammox on the basis of outer carbon source is not added Product nitrate nitrogen can be removed by denitrification, and the two cooperates, and device Bacterial community is complicated, and impact resistance ability is strong.
Excess sludge is carried out fermentation process as denitrifying carbon source by the present invention, is reduced sludge yield, is reduced sewage Treatment plant's sludge treatment expense saves operating cost.
Description of the drawings
Fig. 1 is the structure chart of apparatus of the present invention
Primary symbols are described as follows:1- raw water boxs;2-SBR reactors;3- intermediate water tanks;4-UASB reactors;5- sludge Treatment reactor;6- sludge fermentation tanks;1.1- raw water intake pumps;The first temperature control devices of 2.1-;The first agitating devices of 2.2-;2.3- Gas flowmeter;2.4- air valve;2.5- air compressor;The first pH analyzers of 2.6-;2.7-DO analyzer;2.8- draining Valve;2.9- aeration head;2.10- mud valve I;2.11- sludge pump;3.1- nitrification liquid intake pumps;3.2- nitrification liquid inlet valves;4.1- Gas collecting apparatus;4.2- outlet pipe;4.3- three phase separator;4.4- heating tapes device;4.5- water-distributing device;4.6- internal circulation pump; Circulating valve in 4.7-;5.1- chemical feed pipe;The second agitating devices of 5.2-;5.3- mud valves II;5.4- mud valves III;5.5- reflux is dirty Slurry valve;5.6- return sludge pump;The second temperature control devices of 6.1-;6.2- third agitating devices;The 2nd pH analyzers of 6.3-;6.4- into Dredge pump;6.5- Mud-intake valve.
Specific embodiment
The present invention is described in further detail in conjunction with the accompanying drawings and embodiments.
As shown in Figure 1, the device of the fermentation of FNA reinforcement sludges and realization sewerage short-cut denitrification dephosphorization, including:Raw water box (1), Sbr reactor device (2), intermediate water tank (3), UASB reactors (4), Treatment of Sludge reactor (5), sludge fermentation tank (6);Raw water box (1) it is supplied water by raw water intake pump (1.1) to sbr reactor device (2), sbr reactor device (2) is equipped with the first temperature control device (2.1), the One agitating device (2.2), the first pH analyzers (2.6), DO analyzers (2.7), by being equipped with gas flowmeter (2.3), air Valve (2.4), air compressor (2.5), aeration head (2.9) aerator be oxygenated, pass through drain valve (2.8) water outlet enter Excess sludge is discharged to Treatment of Sludge reactor (5) by intermediate water tank (3) by mud valve I (2.10), sludge pump (2.11);In Between water tank (3) be connected by nitrification liquid intake pump (3.1) and nitrification liquid inlet valve (3.2) with UASB reactors (4);UASB is anti- Device (4) is answered to be provided with gas collecting apparatus (4.1), outlet pipe (4.2), three phase separator (4.3), heating tape device (4.4), water distribution dress Put (4.5), internal circulation pump (4.6), interior circulating valve (4.7);Treatment of Sludge reactor (5) is provided with chemical feed pipe (5.1), second stirs Device (5.2) is mixed, is connected by mud valve II (5.3) with mud valve III (5.4) with sludge fermentation tank (6), it is dirty by flowing back Slurry valve (5.5) and return sludge pump (5.6) are by processed sludge reflux to sbr reactor device (2);Sludge fermentation tank (6) is set Have the second temperature control device (6.1), third agitating device (6.2), the 2nd pH analyzers (6.3), by into dredge pump (6.4) with into mud Fermented sludge is pumped into UASB reactors (4) by valve (6.5).
Test water of the present invention is using the sanitary sewage of Beijing University of Technology's dependents' district discharge, specific water quality:PH is 7.1- 7.9, COD a concentration of 130-180mg/L, NH4 +- N a concentration of 50-70mg/L, NO2 -- N and NO3 -- N detection limit hereinafter, COD/N ratios are 2~3.Seed sludge is tested respectively from the complete nitrification sludge of municipal sewage plant, city domestic sewage Try anaerobic ammonium oxidation apparatus.Sbr reactor device dischargeable capacity used be 10L, draining ratio be 0.5, sludge retention time 15d, daily 4 periods are run, each period includes water inlet (0.25h), stirs (0.5h), is aerated (3.5h), precipitates (1h), draining (0.25h) leaves unused (0.5h);UASB reactors dischargeable capacity be 5L, hydraulic detention time 4.5h, inner circulating reflux ratio 100%.Carrying out practically process is as follows:
Device start-up operation is as follows:
The startup of sbr reactor device:It is anti-that SBR is injected using the complete nitrification sludge of actual cities sewage treatment plant as seed sludge Device (2) is answered, control sludge concentration is 2500-4000mg/L, and hydraulic detention time 6-8h, draining ratio is 40%~60%, control Dissolved oxygen processed is 0.8~1.5mg/L, is 15~20d by discharging excess sludge to control sludge age, excess sludge enters at sludge Manage reactor (5), the inhibition of nitrite oxidizing bacteria is much larger than using free nitrous acid (FNA) to the inhibition of ammonia oxidation bacteria come Realize short distance nitration, when being discharged nitrite accumulation rate more than 95% and persistently maintaining 15 days or more, SBR short distance nitrations are able to It realizes.According to pH change curves, stop aeration before ammonia nitrogen has reacted completely, realize part short distance nitration, make water outlet nitrous/ Between 1.3~1.5, part short distance nitration is stablized to be realized ammonia nitrogen concentration ratio.
The startup of sludge fermentation tank:Sludge fermentation tank (6) is semi batch reacor, and seed sludge is municipal sewage plant Sludge from final clarifier, for sludge retention time SRT at 10~20 days, control pH was pre- through FNA in 9~10, Treatment of Sludge reactor (5) The excess sludge of processing is discharged into sludge fermentation tank (6), according to SRT by fermented sludge by into dredge pump (6.4) and Mud-intake valve (6.5) It is pumped into UASB reactors (4).
The startup of UASB reactors:Seed sludge is mixed for municipal sewage anaerobic ammonia oxidation reactor sludge with sludge from final clarifier Close object, volume ratio 5:1~10:1, to ensure the superiority of anaerobic ammonia oxidizing bacteria.Hydraulic detention time 3-5h, sludge retention Time 10-20d, water inlet is using NH4 +-N/NO2 -- N concentration ratios are 1:1.3 artificial distribution, a concentration of 20mg/L of starting TN and with The gradient of 20mg/L incrementally increases nitrogen load until 60mg/L, and the time point for increasing nitrogen load every time is that autotrophic denitrification rate is more than 95% and persistently maintain 15 days or more, finally complete to Anammox acclimation;Water inlet is using NH4 +-N/NO2 -- N concentration Than being 1:1.3 and TN is the artificial distribution of 60mg/L, while adds sodium acetate and make a concentration of 100- of SCOD as denitrifying carbon source 150mg/L, when TN removal rates higher than 90% and persistently maintain 15 days or more when, Anammox and it is denitrifying couple successfully reality It is existing;SCOD concentration is made to be continuously maintained at 100-150mg/L using sludge fermentation mixture substituted acetic acid sodium as denitrifying carbon source, When TN removal rates are higher than 90% and persistently maintain 15 days or more, realize that Anammox is coupled with denitrifying.
Operation is as follows during runing adjustment:
Sanitary sewage enters sbr reactor device (2) together with the excess sludge handled through FNA, and sbr reactor device (2) first carries out 1~1.5h of anoxia stirring restarts air compressor (2.10), adjusts air valve (2.9) and gas flow meter (2.8) and is exposed Gas, control dissolved oxygen are 0.8~1.5mg/L, and sbr reactor device (2) carries out part short distance nitration reaction, and part mineralized nitrogen is Asia Nitrate nitrogen determines aeration time according to real-time control pH change curves, makes water outlet ammonia nitrogen in 8~12mg/L, nitrous 10~ 15mg/L.The water outlet of sbr reactor device enters intermediate water tank (3), arranges excess sludge to Treatment of Sludge reactor (5), by dirt Mud treatment reactor (5) adds sodium nitrite, makes its interior nitrite concentration for 300~1000mg/L, and by add acid or Alkali controls pH as 5.5~6.0, the Treatment of Sludge time for 12~for 24 hours.The sludge 30~40% handled flows back into sbr reactor Device (2), 60~70% enter sludge fermentation tank (6).Sludge fermentation mixture is together with nitrified effluent from UASB reactors (4) bottom Portion is pumped into, and UASB temperature of reactor is controlled at 28~32 DEG C, 3~5h of hydraulic detention time, is discharged after processing and is passed through outlet pipe row Go out.
Result of the test shows:After stable, in the case where not adding outer carbon source, device effluent COD concentration is 40- 60mg/L, NH4 +- N is a concentration of<3mg/L, NO2 --N<1mg/L, NO3 --N<3mg/L, TN<10mg/L reaches《Urban wastewater treatment Factory's pollutant emission standard》(GB18918-2002) level-one A standards.

Claims (2)

1.FNA reinforcement sludges ferment and the device of realization sewerage short-cut denitrification dephosphorization, it is characterised in that:Equipped with raw water box (1), Sbr reactor device (2), intermediate water tank (3), UASB reactors (4), Treatment of Sludge reactor (5), sludge fermentation tank (6);Raw water box (1) it is supplied water by raw water intake pump (1.1) to sbr reactor device (2), sbr reactor device (2) is equipped with the first temperature control device (2.1), the One agitating device (2.2), the first pH analyzers (2.6), DO analyzers (2.7), by being equipped with gas flowmeter (2.3), air Valve (2.4), air compressor (2.5), aeration head (2.9) aerator be oxygenated, pass through drain valve (2.8) water outlet enter Excess sludge is discharged to Treatment of Sludge reactor (5) by intermediate water tank (3) by mud valve I (2.10), sludge pump (2.11);In Between water tank (3) be connected by nitrification liquid intake pump (3.1) and nitrification liquid inlet valve (3.2) with UASB reactors (4);UASB is anti- Device (4) is answered to be provided with gas collecting apparatus (4.1), outlet pipe (4.2), three phase separator (4.3), heating tape device (4.4), water distribution dress Put (4.5), internal circulation pump (4.6), interior circulating valve (4.7);Treatment of Sludge reactor (5) is provided with chemical feed pipe (5.1), second stirs Device (5.2) is mixed, is connected by mud valve II (5.3) with mud valve III (5.4) with sludge fermentation tank (6), it is dirty by flowing back Slurry valve (5.5) and return sludge pump (5.6) are by processed sludge reflux to sbr reactor device (2);Sludge fermentation tank (6) is set Have the second temperature control device (6.1), third agitating device (6.2), the 2nd pH analyzers (6.3), by into dredge pump (6.4) with into mud Fermented sludge is pumped into UASB reactors (4) by valve (6.5).
2. application claim 1 described device carries out the fermentation of FNA reinforcement sludges and the method for realizing sewerage short-cut denitrification dephosphorization, It is characterized in that, includes the following steps:
1) device start-up operation is as follows:
1.1) startup of sbr reactor device:It is anti-that SBR is injected using the complete nitrification sludge of actual cities sewage treatment plant as seed sludge Device (2) is answered, control sludge concentration is 2500-4000mg/L, and hydraulic detention time 6-8h, draining ratio is 40%~60%, control Dissolved oxygen processed is 0.8~1.5mg/L, is 15~20d by discharging excess sludge to control sludge age, excess sludge enters at sludge Manage reactor (5), the inhibition of nitrite oxidizing bacteria is much larger than using free nitrous acid (FNA) to the inhibition of ammonia oxidation bacteria come Realize short distance nitration, when being discharged nitrite accumulation rate more than 95% and persistently maintaining 15 days or more, SBR short distance nitrations are able to It realizes;According to pH change curves, stop aeration before ammonia nitrogen has reacted completely, realize part short distance nitration, make water outlet nitrous/ Between 1.3~1.5, part short distance nitration is stablized to be realized ammonia nitrogen;
1.2) startup of sludge fermentation tank:Sludge fermentation tank (6) is semi batch reacor, and seed sludge is municipal sewage plant Sludge from final clarifier, for sludge retention time SRT at 10~20 days, control pH was pre- through FNA in 9~10, Treatment of Sludge reactor (5) The excess sludge of processing is discharged into sludge fermentation tank (6), according to SRT by fermented sludge by into dredge pump (6.4) and Mud-intake valve (6.5) It is pumped into UASB reactors (4);
1.3) startup of UASB reactors:Seed sludge is mixed for municipal sewage anaerobic ammonia oxidation reactor sludge with sludge from final clarifier Close object, volume ratio 5:1~10:1, to ensure the superiority of anaerobic ammonia oxidizing bacteria;Hydraulic detention time 3-5h, sludge retention Time 10-20d, water inlet is using NH4 +-N/NO2 -- N concentration ratios are 1:1.3 artificial distribution, a concentration of 20mg/L of starting TN and with The gradient of 20mg/L incrementally increases nitrogen load until 60mg/L, and the time point for increasing nitrogen load every time is that autotrophic denitrification rate is more than 95% and persistently maintain 15 days or more, finally complete to Anammox acclimation;Water inlet is using NH4 +-N/NO2 -- N quality Concentration ratio is 1:1.3 and TN is the artificial distribution of 60mg/L, while add sodium acetate makes SCOD a concentration of as denitrifying carbon source 100-150mg/L when TN removal rates are higher than 90% and when persistently maintaining 15 days or more, Anammox and denitrifying is coupled into Work(is realized;SCOD concentration is made to be continuously maintained at 100- using sludge fermentation mixture substituted acetic acid sodium as denitrifying carbon source 150mg/L when TN removal rates are higher than 90% and persistently maintain 15 days or more, realizes that Anammox is coupled with denitrifying;
2) operation is as follows during runing adjustment:Sanitary sewage enters sbr reactor device (2) together with the excess sludge handled through FNA, Sbr reactor device (2) first carries out 1~1.5h of anoxia stirring, restarts air compressor (2.10), and it is gentle to adjust air valve (2.9) Flowmeter body (2.8) is aerated, and control dissolved oxygen is 0.8~1.5mg/L, and it is anti-that sbr reactor device (2) carries out part short distance nitration Should, part mineralized nitrogen is nitrite nitrogen, and aeration time is determined according to real-time control pH change curves, make water outlet ammonia nitrogen 8~ 12mg/L, nitrous is in 10~15mg/L;The water outlet of sbr reactor device enters intermediate water tank (3), and it is anti-to Treatment of Sludge to arrange excess sludge Device (5) is answered, by adding sodium nitrite to Treatment of Sludge reactor (5), it is 300~1000mg/ to make its interior nitrite concentration L, and pH is controlled as 5.5~6.0 by adding acid or alkali, the Treatment of Sludge time for 12~for 24 hours;The sludge 30 handled~ 40% flows back into sbr reactor device (2), and 60~70% enter sludge fermentation tank (6);Sludge fermentation mixture is together with nitrified effluent It is pumped into from UASB reactors (4) bottom, the control of UASB temperature of reactor is at 28~32 DEG C, 3~5h of hydraulic detention time, after processing Water outlet is discharged by outlet pipe.
CN201810203310.1A 2018-03-13 2018-03-13 Device and method for FNA (FNA) enhanced sludge fermentation and short-range nitrogen and phosphorus removal of sewage Active CN108217950B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810203310.1A CN108217950B (en) 2018-03-13 2018-03-13 Device and method for FNA (FNA) enhanced sludge fermentation and short-range nitrogen and phosphorus removal of sewage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810203310.1A CN108217950B (en) 2018-03-13 2018-03-13 Device and method for FNA (FNA) enhanced sludge fermentation and short-range nitrogen and phosphorus removal of sewage

Publications (2)

Publication Number Publication Date
CN108217950A true CN108217950A (en) 2018-06-29
CN108217950B CN108217950B (en) 2021-08-13

Family

ID=62659420

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810203310.1A Active CN108217950B (en) 2018-03-13 2018-03-13 Device and method for FNA (FNA) enhanced sludge fermentation and short-range nitrogen and phosphorus removal of sewage

Country Status (1)

Country Link
CN (1) CN108217950B (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109912027A (en) * 2019-02-02 2019-06-21 中国矿业大学 A kind of (A/O)2- SBR intensified denitrification and dephosphorization method
CN110002592A (en) * 2019-05-05 2019-07-12 北京工业大学 Short-cut denitrification-sludge fermentation coupling Anaerobic ammonium oxidation system processing sanitary sewage device and method
CN110818217A (en) * 2019-11-28 2020-02-21 湖南大学 Method for strengthening anaerobic digestion of excess sludge by combined pretreatment of freezing and free nitrous acid
CN111333178A (en) * 2020-02-29 2020-06-26 北京工业大学 Device and method for enhancing autotrophic nitrogen removal and synchronous phosphorus recovery of nitrate wastewater through alkaline sludge fermentation
CN111924962A (en) * 2020-08-24 2020-11-13 北京工业大学 Method for rapidly realizing short-cut nitrification treatment of urban sewage based on FNA pretreatment biomembrane
CN112250180A (en) * 2020-09-24 2021-01-22 北京工业大学 Device and method for realizing deep denitrification of domestic sewage by coupling half-shortcut nitrification-anaerobic ammonia oxidation with sulfur autotrophic denitrification
CN112607863A (en) * 2020-12-24 2021-04-06 北京工业大学 Device and method for realizing deep nitrogen and phosphorus removal of low C/N ratio municipal sewage combined sludge fermentation product by utilizing PN/A process
CN113003716A (en) * 2021-02-20 2021-06-22 北京工业大学 Device and method for synchronously treating nitrite nitrogen wastewater and excess sludge
CN113429071A (en) * 2021-07-01 2021-09-24 清华大学 Municipal sewage treatment system
CN113480004A (en) * 2021-07-15 2021-10-08 北京工业大学 Device and method for deeply denitrifying urban sewage after carbon and phosphorus capture and realizing phosphorus recovery through PDA (personal digital Assistant)
CN113620505A (en) * 2021-07-07 2021-11-09 北京工业大学 Device and method for realizing starting and maintaining of short-cut nitrification by alternately and laterally treating hydroxylamine and free nitrite
CN113767073A (en) * 2019-05-24 2021-12-07 昆士兰大学 Method for treating waste water or sludge
CN114671522A (en) * 2022-04-24 2022-06-28 广州一博环保科技有限公司 High-efficient low energy consumption sewage treatment system
CN115403234A (en) * 2022-08-29 2022-11-29 广州市香港科大***研究院 Method for realizing carbon source supplement and sludge reduction based on free nitrite and sulfate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103663879A (en) * 2013-12-24 2014-03-26 北京工业大学 Device and method for synchronously treating high-ammonia-nitrogen wastewater through sludge fermentation
CN104528933A (en) * 2014-11-29 2015-04-22 北京工业大学 Method for realizing continuous-flow city sewage autotrophic nitrogen removal based on FNA treatment of sludge
CN105923770A (en) * 2016-06-15 2016-09-07 北京工业大学 Method and device for sewage denitrification by coupling of shortcut nitrification, anaerobic ammonia oxidation and shortcut denitrification
EP3255016A1 (en) * 2016-06-10 2017-12-13 FCC Aqualia, S.A. Method for starting up and controlling a biological process for ammonium removal at low ammonium concentrations and low temperature through the use of a two stage autotrophic nitrogen removal process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103663879A (en) * 2013-12-24 2014-03-26 北京工业大学 Device and method for synchronously treating high-ammonia-nitrogen wastewater through sludge fermentation
CN104528933A (en) * 2014-11-29 2015-04-22 北京工业大学 Method for realizing continuous-flow city sewage autotrophic nitrogen removal based on FNA treatment of sludge
EP3255016A1 (en) * 2016-06-10 2017-12-13 FCC Aqualia, S.A. Method for starting up and controlling a biological process for ammonium removal at low ammonium concentrations and low temperature through the use of a two stage autotrophic nitrogen removal process
CN105923770A (en) * 2016-06-15 2016-09-07 北京工业大学 Method and device for sewage denitrification by coupling of shortcut nitrification, anaerobic ammonia oxidation and shortcut denitrification

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
委燕等: "游离亚硝酸预处理强化剩余污泥发酵同步反硝化性能", 《中国环境科学》 *
马放等: "《环境生物技术》", 31 May 2003 *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109912027A (en) * 2019-02-02 2019-06-21 中国矿业大学 A kind of (A/O)2- SBR intensified denitrification and dephosphorization method
CN110002592B (en) * 2019-05-05 2021-09-14 北京工业大学 Device and method for treating domestic sewage by coupling short-cut denitrification-sludge fermentation with anaerobic ammonia oxidation system
CN110002592A (en) * 2019-05-05 2019-07-12 北京工业大学 Short-cut denitrification-sludge fermentation coupling Anaerobic ammonium oxidation system processing sanitary sewage device and method
CN113767073A (en) * 2019-05-24 2021-12-07 昆士兰大学 Method for treating waste water or sludge
CN110818217A (en) * 2019-11-28 2020-02-21 湖南大学 Method for strengthening anaerobic digestion of excess sludge by combined pretreatment of freezing and free nitrous acid
CN111333178A (en) * 2020-02-29 2020-06-26 北京工业大学 Device and method for enhancing autotrophic nitrogen removal and synchronous phosphorus recovery of nitrate wastewater through alkaline sludge fermentation
CN111333178B (en) * 2020-02-29 2021-09-24 北京工业大学 Device and method for enhancing autotrophic nitrogen removal and synchronous phosphorus recovery of nitrate wastewater through alkaline sludge fermentation
CN111924962A (en) * 2020-08-24 2020-11-13 北京工业大学 Method for rapidly realizing short-cut nitrification treatment of urban sewage based on FNA pretreatment biomembrane
CN112250180A (en) * 2020-09-24 2021-01-22 北京工业大学 Device and method for realizing deep denitrification of domestic sewage by coupling half-shortcut nitrification-anaerobic ammonia oxidation with sulfur autotrophic denitrification
CN112250180B (en) * 2020-09-24 2022-03-15 北京工业大学 Device and method for realizing deep denitrification of domestic sewage by coupling half-shortcut nitrification-anaerobic ammonia oxidation with sulfur autotrophic denitrification
CN112607863A (en) * 2020-12-24 2021-04-06 北京工业大学 Device and method for realizing deep nitrogen and phosphorus removal of low C/N ratio municipal sewage combined sludge fermentation product by utilizing PN/A process
CN113003716A (en) * 2021-02-20 2021-06-22 北京工业大学 Device and method for synchronously treating nitrite nitrogen wastewater and excess sludge
CN113429071A (en) * 2021-07-01 2021-09-24 清华大学 Municipal sewage treatment system
CN113620505A (en) * 2021-07-07 2021-11-09 北京工业大学 Device and method for realizing starting and maintaining of short-cut nitrification by alternately and laterally treating hydroxylamine and free nitrite
CN113480004A (en) * 2021-07-15 2021-10-08 北京工业大学 Device and method for deeply denitrifying urban sewage after carbon and phosphorus capture and realizing phosphorus recovery through PDA (personal digital Assistant)
CN114671522A (en) * 2022-04-24 2022-06-28 广州一博环保科技有限公司 High-efficient low energy consumption sewage treatment system
CN115403234A (en) * 2022-08-29 2022-11-29 广州市香港科大***研究院 Method for realizing carbon source supplement and sludge reduction based on free nitrite and sulfate

Also Published As

Publication number Publication date
CN108217950B (en) 2021-08-13

Similar Documents

Publication Publication Date Title
CN108217950A (en) The device and method that FNA reinforcement sludges ferment and realize sewerage short-cut denitrification dephosphorization
CN108439595A (en) The denitrifying methods of foul water fraction short distance nitration-Anammox/ are realized using sludge fermentation object
CN108439599B (en) Device and method for deep nitrogen and phosphorus removal by coupling endogenous short-cut denitrification with ANAMMOX of municipal domestic sewage
CN107032506A (en) It is segmented the apparatus and method that water outlet short distance nitration Anammox/ denitrifications handle sanitary sewage
CN108545830A (en) A kind of technique for strengthening continuous flow municipal sewage part short distance nitration Anammox using sludge fermentation
CN108439593B (en) Device and method for treating urban domestic sewage by continuous flow segmented water inlet DEAMOX combined sludge fermentation
CN110002697B (en) Device and method for generating methane and performing IFAS A/O SPNAPD denitrification by UASB (upflow anaerobic sludge blanket) of landfill leachate
CN105540841B (en) A kind of aerobic/anaerobic biofilter biological denitrification method and device
CN105923770A (en) Method and device for sewage denitrification by coupling of shortcut nitrification, anaerobic ammonia oxidation and shortcut denitrification
CN113800636B (en) Method and device for treating sludge digestive juice by coupling short-cut nitrification/anaerobic ammonia oxidation-fermentation and short-cut denitrification/anaerobic ammonia oxidation
CN110028158B (en) Method and device for endogenous short-cut denitrification coupling anaerobic ammonia oxidation nitrogen and phosphorus removal of municipal domestic sewage
CN105198084B (en) A kind of apparatus and method that advanced nitrogen is realized by preamble part denitrification coupling ammoxidation DEAMOX techniques
CN102101746A (en) Low-carbon urban sewage biological phosphorus removal and autotrophic biological nitrogen removal device and method
CN108409033A (en) FNA strengthens the apparatus and method of the segmental influent UCT advanced nitrogen dephosphorization of short distance nitration
CN101264978B (en) Method for fast realizing short distance deep denitrogenation by SBR process
CN107381815A (en) The apparatus and method that a kind of endogenous short-cut denitrification/anaerobic ammonia oxidation process of main flow realizes domestic sewage advanced denitrogenation
CN113233592B (en) Treatment device and method for realizing synchronous deep denitrification and decarbonization of advanced landfill leachate and domestic sewage
CN113402021A (en) Device and method for realizing sewage denitrification and sludge reduction by integrating in-situ sludge hydrolysis acidification and short-cut denitrification anaerobic ammonia oxidation
CN110054291A (en) Low C/N is followed by short-cut denitrification/anaerobic ammonia oxidation process device and method than sanitary sewage short distance nitration/Anammox
CN110002587A (en) A kind of device and method of district drainage formula short distance nitration parallel connection Anammox denitrification dephosphorization coupling endogenous denitrification
CN109368791A (en) The method for realizing short-cut denitrification Anammox by adding sludge fermentation object
CN110002595A (en) Two sections of sequencing batch reactors realize the treatment process of municipal sewage denitrogenation dephosphorizing coupling sludge fermentation
CN108128897A (en) The apparatus and method of synchronous short-cut nitrification and denitrification dephosphorization Treating Municipal Sewage are realized based on azanol
CN108862581A (en) A kind of device and method that AO biomembrane+sludge fermentation coupling denitrification realizes sewage deep denitrogenation synchronous sludge decrement
CN113716693A (en) Device and method for deep denitrification of landfill leachate based on anaerobic-aerobic-anoxic operation

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant