CN108197785A - A kind of harmful element is on method for building up of the blast furnace fuel than the computational methods of influence - Google Patents

A kind of harmful element is on method for building up of the blast furnace fuel than the computational methods of influence Download PDF

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CN108197785A
CN108197785A CN201711387952.3A CN201711387952A CN108197785A CN 108197785 A CN108197785 A CN 108197785A CN 201711387952 A CN201711387952 A CN 201711387952A CN 108197785 A CN108197785 A CN 108197785A
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blast furnace
harmful element
iron
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CN108197785B (en
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张建良
焦克新
王杰
王一杰
刘征建
王广伟
邓勇
王翠
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University of Science and Technology Beijing USTB
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    • G06COMPUTING; CALCULATING OR COUNTING
    • G06QINFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • GPHYSICS
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    • G06QINFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
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Abstract

The invention discloses a kind of harmful element on method for building up of the blast furnace fuel than the computational methods of influence, belong to ironmaking new technical field, the economic utilization for solving the problems, such as high harmful element content iron ore.Circulation collection behavior of this method based on harmful element alkali metal, zinc, lead etc. in blast furnace, it is proposed that harmful element is on concept of the blast furnace fuel than influence.Determine blast furnace process common 4 kinds of harmful elements Na, K, Zn, Pb to blast furnace fuel than affecting laws, establish harmful element on blast furnace fuel than influence computational methods.Due to the adoption of the above technical scheme, this method can accurately calculate harmful element to blast furnace fuel than influence degree, to iron and steel enterprise assessment " economic furnace charge " value have important directive significance.Simultaneously for the modification of corresponding index, also available for other harmful elements on calculating of the blast furnace fuel than influence.

Description

A kind of harmful element is on method for building up of the blast furnace fuel than the computational methods of influence
Technical field
The invention belongs to smelt iron new technical field, it is related to harmful element to computational methods of the blast furnace fuel than influence, especially It is a kind of harmful element on method for building up of the blast furnace fuel than the computational methods of influence.
Background of invention
Since production capacity is excessive, entire steel industry, which faces production capacity, to be protected in the environment of existence for China in Recent Years iron and steel enterprise, Each iron and steel enterprise is reduces production cost one after another using " economic furnace charge ", a large amount of poor qualities higher using harmful element content Ore deposit causes blast furnace feeding harmful element load constantly to increase.
Forefathers have done a large amount of and have studied about influence of the harmful element to blast fumance, and work is concentrated mainly on to harmful The cycle behavior of element furnace entering volume and discharge rate apparent harmful element for statistical analysis in blast furnace, alkali metal, zinc etc. are harmful Element is to the affecting laws and mechanism study of the crude fuels metallurgical performance such as sinter, pellet and coke, and harmful element is to blast furnace The work of the research of erosion mechanism and furnace nodulation reason with refractory material etc., these work are to preventing harmful element from endangering Evil, instruct blast furnace normally produce play the role of it is very important.But in relation to harmful element to blast furnace fuel than influence, energy profit Influence research is less, in order to show harmful element to blast furnace fuel than affecting laws, which proposes one kind and is based on The computational methods of actual environment in harmful element physicochemical properties and blast furnace.This method can accurately calculate harmful element To blast furnace fuel than influence degree, to iron and steel enterprise assessment " economic furnace charge " value have important directive significance.
Invention content
To solve the above-mentioned problems, it is an object of the invention to establish a kind of evaluation harmful element of science to blast furnace fuel Than the method for influence, the application for blast furnace " economic furnace charge " provides the harmful element of guidance to calculating side of the blast furnace fuel than influence The method for building up of method.
The technical scheme is that:A kind of harmful element on method for building up of the blast furnace fuel than the computational methods of influence, Circulation collection behavior of this method based on harmful element alkali metal, zinc, lead in blast furnace, it is proposed that harmful element is to blast furnace fuel Than the concept of influence, by determine blast furnace process common 4 kinds of harmful elements Na, K, Zn, Pb to blast furnace fuel than influence advise Rule establishes harmful element to blast furnace fuel than influencing computational methods.
Further, this method specifically includes following steps:
(1) the primary evaluation index of influence of the harmful element to blast furnace energy consumption is blast fumance coke ratio K values, and wherein coke ratio is managed It needs that parameter is calculated as below by calculating:Enter Fe in stove iron-bearing material2O3Content w (Fe2O3), FeO contents w (FeO), iron ore Grade w (TFe);Produce the hot metal composition w of steel enterprise[Si]、w[Mn]、w[P]、w(S);Air blast parameter in blast furnace normal productive process Air quantity V, oxygen enrichment percentageTop gas ingredient
(2) coke for entering stove in blast furnace is oxidized to CO, CO2When capture there are three types of the sources of oxygen, be respectively in furnace charge with It is that iron combines, in furnace charge with the combinations such as oligo-element Si, Mn, P, S and in air blast, accounting equation difference is as follows:
Wherein, yARepresent that production 1mol iron captures the molal quantity of oxygen, y from ferriferous oxidefRepresent production 1mol iron from SiO2、MnO、P2O5And the molal quantity of oxygen, y are captured in desulfurizationbC aoxidizes the molal quantity for capturing oxygen before representing production 1mol iron winds mouths, W [Fe] represents the content of iron in the pig iron, and V is the air blast parameter air quantity in blast furnace normal productive process.
Oxygen to carbon atom ratio can be calculated directly according to gas composition in coal gas:
(3) rectangular coordinate system is taken, ordinate isAbscissa isLi Site operation lines can be drawn, according to inner This special operation lines, can calculate carbon iron atom ratio:
(4) tan α are that the slope of operation lines is convertible into the amount of coke that the smelting pig iron per ton is consumed, should when calculating coke ratio The carbon amounts of molten iron carburizing consumption is added in, deducts the carbon amounts that coal powder injection is brought into, the two conversion formula is as follows.
Wherein, K represents coke ratio, and M represents coal ratio, w (C)KRepresent coke phosphorus content, w (C)MRepresent coal dust phosphorus content, w [C] Represent the content of pig iron kind carbon.
(5) harmful element can reduce gas utilization rate, change oxygen to carbon atom ratio, and calculation formula is as follows.
Wherein, XiRepresent that harmful element enters stove load, YiRepresent harmful element circulation collection multiple, MiRepresent average molecular Quality, V (CO2) it is CO in stock gas2Volume, V (CO) be stock gas in CO volume.
(6) oxygen to carbon atom ratio change makes operation line slope change, coke ratio raising, and coke ratio incremental computations formula is as follows.
Wherein, niRepresent constant, it is related with blast furnace crude fuel condition and operation.
The beneficial effects of the invention are as follows:The present invention can be used for the ferrous material economy that harmful element content is higher in blast furnace Evaluation utilizes the reference frame for providing quantization for blast furnace " economic furnace charge ".This method is using practical blast fumance data and is harmful to Reaction theory of the element in blast furnace on the basis of other parameter and assay means is not introduced to harmful element furnace charge into Row Economic Evaluation and method evaluation is accurate, it may be verified that property is good, has to blast furnace crude fuel procurement staff buying important Directive significance is laid a good foundation to reduce ironmaking cost.
Description of the drawings
Fig. 1 is Li Site operating curve schematic diagrames.
Fig. 2 is the Li Site operating curve schematic diagrames by harmful element influences.
Specific embodiment
Below in conjunction with specific implementation example specific embodiment again to the above of the present invention further specifically It is bright:
For a kind of harmful element of the present invention on computational methods of the blast furnace fuel than influence, this method specifically includes following steps:
Assay is carried out to the ferrous material of blast furnace feeding first, determines the chemical composition of ferrous material:Enter stove iron content Fe in raw material2O3Content w (Fe2O3), FeO contents w (FeO), the grade w (TFe) of iron ore;Produce the hot metal composition of steel enterprise w[Si]、w[Mn]、w[P]、w(S);Air blast parameter air quantity V, oxygen enrichment percentage in blast furnace normal productive processTop gas into Point
Secondly, it is calculated under the conditions of current blast fumance using using equation below, in blast furnaceAtomic ratio:
In formula, yACapture the molal quantity of oxygen, y from ferriferous oxide for production 1mol ironfTo produce 1mol iron from SiO2、 MnO、P2O5And the molal quantity of oxygen, y are captured in desulfurizationbCapture the molal quantity of oxygen for C oxidations before production 1mol iron winds mouths, w [Fe] is The content of iron in the pig iron, V be blast furnace normal productive process in air blast parameter air quantity, y[Si]For the molal quantity of elements Si, y[Mn]For The molal quantity of element M n, Sy[P]For the molal quantity of element P, y[S]Molal quantity for element S.
Further, assay is carried out to top gas, determines top gas ingredient (the assay stage Preferably using the method averaged repeatedly is chemically examined, ensure the accuracy of assay result), and calculate blast furnace using equation below It is interiorAtomic ratio.
According to blast furnace Li Site operation lines calculating principles, Li Site operation lines are drawn, are illustrated in fig. 1 shown below;
According to Li Site operating curves, Li Site operation line slope tan α are calculated:
According to the relationship of Li Site slopes and blast furnace coke ratio, blast furnace coke ratio K values are converted by equation below:Wherein coke Carbon content is 85.63%, and coal dust carbon content is 77.48%.
Further, influence of the harmful element to oxygen to carbon atom ratio, is calculated by following formula.
Li Site operating curves by harmful element influences are as shown in Figure 2.
Further, coke ratio increment is calculated by equation below.
Table 1 is the content of iron in iron ore:
1 components of iron ore of table
Table 2 is blast furnace operating parameter:
2 blast furnace operating parameter of table
Table 3 is hot metal composition (1505 DEG C):
3 hot metal composition of table
Table 4 is slag composition:
4 slag composition of table
Table 5 is gas composition:
5 gas composition of table
Table 6 enters stove load and circulation collection multiple for harmful element:
6 harmful element of table enters stove load and circulation collection multiple
Table 7 is the result of calculation according to the above method:
7 result of calculation of table
The foregoing is merely the preferred embodiments of the present invention, are not intended to limit the invention, all theories and original in the present invention Within then, any modification, equivalent substitution and improvements done should be included within the scope of the present invention.

Claims (2)

1. a kind of harmful element is on method for building up of the blast furnace fuel than the computational methods of influence, it is characterised in that:
Circulation collection behavior of this method based on harmful element alkali metal, zinc, lead in blast furnace, it is proposed that harmful element is to blast furnace The concept that fuel ratio influences, by determine common 4 kinds of harmful elements Na, K, Zn, the Pb of blast furnace process to blast furnace fuel than shadow Rule is rung, establishes harmful element to blast furnace fuel than influencing computational methods.
2. method for building up according to claim 1, which is characterized in that this method specifically includes following steps:
(1) assay is carried out to the ferrous material of blast furnace feeding, determines the chemical composition of ferrous material:Enter in stove iron-bearing material Fe2O3Content w (Fe2O3), FeO contents w (FeO), the grade w (TFe) of iron ore;Produce the hot metal composition w of steel enterprise[Si]、 w[Mn]、w[P]、w(S);Air blast parameter air quantity V, oxygen enrichment percentage in blast furnace normal productive processTop gas ingredient
It is calculated under the conditions of current blast fumance using equation below, in blast furnaceAtomic ratio:
In formula, yACapture the molal quantity of oxygen, y from ferriferous oxide for production 1mol ironfTo produce 1mol iron from SiO2、MnO、P2O5 And the molal quantity of oxygen, y are captured in desulfurizationbCapture the molal quantity of oxygen for C oxidations before production 1mol iron winds mouths, w [Fe] is in the pig iron The content of iron, V be blast furnace normal productive process in air blast parameter air quantity, y[Si]For the molal quantity of elements Si, y[Mn]For element M n Molal quantity, Sy[P]For the molal quantity of element P, y[S]For the molal quantity of element S, m (O) is the content of oxygen, and m (Fe) is containing for iron Amount;
(2) assay is carried out to top gas, determines top gas ingredient, and blast furnace is calculated using equation below It is interiorAtomic ratio:
In formula:For CO in top gas ingredient2Content,Contain for CO in top gas ingredient Amount, the content that m (C) is iron;
(3) rectangular coordinate system is taken, ordinate isAbscissa isLi Site operation lines can be drawn, according to Li Site Operation lines can calculate carbon iron atom and compare K:
In formula, tan α are that the slope of operation lines is convertible into the amount of coke that the smelting pig iron per ton is consumed,
K represents coke ratio, and M represents coal ratio, w (C)KRepresent coke phosphorus content, w (C)MIt represents in coal formula,
Powder phosphorus content, w [C] represent the content of pig iron kind carbon;
(4) harmful element can reduce gas utilization rate XB, change oxygen to carbon atom ratio, calculation formula is as follows:
In formula:XiRepresent that harmful element enters stove load, YiRepresent harmful element circulation collection multiple, MiRepresent relative molecular mass, V(CO2) it is CO in stock gas2Volume, V (CO) be stock gas in CO volume;
(5) oxygen to carbon atom ratio change makes operation line slope change, coke ratio raising, and coke ratio increasing is obtained according to formula is calculated as below Measure C:
In formula:K2For the coke ratio influenced by harmful element, K1It is not affected by the coke ratio of harmful element influence, XiRepresent harmful element Enter stove load, YiRepresent harmful element circulation collection multiple, MiRepresent relative molecular mass, niConstant is represented, with blast furnace crude fuel Condition is related with operation.
CN201711387952.3A 2017-12-20 2017-12-20 Method for establishing method for calculating influence of harmful elements on fuel ratio of blast furnace Active CN108197785B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110136781A (en) * 2019-04-23 2019-08-16 武汉科技大学 The calculation method of alkali metal element enriching quantity in a kind of blast furnace
CN113343416A (en) * 2021-04-27 2021-09-03 武汉科技大学 Method for establishing influence and regulation and control standard of harmful elements on blast furnace smelting
CN113667781A (en) * 2021-07-29 2021-11-19 北京首钢股份有限公司 Method for reducing fuel ratio of blast furnace

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CN101709341A (en) * 2009-11-27 2010-05-19 北京科技大学 Method for treating iron-containing waste materials in iron and steel plant
CN103468843A (en) * 2013-09-19 2013-12-25 武钢集团昆明钢铁股份有限公司 Method for producing qualified pig iron from low-grade high-harmful-element lean ores
CN106435072A (en) * 2016-11-04 2017-02-22 山西太钢不锈钢股份有限公司 Method for adjusting fuel rate during furnace condition resumption process according to gas utilization rate

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JPS5483604A (en) * 1977-12-16 1979-07-03 Nippon Steel Corp Manganese-containing flux used in manufacture of sintered ore
CN101709341A (en) * 2009-11-27 2010-05-19 北京科技大学 Method for treating iron-containing waste materials in iron and steel plant
CN103468843A (en) * 2013-09-19 2013-12-25 武钢集团昆明钢铁股份有限公司 Method for producing qualified pig iron from low-grade high-harmful-element lean ores
CN106435072A (en) * 2016-11-04 2017-02-22 山西太钢不锈钢股份有限公司 Method for adjusting fuel rate during furnace condition resumption process according to gas utilization rate

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110136781A (en) * 2019-04-23 2019-08-16 武汉科技大学 The calculation method of alkali metal element enriching quantity in a kind of blast furnace
CN110136781B (en) * 2019-04-23 2020-12-18 武汉科技大学 Method for calculating enrichment amount of alkali metal elements in blast furnace
CN113343416A (en) * 2021-04-27 2021-09-03 武汉科技大学 Method for establishing influence and regulation and control standard of harmful elements on blast furnace smelting
CN113343416B (en) * 2021-04-27 2022-06-03 武汉科技大学 Method for establishing influence and regulation and control standard of harmful elements on blast furnace smelting
CN113667781A (en) * 2021-07-29 2021-11-19 北京首钢股份有限公司 Method for reducing fuel ratio of blast furnace

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