CN108192371A - A kind of corrosion-resistant cold-resistant cable material and preparation method thereof - Google Patents
A kind of corrosion-resistant cold-resistant cable material and preparation method thereof Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/46—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes silicones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Abstract
The invention discloses a kind of corrosion-resistant cold-resistant cable material and preparation method thereof, including being composed of the following raw materials by weight：20 35 parts of thermoplastic elastomer (TPE), 11 15 parts of nitrile rubber, 15 35 parts of graphene oxide, 20 25 parts of vinylsiloxane rubber, 20 30 parts of rose crystal type nano calcium carbonate, 13 22 parts of nano phase ag_2 o, 14 19 parts of low density polyethylene (LDPE), 26 parts of calcinated argil, 28 parts of polybutylene terephthalate (PBT), 26 parts of ceramic fibre, 48 parts of nano aluminium oxide, 28 parts of cumyl peroxide.The present invention is added in combination compounded mix, lead salt compound stabilizer, dicyclopentadiene, iso-cyanuric acid triallyl ester and silane coupling agent using the proportioning of the above-mentioned raw materials such as thermoplastic elastomer (TPE), nitrile rubber, graphene oxide, vinylsiloxane rubber, rose crystal type nano calcium carbonate, nano phase ag_2 o progress science and carries out reaction fusion, process of preparing is simple, prepared product has preferable corrosion-resistant, fire protection flame retarding, insulation performance, is suitble to use in multiple fields.
Description
Technical field
The present invention relates to cable material manufacture technology fields, and in particular to a kind of corrosion-resistant cold-resistant cable material and its system
Preparation Method.
Background technology
With the rapid development of global economy and the continuous reinforcement of mankind's environmental consciousness, green, low-carbon environment-friendly building are
As the development trend of building trade.Superstructure the more is built the more high, and the scale of underground installation is increasing, and electric wire is increasingly
It is widely used, laying is also more and more intensive, and because of the damage or aging of cable jacket, and the fire caused is also increasingly
It is more.How to reduce the incidence of fire and the death rate of fire occurs, develop low cigarette, Halogen, fire-retardant, environmentally friendly cable material
One of direction of scientific rersearch of wires and cables industry is become.
As China's city intelligent, the high stratification of building, electric wire secretly the development of depositedization and become increasingly conspicuous, construction timber is with building
Building object projected life synchronizes oneself as engine request, building with wherein secretly deposited electric wire should the same service life, to prevent midway
Building life cycle is shortened the damage of building structure in thread-changing；Meanwhile with China《Green building assessment standard》And with body
The constantly improve of system, electric wire should also keep up with green paces.Research and develop good safety, the feature of environmental protection, energy saving low smoke and zero halogen building
Cable insulation material is the development for adapting to society.
China had for more than 30 years so far from reforming and opening up to the outside world, and the electric wire used in large amount of building has occurred insulating and sheath
Aging, electric wire " are died ".According to incompletely statistics, in the electrical fire that all building fields occur both at home and abroad, there is 85%
It is due to electric wire aging above, line short is caused to strike sparks and cause fire.Therefore, novel low-smoke zero-halogen building cable is exhausted
Edge material just becomes society and is badly in need of product.At present, domestic construction wiring is most of uses polyvinyl chloride (PVC) electric wire.
Invention content
To solve the above problems, the present invention provides a kind of corrosion-resistant cold-resistant cable materials and preparation method thereof.
To achieve the above object, the technical solution taken of the present invention is：
A kind of corrosion-resistant cold-resistant cable material and preparation method thereof, including being composed of the following raw materials by weight：Thermoplastic elastic
20-35 parts of body, 11-15 parts of nitrile rubber, 15-35 parts of graphene oxide, 20-25 parts of vinylsiloxane rubber, rose crystal type nano
20-30 parts of calcium carbonate, 13-22 parts of nano phase ag_2 o, 14-19 parts of low density polyethylene (LDPE), 2-6 parts of calcinated argil, poly- terephthaldehyde
Sour butanediol ester 2-8 parts, 2-6 parts of ceramic fibre, 4-8 parts of nano aluminium oxide, 2-8 parts of cumyl peroxide, modified zeolite powder
7-14 parts, 5-11 parts of compounded mix, 2-4 parts of lead salt compound stabilizer, 6-9 parts of dicyclopentadiene, triallyl fulminuric acid
3-7 parts of 2-6 parts of ester and silane coupling agent.
Further, a kind of corrosion-resistant cold-resistant cable material, including being composed of the following raw materials by weight：Thermoplastic elastic
22-30 parts of body, 12-14 parts of nitrile rubber, 16-34 parts of graphene oxide, 22-24 parts of vinylsiloxane rubber, rose crystal type nano
21-28 parts of calcium carbonate, 14-20 parts of nano phase ag_2 o, 15-18 parts of low density polyethylene (LDPE), 3-5 parts of calcinated argil, poly- terephthaldehyde
Sour butanediol ester 3-7 parts, 3-5 parts of ceramic fibre, 5-7 parts of nano aluminium oxide, 3-7 parts of cumyl peroxide, modified zeolite powder
8-13 parts, 6-10 parts of compounded mix, 3-4 parts of lead salt compound stabilizer, 7-9 parts of dicyclopentadiene, triallyl fulminuric acid
4-6 parts of 3-5 parts of ester and silane coupling agent.
Further, including being composed of the following raw materials by weight：25 parts of thermoplastic elastomer (TPE), 14 parts of nitrile rubber, oxidation
18 parts of graphene, 23 parts of vinylsiloxane rubber, 25 parts of rose crystal type nano calcium carbonate, 18 parts of nano phase ag_2 o, low density polyethylene
16 parts of alkene, 4 parts of calcinated argil, 4 parts of polybutylene terephthalate (PBT), 4 parts of ceramic fibre, 6 parts of nano aluminium oxide, peroxidating two
6 parts of isopropylbenzene, 9 parts of modified zeolite powder, 8 parts of compounded mix, 3 parts of lead salt compound stabilizer, 8 parts of dicyclopentadiene, triallyl
5 parts of 4 parts of fulminuric acid ester and silane coupling agent.
Further, a kind of preparation method of corrosion-resistant cold-resistant cable material, includes following steps：
S1, by 22-30 parts of thermoplastic elastomer (TPE), 22-24 parts of vinylsiloxane rubber, 12-14 parts of nitrile rubber, poly terephthalic acid
3-7 parts of butanediol ester, 16-34 parts of graphene oxide, 15-18 parts of low density polyethylene (LDPE), the mixer for putting into 66-88 DEG C together
In, it is kneaded 10-20min；
S2, by 14-20 parts of nano phase ag_2 o, 21-28 parts of rose crystal type nano calcium carbonate, 3-5 parts of calcinated argil, ceramic fibre 3-
5 parts, 5-7 parts of nano aluminium oxide, 3-7 parts of cumyl peroxide, 8-13 parts of modified zeolite powder, 6-10 parts of compounded mix, lead salt
4-6 parts of 3-4 parts of compound stabilizer, 7-9 parts of dicyclopentadiene, 3-5 parts of iso-cyanuric acid triallyl ester and silane coupling agent,
Enter in high-speed mixer, mixed at high speed 10-20min, stirred evenly at being 70-80 DEG C in temperature, obtain mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 5-10min;
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
The present invention is using thermoplastic elastomer (TPE), nitrile rubber, graphene oxide, vinylsiloxane rubber, rose crystal type nano
The above-mentioned raw materials such as calcium carbonate, nano phase ag_2 o, low density polyethylene (LDPE), calcinated argil, polybutylene terephthalate (PBT) carry out section
Proportioning is added in combination compounded mix, lead salt compound stabilizer, dicyclopentadiene, iso-cyanuric acid triallyl ester and silane
Coupling agent carries out reaction fusion, and process of preparing is simple, and prepared product has preferable corrosion-resistant, fire protection flame retarding, absolutely
Edge performance is suitble to use in multiple fields.
Thermoplastic elastomer (TPE) has good flexibility and thermal stability；CABLE MATERIALS good flame resistance of the present invention, prevents fire
Calamity increases the safety of building cable.
Specific embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being composed of the following raw materials by weight：20-35 parts of thermoplastic elastomer (TPE), nitrile rubber 11-15
Part, 15-35 parts of graphene oxide, 20-25 parts of vinylsiloxane rubber, 20-30 parts of rose crystal type nano calcium carbonate, nano phase ag_2 o
13-22 parts, 14-19 parts of low density polyethylene (LDPE), 2-6 parts of calcinated argil, 2-8 parts of polybutylene terephthalate (PBT), ceramic fibre
2-6 parts, 4-8 parts of nano aluminium oxide, 2-8 parts of cumyl peroxide, 7-14 parts of modified zeolite powder, 5-11 parts of compounded mix, lead
3-7 parts of 2-4 parts of salt compound stabilizer, 6-9 parts of dicyclopentadiene, 2-6 parts of iso-cyanuric acid triallyl ester and silane coupling agent.
A kind of corrosion-resistant cold-resistant cable material, including being composed of the following raw materials by weight：Thermoplastic elastomer (TPE) 22-30
Part, 12-14 parts of nitrile rubber, 16-34 parts of graphene oxide, 22-24 parts of vinylsiloxane rubber, rose crystal type nano calcium carbonate
21-28 parts, 14-20 parts of nano phase ag_2 o, 15-18 parts of low density polyethylene (LDPE), 3-5 parts of calcinated argil, poly terephthalic acid fourth two
3-7 parts of alcohol ester, 3-5 parts of ceramic fibre, 5-7 parts of nano aluminium oxide, 3-7 parts of cumyl peroxide, 8-13 parts of modified zeolite powder,
6-10 parts of compounded mix, 3-4 parts of lead salt compound stabilizer, 7-9 parts of dicyclopentadiene, 3-5 parts of iso-cyanuric acid triallyl ester
With 4-6 parts of silane coupling agent.
A kind of corrosion-resistant cold-resistant cable material, including being composed of the following raw materials by weight：25 parts of thermoplastic elastomer (TPE), fourth
14 parts of nitrile rubber, 18 parts of graphene oxide, 23 parts of vinylsiloxane rubber, 25 parts of rose crystal type nano calcium carbonate, nano phase ag_2 o
18 parts, 16 parts of low density polyethylene (LDPE), 4 parts of calcinated argil, 4 parts of polybutylene terephthalate (PBT), 4 parts of ceramic fibre, nano oxygen
Change 6 parts of aluminium, 6 parts of cumyl peroxide, 9 parts of modified zeolite powder, 8 parts of compounded mix, 3 parts of lead salt compound stabilizer, bicyclic penta
5 parts of 8 parts of diene, 4 parts of iso-cyanuric acid triallyl ester and silane coupling agent.
A kind of preparation method of corrosion-resistant cold-resistant cable material, includes the following steps：
S1, by 22-30 parts of thermoplastic elastomer (TPE), 22-24 parts of vinylsiloxane rubber, 12-14 parts of nitrile rubber, poly terephthalic acid
3-7 parts of butanediol ester, 16-34 parts of graphene oxide, 15-18 parts of low density polyethylene (LDPE), the mixer for putting into 66-88 DEG C together
In, it is kneaded 10-20min；
S2, by 14-20 parts of nano phase ag_2 o, 21-28 parts of rose crystal type nano calcium carbonate, 3-5 parts of calcinated argil, ceramic fibre 3-
5 parts, 5-7 parts of nano aluminium oxide, 3-7 parts of cumyl peroxide, 8-13 parts of modified zeolite powder, 6-10 parts of compounded mix, lead salt
4-6 parts of 3-4 parts of compound stabilizer, 7-9 parts of dicyclopentadiene, 3-5 parts of iso-cyanuric acid triallyl ester and silane coupling agent,
Enter in high-speed mixer, mixed at high speed 10-20min, stirred evenly at being 70-80 DEG C in temperature, obtain mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 5-10min；
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
Embodiment 1：
A kind of preparation method of corrosion-resistant cold-resistant cable material, includes the following steps：
S1, by 27 parts of thermoplastic elastomer (TPE), 23 parts of vinylsiloxane rubber, 13 parts of nitrile rubber, polybutylene terephthalate (PBT) 6
Part, is put into 69 DEG C of mixer 19 parts of graphene oxide, 16 parts of low density polyethylene (LDPE) together, is kneaded 17min；
S2, by 17 parts of nano phase ag_2 o, 26 parts of rose crystal type nano calcium carbonate, 4 parts of calcinated argil, 4 parts of ceramic fibre, nano oxygen
Change 6 parts of aluminium, 6 parts of cumyl peroxide, 11 parts of modified zeolite powder, 8 parts of compounded mix, 3 parts of lead salt compound stabilizer, bicyclic penta
5 parts of 8 parts of diene, 4 parts of iso-cyanuric acid triallyl ester and silane coupling agent, are poured into high-speed mixer, mixed at high speed
16min stirs evenly at being 76 DEG C in temperature, obtains mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 9min;
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
Embodiment 2：
A kind of preparation method of corrosion-resistant cold-resistant cable material, includes the following steps：
S1, by 30 parts of thermoplastic elastomer (TPE), 24 parts of vinylsiloxane rubber, 14 parts of nitrile rubber, polybutylene terephthalate (PBT) 7
Part, is put into 88 DEG C of mixer 34 parts of graphene oxide, 18 parts of low density polyethylene (LDPE) together, is kneaded 20min；
S2, by 20 parts of nano phase ag_2 o, 28 parts of rose crystal type nano calcium carbonate, 5 parts of calcinated argil, 5 parts of ceramic fibre, nano oxygen
Change 7 parts of aluminium, 7 parts of cumyl peroxide, 13 parts of modified zeolite powder, 10 parts of compounded mix, 4 parts of lead salt compound stabilizer, bicyclic
6 parts of 9 parts of pentadiene, 5 parts of iso-cyanuric acid triallyl ester and silane coupling agent, are poured into high-speed mixer, mixed at high speed
20min stirs evenly at being 80 DEG C in temperature, obtains mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 10min;
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
Embodiment 3：
A kind of preparation method of corrosion-resistant cold-resistant cable material, includes the following steps：
S1, by 22 parts of thermoplastic elastomer (TPE), 22 parts of vinylsiloxane rubber, 12 parts of nitrile rubber, polybutylene terephthalate (PBT) 3
Part, is put into 66 DEG C of mixer 16 parts of graphene oxide, 15 parts of low density polyethylene (LDPE) together, is kneaded 10min；
S2, by 14 parts of nano phase ag_2 o, 21 parts of rose crystal type nano calcium carbonate, 3 parts of calcinated argil, 3 parts of ceramic fibre, nano oxygen
Change 5 parts of aluminium, 3 parts of cumyl peroxide, 8 parts of modified zeolite powder, 6 parts of compounded mix, 3 parts of lead salt compound stabilizer, bicyclic penta
4 parts of 7 parts of diene, 3 parts of iso-cyanuric acid triallyl ester and silane coupling agent, are poured into high-speed mixer, mixed at high speed
10min stirs evenly at being 70 DEG C in temperature, obtains mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 5min;
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
The present invention is using thermoplastic elastomer (TPE), nitrile rubber, graphene oxide, vinylsiloxane rubber, rose crystal type nano
The above-mentioned raw materials such as calcium carbonate, nano phase ag_2 o, low density polyethylene (LDPE), calcinated argil, polybutylene terephthalate (PBT) carry out section
Proportioning is added in combination compounded mix, lead salt compound stabilizer, dicyclopentadiene, iso-cyanuric acid triallyl ester and silane
Coupling agent carries out reaction fusion, and process of preparing is simple, and prepared product has preferable corrosion-resistant, fire protection flame retarding, absolutely
Edge performance is suitble to use in multiple fields.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, several improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (4)
1. a kind of corrosion-resistant cold-resistant cable material, which is characterized in that including being composed of the following raw materials by weight：Thermoplastic elastic
20-35 parts of body, 11-15 parts of nitrile rubber, 15-35 parts of graphene oxide, 20-25 parts of vinylsiloxane rubber, rose crystal type nano
20-30 parts of calcium carbonate, 13-22 parts of nano phase ag_2 o, 14-19 parts of low density polyethylene (LDPE), 2-6 parts of calcinated argil, poly- terephthaldehyde
Sour butanediol ester 2-8 parts, 2-6 parts of ceramic fibre, 4-8 parts of nano aluminium oxide, 2-8 parts of cumyl peroxide, modified zeolite powder
7-14 parts, 5-11 parts of compounded mix, 2-4 parts of lead salt compound stabilizer, 6-9 parts of dicyclopentadiene, triallyl fulminuric acid
3-7 parts of 2-6 parts of ester and silane coupling agent.
2. a kind of corrosion-resistant cold-resistant cable material according to claim 1, which is characterized in that including by following parts by weight
Raw material forms：22-30 parts of thermoplastic elastomer (TPE), 12-14 parts of nitrile rubber, 16-34 parts of graphene oxide, vinylsiloxane rubber
22-24 parts, 21-28 parts of rose crystal type nano calcium carbonate, 14-20 parts of nano phase ag_2 o, 15-18 parts of low density polyethylene (LDPE), calcining
3-5 parts of clay, 3-7 parts of polybutylene terephthalate (PBT), 3-5 parts of ceramic fibre, 5-7 parts of nano aluminium oxide, peroxidating two are different
3-7 parts of propyl benzene, 8-13 parts of modified zeolite powder, 6-10 parts of compounded mix, 3-4 parts of lead salt compound stabilizer, dicyclopentadiene 7-9
4-6 parts of part, 3-5 parts of iso-cyanuric acid triallyl ester and silane coupling agent.
3. a kind of corrosion-resistant cold-resistant cable material according to claim 1, which is characterized in that including by following parts by weight
Raw material forms：25 parts of thermoplastic elastomer (TPE), 14 parts of nitrile rubber, 18 parts of graphene oxide, 23 parts of vinylsiloxane rubber, rose are brilliant
25 parts of type nano-calcium carbonate, 18 parts of nano phase ag_2 o, 16 parts of low density polyethylene (LDPE), 4 parts of calcinated argil, poly terephthalic acid fourth two
4 parts of alcohol ester, 4 parts of ceramic fibre, 6 parts of nano aluminium oxide, 6 parts of cumyl peroxide, 9 parts of modified zeolite powder, compounded mix 8
Part, 3 parts of lead salt compound stabilizer, 8 parts of dicyclopentadiene, 4 parts of iso-cyanuric acid triallyl ester and 5 parts of silane coupling agent.
4. the preparation method of a kind of corrosion-resistant cold-resistant cable material according to claim 1, which is characterized in that including such as
Lower step：
S1, by 22-30 parts of thermoplastic elastomer (TPE), 22-24 parts of vinylsiloxane rubber, 12-14 parts of nitrile rubber, poly terephthalic acid
3-7 parts of butanediol ester, 16-34 parts of graphene oxide, 15-18 parts of low density polyethylene (LDPE), the mixer for putting into 66-88 DEG C together
In, it is kneaded 10-20min；
S2, by 14-20 parts of nano phase ag_2 o, 21-28 parts of rose crystal type nano calcium carbonate, 3-5 parts of calcinated argil, ceramic fibre 3-
5 parts, 5-7 parts of nano aluminium oxide, 3-7 parts of cumyl peroxide, 8-13 parts of modified zeolite powder, 6-10 parts of compounded mix, lead salt
4-6 parts of 3-4 parts of compound stabilizer, 7-9 parts of dicyclopentadiene, 3-5 parts of iso-cyanuric acid triallyl ester and silane coupling agent,
Enter in high-speed mixer, mixed at high speed 10-20min, stirred evenly at being 70-80 DEG C in temperature, obtain mixed material；
S3, it step S2 is obtained mixed material is added in the kneading machine of step S1 to be kneaded 5-10min;
S4, by mixture mill, after mill after tabletting, slitting, cooling, put into double screw extruder, be extruded into particle, be made
CABLE MATERIALS.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841180A (en) * | 2018-07-16 | 2018-11-20 | 江苏省苏安能节能建材科技有限公司 | A kind of Water-based silicone rubber can porcelain composite material and preparation method and application |
| CN108948468A (en) * | 2018-08-01 | 2018-12-07 | 安徽锦华氧化锌有限公司 | A kind of preparation method of the corrosion-resistant vulcanization rubber compound of the oil resistant of the alumina filled modification of graphene oxide-glass fibre- |
| CN110591363A (en) * | 2019-09-24 | 2019-12-20 | 中辰电缆股份有限公司 | Extremely cold-resistant cable material and preparation method thereof |
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| CN105111562A (en) * | 2015-08-27 | 2015-12-02 | 江苏易成电力器材有限公司 | High-temperature-resistant flame-retardant cable material |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108841180A (en) * | 2018-07-16 | 2018-11-20 | 江苏省苏安能节能建材科技有限公司 | A kind of Water-based silicone rubber can porcelain composite material and preparation method and application |
| CN108841180B (en) * | 2018-07-16 | 2021-04-13 | 江苏省苏安能节能建材科技有限公司 | Water-based silicon rubber ceramizable composite material and preparation method and application thereof |
| CN108948468A (en) * | 2018-08-01 | 2018-12-07 | 安徽锦华氧化锌有限公司 | A kind of preparation method of the corrosion-resistant vulcanization rubber compound of the oil resistant of the alumina filled modification of graphene oxide-glass fibre- |
| CN108948468B (en) * | 2018-08-01 | 2021-02-05 | 安徽锦华氧化锌有限公司 | Preparation method of graphene oxide-glass fiber-alumina filling modified oil-resistant corrosion-resistant vulcanized rubber compound |
| CN110591363A (en) * | 2019-09-24 | 2019-12-20 | 中辰电缆股份有限公司 | Extremely cold-resistant cable material and preparation method thereof |
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Application publication date: 20180622 |