CN108192054B - 一种聚氨酯泡沫用酚醛树脂多元醇的制造方法 - Google Patents
一种聚氨酯泡沫用酚醛树脂多元醇的制造方法 Download PDFInfo
- Publication number
- CN108192054B CN108192054B CN201711308623.5A CN201711308623A CN108192054B CN 108192054 B CN108192054 B CN 108192054B CN 201711308623 A CN201711308623 A CN 201711308623A CN 108192054 B CN108192054 B CN 108192054B
- Authority
- CN
- China
- Prior art keywords
- phenolic resin
- modifier
- polyurethane foam
- catalyst
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 31
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 31
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 22
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 22
- -1 phenolic resin polyol Chemical class 0.000 title claims description 23
- 229920005862 polyol Polymers 0.000 title claims description 23
- 238000002360 preparation method Methods 0.000 title description 3
- 239000003607 modifier Substances 0.000 claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000004321 preservation Methods 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 230000018044 dehydration Effects 0.000 claims abstract description 3
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 35
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 229940113115 polyethylene glycol 200 Drugs 0.000 claims description 8
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 7
- 229940043276 diisopropanolamine Drugs 0.000 claims description 7
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 5
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 5
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004246 zinc acetate Substances 0.000 claims description 5
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 4
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920002866 paraformaldehyde Polymers 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 12
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 10
- 229920005906 polyester polyol Polymers 0.000 abstract description 10
- 229920000570 polyether Polymers 0.000 abstract description 10
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract description 8
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 238000009413 insulation Methods 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 239000006261 foam material Substances 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/544—Polycondensates of aldehydes with nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711308623.5A CN108192054B (zh) | 2017-12-11 | 2017-12-11 | 一种聚氨酯泡沫用酚醛树脂多元醇的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711308623.5A CN108192054B (zh) | 2017-12-11 | 2017-12-11 | 一种聚氨酯泡沫用酚醛树脂多元醇的制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN108192054A CN108192054A (zh) | 2018-06-22 |
CN108192054B true CN108192054B (zh) | 2020-03-17 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201711308623.5A Active CN108192054B (zh) | 2017-12-11 | 2017-12-11 | 一种聚氨酯泡沫用酚醛树脂多元醇的制造方法 |
Country Status (1)
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CN (1) | CN108192054B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA3090763A1 (en) * | 2018-02-07 | 2019-08-15 | Cidra Corporate Services Llc | Open cell or reticulated foam having 3-dimensional open-network structure made of a hydrophobic material for selective separation of mineral particles |
CN110054751A (zh) * | 2019-04-23 | 2019-07-26 | 徐州工程学院 | 一种自控温阻燃聚氨酯保温材料及其制备方法 |
CN110511340A (zh) * | 2019-08-29 | 2019-11-29 | 万华节能科技集团股份有限公司 | 一种可用于渗流条件下的高强度双组份聚氨酯材料及其制备方法 |
CN111607191A (zh) * | 2020-07-08 | 2020-09-01 | 上海尖端工程材料有限公司 | 一种阻燃超低导热系数pfu泡沫及其制作方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1435366A1 (en) * | 2003-01-03 | 2004-07-07 | Dow Global Technologies Inc. | Polyol composition and polyisocyanate-based foam prepared therefrom |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR9913873B1 (pt) * | 1998-09-10 | 2009-05-05 | processo para preparar um poliol de mannich. | |
CN101676312A (zh) * | 2008-09-18 | 2010-03-24 | 上海昊海化工有限公司 | 一种新型改性酚醛树脂及其生产方法 |
-
2017
- 2017-12-11 CN CN201711308623.5A patent/CN108192054B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1435366A1 (en) * | 2003-01-03 | 2004-07-07 | Dow Global Technologies Inc. | Polyol composition and polyisocyanate-based foam prepared therefrom |
Also Published As
Publication number | Publication date |
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CN108192054A (zh) | 2018-06-22 |
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Effective date of registration: 20240307 Address after: 233000 No. 11, Century Avenue, Huaiyuan Economic Development Zone, Bengbu City, Anhui Province Patentee after: Anhui Fushite Construction Engineering Co.,Ltd. Country or region after: China Address before: 233000 fifth floor of Management Committee, No. 1 Feihe North Road, mohekou Industrial Zone, Huaishang District, Bengbu City, Anhui Province Patentee before: ANHUI MAX TECHNOLOGY Co.,Ltd. Country or region before: China |
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Effective date of registration: 20240313 Address after: Room 102, No. 31 Maojia Road, Baoshan District, Shanghai, 2019 Patentee after: Shanghai Hebang Ecological Building Technology Co.,Ltd. Country or region after: China Address before: 233000 No. 11, Century Avenue, Huaiyuan Economic Development Zone, Bengbu City, Anhui Province Patentee before: Anhui Fushite Construction Engineering Co.,Ltd. Country or region before: China |