CN108191104A - A kind of dye waste water treatment method - Google Patents
A kind of dye waste water treatment method Download PDFInfo
- Publication number
- CN108191104A CN108191104A CN201711462441.3A CN201711462441A CN108191104A CN 108191104 A CN108191104 A CN 108191104A CN 201711462441 A CN201711462441 A CN 201711462441A CN 108191104 A CN108191104 A CN 108191104A
- Authority
- CN
- China
- Prior art keywords
- waste water
- water treatment
- treatment method
- photoreactor
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/026—Fenton's reagent
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/08—Nanoparticles or nanotubes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The invention discloses a kind of dye waste water treatment methods, include the following steps:Waste water from dyestuff is introduced in grille well, large granular impurity is removed, and large granular impurity is focused on through grid filtration;Waste water in middle grille well is introduced in sedimentation basin, carries out precipitation process;Upper strata waste water in sedimentation basin is introduced in regulating reservoir, adds conditioning agent by the pH value of waste water;Waste water after adjusting pH value is introduced in Photoreactor, adds in catalyst, carries out catalytic degradation reaction;The catalyst is has loaded Fe2+Porous silica material and H2O2;Liquid in Photoreactor is introduced in filtering ponds, is filtered processing, filtrate qualified discharge.The present invention carries out photocatalytic degradation reaction by Fenton reagent in Photoreactor, and Fenton reagent is has loaded Fe2+Porous silica material and H2O2, loaded Fe2+Porous silica material act not only as Fe2+Supplier, porous silica material can adsorb dyestuff so that the process of degradation of dye greatly shortens, and degradation efficiency greatly improves.
Description
Technical field
The present invention relates to technical field of waste water processing, particularly a kind of dye waste water treatment method.
Background technology
Dyestuff is during production and processing, and in addition to being normally processed using water, some is with the shape of waste water
Formula is discharged, and waste water from dyestuff is after discharge if cannot handle well, it is easy to earth's surface and underground water pollution are directly contributed, these
Water often brings irreversible injury once being quoted by animal and people.Titanium dioxide series catalyst is mainly utilized at present
The degradation of dyestuff is carried out under natural light, but due to the wider band gap of titanium dioxide, makes this kind of catalyst only special
Instrument and consume competence exertion under conditions of a large amount of non-renewable energy resources simultaneously and act on, and catalytic process take it is longer.
Invention content
To solve problem above, it is an object of the invention to provide a kind of dye waste water treatment methods.
It is realized the purpose of the present invention is technical solution in this way, a kind of dye waste water treatment method, including following
Step:
Step 1:Waste water from dyestuff is introduced in grille well, large granular impurity is removed, and by large granular impurity through grid filtration
It is focused on;
Step 2:Waste water in step 1 in grille well is introduced in sedimentation basin, carries out precipitation process;
Step 3:Upper strata waste water in step 2 in sedimentation basin is introduced in regulating reservoir, adds conditioning agent by the pH value of waste water;
Step 4:Waste water after adjusting pH value in step 3 is introduced in Photoreactor, catalyst is added in, carries out catalysis drop
Solution reaction;The catalyst is has loaded Fe2+Porous silica material and H2O2;
Step 5:Liquid in Photoreactor is introduced in filtering ponds, is filtered processing, filtrate qualified discharge.
Further, Fe in the catalyst2+With H2O2Molar ratio be 1:15.
Further, agitating device is equipped in the regulating reservoir.
Further, it is described to have loaded Fe2+Porous silica material aperture be nanoscale.
Further, the conditioning agent in the step 3 is one or both of NaOH and KOH.
By adopting the above-described technical solution, beneficial effects of the present invention are:The present invention is by Fenton reagent in light reaction
Photocatalytic degradation reaction is carried out in device, Fenton reagent is has loaded Fe2+Porous silica material and H2O2, loaded Fe2+It is porous
Silicon materials act not only as Fe2+Supplier, and porous silica material can adsorb dyestuff so that degradation of dye
Process greatly shortens, and degradation efficiency greatly improves.
Other advantages, target and the feature of the present invention will be illustrated in the following description to a certain extent, and
And to a certain extent, based on will be apparent to those skilled in the art to investigating hereafter, Huo Zheke
To be instructed from the practice of the present invention.The target and other advantages of the present invention can be wanted by following specification and right
Book is sought to realize and obtain.
Specific embodiment
With reference to embodiment, the invention will be further described.
The invention discloses a kind of dye waste water treatment methods, include the following steps:
Step 1:Waste water from dyestuff is introduced in grille well, large granular impurity is removed, and by large granular impurity through grid filtration
It is focused on;
Step 2:Waste water in step 1 in grille well is introduced in sedimentation basin, carries out precipitation process;
Step 3:Upper strata waste water in step 2 in sedimentation basin is introduced in regulating reservoir, adds conditioning agent by the pH value of waste water;
Step 4:Waste water after adjusting pH value in step 3 is introduced in Photoreactor, catalyst is added in, carries out catalysis drop
Solution reaction;The catalyst is has loaded Fe2+Porous silica material and H2O2;
Step 5:Liquid in Photoreactor is introduced in filtering ponds, is filtered processing, filtrate qualified discharge.
Fe in the catalyst2+With H2O2Molar ratio be 1:15.
Agitating device is equipped in the regulating reservoir.
Agitating device is equipped in the Photoreactor.
It is described to have loaded Fe2+Porous silica material aperture be nanoscale.
Conditioning agent in the step 3 is one or both of NaOH and KOH.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of the technical program, should all be covered in the present invention
Right in.
Claims (5)
1. a kind of dye waste water treatment method, it is characterised in that:Include the following steps:
Step 1:Waste water from dyestuff is introduced in grille well, large granular impurity is removed, and large granular impurity is carried out through grid filtration
Centralized processing;
Step 2:Waste water in step 1 in grille well is introduced in sedimentation basin, carries out precipitation process;
Step 3:Upper strata waste water in step 2 in sedimentation basin is introduced in regulating reservoir, adds conditioning agent by the pH value of waste water;
Step 4:Waste water after adjusting pH value in step 3 is introduced in Photoreactor, adds in catalyst, it is anti-to carry out catalytic degradation
It should;The catalyst is has loaded Fe2+Porous silica material and H2O2;
Step 5:Liquid in Photoreactor is introduced in filtering ponds, is filtered processing, filtrate qualified discharge.
2. dye waste water treatment method according to claim 1, it is characterised in that:Fe in the catalyst2+With H2O2Rub
You are than being 1:15.
3. dye waste water treatment method according to claim 1, it is characterised in that:Stirring dress is equipped in the regulating reservoir
It puts.
4. dye waste water treatment method according to claim 1, it is characterised in that:It is described to have loaded Fe2+Porous silicon material
The aperture of material is nanoscale.
5. dye waste water treatment method according to claim 1, it is characterised in that:Conditioning agent in the step 3 is
One or both of NaOH and KOH.
Priority Applications (1)
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CN201711462441.3A CN108191104A (en) | 2017-12-28 | 2017-12-28 | A kind of dye waste water treatment method |
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CN201711462441.3A CN108191104A (en) | 2017-12-28 | 2017-12-28 | A kind of dye waste water treatment method |
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CN108191104A true CN108191104A (en) | 2018-06-22 |
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CN201711462441.3A Pending CN108191104A (en) | 2017-12-28 | 2017-12-28 | A kind of dye waste water treatment method |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109231700A (en) * | 2018-10-26 | 2019-01-18 | 东江环保股份有限公司江苏分公司 | The integrated approach technique of active dyeing waste water |
CN109250849A (en) * | 2018-09-22 | 2019-01-22 | 福建凤竹纺织科技股份有限公司 | A kind of processing method of textile waste |
CN112062337A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Photocatalytic oxidation type dye wastewater treatment method |
CN112675881A (en) * | 2021-01-08 | 2021-04-20 | 东南大学 | Composite photocatalyst for degrading morpholine wastewater, preparation method and special equipment |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381178A (en) * | 2008-10-08 | 2009-03-11 | 河北工业大学 | Printing and dyeing wastewater processing technique |
CN106277589A (en) * | 2016-08-25 | 2017-01-04 | 南京大学盐城环保技术与工程研究院 | A kind of system and method utilizing ferrum carbon Fenton pretreatment UBF A/O to process waste water from dyestuff |
-
2017
- 2017-12-28 CN CN201711462441.3A patent/CN108191104A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381178A (en) * | 2008-10-08 | 2009-03-11 | 河北工业大学 | Printing and dyeing wastewater processing technique |
CN106277589A (en) * | 2016-08-25 | 2017-01-04 | 南京大学盐城环保技术与工程研究院 | A kind of system and method utilizing ferrum carbon Fenton pretreatment UBF A/O to process waste water from dyestuff |
Non-Patent Citations (1)
Title |
---|
ZHAO CHAO: "Visible light-induced degradation of organic pollutants using Fe(II) supported on silica gel as an effective catalyst", 《CHINESE SCIENCE BULLETIN》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109250849A (en) * | 2018-09-22 | 2019-01-22 | 福建凤竹纺织科技股份有限公司 | A kind of processing method of textile waste |
CN109231700A (en) * | 2018-10-26 | 2019-01-18 | 东江环保股份有限公司江苏分公司 | The integrated approach technique of active dyeing waste water |
CN112062337A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Photocatalytic oxidation type dye wastewater treatment method |
CN112675881A (en) * | 2021-01-08 | 2021-04-20 | 东南大学 | Composite photocatalyst for degrading morpholine wastewater, preparation method and special equipment |
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Application publication date: 20180622 |
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