CN108190995A - A kind of adsorbing sphere for organic pollutants in water body - Google Patents

A kind of adsorbing sphere for organic pollutants in water body Download PDF

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Publication number
CN108190995A
CN108190995A CN201810214727.8A CN201810214727A CN108190995A CN 108190995 A CN108190995 A CN 108190995A CN 201810214727 A CN201810214727 A CN 201810214727A CN 108190995 A CN108190995 A CN 108190995A
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China
Prior art keywords
parts
water body
adsorbing sphere
activated carbon
particle
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Pending
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CN201810214727.8A
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Chinese (zh)
Inventor
刘伟
刘滨
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Guizhou Ruixin Environmental Protection Ltd By Share Ltd
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Guizhou Ruixin Environmental Protection Ltd By Share Ltd
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Priority to CN201810214727.8A priority Critical patent/CN108190995A/en
Publication of CN108190995A publication Critical patent/CN108190995A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/586Treatment of water, waste water, or sewage by removing specified dissolved compounds by removing ammoniacal nitrogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • C02F3/322Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae use of algae
    • C02F3/325Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae use of algae as symbiotic combination of algae and bacteria
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F2003/001Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
    • C02F2003/003Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms using activated carbon or the like
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Ecology (AREA)
  • Botany (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

This programme discloses a kind of adsorbing sphere for organic pollutants in water body of water pollutant cleaning applications, the adsorbing sphere is including the use of skeleton spherical made of biodegradation material, the spherical skeletal internal is equipped with cavity, the surface of skeleton is evenly equipped with hole, and activated carbon, ceramic particle, activated sludge and zeolite granular are filled in the cavity.This programme can eliminate three kinds of pollutants main in water body with comprehensive, including organic matter, ammonia nitrogen, suspension algae, effectively remove the various major pollutants of water body;Meanwhile the adsorbing sphere of this programme or the high-effective microorganism carrier of helotism;Accelerate the foundation of the natural water ecosystem;Promote microbial diversity.

Description

A kind of adsorbing sphere for organic pollutants in water body
Technical field
The present invention relates to water pollutant cleaning applications, and in particular to a kind of adsorbing sphere for organic pollutants in water body.
Background technology
Mainly by municipal sewage, the discharge such as food industry and paper industry contains large amount of organic for water body organic contamination Pollution caused by waste water.Organic pollution is carried out in biological oxidation decomposable process in water, needs to consume a large amount of dissolved oxygens, and one Oxygen supply is insufficient in denier water body, can stop oxidation, cause the anaerobic fermentation of organic matter, gives out stench, pollutes ring Border, murder by poisoning have biology.Assuming that the organic pollution materials contained amount for being drained into water body is higher, can cause in water after reacting Dissolved oxygen is largely consumed, self detergent power of water body can also weaken simultaneously even to disappear.Organic pollution is in such case Under can carry out anaerobic reaction, generate various reducibility gas, these gases cause animals and plants in water to be difficult to survive, and can make water It is muddy that body gradually becomes blacking, and generates stench, seriously polluted the ecological environment of urban water-body.If the content of organics in water It is fewer, then its oxygen consumed is easy for being supplemented from the air of dissolving, so can just make aquatic ecosystem Cycle be maintained, otherwise will destroy aquatic ecosystem.
Also there are a large amount of ammonia nitrogen class substance and algae substances in addition to organic matter for pollutant in water body, these are all shadows The principal element of Xiangshui County's weight, with the acceleration of urban life rhythm, the discharge capacity of house refuse and sewage is all great Rise.But be scarcely out of swaddling-clothes at present for the treatment technology of pollutant in water body, the elimination of pollutant in water body is imitated Fruit is bad, it is impossible to accelerate the foundation of the natural water ecosystem.
Invention content
It is in the prior art right to solve the invention is intended to provide a kind of adsorbing sphere for organic pollutants in water body The elimination of pollutant is not thorough in water body, and water ecosystem is caused to establish the technical issues of slow.
A kind of adsorbing sphere for organic pollutants in water body in this programme, the adsorbing sphere is including the use of biodegradable material Spherical skeleton made of material, the spherical skeletal internal are equipped with cavity, and the surface of skeleton is evenly equipped with hole, is filled in the cavity Active charcoal, ceramic particle, activated sludge and zeolite granular.
The operation principle of this programme:
1st, the principle of organic matter in water body is removed:This programme when in use, first with strong oxidizer, potassium permanganate, two Chlorine monoxid medicament impregnates adsorbing sphere, and then adsorbing sphere is immersed in sewage, organic matter is adsorbed, the activated carbon of filling, Ceramic particle, activated sludge and zeolite granular carry out biological oxidation to pollutant, and most organic matter is decomposed or transformed into micro- at last Biological components, so as to remove the organic matter in water body.
2nd, the principle of ammonia nitrogen is removed:Hole is evenly distributed on spherical skeleton surface in scheme, forms more hollow structures, the work in cavity Property charcoal, ceramic particle, activated sludge and zeolite granular, containing Mg (OH) 2, H3PO4, NH4+ in chemical composition, can adsorb Organic matter in water body forms precipitation MgNH4PO46H2O, so as to which the ammonia nitrogen class substance in water body be removed.
3rd, the principle of suspension algae is controlled:Adsorbing sphere, superpower table are impregnated using compounds such as rosin amine, aldehyde, ketone More nutrients are transferred to its surface by area adsorptivity, so as to which planktonic algae be made to be on a sticky wicket in struggle for existence, It is caused to be unable to normal growth, breeding even extinction.
The advantageous effect of this programme is:1st, this programme can disappear to three kinds of pollutants main in water body with comprehensive It removes, including organic matter, ammonia nitrogen, suspension algae, effectively removes the various major pollutants of water body;2nd, simultaneously, the absorption of this programme Ball or the high-effective microorganism carrier of helotism;3rd, accelerate the foundation of the natural water ecosystem;4th, promote Microbial diversity Property.
It is the scheme of optimization below:
Prioritization scheme one:For the adsorbing sphere of organic pollutants in water body, the activated carbon, ceramic particle, activated sludge and The parts by weight of zeolite granular are:50~60 parts of activated carbon, 15~26 parts of ceramic particle, 12~15 parts of activated sludge, zeolite 25~38 parts of grain.Each component is more preferable to the effect of the pollutant integrated treatment in water body in the range of the restriction of this prioritization scheme.
Prioritization scheme two, based on prioritization scheme one:For the adsorbing sphere of organic pollutants in water body, the activated carbon, ceramics The parts by weight of particle, activated sludge and zeolite granular are:60 parts of activated carbon, 26 parts of ceramic particle, 13 parts of activated sludge, zeolite 30 parts of particle.This programme is partial to organic pollution comparatively serious situation in water body, lays particular emphasis on the removing to organic matter.
Prioritization scheme three, based on prioritization scheme two:For the adsorbing sphere of organic pollutants in water body, the activated carbon, ceramics The parts by weight of particle, activated sludge and zeolite granular are:50 parts of activated carbon, 20 parts of ceramic particle, 12 parts of activated sludge, zeolite 38 parts of particle.This programme is partial to ammonia and nitrogen pollution comparatively serious situation in water body, lays particular emphasis on the removing to ammonia nitrogen.
Prioritization scheme four, based on prioritization scheme three:For the adsorbing sphere of organic pollutants in water body, the activated carbon, ceramics The parts by weight of particle, activated sludge and zeolite granular are:55 parts of activated carbon, 15 parts of ceramic particle, 15 parts of activated sludge, zeolite 25 parts of particle.This programme is partial to suspension algae pollution comparatively serious situation in water body, lays particular emphasis on to suspension algae The removing of class.
Specific embodiment
Below by the further details of explanation of specific embodiment:
Embodiment 1:A kind of adsorbing sphere for organic pollutants in water body, including the use of spherical made of biodegradation material Skeleton, spherical skeletal internal are equipped with cavity, and the surface of skeleton is evenly equipped with hole, activated carbon, ceramic particle, work are filled in cavity Property sludge and zeolite granular;Activated carbon, ceramic particle, activated sludge and zeolite granular parts by weight be:60 parts of activated carbon, pottery 26 parts of porcelain particle, 13 parts of activated sludge, 30 parts of zeolite granular.
Embodiment 2:A kind of adsorbing sphere for organic pollutants in water body, including the use of spherical made of biodegradation material Skeleton, spherical skeletal internal are equipped with cavity, and the surface of skeleton is evenly equipped with hole, activated carbon, ceramic particle, work are filled in cavity Property sludge and zeolite granular;Activated carbon, ceramic particle, activated sludge and zeolite granular parts by weight be:50 parts of activated carbon, pottery 20 parts of porcelain particle, 12 parts of activated sludge, 38 parts of zeolite granular.
Embodiment 3:A kind of adsorbing sphere for organic pollutants in water body, including the use of spherical made of biodegradation material Skeleton, spherical skeletal internal are equipped with cavity, and the surface of skeleton is evenly equipped with hole, activated carbon, ceramic particle, work are filled in cavity Property sludge and zeolite granular;Activated carbon, ceramic particle, activated sludge and zeolite granular parts by weight be:55 parts of activated carbon, pottery 15 parts of porcelain particle, 15 parts of activated sludge, 25 parts of zeolite granular.
Biodegradation material in above scheme can be:Biopolvester, biology cellulose, polysaccharide, polyaminoacid, heat One kind in plastic starch plastics etc..
This programme impregnates adsorbing sphere when in use, first with strong oxidizer, potassium permanganate, chlorine dioxide medicament, then Adsorbing sphere is immersed in sewage, organic matter is adsorbed, biological oxidation, most organic matter is decomposed or transformed into micro- at last Biological components, so as to remove the organic matter in water body;Hole is evenly distributed on spherical skeleton surface in scheme, forms more hollow structures, it is empty Activated carbon, ceramic particle, activated sludge and zeolite granular in chamber, containing Mg (OH) 2, H3PO4, NH4+ in chemical composition, Organic matter that can be in adsorbed water body, forms precipitation MgNH4PO46H2O, so as to which the ammonia nitrogen class substance in water body be removed;Make Adsorbing sphere is impregnated with compounds such as rosin amine, aldehyde, ketone, more nutrients are transferred to its table by superpower surface area adsorptivity Face so as to which planktonic algae be made to be on a sticky wicket in struggle for existence, causes it to be unable to normal growth, breeding even extinction.
This programme can eliminate three kinds of pollutants main in water body with comprehensive, including organic matter, ammonia nitrogen, hang Buoyancy algae effectively removes the various major pollutants of water body;Meanwhile the adsorbing sphere of this programme or efficient micro- life of helotism Object carrier;Accelerate the foundation of the natural water ecosystem;Promote microbial diversity.

Claims (5)

1. a kind of adsorbing sphere for organic pollutants in water body, it is characterised in that:The adsorbing sphere is including the use of biodegradable material Spherical skeleton made of material, the spherical skeletal internal are equipped with cavity, and the surface of skeleton is evenly equipped with hole, is filled in the cavity Active charcoal, ceramic particle, activated sludge and zeolite granular.
2. the adsorbing sphere according to claim 1 for organic pollutants in water body, it is characterised in that:The activated carbon, pottery The parts by weight of porcelain particle, activated sludge and zeolite granular are:50~60 parts of activated carbon, 15~26 parts of ceramic particle, activity are dirty 12~15 parts of mud, 25~38 parts of zeolite granular.
3. the adsorbing sphere according to claim 2 for organic pollutants in water body, it is characterised in that:The activated carbon, pottery The parts by weight of porcelain particle, activated sludge and zeolite granular are:60 parts of activated carbon, 26 parts of ceramic particle, 13 parts of activated sludge, boiling 30 parts of stone particle.
4. the adsorbing sphere according to claim 2 for organic pollutants in water body, it is characterised in that:The activated carbon, pottery The parts by weight of porcelain particle, activated sludge and zeolite granular are:50 parts of activated carbon, 20 parts of ceramic particle, 12 parts of activated sludge, boiling 38 parts of stone particle.
5. the adsorbing sphere according to claim 2 for organic pollutants in water body, it is characterised in that:The activated carbon, pottery The parts by weight of porcelain particle, activated sludge and zeolite granular are:55 parts of activated carbon, 15 parts of ceramic particle, 15 parts of activated sludge, boiling 25 parts of stone particle.
CN201810214727.8A 2018-03-15 2018-03-15 A kind of adsorbing sphere for organic pollutants in water body Pending CN108190995A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109133519A (en) * 2018-09-20 2019-01-04 河南省科学院地理研究所 A kind of river bottom mud ecological treatment method
CN109201012A (en) * 2018-10-12 2019-01-15 新疆天物生态科技股份有限公司 A kind of inclusion adsorbate and preparation method thereof for handling ammonia nitrogen waste water
CN111302428A (en) * 2020-04-02 2020-06-19 四川锦城佳禾生态环保科技有限公司 Be applied to sewage treatment's improvement device based on particle adsorption
CN111995059A (en) * 2020-08-27 2020-11-27 贵州理工学院 Nano-material water treatment composition
CN112156757A (en) * 2020-10-30 2021-01-01 林建东 Composite adsorption material structure and manufacturing method thereof

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CN201785245U (en) * 2010-05-27 2011-04-06 北京坎普尔环保技术有限公司 Compound biological packing and bioreactor thereof
CN102101008A (en) * 2011-01-28 2011-06-22 河北亚太环境科技发展股份有限公司 Oxidation type air purifying material and preparation method thereof
CN104355355B (en) * 2014-11-06 2016-09-14 中国环境科学研究院 A kind of porous adsorbing material processing organic wastewater

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CN102101008A (en) * 2011-01-28 2011-06-22 河北亚太环境科技发展股份有限公司 Oxidation type air purifying material and preparation method thereof
CN104355355B (en) * 2014-11-06 2016-09-14 中国环境科学研究院 A kind of porous adsorbing material processing organic wastewater

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109133519A (en) * 2018-09-20 2019-01-04 河南省科学院地理研究所 A kind of river bottom mud ecological treatment method
CN109201012A (en) * 2018-10-12 2019-01-15 新疆天物生态科技股份有限公司 A kind of inclusion adsorbate and preparation method thereof for handling ammonia nitrogen waste water
CN109201012B (en) * 2018-10-12 2021-05-04 新疆天物生态科技股份有限公司 Inclusion adsorbate for treating ammonia nitrogen wastewater and preparation method thereof
CN111302428A (en) * 2020-04-02 2020-06-19 四川锦城佳禾生态环保科技有限公司 Be applied to sewage treatment's improvement device based on particle adsorption
CN111995059A (en) * 2020-08-27 2020-11-27 贵州理工学院 Nano-material water treatment composition
CN112156757A (en) * 2020-10-30 2021-01-01 林建东 Composite adsorption material structure and manufacturing method thereof

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