CN108178251A - A kind of electro-catalysis Multifunctional water purifying device and its electro-catalysis Multifunctional water purification method - Google Patents

A kind of electro-catalysis Multifunctional water purifying device and its electro-catalysis Multifunctional water purification method Download PDF

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Publication number
CN108178251A
CN108178251A CN201810168512.7A CN201810168512A CN108178251A CN 108178251 A CN108178251 A CN 108178251A CN 201810168512 A CN201810168512 A CN 201810168512A CN 108178251 A CN108178251 A CN 108178251A
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partition board
electro
catalysis
reactor
gas
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CN108178251B (en
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李浩隆
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Zhejiang Sheng Ke Environmental Engineering Co Ltd
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Zhejiang Sheng Ke Environmental Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention discloses a kind of electro-catalysis Multifunctional water purifying device and its electro-catalysis Multifunctional water purification method.Described device includes a reactor, and inside forms several regions by multiple partition boards, includes three partition boards in the multiple partition board, each partition board can be integrally formed.Buffering oil removal settling zone is formed between partition board two, side wall one, bottom wall;U-shaped runner one is formed between partition board one, partition board two, the section start of U-shaped runner one forms coarse filter area, is later commutating zone;Electro-catalysis pole plate area is formed between partition board one, partition board three, several electro-catalysis pole plates are installed in electro-catalysis pole plate area;U-shaped runner two is formed between partition board three, side wall two, the openend of U-shaped runner two forms the exhalant region communicated with water outlet.The liquid of water inlet is first downwards via the precipitation filtering of buffering oil removal settling zone, again upwardly through coarse filter area coarse filtration, then rectification in U-shaped runner one is flowed upward to, be redirected into the catalysis reaction of electro-catalysis pole plate area later, it turns again to enter U-shaped runner two, and be discharged by water outlet in exhalant region.

Description

A kind of electro-catalysis Multifunctional water purifying device and its electro-catalysis Multifunctional water purification method
Technical field
A kind of purified water treatment device and its clean water treatment side the present invention relates to water pollutant purification treatment technology field Method more particularly to go miscellaneous organic matter, oils, granulator in water removal, suspended matter, ammonia nitrogen, anion surfactant, coloration, A kind of electro-catalysis Multifunctional water purifying device of bacterial virus and its electro-catalysis Multifunctional water purification method.
Background technology
With the anxiety of water resource, environmental pollution it is serious, people's consciousness of saving water is gradually increased, and Treated sewage reusing is more and more general And.Buck is a kind of sewage relatively low without fecaluria, pollution level in sanitary sewage, and generated grey water usually accounts in family The 50%~80% of total water consumption to reuse after its categorised collection and processing, can obtain good environmental benefit and economic benefit. Buck after treatment can reuse field be mainly not with human contact use water, such as flush the toilet, afforest, carwash, sprinkling road, Concrete stirring, fire-fighting, boiler, wetland, scenic water, groundwater recharge water even agricultural irrigation water etc..There is research table It is bright, ash water recycling in flush the toilet or pour can saving domestic water total amount 30%~50%.
Aboard, since space is limited, it is more limited often to save the clear water amount that compartment loads.Whole waters, which are provided to, to be washed Chamber wash, toilet clean, cleaning uses, so water consumption is very nervous.Moreover, after washroom, toilet hand basin use Buck and the Heisui River of flush toilets will be discharged into vehicle-mounted sewage-treatment plant together, this bears the water for aggravating processing unit Lotus.It is back to non-human contact after if buck under the relatively low hand basin of pollution level, wash basin can be collected separately, individually be handled Flush toilets, will can save more than the 30% of train total water consumption.
Existing ash water recycling treatment technology uses oil removal, coagulation air-float, coagulating sedimentation, filtering, biochemical processing process more, These technologies can occupy larger space, have the continuous or periodic discharge of sludge, and single technique is difficult by organic matter, ammonia The multiple pollutants such as nitrogen, coloration, bacterial virus, anion surfactant, vegetable and animals oils remove simultaneously.So ash water recycling Processing needs a kind of processing unit multi-functional, footprint is compact.
Invention content
The purpose of the present invention is to provide a kind of electro-catalysis Multifunctional water purifying device and its electro-catalysis Multifunctional water purification method, The electro-catalysis Multifunctional water purifying device is suitably mounted under toilet hand basin or under closet basin, and removing has in buck The pollutants such as machine object, ammonia nitrogen, coloration, bacterial virus, anion surfactant, vegetable and animals oils realize that ash water recycling is quickly located Reason.
The present invention is realized using following technical scheme:A kind of electro-catalysis Multifunctional water purifying device, it includes a reactor, The reactor is equipped with several water inlets, several water outlets;The inside of the reactor forms several areas by multiple partition boards Domain, and several regions sequentially form the runner of liquid communication from the water inlet to the water outlet;
Include in the multiple partition board:Partition board one, one end setting is fixed on the bottom wall of the reactor, another End is opposite with the roof of the reactor;Partition board two, one end setting are fixed on the side of partition board one, and the other end is first towards institute The extension of side wall one for stating reactor turns again to towards roof extend and close to roof;If the region parallel with bottom wall opens up on partition board two Mainstream through-hole one;Partition board three, one end setting are fixed on roof, and the other end first extends towards bottom wall, then in partition board one Top turns to towards the side wall two close to the reactor and tilts extension, and extend between partition board one and side wall two, turns again to court Bottom wall extends and close to bottom wall;Side wall two is oppositely arranged with side wall one;
Wherein, buffering oil removal settling zone is formed between partition board two, side wall one, bottom wall;U is formed between partition board one, partition board two Shape runner one, the section start of U-shaped runner one form coarse filter area, are later commutating zone;Electro-catalysis is formed between partition board one, partition board three Pole plate area, several electro-catalysis pole plates of installation in electro-catalysis pole plate area;U-shaped runner two, U-shaped stream are formed between partition board three, side wall two The openend in road two forms the exhalant region communicated with the water outlet.
As being further improved for said program, several gas vents communicated with the inside reactor are opened up on roof, Roof is externally provided with the exhaust gas purification room communicated with the gas vent, and the gas in the reactor is net via exhaust gas purification room It is discharged after change.
Further, partition board four is further included in the multiple partition board, one end of partition board four, which is erect, to be fixed on roof, every The other end of plate four first extends towards the rake of partition board three, and then turn to court in the top of three rake of partition board inclines by proximal wall two Tiltedly extension, turns again to extend vertically and be fixed on side wall two towards side wall two, partition board four opens up several recirculation holes two later;Partition board Four the exhalant region is isolated from U-shaped runner two, and the runner of U-shaped runner two is made to become narrow, and in the opening of U-shaped runner two End forms gas-liquid separation zone;The liquid of U-shaped runner two is by two refined filtration of recirculation hole, then flows upward to the exhalant region, U-shaped The gas vent is led in gas aggressiveness to the gas-liquid separation zone in runner two again.
Further, the electro-catalysis Multifunctional water purifying device further includes chimney filter structure, and the chimney filter structure is an end seal It closes, the other end is helicitic texture, generally hollow cylindrical, and tube wall carries the chimney filter of filter gap;The chimney filter passes through screw thread knot What structure and being welded on surrounded the water outlet screws installation with new designs of threaded joints.
Further, partition board two makes to form scum silica frost air supporting between partition board two, partition board three than partition board one more close to roof The gas vent is led in area, gas aggressiveness to the scum silica frost air flotation zone in the reactor.
Further, exhaust gas purification room setting exhaust outlet, after the gas in the reactor is purified via exhaust gas purification room It is discharged by exhaust outlet.
As being further improved for said program, slip plate is further included in the multiple partition board, slip plate is located at buffering In oil removal settling zone, and the bonding pad for connecting side wall one, bottom wall in the reactor simultaneously is closed, made in buffering oil removal settling zone Heavy mud be gathered between partition board one and slip plate.
As being further improved for said program, the bottom end of U-shaped runner two sets several temperature sensor interfaces, and temperature passes Sensor interface measures the temperature sensor of electro-catalysis pole plate area leaving water temperature for installing.
As being further improved for said program, on the bottom wall and position of corresponding buffering oil removal settling zone sets sewage draining exit, And/or on the bottom wall and position in corresponding electro-catalysis pole plate area sets spare sewage draining exit.
The present invention also provides the electro-catalysis Multifunctional water purification method of above-mentioned arbitrary electro-catalysis Multifunctional water purifying device, the electricity Being catalyzed Multifunctional water purification method is:
The liquid of the water inlet is first downwards via the precipitation filtering of buffering oil removal settling zone, then upwardly through the recirculation hole One coarse filtration, then rectification in U-shaped runner one is flowed upward to, it is redirected into the catalysis reaction of electro-catalysis pole plate area later, turns again to enter U Shape runner two, and be discharged in the exhalant region by the water outlet;
When offering several gas vents communicated with the inside reactor on roof, the gas warp in the reactor It is discharged after being purified by exhaust gas purification room;And when further including partition board four in the multiple partition board, the liquid of U-shaped runner two passes through Two refined filtration of recirculation hole, then the exhalant region is flowed upward to, the gas aggressiveness in U-shaped runner two to the gas-liquid separation zone is again Lead to the gas vent.
When electrode plate groups are assembled as being further improved for said program, in electro-catalysis pole plate area, the electrode plate groups with One includes insulation crust, and for electrode plate, particle loaded electrode between pole plate, each side plate of shell is formed with groove rabbet assembly for inside The mode of integrated member be fixed on the panel of the reactor, when the electrode plate groups are packed into electro-catalysis pole plate area, in institute It states on the inside of the backboard of reactor and is provided with four fixed columns for positioning the electrode plate groups, and on the shell of the electrode plate groups Counterbore socket joint correspond to.
The electro-catalysis Multifunctional water purifying device compact overall structure of the present invention is installed convenient for small space, by oil removal, sinks Shallow lake, air supporting, electro-catalysis electrolysis, absorption, filtering, sterilization, exhaust-gas treatment, blowdown are integrated in a compact reactor, similar One miniature water treatment system, available for going, oils in water removal, granulator is miscellaneous, suspended matter, organic matter, nitrogen nitrogen, surface-active The pollutants such as agent, coloration, stink, bacterial virus.The present invention can be additionally used in having water source but the occasion without tap water, such as field work After device purification, reactor is discharged again through micro-filtration or ultrafiltration, activated carbon adsorption for vehicle, campsite, surface water or underground water, you can Make the domestic water for meeting drinking water standard.
Description of the drawings
Fig. 1 is that the electro-catalysis Multifunctional water purifying device of the embodiment of the present invention 1 removes the internal structure signal after side wall three Figure.
Fig. 2 is the external structure schematic diagram of electro-catalysis Multifunctional water purifying device in Fig. 1.
Fig. 3 is the left view of Fig. 2.
Fig. 4 is the vertical view of Fig. 2.
Fig. 5 is that the electro-catalysis Multifunctional water purifying device of the embodiment of the present invention 2 removes the internal structure signal after side wall three Figure.
Fig. 6 is that the electro-catalysis Multifunctional water purifying device of the embodiment of the present invention 3 removes the internal structure signal after side wall three Figure.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to the accompanying drawings and embodiments, it is right The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, not For limiting the present invention.
Embodiment 1
Also referring to Fig. 1 to Fig. 4, shown product is a kind of electro-catalysis Multifunctional water purifying device of the embodiment of the present invention 1. Electro-catalysis Multifunctional water purifying device mainly includes reactor, can also set power supply box, power supply box can exterior side by side, such as install On the outside of reactor, power supply is provided for entire purifier, when purifier installs sensor when electronic devices, may also set up Controller runs entire purifier for controlling.
Reactor can set various openings or through-hole for purifying water source on reactor, quantity of each opening not by Limit, such as water inlet, water outlet, water level switch mouth, temperature sensor mouth, sewage draining exit, exhaust outlet, soil cleaning port, electro-catalysis pole plate group Part installing port, gas vent etc..Water inlet can install water inlet interface 1, and water outlet can install water outlet mouthpiece 9, and sewage draining exit can be installed Blowdown valve 5 or spare blowdown valve 6, exhaust outlet can install exhaust port 10, and water level switch mouth can install water level switch interface 8, temperature Spending sensor port can mounting temperature sensor, etc..
The inside of reactor forms several regions by multiple partition boards, and several regions from water inlet to water outlet according to The secondary runner for forming liquid communication.The multiple partition board include partition board 1, partition board 2 13, partition board 3 14, partition board 43, Partition board five (namely slip plate 4).
One end of partition board 1 is erect and is fixed on the bottom wall 16 of the reactor, the top of the other end and the reactor Wall 17 is opposite.One end of partition board 2 13 is erect and is fixed on the side of partition board 1, and the other end is first towards the side of the reactor The extension of wall 1 turns again to extend towards roof 17 and close to roof 17.The region parallel with bottom wall 16 opens up several on partition board 2 13 Recirculation hole one.One end of partition board 3 14 is erect and is fixed on roof 17, and the other end first extends towards bottom wall 16, then in partition board one 11 top turns to towards the side wall 2 19 close to the reactor and tilts extension, and extend to partition board 1 and side wall 2 19 it Between, it turns again to extend towards bottom wall 16 and close to bottom wall 16.Side wall 2 19 is oppositely arranged with side wall 1.
Buffering oil removal settling zone 20 is formed between partition board 2 13, side wall 1, bottom wall 16.Partition board 1, partition board 2 13 it Between form U-shaped runner 1, the section start of U-shaped runner 1 forms coarse filter area, is later commutating zone.Partition board 1, partition board three Electro-catalysis pole plate area 22 is formed between 14, several electro-catalysis pole plates 2 are installed in electro-catalysis pole plate area 22.Partition board 3 14, side wall two U-shaped runner 2 23 is formed between 19, the openend of U-shaped runner 2 23 forms the exhalant region communicated with the water outlet.
The electro-catalysis Multifunctional water purification method of electro-catalysis Multifunctional water purifying device is:The liquid of water inlet is first downwards via slow The precipitation filtering of oil removal settling zone 20 is rushed, then upwardly through one coarse filtration of recirculation hole, then flowed upward to whole in U-shaped runner 1 Stream is redirected into the catalysis reaction of electro-catalysis pole plate area 22, turns again to enter U-shaped runner 2 23, and lead in the exhalant region later Cross the water outlet water outlet.
One end of partition board 43 is erect and is fixed on roof 17, and the other end of partition board 43 first prolongs towards the rake of partition board 3 14 It stretches, is then turned in the top of 3 14 rake of partition board towards by proximal wall 2 19 and tilt extension, turned again to later towards side wall 2 19 It extends vertically and is fixed on side wall 2 19, the rake of partition board 43 opens up several recirculation holes two.More than partition board 43 inclines Inclined portion, partition board 43 can be horizontal, tilt, there is recirculation hole two in vertical three faces.
Partition board 43 is isolated by the exhalant region from U-shaped runner 2 23, and the runner of U-shaped runner 2 23 is made to become narrow, and Gas-liquid separation zone is formed in the openend of U-shaped runner 2 23.The liquid of U-shaped runner 2 23 by two refined filtration of recirculation hole, then Flow upward to the exhalant region, the gas vent is led in gas aggressiveness to the gas-liquid separation zone in U-shaped runner 2 23 again.
The electro-catalysis Multifunctional water purifying device may also include chimney filter structure, and the chimney filter structure is one end closing, another It holds as helicitic texture, generally hollow cylindrical, chimney filter of the tube wall with filter gap.Below the preferred 0.5mm width in gap.It should Chimney filter is by the end of thread and is welded on and surrounds water outlet and with new designs of threaded joints screw installation.
Several gas vents communicated with the inside reactor are opened up on roof 17, roof 17 is externally provided with and the gas vent The exhaust gas purification room 15 communicated, the gas in the reactor are discharged after being purified via exhaust gas purification room 15.When roof 17 On when offering several gas vents communicated with the inside reactor, the gas in the reactor is via exhaust gas purification room 15 It is discharged after purification.And when further including partition board 43 in the multiple partition board, the liquid of U-shaped runner 2 23 passes through the circulation Two refined filtration of hole, then the exhalant region is flowed upward to, the gas aggressiveness in U-shaped runner 2 23 to the gas-liquid separation zone leads to institute again State gas vent.Gas in the reactor is discharged after being purified via exhaust gas purification room 15 by exhaust outlet 10.
Slip plate 4 is located in buffering oil removal settling zone 20, and closes in the reactor and connect side wall 1, bottom wall simultaneously 16 bonding pad makes the heavy mud in buffering oil removal settling zone 20 be gathered between partition board 1 and slip plate 4.
In the present embodiment, on side wall 2 19 and in the lower section of water outlet setting water level switch interface 8.U-shaped runner 2 23 bottom end sets several temperature sensor interfaces 7, and temperature sensor interface 7 goes out for installing measurement electro-catalysis pole plate area 22 The temperature sensor of coolant-temperature gage.The position setting sewage draining exit of on bottom wall 16 and corresponding buffering oil removal settling zone 20 (can install blowdown Valve) and/or, on the bottom wall 16 and position in corresponding electro-catalysis pole plate area 22 sets sewage draining exit (can install spare blowdown valve).Bottom wall Sewage draining exit on 16 it is not necessary to, can be used as spare.
The inside reactor of electro-catalysis Multifunctional water purifying device is divided into buffering oil removal settling zone, coarse filter area, rectification by partition board Area, contact zone, air flotation zone, electro-catalysis pole plate area, reaction zone, fine filter area, gas-liquid separation zone, exhalant region, and partition board are by reactor Internal insulation forms two U-shaped runners.The identical buck of two U-shaped runners is by two U-shaped runners filtering in reactor, electricity Solution finally flows into fine filter area on the upside of the end of second U-shaped runner, enters exhalant region by fine filter area filtering, waits to be used.
Electro-catalysis Multifunctional water purifying device is compact-sized, and good appearance is succinct, is installed convenient for small space, by oil removal, sinks Shallow lake, air supporting, electro-catalysis electrolysis, absorption, filtering, sterilization, exhaust-gas treatment, blowdown are integrated in a compact reactor, similar One miniature water treatment system, available for going, oils in water removal, granulator is miscellaneous, suspended matter, organic matter, nitrogen nitrogen, surface-active The pollutants such as agent, coloration, stink, bacterial virus.
Buck enters reactor from the water inlet interface 1 at the top of device, initially enters buffering oil removal settling zone, is set in the region The strainer that filtering hole is 0.1mm~2mm, strainer conveniently fast disassembling are equipped with, and stainless steel can be used or plastic material is made Strainer (such as filter screen orifice plate or filtering silk screen), for filtering out granule foreign.Buck is buffering oil removal settling zone current stabilization, under To flow velocity less than after 1mm/s, the particles mechanical admixtures such as entrained animal and plant fat, oil slick, heavy silt are carried out Separation, grain size 100um more than oil droplets float to form oil slick, and heavy particle sinks to reactor bottom and forms bed mud.It is buffering The bottom of oil removal settling zone is equipped with blowdown valve 5, can exclude the timing of heavy mud, in order to which bed mud preferably is excluded reactor, so as to Inside reactor not contamination is maintained, the place far from blowdown valve 5 is equipped with slip plate 4 in buffering oil removal settling zone, convenient for that will sink Mud is arranged to blowdown valve 5, prevents heavy mud accumulation, and the design of slip plate 4 can preferably exclude heavy mud outside reactor.
Because the runner of inside reactor is U-shaped structure, the buck into buffering oil removal settling zone lower part flows up, this When, buck filters out the granule foreign that diameter is more than 1mm, buck continuation is up flowed, shape after impurity is filtered by recirculation hole one Into heavy mud.
Buck flows more steadily after commutating zone rectification, rises to contact zone.Buck is electrolysed with electro-catalysis pole plate area The a large amount of micro air bubbles moved upwards generated come into full contact with, and micro air bubble adheres to fine suspended particulate substance and oil droplet, and surface is lived Property hydrophobic contaminants, the aggregation of formation such as agent continuously rise to air flotation zone, become scum silica frost, so as to be isolated from buck It goes.
The buck for flowing through contact zone enters another U-shaped runner, and buck flow down enters electro-catalysis pole plate area.Electro-catalysis Pole plate area is made of (1~10mm) at a certain distance titanium-based noble metal coating web plate arranged or tablet, and particle is filled between plate Electrode (granular activated carbon or metallic particles or other granular materials with certain conductive capability, large specific surface area), together Form three-diemsnional electrode bed.As needed for power supply supplying electrode plate voltage, current density, it is organic in buck under electric field action Object, surfactant, colour former carry out electrochemical combustion, and hypochlorite, chlorine, chlorine dioxide generated with electrolysis etc. is living Property the strong oxide such as chlorine, hydroxyl radical free radical, ozone generate oxidative degradation, be degraded to a large amount of organic pollutions inorganic The substances such as salt, water, carbon dioxide, nitrogen.Simultaneously under the charge neutrality of electric field effect, the colloid in buck realizes de- steady, collision The gas stripping of high density micro air bubble formation for flocculating into bulky grain sediment or being generated with electrode plate brings air flotation zone into.Electricity The gas stripping that a large amount of micro air bubbles that pole plate area generates are formed is catalyzed, gas that on the one hand can be in stripping buck drives one Buck is divided to flow up, is contacted with incoming buck, and FLOTATION SEPARATION effect is fully completed in the air flotation zone of setting, reaches internal Circulating reflux effect.This effect is to carry out flow hour more prominent.
The buck in outflow pole plate area flows downward, and cross the partition board in electro-catalysis pole plate area, then flows up, at this point, The Strong oxdiative substance that electro-catalysis electrolysis generates continues to carry out oxidation reaction with the pollutant in water.Buck flows upwardly into refined filtration Area, the minimum gas that a small amount of micro air bubble and reaction that flow is carried out from electrode plate area generate, is completed de- in gas-liquid separation zone Fufen from.Water flows through recirculation hole two simultaneously, the particulate matter of remaining a small amount of more than grain size 0.3mm is intercepted, qualified water enters after filter Exhalant region waits for reuse.
The electrode plate groups of the present invention are a removable components of entirety, are conveniently replaceable.Shell is insulating polymeric material, is also prevented Only contacted with reactor conductive material housing.Electrode plate shell is to be machined with groove, realizes assembled installation.Moreover, electrode plate When being assembled into, there are four fixed columns for setting on reactor backboard, can play the role of keeper electrode plate group, prevent suspension from installing Battery plate plate group damage is shaken under external impacts.In the present embodiment, in electro-catalysis pole plate area 22 during assembling electrode plate groups, institute Electrode plate groups are stated with one comprising insulation crust, inside is electrode plate, and particle loaded electrode between pole plate, each side plate of shell is with groove The mode for the integrated member that rabbet assembly is formed is fixed on the panel of the reactor, and the electrode plate groups are packed into electro-catalysis pole During plate area 22, on the inside of the backboard of the reactor on be provided with four fixed columns for positioning the electrode plate groups, with the electricity Counterbore socket joint on the shell of pole plate group corresponds to.
The a small amount of gas and flowed with the gas that water inlet is brought into reactor head that air flotation zone, gas-liquid separation zone generate, and The gas purification of reactor head is arranged on through being separately positioned on the porous plate inflow at the top of air flotation zone and at the top of gas-liquid separation zone Area.The hole of the porous plate can be circular hole, or bar hole has ventilative, defoaming effect.
Active adsorbing material 11 is filled in gas purification area, activated carbon, extraordinary absorption resin etc., which may be used, has suction The material of the gas pollutants such as attached chlorine residue, peculiar smell, exhaust gas contact after entering the region with sorbing material 11, generate adsorption cleaning and make With clean gas is discharged into discharge areas by exhaust outlet 10.And penetrate the gas of ventilative orifice plate or bubble may carry it is tiny Water droplet under the contact adherency, aggtegation in sorbing material, can form big water droplet, air flotation zone gas-liquid separation is flowed back to from porous plate Area.
For preferably blowdown, sewage draining exit may be provided with two, sewage draining exit 5, and spare sewage draining exit 6 is U-shaped positioned at two respectively The lowermost end of runner leans on centre position.If it can only be incited somebody to action by first U-shaped runner bottom setting automatic blowdown valve of water inlet The gap of 1.5mm or so is outputed in Partition for realigning water flow bottom, can empty the water in the second U-shaped runner in emptying.And because seam Gap is small, will not form big short stream, can be rich in the buck of reaction zone is flowed into even if through the seam with outflow electro-catalysis pole plate area The buck mixing of Strong oxdiative substance, contained pollutant are degraded processing together.Or in two U-shaped port plates (Partition for realigning water flow) Upper setting inverted U pipe, the siphonage that water level reduces to be formed when being emptied using first U-shaped runner will be in second U-shaped runner Water exhaust.At this moment, the sewage draining exit of second U-shaped runner bottom can be opened in periodic maintenance, sediment cleaning.
The activated carbon after specially treated can be selected in the granule electrode of electro-catalysis pole plate area filling, has both granule electrode and suction Enclosure material act on, adsorbable removal partial organic substances, with coloration, peculiar smell, oils pollutant.And the strong oxygen of electrocatalytic reaction The pollutant oxidative degradation of activated carbon adsorption can be played activated carbon section palingenesis by change effect again.And the particle electricity of filling Pole can be substantially reduced electric field electrode resistance.Electrode plate assembly is Whole-dismountable structure, convenient for taking out clean and maintenance.If electrode applies Layer failure can also return factory and carry out coating reparation again.The granule electrode filled between plate by electrode plate surrounding it is removable it is anti-oxidant, The enclosure space that anti-corrosion, insulation board is formed is fixed, and prevents from being lost in, and after expiring in the service life, can be taken off electrode plate assembly, then will insulation Plate box cover is dismantled, and shakes out old granule electrode, is reloaded into new particle electrode, closes lid, and component loading reactor can be thrown again Enter work.The replacement granule electrode time does not exceed 15 minutes generally.After the sorbing material service life in gas purification area expires, it can twist Fall gas chamber cover board fixing bolt, remove cover board, dig out old sorbing material, then wiped clean inner wall, be packed into pretreated absorption Material.
Gas to prevent reactor is overflowed from water inlet, can be extended water inlet pipe, be stretched into 3~5cm under the liquid level of oil separation area, Play the role of fluid-tight.
For prevent for a long time without water inlet and electrode plate work always caused by water body heating, close to electrode plate position It puts, if electrode plate goes out the reaction zone set temperature sensor 7 of stream, if water temperature reaches setting value (generally 40 DEG C), electro-catalysis Electrode power-off is transferred to standby mode, and when water temperature is down to reset value (being usually 35 DEG C), control power supply is powered to electrode plate, Restart work.
The runner of whole device can be stainless steel welded composition, or integral die-cast is molded, preferably whole pressure Type casting moulding.The buffering oil removal settling zone of whole device, coarse filter area, commutating zone, contact zone, air flotation zone, electro-catalysis pole plate area, reaction Area is connected by flow sequence, forms two U-shaped runners.The whole runner of device is unobstructed, meet hydrodynamics grease, Solid-liquid, gas-liquid separation fluidised form direction, inside do not need to pipeline connection, are substantially reduced footprint, also improve the intensity of device And stability.
Apparatus of the present invention are directed to the water quality characteristics of buck, using the method for electrochemistry, in the direct oxidation of electro-catalysis electric field With indirect oxidation act under and electric field charge neutrality the effects that under, remove buck in LAS, organic matter, ammonia nitrogen, coloration;And it ties Close mechanical filter, gravitational settling, dissolved air flotation, removal mechanical particle sundries, grease oils, suspended particulate substance, so as to fulfill more The removal effect of kind pollutant.Apparatus of the present invention can be directly mounted under hand basin, and environmental impact factor is small, and buck is rapidly completed Purification greatly improves grey Water warfare, collects reuse efficiency, and water outlet can be back to the purposes such as toilet flushing, greening.
The present apparatus is suitable for removing the organic matter buck, ammonia nitrogen, coloration, bacterial virus, anion surfactant, moving The pollutants such as vegetable oil.Compared with existing medicament oxidation, coagulating sedimentation, coagulation air-float, Purification biotechnology, it can be mounted on Under hand basin or under closet basin or other available spaces have removal pollutant kind more, do not need to replace filter The advantages of material, processing speed is fast, and footprint is small, automatic running, management service facilitates.
Embodiment 2
Referring to Fig. 5, the electro-catalysis Multifunctional water purifying device of the present embodiment, and partition board 43 is not provided with, on functional effect Though it is also a kind of electro-catalysis Multifunctional water purifying device of energy reliability service unlike embodiment 1.
In the present embodiment, the buck that hand basin is collected first filters out large granular impurity through a point interior 2mm strainers, is then fed into Reactor.Reactor be sequentially completed buffering, oil removal, precipitation, coarse filtration, rectification, gas-liquid contact, scum silica frost separation, electrocatalytic reaction, Oxidative degradation, gas-liquid separation, fine filtering, purified water are flowed out from water outlet.
Buck in buffering area current stabilization, it is lower to flow velocity less than after 1mm/s, the oil slick such as entrained animal and plant fat, petroleum-type, The particles such as heavy silt mechanical admixture carries out Gravity Separation, and the oil droplet of more than grain size 100um floats to form oil slick, than great Particle sink to reactor bottom formed bed mud.Buck into buffering oil removal settling zone lower part is crossed oil separating plate and is transferred upwards Stream, at this point, buck first passes through coarse filtration plate, filters out the granule foreign more than 1mm.Flowing is continued up by the buck of coarse filtration plate, Contact zone is more steadily risen to after rectified area's rectification, a large amount of micro air bubbles moved upwards generated with electro-catalysis pole plate area It comes into full contact with, micro air bubble adheres to fine suspended particulate substance and the hydrophobic contaminants such as oil droplet, surfactant, the aggregation of formation Object continuously rises to air flotation zone, forms scum silica frost, so as to be separated from buck.And the buck for flowing into contact zone crosses commutating zone Enter electro-catalysis pole plate area after partition board.The titanium-based noble metal coating that electro-catalysis pole plate area is arranged by (1~10mm) at a certain distance Web plate or tablet form, and filled with granule electrode, (granular activated carbon or metallic particles are other with certain conductive energy between plate The granular materials of power, large specific surface area), three-diemsnional electrode bed is formed together.As voltage, the electric current needed for power supply supplying electrode plate Density, under electric field action, organic matter, surfactant, colour former in buck carry out electrochemical combustion, and are produced with electrolysis The strong oxide such as raw hypochlorite, chlorine, chlorine dioxide isoreactivity chlorine, hydroxyl radical free radical, ozone generates oxidative degradation, A large amount of organic pollutions is made to be degraded to the products such as inorganic salts, water, carbon dioxide, nitrogen.The charge neutrality effect of electric field simultaneously, will The colloid in buck is made to realize the high density micro air bubble de- steady, collision flocculation is generated into bulky grain sediment or with electrode plate The gas stripping of formation brings air flotation zone into.The gas stripping that a large amount of micro air bubbles that electrode plate area generates are formed, on the one hand can blow Gas in deliming water, and a part of buck can be driven to meet direction of flow flowing upwards, the molten gas recirculation water of microbubble is formed, with coming Buck contact is flowed, and FLOTATION SEPARATION effect is fully completed in the air flotation zone of setting, reaches internal circulating reflux effect.This effect Coming, flow hour is more prominent.
The buck in outflow pole plate area flows downward, and cross pole plate and separate plate, then flows up, at this point, electro-catalysis is electric The Strong oxdiative substance that solution generates continues to carry out oxidation reaction with the pollutant in water.Buck flows upwardly into fine filter area, flow The minimum gas that a small amount of micro air bubble and reaction carried out from electrode plate area generates, desorption separation is completed in gas-liquid separation zone. Water phase flows through refined filtration plate tube, the particulate matter of remaining a small amount of more than grain size 0.3mm is intercepted, qualified water is flowed out through water outlet after filter Reactor.
The a small amount of gas and flowed with the gas that water inlet is brought into reactor head that air flotation zone, gas-liquid separation zone generate, and The gas purification of reactor head is arranged on through being separately positioned on the porous plate inflow at the top of air flotation zone and at the top of gas-liquid separation zone Area.The hole of the porous plate can be circular hole, or bar hole has ventilative, defoaming effect.
Gas purification is filled with active adsorbing material in area, and activated carbon, extraordinary absorption resin etc., which may be used, has absorption The material of the gas pollutants such as chlorine residue, peculiar smell, exhaust gas contact after entering the region with the sorbing material with very big specific surface area, Adsorption cleaning effect is generated, clean gas is discharged into discharge areas by exhaust outlet.And penetrate the gas or bubble of ventilating porous plate Small water droplet may be carried, under the contact adherency, aggtegation in sorbing material, big water droplet can be formed, flowed back to from porous plate Air flotation zone gas-liquid separation zone.
Buffer the oil slick of oil removal settling zone, heavy mud, the impurity intercepted by coarse filtration plate, the scum silica frost of air flotation zone, the interception of refined filtration plate Impurity can by the sewage draining exit of reactor bottom discharge reactor, so as to maintain inside reactor not contamination.And it is precipitating Position of the area far from sewage draining exit is provided with slip plate, can will be heavy muddy and slippery to sewage draining exit, convenient for displacer outside.Reactor blowing time Or it empties or is emptied according to water pollution degree timing is carried out daily.Sewage draining exit can install manually-operated gate by artificial timing blowdown or dress If automatic valve is by the electrical program control of sewage disposal time.
Because the pollutant that coarse filtration plate and refined filtration plate intercept leans on sewage draining exit side, and be deviation upward flow filtration, this Sample is convenient for pollutant during blowdown to be taken away with lower to flow, and played during blowdown by the reverse flow of filter plate fine gap and wash away filter Plate tube acts on, and keeps the excessively logical area of filter plate tube, prevents from blocking.The pollutant of richness product is not only discharged reaction by the blowdown of timing Device, also prevents the enrichment of hardness components in water, effectively slows down and forms calcium scale on filter plate, electro-catalysis pole plate.Also, electro-catalysis Power supply has the function of frequently pole-reversing, and positive and negative property polar period alternating effectively prevent cathode to work long hours and adsorbs dirt, increase The phenomenon that electric field internal resistance.Principle innovation with this configuration can greatly prolong the scheduled maintenance period of reactor.
Sewage draining exit is typically provided with two, leans on centre position positioned at the lowermost end of two U-shaped runners respectively.If only by into During first U-shaped runner bottom setting automatic blowdown valve at the mouth of a river, Partition for realigning water flow bottom can be outputed to the gap of 1.5mm or so, The water in the second U-shaped runner can be emptied in emptying.And because the gap is small, big short stream will not be formed, even if through should The buck that seam flows into electrode plate reaction zone also can be with outflow electrode plate area, the buck mixing rich in Strong oxdiative substance, contained pollution Object is degraded processing together.Or inverted U pipe is set on two U-shaped port plates (Partition for realigning water flow), utilize first U-shaped stream Water level reduces the siphonage to be formed and exhausts the water in second U-shaped runner during evacuating pipeline.At this moment, second U-shaped runner bottom The sewage draining exit in portion can be opened in periodic maintenance, sediment cleaning.
If the granule electrode of electro-catalysis pole plate area filling selects the activated carbon after specially treated, granule electrode and suction are had both Enclosure material acts on, adsorbable removal partial organic substances, coloration, peculiar smell, oil pollutant, and the strong oxidation of electrocatalytic reaction The pollutant oxidative degradation of activated carbon adsorption can be played activated carbon section palingenesis again.The granule electrode of filling can be significantly Electric field electrode resistance is reduced, and passes through control.
Electrode plate assembly is Whole-dismountable structure, convenient for taking out clean and maintenance.If electrode coating fail, can also return factory into Row coating reparation again.The granule electrode filled between plate is made of removable anti-oxidant, the anti-corrosion, insulation board of electrode plate surrounding Enclosure space is fixed, and prevents from being lost in, and after expiring in the service life, be can be taken off electrode plate assembly, then insulation board box cover is dismantled, is shaked out old Granule electrode is reloaded into new particle electrode, closes lid, and component loading reactor can be devoted oneself to work again.Replace particle electricity The pole time does not exceed 15 minutes generally.After the sorbing material service life in gas purification area expires, gas chamber cover board can be twisted off and fix spiral shell Bolt removes cover board, digs out old sorbing material, then wiped clean inner wall, is packed into pretreated sorbing material.
Gas to prevent reactor is overflowed from water inlet, can be extended water inlet pipe, be stretched into 3~5cm under the liquid level of oil separation area, Play the role of fluid-tight.
For prevent for a long time without water inlet and electrode plate work always caused by water body heating, close to electrode plate position It puts, if electrode plate goes out the reaction zone set temperature sensor of stream, temperature signal is passed to control power supply box, if water temperature reaches setting Value (generally 40 DEG C), then electro catalytic electrode power-off is transferred to standby mode, when water temperature is down to reset value (being usually 35 DEG C) When, control power supply is powered to electrode plate, restarts work.
Electrode plate is still powered work during to prevent reactor from emptying, and the position of electrode plate, such as refined filtration are higher than in reactor Area sets liquid-level switch electrode, when water level is less than the electrode position, control power supply is enabled to be powered off to electrode plate, device is transferred to standby Or shutdown status.When water level, which rises to, starts working electrode position, device energization work.
Supply unit has the accumulation electro-catalysis pole plate working time, when reaching setting value, is carried by acousto-optic or display screen The administrative staff that wake up carry out maintaining.Welding or monoblock cast forming integrally can be used in reactor, and entirely dismantled and assembled match can also be used Structure.Stainless steel, polymer plastic etc. may be selected in material.
For ease of processing, internal zone dividing partition board, filter plate can be processed one in the position that reactor front and back panel contacts The communication of depthkeeping degree, convenient for positioning welding or direct compression fit.Oil removal, precipitation, air flotation zone channel size can be according to stokes This formula, which calculates, to be determined.
The device can be additionally used in having water source but the occasion without tap water, such as field operation vehicle, campsite, surface water or underground water After device purification, reactor is discharged again through micro-filtration or ultrafiltration, activated carbon adsorption, you can makes the life for meeting drinking water standard Apply flexibly water.
Embodiment 3
Referring to Fig. 6, the electro-catalysis Multifunctional water purifying device of the present embodiment, fine filter area can be used be fixed on reactor before The refined filtration plate of rear panel uses threaded end, screws the refined filtration pipe for being installed on water outlet position.It is processed on refined filtration plate The hole of below 0.5mm or item seam;Refined filtration Guan Zeyong wedge shape stainless (steel) wire items, which roll, to be welded, and smooth in appearance welcomes stream on one side Direction prevents from intercepting impurity adherency.When refined filtration plate generates clogging, the cover board that can will remove contamination is dismantled, with high pressure water flow or brush Son removes the dirt of filter opening/seam.According to refined filtration blockage when, the cover board that also will can first remove contamination is dismantled, and then backs out refined filtration pipe, Carry out exterior washings.It cleans out and resets installation again.If reactor people structure or oils accumulation pollution, can in periodic maintenance, Dirty object is removed to reactor injection acid water or injection heat alkali liquid removes organic burs such as oils.Certainly, refined filtration plate, refined filtration The stainless steel cloth of identical pore size filter, plastic mesh plate can also be used in plate tube.
Embodiment 4
In the present embodiment, it is still powered work for electrode plate when preventing the reactor from emptying, electrode plate is higher than in reactor Position, if fine filter area set liquid-level switch electrode, when water level be less than the electrode position when, enable control power supply break to electrode plate Electricity, device are transferred to standby or shutdown status.When water level, which rises to, starts working electrode position, device energization work.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of electro-catalysis Multifunctional water purifying device, it is characterised in that:It includes a reactor, if the reactor is equipped with Dry water inlet, several water outlets;The inside of the reactor forms several regions by multiple partition boards, and several regions from The water inlet sequentially forms the runner of liquid communication to the water outlet;
Include in the multiple partition board:
Partition board one (12), one end setting are fixed on the bottom wall (16) of the reactor, the other end and the reactor Roof (17) is opposite;
Partition board two (13), one end setting are fixed on the side of partition board one (12), and the other end is first towards the side of the reactor Wall one (18) extension turns again to towards roof (17) extend and close to roof (17);The area parallel with bottom wall (16) on partition board two (13) Domain opens up several recirculation holes one;
Partition board three (14), one end setting are fixed on roof (17), and the other end first extends towards bottom wall (16), then in partition board The top of one (11) turns to towards the side wall two (19) close to the reactor and tilts extension, and extend to partition board one (11) and side wall Between two (19), turn again to towards bottom wall (16) extend and close to bottom wall (16);Side wall two (19) is oppositely arranged with side wall one (18);
Wherein, buffering oil removal settling zone (20) is formed between partition board two (13), side wall one (18), bottom wall (16);Partition board one (12), U-shaped runner one (21) is formed between partition board two (13), the section start of U-shaped runner one (21) forms coarse filter area, is later commutating zone; Electro-catalysis pole plate area (22) are formed between partition board one (12), partition board three (14), several electricity of installation are urged in electro-catalysis pole plate area (22) Change pole plate (2);U-shaped runner two (23), the openend shape of U-shaped runner two (23) are formed between partition board three (14), side wall two (19) Into the exhalant region communicated with the water outlet.
2. electro-catalysis Multifunctional water purifying device as described in claim 1, it is characterised in that:Opened up on roof (17) with it is described anti- Several gas vents communicated inside device are answered, roof (17) is externally provided with the exhaust gas purification room (15) communicated with the gas vent, Gas in the reactor is discharged after being purified via exhaust gas purification room (15).
3. electro-catalysis Multifunctional water purifying device as claimed in claim 2, it is characterised in that:It is further included in the multiple partition board Partition board four (3), one end of partition board four (3), which is erect, to be fixed on roof (17), and the other end of partition board four (3) is first towards partition board three (14) Rake extension, then the top of partition board three (14) rake turn to towards by proximal wall two (19) tilt extension, Zhi Houzai Steering is extended vertically towards side wall two (19) and is fixed on side wall two (19), and partition board four (3) opens up several recirculation holes two;Partition board four (3) exhalant region from U-shaped runner two (23) is isolated, and the runner of U-shaped runner two (23) is made to become narrow, and in U-shaped stream The openend in road two (23) forms gas-liquid separation zone;The liquid of U-shaped runner two (23) is by two refined filtration of recirculation hole, then upwards It flow to the exhalant region, the gas vent is led in gas aggressiveness to the gas-liquid separation zone in U-shaped runner two (23) again.
4. electro-catalysis Multifunctional water purifying device as claimed in claim 2, it is characterised in that:The electro-catalysis Multifunctional water purification dress It puts and further includes chimney filter structure, the chimney filter structure is one end closing, and the other end is helicitic texture, generally hollow cylindrical, pipe Cornice has the chimney filter of filter gap;The chimney filter is by helicitic texture and is welded on being revolved with new designs of threaded joints for the encirclement water outlet Tight installation.
5. electro-catalysis Multifunctional water purifying device as claimed in claim 2, it is characterised in that:Partition board two (13) is than partition board one (12) More to make to form scum silica frost air flotation zone between partition board two (13), partition board three (14), the gas in the reactor close to roof (17) The gas vent is led in aggressiveness to the scum silica frost air flotation zone.
6. electro-catalysis Multifunctional water purifying device as claimed in claim 2, it is characterised in that:Exhaust gas purification room (15) setting exhaust Mouthful (10), the gas in the reactor are discharged after being purified via exhaust gas purification room (15) by exhaust outlet (10).
7. electro-catalysis Multifunctional water purifying device as described in claim 1, it is characterised in that:It is further included in the multiple partition board Slip plate (4), slip plate (4) are closed in the reactor in buffering oil removal settling zone (20) and connect side wall one simultaneously (18), the bonding pad of bottom wall (16) makes the heavy mud in buffering oil removal settling zone (20) be gathered in partition board one (12) and slip plate (4) Between.
8. electro-catalysis Multifunctional water purifying device as described in claim 1, it is characterised in that:The bottom end of U-shaped runner two (23) is set Several temperature sensor interfaces (7) are put, temperature sensor interface (7) measures electro-catalysis pole plate area (22) leaving water temperature for installing Temperature sensor.
9. a kind of electro-catalysis of electro-catalysis Multifunctional water purifying device as claimed in any of claims 1 to 8 in one of claims is multi-functional net Water method, it is characterised in that:The electro-catalysis Multifunctional water purification method is:
The liquid of the water inlet is first downwards via buffering oil removal settling zone (20) precipitation filtering, then upwardly through the recirculation hole One coarse filtration, then the interior rectification of U-shaped runner one (21) is flowed upward to, it is redirected into electro-catalysis pole plate area (22) catalysis reaction later, then U-shaped runner two (23) is redirected into, and is discharged in the exhalant region by the water outlet;
When offering several gas vents communicated with the inside reactor on roof (17), the gas warp in the reactor It is discharged after being purified by exhaust gas purification room (15);And when further including partition board four (3) in the multiple partition board, U-shaped runner two (23) liquid is by two refined filtration of recirculation hole, then flows upward to the exhalant region, the gas aggressiveness in U-shaped runner two (23) Lead to the gas vent again to the gas-liquid separation zone.
10. electro-catalysis Multifunctional water purification method as claimed in claim 9, it is characterised in that:Interior group of electro-catalysis pole plate area (22) During loading electrode plate group, for the electrode plate groups with one comprising insulation crust, inside is electrode plate, particle loaded electrode between pole plate, Each side plate of shell is fixed in a manner of the integrated member that groove rabbet assembly is formed on the panel of the reactor, the electrode When plate is assembled into electro-catalysis pole plate area (22), on the inside of the backboard of the reactor on be provided with the four of the positioning electrode plate groups A fixed column, it is corresponding with the counterbore socket joint on the shell of the electrode plate groups.
CN201810168512.7A 2018-02-28 2018-02-28 Electro-catalysis multifunctional water purifying device and electro-catalysis multifunctional water purifying method thereof Active CN108178251B (en)

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