CN108166283A - A kind of reactive dye discharge printing process - Google Patents

A kind of reactive dye discharge printing process Download PDF

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Publication number
CN108166283A
CN108166283A CN201711462951.0A CN201711462951A CN108166283A CN 108166283 A CN108166283 A CN 108166283A CN 201711462951 A CN201711462951 A CN 201711462951A CN 108166283 A CN108166283 A CN 108166283A
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CN
China
Prior art keywords
reactive dye
dosage
printing process
sodium
discharge printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711462951.0A
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Chinese (zh)
Inventor
蔡连杰
曹文斌
杨中兰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongying Annuoqi Textile Material Co., Ltd.
SHANGHAI ANOKY DIGITAL TECHNOLOGY CO., LTD.
Shanghai Shangyu Digital Technology Co., Ltd.
Yantai Anoky Fine Chemical Co., Ltd.
Yantai Shangyu Digital Technology Co., Ltd.
Shanghai Anoky Group Co Ltd
Original Assignee
DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd
Shanghai Anoky Digital Technology Co Ltd
Yantai Anoky Fine Chemical Co Ltd
Shanghai Anoky Group Co Ltd
Jiangsu Anoky Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd, Shanghai Anoky Digital Technology Co Ltd, Yantai Anoky Fine Chemical Co Ltd, Shanghai Anoky Group Co Ltd, Jiangsu Anoky Chemicals Co Ltd filed Critical DONGYING ANNUOQI TEXTILE MATERIAL Co Ltd
Priority to CN201711462951.0A priority Critical patent/CN108166283A/en
Publication of CN108166283A publication Critical patent/CN108166283A/en
Withdrawn legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15Locally discharging the dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67375Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341 with sulfur-containing anions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/66Natural or regenerated cellulose using reactive dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of reactive dye discharge printing process.Include the following steps successively:Bottom dyeing, 80 DEG C of drying, discharge printing, drying, decatize, washing are soaped, are washed;Background color dye liquor includes following components:Vinyl-sulfone reactive dyes 0~5%, sodium trichloroacetate and/or sodium bicarbonate 2~4%, reservehao S are 0.5~1.5%, and urea 5~8% and surplus are water;It pulls out printing paste and includes following components:One chloro-s-triazine reactive dye 0~5%, sodium sulfite 2~5%, sodium bicarbonate 0~4%, reservehao S are 0.5~1.5%, urea 0~10%, and sodium alginate paste 45~55% and surplus are water.The discharge printing process of the present invention, has that dawn whiteness is high, can dawn background color it is complete, the advantages that technological process is short, energy conservation and environmental protection;Conventional steaming box can be used during the technique decatize, without using closed reduction steaming box, process odorlessness and formaldehydeless release.

Description

A kind of reactive dye discharge printing process
Technical field
The present invention relates to a kind of reactive dye discharge printing process.
Background technology
Discharge printing, also referred to as discharge printing are that one kind chemically makes its background color dyestuff local failure on dyeing and weaving object, disappears Color, so as to print again decorative pattern printing technology, in the printing technology, print white decorative pattern calls dawn, printing to obtain colored flower Line is known as pulling color, and the chemical agent that destruction background color dyestuff is allowed to colour killing calls discharging agent.
It is that the chromophoric group of background color is destroyed using the strong reducing property of rongalite that regular activated dyestuff, which pulls out print technique, is entered Color uses the reducing dye of resistance to reducing agent.Regular activated dyestuff pulls out print technique and is generally divided into neutral discharge and alkaline discharge, the two Difference lies in whether alkaline agent is added, the selection of alkaline agent can be caustic soda (30%36 ° of Be, soda ash or potassium carbonate;The selecting party of dyestuff Face, the dyestuff of general Vinyl-Sulfone Type using its not alkali resistance, under the conditions of neutral or alkaline reduction can dawn, a chloro-s-triazine or The dyestuff of dichloro s-triazine largely can dawn under alkaline condition, and pulled out to the greatest extent using anthraquinone as the dyestuff of parent is then more difficult, such as Gorgeous orchid KN-R (No. 19 gorgeous orchids), in addition, the also more difficult dawn of the bright blue 21 isoreactivity dyestuff containing copper phthalein blueness structure, leads to that bottom can be pulled out The shortcomings that color chromatography is not complete.In addition, regular activated dyestuff is pulled out in print technique, enter also unstable there are reducing dye color development during color It is fixed, high to reduction steaming box seal requirement, smell is big, Form aldehyde release, technological process length (need stream of washing and soap twice Journey, sewage quantity are big) etc. techniques and environmental protection aspect the shortcomings that.
Invention content
The technical problems to be solved by the invention are to overcome regular activated dyestuff in the prior art to pull out in print technique, bright blue Reducing dye color development is unstable when dyestuff and brilliant blue dye cause dawn bad and enter color, reduction steaming box seal is wanted The defects of asking big height, smell, Form aldehyde release, long technological process, provides a kind of reactive dye discharge printing process.The discharge prints Flower process compared to former conventional discharge technique, has that dawn whiteness is high, can dawn background color it is complete, technological process is short, energy conservation and environmental protection etc. Advantage.In addition, conventional steaming box can be used during the discharge printing process decatize, without using closed reduction steaming box, process Odorlessness and formaldehydeless release.
The present invention solves above-mentioned technical problem by the following technical programs.
The present invention provides a kind of reactive dye discharge printing process, include the following steps successively:Bottom dyeing, first Secondary drying, discharge printing, second of drying, decatize, first wash are soaped, second wash, you can;
Wherein, in the technique of the bottom dyeing, the background color dye liquor of use includes following components:Vinyl-sulfone reactive dyes 0~5%, sodium trichloroacetate and/or sodium bicarbonate (i.e. sodium bicarbonate) 2~4%, reservehao S dosage are 0.5~1.5%, urea 5 ~8% and surplus be water, above-mentioned percentage is the mass percent that each component is respectively relative to the background color dye liquor total amount;
The temperature of the first time drying is less than 80 DEG C;
In the technique of the discharge printing, the printing paste of pulling out of use includes following components:One chloro-s-triazine reactive dye 0~ 5%, sodium sulfite 2~5%, sodium bicarbonate 0~4%, reservehao S dosage is 0.5~1.5%, urea 0~10%, alginic acid Sodium paste 45~55% and surplus are water, and above-mentioned percentage is that each component is respectively relative to the quality percentage for pulling out printing paste total amount Than.
In the present invention, suitable for the reactive dye discharge printing process raw material can be this field routine embryo cloth, one As be white, can be the woven fabric of the cellulose fibres such as cotton, fiber crops, synthetic cotton manufacture.
In the present invention, the operation of the bottom dyeing and condition can be reactive dye discharge printing process routine operation with Condition, generally using padding process.After the bottom dyeing, embryo cloth liquid carrying rate is generally 60~80%.In practical printer In skill, the depth that the vinyl-sulfone reactive dyes can reach as required adjusts dosage, and dosage is higher, and dyeing is deeper.
In the background color dye liquor, the type of the vinyl-sulfone reactive dyes can be the vinyl-sulfone reactive of this field routine The DR series dyes of the type of dyestuff, preferably its group limited company of Town in Shanghai promise are more preferably golden yellow DR, red DR, bright blue DR, gorgeous indigo plant DR or dark blue DR.The dosage of the vinyl-sulfone reactive dyes is preferably 2~4%.
In the background color dye liquor, the dosage of the sodium trichloroacetate or sodium bicarbonate is preferably 3%.
In the background color dye liquor, the dosage of the reservehao S is preferably 1%.
In the background color dye liquor, the dosage of the urea is preferably 6%.
In the present invention, to ensure that the background color dyestuff lacks fixation as possible, the temperature of the first time drying need to ensure not surpass Cross 80 DEG C.If the temperature of the first time drying, more than 80 DEG C, sodium trichloroacetate or sodium bicarbonate can decompose release alkaline agent, background color dye Liquid can be anchored at partly on cloth under alkaline condition, and can not subsequently be pulled out the sodium sulfite dawn in printing paste.The first time The temperature of drying is preferably 70~80 DEG C.
In the present invention, the operation of the discharge printing and condition can be reactive dye discharge printing process routine operation with Condition.
In the present invention, if according to common sense in the field it is found that the chloro-s-triazine reactive dye do not add, for dawn; If addition, to print to obtain chromatic pattern, i.e. pulling color.
Described to pull out in printing paste, the type of the chloro-s-triazine reactive dye can be the chloro-s-triazine work of this field routine The p-type dyestuff of the type, preferably its group limited company of Town in Shanghai promise of property dyestuff, is more preferably gorgeous indigo plant P-3R, gold Yellow P-2RN or red P-4BH.The dosage of the one chloro-s-triazine reactive dye is preferably 0~2%.
Described to pull out in printing paste, the dosage of the sodium sulfite is preferably 3~4%.
Described to pull out in printing paste, the dosage of the sodium bicarbonate is preferably 3%.
Described to pull out in printing paste, the dosage of the reservehao S is preferably 1%.
Described to pull out in printing paste, the dosage of the urea is preferably 6%.
Described to pull out in printing paste, the dosage of the sodium alginate paste is preferably 50%.The sodium alginate paste is preferably 4 ~6wt% sodium alginates are dissolved in gained in 94~96wt% water.
In the present invention, the operation of second of drying and condition can be the operation of reactive dye discharge printing process routine And condition.The temperature of second of drying is preferably 95~105 DEG C, is more preferably 100 DEG C.
In the present invention, the operation of the decatize and condition can be operation and the item of reactive dye discharge printing process routine Part, the condition of the decatize are preferably:100~105 DEG C of temperature, 6~10min of time;It is more preferably 102 DEG C of temperature, the time 8min.Conventional steaming box can be used during the decatize, without using closed reduction steaming box.
In the present invention, the first wash, it is described soap, the operation of the second wash and condition can be activity dye Expect operation and the condition of discharge printing process routine.
On the basis of common knowledge of the art, above-mentioned each optimum condition can be combined arbitrarily to get each preferable reality of the present invention Example.
The reagents and materials used in the present invention are commercially available.
The positive effect of the present invention is:
The reactive dye discharge printing process of the present invention compared to former conventional discharge technique, has dawn whiteness height, can dawn The advantages that background color is complete, and technological process is short, energy conservation and environmental protection.In addition, conventional steaming box can be used during the discharge printing process decatize, Without using closed reduction steaming box, process odorlessness and formaldehydeless release.
Specific embodiment
It is further illustrated the present invention below by the mode of embodiment, but does not therefore limit the present invention to the reality It applies among a range.Test method without specific conditions in the following example, according to conventional methods and conditions or according to quotient Product specification selects.
Dyestuff employed in embodiment and comparative example is purchased from its group limited company of Town in Shanghai promise;Sodium alginate Paste is that 5wt% sodium alginates are dissolved in gained in 95wt% water;Used white embryo cloth can be the fibers such as cotton, fiber crops, synthetic cotton The woven fabric or looped fabric of cellulose fiber manufacture.
Embodiment 1~15
Reactive dye discharge printing process includes the following steps:
It by white embryo cloth successively through bottom dyeing, dries for the first time, discharge printing, second of drying, decatize, first time water It washes, soaps, second wash, you can;
Wherein, bottom dyeing passes through padding process;The temperature of drying is 70~80 DEG C for the first time;The temperature of second of drying It is 100 DEG C;The condition of decatize is:102 DEG C of temperature, time 8min;First wash is soaped, the operation of second wash and item Part is operation and the condition of reactive dye discharge printing process routine.
In background color formula for dye liquor, in embodiment 1~15, amount of urea is 6%, and reservehao S dosage is 1%, surplus For water.Other material varieties and dosage are as shown in table 1.In table 1, in background color formula for dye liquor, each percentage is each component difference Relative to the mass percent of background color dye liquor total amount.
It pulls out in printing paste formula, Examples 1 to 10 dawn amount of urea is 0%, and sodium bicarbonate (sodium bicarbonate) dosage is 0%;It is 6% that 11~15 color of embodiment, which pulls out amount of urea, and sodium bicarbonate (sodium bicarbonate) dosage is 3%.Embodiment 1~15 In, it is 1% to pull out reservehao S dosage in printing paste, and 5% sodium alginate paste dosage is 50%, and surplus is water.Other material varieties And dosage is as shown in table 1.In table 1, pull out in printing paste formula, each percentage is the matter that each component is respectively relative to pull out printing paste total amount Measure percentage.
Table 1
Comparative example 1
Comparative example 1 is pulled out in printing paste, and the dosage of sodium sulfite is 1%.In addition to the dosage of sodium sulfite has difference, Qi Tayuan Expect that the conditions such as type, amounts of components and printing technology are same as in Example 10.
Comparative example 2
In the printing technology of comparative example 2, the temperature of drying is 100 DEG C for the first time.Except first time, the temperature of drying has difference Outside, the conditions such as other raw material types, amounts of components and printing technology are same as in Example 10.
Comparative example 3
Comparative example 3 is pulled out in printing paste, and the dosage of sodium sulfite is 6%.In addition to the dosage of sodium sulfite has difference, Qi Tayuan Expect that the conditions such as type, amounts of components and printing technology are identical with embodiment 15.
Effect example
Examples 1 to 10, the dawn effect of comparative example 1~2 and standard staining gray card (ISO 105/A03) are commented Grade, the results are shown in Table 2.Wherein, flower pattern fineness is judged by estimating.
Table 2
As known from Table 2, the reactive dye discharge printing process of Examples 1 to 10 has vinyl-sulfone reactive dyes preferably Dawn effect, can dawn background color it is complete.Comparative example 1 is relatively low because pulling out ink sodium sulfite dosage, leads to not fully pull out most bottom Color dyestuff.Comparative example 2 causes ground-color portion fixation to cause dawn ineffective because padding background color post-baking temperature higher than 80 DEG C.
The reactive dye discharge printing process of embodiment 11~15 can produce the fine high-grade discharge printing production of various decorative patterns Product improve added value of product.
The reactive dye discharge printing process of embodiment 11~15 can produce the fine high-grade discharge printing production of various decorative patterns Product can improve added value of product, and product items color fastness can meet the requirement of general textile, as shown in table 3.Wherein, The testing standard of wear resistance is ISO 105X12;The testing standard of fastness to perspiration is 105 E04 of ISO;The survey of soaping fastness Test-object standard is 105 C03 of ISO.
Table 3
As shown in Table 3, in comparative example 3 when pulling out ink sodium sulfite excess, can also have to flower pattern periphery background color certain broken Bad effect, leads to white circle occur, reduces product quality, therefore, the used in amounts for pulling out ink controls a certain range.

Claims (10)

1. a kind of reactive dye discharge printing process, which is characterized in that it includes the following steps successively:Bottom dyeing, for the first time Drying, discharge printing, second of drying, decatize, first wash are soaped, second wash, you can;
Wherein, in the technique of bottom dyeing, the background color dye liquor of use includes following components:Vinyl-sulfone reactive dyes 0~5%, Sodium trichloroacetate and/or sodium bicarbonate 2~4%, reservehao S dosage are 0.5~1.5%, and urea 5~8% and surplus are water, on It is the mass percent that each component is respectively relative to background color dye liquor total amount to state percentage;
The temperature of the first time drying is less than 80 DEG C;
In the technique of discharge printing, the printing paste of pulling out of use includes following components:One chloro-s-triazine reactive dye 0~5%, sulfurous acid Sodium 2~5%, sodium bicarbonate 0~4%, reservehao S dosage are 0.5~1.5%, urea 0~10%, sodium alginate paste 45~ 55% and surplus be water, above-mentioned percentage is the mass percent that each component is respectively relative to pull out printing paste total amount.
2. reactive dye discharge printing process as described in claim 1, which is characterized in that suitable for the reactive dye discharge Woven fabric of the raw material of printing technology for the manufacture of the cellulose fibres such as cotton, fiber crops, synthetic cotton;
And/or the technique of the bottom dyeing is padding process.
3. reactive dye discharge printing process as described in claim 1, which is characterized in that in the background color dye liquor, the second The type of alkene sulfone type reactive dye is the DR series dyes of its group limited company of Town in Shanghai promise.
4. reactive dye discharge printing process as claimed in claim 3, which is characterized in that the vinyl-sulfone reactive dyes Type is golden yellow DR, red DR, bright blue DR, gorgeous indigo plant DR or dark blue DR.
5. reactive dye discharge printing process as described in claim 1, which is characterized in that in the background color dye liquor, the second The dosage of alkene sulfone type reactive dye is 2~4%;
In the background color dye liquor, the dosage of the sodium trichloroacetate or sodium bicarbonate is 3%;
In the background color dye liquor, the dosage of the reservehao S is 1%;
And/or in the background color dye liquor, the dosage of the urea is 6%.
6. reactive dye discharge printing process as described in claim 1, which is characterized in that first time temperature of drying is 70~80 DEG C.
7. reactive dye discharge printing process as described in claim 1, which is characterized in that described to pull out in printing paste a, chlorine P-type dyestuff of the type of s-triazine reactive dye for its group limited company of Town in Shanghai promise, preferably gorgeous indigo plant P-3R, gold Yellow P-2RN or red P-4BH.
8. reactive dye discharge printing process as described in claim 1, which is characterized in that the chloro-s-triazine reactive dye Dosage be 0~2%;
Described to pull out in printing paste, the use of the sodium sulfite is 3~4%;
Described to pull out in printing paste, the dosage of the sodium bicarbonate is 3%;
Described to pull out in printing paste, the dosage of the reservehao S is 1%;
Described to pull out in printing paste, the dosage of the urea is 6%;
And/or it is described pull out in printing paste, the dosage of the sodium alginate paste is 50%;The sodium alginate paste is preferably 4~ 6wt% sodium alginates are dissolved in gained in 94~96wt% water.
9. reactive dye discharge printing process as described in claim 1, which is characterized in that the temperature of second drying is 95~105 DEG C;
And/or the condition of the decatize is:100~105 DEG C of temperature, 6~10min of time.
10. reactive dye discharge printing process as claimed in claim 9, which is characterized in that the temperature of second of drying It is 100 DEG C;
And/or the condition of the decatize is:102 DEG C of temperature, time 8min.
CN201711462951.0A 2017-12-28 2017-12-28 A kind of reactive dye discharge printing process Withdrawn CN108166283A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110004735A (en) * 2019-03-01 2019-07-12 安徽职业技术学院 A kind of ground colour dyestuff and the technique using ground colour dyestuff progress discharge printing
CN110965366A (en) * 2019-12-24 2020-04-07 华纺股份有限公司 Sodium sulfite anti-printing paste recycling method

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Publication number Priority date Publication date Assignee Title
JPH0782674A (en) * 1993-09-13 1995-03-28 Daido Maruta Senko Kk Printing of textile product containing acetate and cellulose
JPH08291480A (en) * 1995-04-19 1996-11-05 Kanebo Ltd Method for printing on fiber structure
CN1687521A (en) * 2005-03-21 2005-10-26 浙江理工大学 Printing discharge dyeing paste for coating material to discharge dye silk broadcloth, and discharge printing technique of extracting activity of coating material
CN102409556A (en) * 2011-09-20 2012-04-11 宁波申洲针织有限公司 Method for preventing contrast color of reactive print color

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0782674A (en) * 1993-09-13 1995-03-28 Daido Maruta Senko Kk Printing of textile product containing acetate and cellulose
JPH08291480A (en) * 1995-04-19 1996-11-05 Kanebo Ltd Method for printing on fiber structure
CN1687521A (en) * 2005-03-21 2005-10-26 浙江理工大学 Printing discharge dyeing paste for coating material to discharge dye silk broadcloth, and discharge printing technique of extracting activity of coating material
CN102409556A (en) * 2011-09-20 2012-04-11 宁波申洲针织有限公司 Method for preventing contrast color of reactive print color

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Title
中国印染行业协会: "《印染行业染化料配制工(印花)操作指南》", 31 July 2007, 中国纺织出版社 *
李晓春: "《纺织品印花》", 31 August 2002, 中国纺织出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110004735A (en) * 2019-03-01 2019-07-12 安徽职业技术学院 A kind of ground colour dyestuff and the technique using ground colour dyestuff progress discharge printing
CN110965366A (en) * 2019-12-24 2020-04-07 华纺股份有限公司 Sodium sulfite anti-printing paste recycling method
CN110965366B (en) * 2019-12-24 2022-07-12 华纺股份有限公司 Sodium sulfite anti-printing paste recycling method

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