CN108165090A - Water-base gravure plastic film table print dumb light ink and preparation method thereof - Google Patents
Water-base gravure plastic film table print dumb light ink and preparation method thereof Download PDFInfo
- Publication number
- CN108165090A CN108165090A CN201711346458.2A CN201711346458A CN108165090A CN 108165090 A CN108165090 A CN 108165090A CN 201711346458 A CN201711346458 A CN 201711346458A CN 108165090 A CN108165090 A CN 108165090A
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- CN
- China
- Prior art keywords
- water
- dumb light
- plastic film
- base gravure
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-base gravure plastic film table print dumb light ink and preparation method thereof, are made of the raw material of following weight percentage：Pigment 10 15%, dumb light material 6 8%, combination binder 38 42%, solvent 32.5 27.8%, auxiliary material 6 8%, add up to 100%；Also disclose the preparation method of above-mentioned ink；The water-base gravure table print dumb light ink of the present invention has the characteristics that：Ink safety and environmental protection, VOC content are low；Good fluidity, colour saturation is high, and printability is good；Printed matter low gloss, levelability are good, form and aspect have dim stereovision, and attachment fastness is good, and unharmful substance remains after drying.Printed matter has resistance to blocking, resistance to migration, rub resistance and water resistance.Dumb light ink is printed suitable for the water-base gravure plastic film table of the market demand.
Description
Technical field
The present invention relates to a kind of ink more particularly to a kind of water-base gravure plastic film table print dumb light ink and its preparation sides
Method.
Background technology
Environmental protection and ink industry combine water-base gravure ink actual conditions jointly, according to《People's Republic of China's environment is protected
Protect professional standard HJ/T371-2007》Gravure water-based ink environmental protection and coherent detection mark have been put into effect in requirement in standard accordingly
Quasi- GB/T4103-2010《Water-base gravure plastic film table printing ink》, it is intended to provide water-base gravure plastic film table printing ink
Technology requirement, test method etc., specific function water-base gravure plastic film table print dumb light ink have a low gloss, printing it is dim
Mystique has very big market demand, while also within standard requirement.
HJ/T371-2007 standards are to the regulation of water-base gravure table printing ink：It is molten without halogenated hydrocarbon solvent, benzene and benzene class
Agent, ammonia and its compounds content≤3%, methanol content≤2%, VOC content≤30%, cadmium, lead, Cr VI, mercury total content≤
100mg/Kg。
The exploitation in terms of water-base gravure plastic film table prints dumb light ink, main problem include at present：First, in drying
In the balance of rate and VOC content, when present situation is mainly that VOC content is less than 30%, print speed printing speed is higher than 100m/s, and roars of laughter road lengthens
It still cannot thoroughly be dried to printed matter during 3 meters of the limit；Second is that be than before solvent type table print dumb light ink levelability it is worse,
When KPP draws a design, second printing plate (80% neutral depth version) all shifts out-of-flatness, the shallow halftone water-based ink transfer of third less than
Position causes water-base gravure plastic film table print dumb light ink that environmental requirement and printing effect is temporarily not achieved.
Invention content
An object of the present invention, in that a kind of edibility ink is provided, to solve the above problems.
To achieve these goals, the technical solution adopted by the present invention is such：
A kind of water-base gravure plastic film table prints dumb light ink, is made of the raw material of following weight percentage：
Pigment 10-15%
Dumb light material 6-8%
Combine binder 38-42%
Solvent 32.5-27.8%
Auxiliary agent 6-8%
Add up to 100%.
As preferred technical solution：The combination binder includes water-based acrylic resin HY505, acrylic acid ester emulsion
XM-600 and catalytic resin liquid DMP-30 be mixed to prepare from modified emulsion.
As preferred technical solution：The pigment is aqueous azo benzidine yellow 1138.
As preferred technical solution：The dumb light material is SM-6300.
As preferred technical solution：The solvent includes true solvent and false solvent.
As further preferred technical solution：The true solvent is deionized water and ethyl alcohol, and the vacation solvent is the third two
Alcohol methyl ether.
As preferred technical solution：The auxiliary agent include adhesive force agent, dispersant, dimethylaminoethanol, foam inhibitor and
Drying regulator.
The second object of the present invention is to provide the preparation sides of above-mentioned water-base gravure plastic film table print dumb light ink
Method, the technical solution used is will remove adhesive force agent, foam inhibitor, drying regulator and 9% deionized water in the ratio
Outside, it after remaining resin lotion and solvent stir evenly in advance, adds in pigment and dumb light material is further continued for stirring evenly；Blending ingredients are again
It is ground by grinder, treats that fineness reaches<Stop grinding after 20 μm, charging foam inhibitor, adhesive force after then adding in
It is stirred for uniformly after agent and the remaining deionized water for being used to clean grinder, the last adjusting stage determines ink pH, adds in
Drying regulator makes viscosity reach painting 4#20-28 seconds/25 DEG C of cup, pH value is finally filtered packaging, i.e., between 8.0-9.0
.
Pigment of the present invention requirement colorability is strong, is aided with a certain amount of dumb light filler, and form and aspect are deep during shallow reticulated printing, simultaneously
There is dim mystique again.It is required that the excellent pigment of alkali resistance and filler have in water-base gravure plastic film table prints dumb light ink
Good dispersibility and machinability.Preferably using aqueous azo benzidine yellow 1138 in the present invention, institute's accounting in water-based ink
Example is 10-15%, and it is SM-6300, dumb light filler proportion 6-8% to select dumb light material.
Binder of the present invention is used based on resin aqueous emulsion, preferably aqueous the third of Jinan Hao Ming Chemical Co., Ltd.s offer
The lotion that olefin(e) acid resin HY505 dissolvings form, feature have for azo pigments good dispersion, and suds are good, outstanding water resistant
Property and film forming.The acrylic acid ester emulsion XM-600 provided by Dongguan City Xin Mao Chemical Co., Ltd.s is provided, adds in catalysis
Resin liquid DMP-30, according to mass ratio XM-600：DMP-30=95：5 ratio is carried out with 50 ± 5 DEG C and 1200r/min rotating speeds
Emulsification mixing, this strong adhesive force on PE, PP film from modified resin lotion, rate of drying is fast, can significantly improve ink
Rate of drying, in addition its soft texture, is adjusted ink overall viscosity.The ink that the cooperation of this various kinds of resin forms, water have it
There are preferable solubility, adjustable glossiness, suitable for the production of dumb light ink.The combined type binder proportion is 38-
42%.
The true solvent of the present invention predominantly makes deionized water by oneself, and two kinds of solvents of ethyl alcohol select a small amount of false solvent propylene glycol methyl ether
Adjust levelability.True solvent selects three kinds of ratios to adjust rate of drying, and wherein quick-drying ratio is：Deionized water：Ethyl alcohol=5:5,
In do ratio be：Deionized water：Ethyl alcohol=6:4, slow curing ratio is：Deionized water：Ethyl alcohol=7.5:2.5.The true solvent of the mixing
Proportion is 30-35%, and false solvent ratios are 2%.
It is adhesive promoter present invention preferably employs gum dammar, aqueous dispersion BOK-033 is preferably selected, with diformazan
Ethylaminoethanol DMAE is as PH stabilizer, then is aided with a small amount of waterborne organic silicon foam inhibitor DOW CORNING DC-65, according to testing result,
It is preferred that quick dry agent TS2035 or drying retardant M30 is selected suitably to be adjusted as drying regulator.Selected auxiliary agent proportion
For 5-6%.
Compared with prior art, the advantage of the invention is that：The water-base gravure table print dumb light ink of the present invention has following
Feature：Ink safety and environmental protection, VOC content are low；Good fluidity, colour saturation is high, and printability is good；Printed matter low gloss, stream
Levelling is good, form and aspect have dim stereovision, and attachment fastness is good, and unharmful substance remains after drying.Printed matter have resistance to blocking,
Resistance to migration, rub resistance and water resistance.Dumb light ink is printed suitable for the water-base gravure plastic film table of the market demand.
Specific embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1-3
Component and ratio as shown in Table 1 is respectively adopted
Preparation method is：Adhesive force agent, foam inhibitor, drying regulator and 9% deionization will be removed in the ratio
Outside water, after remaining resin lotion and solvent stir evenly in advance, add in pigment and dumb light material is further continued for stirring evenly；Blending ingredients
It is ground again by grinder, treats that fineness reaches<Stop grinding after 20 μm, charging foam inhibitor, attachment after then adding in
It is stirred for uniformly after power agent and the remaining deionized water for being used to clean grinder, the last adjusting stage determines ink pH, adds
Enter drying regulator, viscosity is made to reach painting 4#20-28 seconds/25 DEG C of cup, pH value is finally filtered packaging between 8.0-9.0,
To obtain the final product.
Print request：Print speed printing speed：150-240 ms/min；
Intaglio plate depth：30-45 microns；
Drying temperature：45-55℃；
Print viscosity：11-15 seconds/25 DEG C/thin-walled 3# examines grace cup.
The component and its ratio of the ink of 1 embodiment 1-3 of table
Wherein, in table 1 it is according to mass ratio XM-600 " from modified resin lotion "：DMP-30=95：5 ratio is with 50
± 5 DEG C carry out what emulsification was mixed to get with 1200r/min rotating speeds.
Embodiment 4
Embodiment 1-3 resulting products are subjected to Indexs measure respectively, the results are shown in Table 2：
The Indexs measure result of each criterion and the product of the present invention.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of water-base gravure plastic film table prints dumb light ink, it is characterised in that：It is made of the raw material of following weight percentage：
Pigment 10-15%
Dumb light material 6-8%
Combine binder 38-42%
Solvent 32.5-27.8%
Auxiliary agent 6-8%
Add up to 100%.
2. water-base gravure plastic film table according to claim 1 prints dumb light ink, it is characterised in that：The combination connection
Material includes water-based acrylic resin HY505, acrylic acid ester emulsion XM-600 and changes certainly with what catalytic resin liquid DMP-30 was mixed to prepare
Property lotion.
3. water-base gravure plastic film table according to claim 1 prints dumb light ink, it is characterised in that：The pigment is water
Property azo benzidine yellow 1138.
4. water-base gravure plastic film table according to claim 1 prints dumb light ink, it is characterised in that：The dumb light material is
SM-6300。
5. water-base gravure plastic film table according to claim 1 prints dumb light ink, it is characterised in that：The solvent includes
True solvent and false solvent.
6. water-base gravure plastic film table according to claim 5 prints dumb light ink, it is characterised in that：The true solvent is
Deionized water and ethyl alcohol, the vacation solvent is propylene glycol monomethyl ether.
7. water-base gravure plastic film table according to claim 1 prints dumb light ink, it is characterised in that：The auxiliary agent includes
Adhesive force agent, dispersant, dimethylaminoethanol, foam inhibitor and drying regulator.
8. the preparation method of the water-base gravure plastic film table print dumb light ink of claim 1 to 7 any one, feature exist
In：By in the ratio in addition to adhesive force agent, foam inhibitor, drying regulator and 9% deionized water, remaining resin lotion and molten
After agent stirs evenly in advance, add in pigment and dumb light material is further continued for stirring evenly；Blending ingredients are ground again by grinder
Mill, treats that fineness reaches<Stop grinding after 20 μm, charging foam inhibitor after then adding in, adhesive force agent and remaining for cleaning
It is stirred for after the deionized water of grinder uniformly, the last adjusting stage determines ink pH, adds in drying regulator, reaches viscosity
To painting 4#Cup 20-28 second/25 DEG C, pH value between 8.0-9.0, be finally filtered pack to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711346458.2A CN108165090A (en) | 2017-12-15 | 2017-12-15 | Water-base gravure plastic film table print dumb light ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711346458.2A CN108165090A (en) | 2017-12-15 | 2017-12-15 | Water-base gravure plastic film table print dumb light ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108165090A true CN108165090A (en) | 2018-06-15 |
Family
ID=62522211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711346458.2A Pending CN108165090A (en) | 2017-12-15 | 2017-12-15 | Water-base gravure plastic film table print dumb light ink and preparation method thereof |
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| CN (1) | CN108165090A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111789A (en) * | 2018-09-03 | 2019-01-01 | 厦门欧化实业有限公司 | A kind of no benzene exempts to handle dumb light base gravure ink and preparation method thereof |
| CN113402924A (en) * | 2021-06-23 | 2021-09-17 | 亚化(福建)油墨科技有限公司 | Energy-saving environment-friendly water-based gravure printing ink formula and preparation process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002038065A (en) * | 2000-07-25 | 2002-02-06 | Printing Bureau Ministry Of Finance | Resin composition for intaglio printing ink, ink composition made by using it and printed matter obtained therefrom |
| CN103756410A (en) * | 2014-01-15 | 2014-04-30 | 东莞市宏达聚氨酯有限公司 | Water-based ink for gravure of PE plastic thin film and preparation method thereof |
| CN104263293A (en) * | 2014-09-19 | 2015-01-07 | 华烁科技股份有限公司 | Low-fluidity adhesive for flex-rigid printed circuit board, adhesive film and preparation method of low-fluidity adhesive |
| CN106752355A (en) * | 2015-11-25 | 2017-05-31 | 重庆伟恒包装有限公司 | The preparation method of ink used for plastic coating |
-
2017
- 2017-12-15 CN CN201711346458.2A patent/CN108165090A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002038065A (en) * | 2000-07-25 | 2002-02-06 | Printing Bureau Ministry Of Finance | Resin composition for intaglio printing ink, ink composition made by using it and printed matter obtained therefrom |
| CN103756410A (en) * | 2014-01-15 | 2014-04-30 | 东莞市宏达聚氨酯有限公司 | Water-based ink for gravure of PE plastic thin film and preparation method thereof |
| CN104263293A (en) * | 2014-09-19 | 2015-01-07 | 华烁科技股份有限公司 | Low-fluidity adhesive for flex-rigid printed circuit board, adhesive film and preparation method of low-fluidity adhesive |
| CN106752355A (en) * | 2015-11-25 | 2017-05-31 | 重庆伟恒包装有限公司 | The preparation method of ink used for plastic coating |
Non-Patent Citations (2)
| Title |
|---|
| 伍秋涛: "《实用塑料凹版印刷技术》", 30 June 2007 * |
| 江谷等: "《软包装印刷及后加工技术》", 30 September 2007 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109111789A (en) * | 2018-09-03 | 2019-01-01 | 厦门欧化实业有限公司 | A kind of no benzene exempts to handle dumb light base gravure ink and preparation method thereof |
| CN109111789B (en) * | 2018-09-03 | 2021-08-17 | 厦门欧化实业有限公司 | Benzene-free treatment-free matte gravure ink and preparation method thereof |
| CN113402924A (en) * | 2021-06-23 | 2021-09-17 | 亚化(福建)油墨科技有限公司 | Energy-saving environment-friendly water-based gravure printing ink formula and preparation process |
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Application publication date: 20180615 |
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| RJ01 | Rejection of invention patent application after publication |